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By G. A. Kosick, C. A. Harris

"Metallurgy at the Polaris Mine is approaching an impasse, with lead and zinc concentrate grades and recoveries approaching their theoretical maximums. In an effort to increase productivity, plant throughput and operating material costs became a major focus of milling personnel.one method of increasing plant throughput was to minimize flotation circuit upsets by; standardizing operating strategy, decreasing control action response time of operators, increasing training of operators, and providing a more available decision support system for operators.To achieve these goals, Polaris personnel decided to utilize expert system technology to develop a real-time process controller for the flotation circuit which would be capable of justifying its actions to operating personnel.This paper describes the procedures followed in constructing the first process controller in the mineral industry which is based on the principles of Artificial Intelligence.IntroductionThe Polaris Concentrator was constructed in 1980 on a barge in Trois Rivieres, Quebec and towed to its present location on Little Cornwallis Island, North West Territories, about 1450 kilometers from the North Pole. The plant presently treats about 2,800 MTPD of new feed with average feed grades of 3% Pb, 13% Zn and 5% Fe. Current production averages 36,000 tonnes of lead concentrate and 220,000 tonnes of zinc concentrate annually.In an effort to increase the efficiency of the concentrator, the decision was made to implement an innovative control system on the flotation circuit. This system would embody and utilize heuristics ""rules-of-thumb"" gained from operators to make on-line process decisions. It would also justify these decisions on a demand basis."

Jan 1, 1988

By James D. Bittner

Separation Technologies, LLC (ST) has developed a processing system based on triboelectric charging and electrostatic separation that provides the mineral processing industry a means to beneficiate fine materials with an entirely dry technology. The environmentally friendly process can eliminate wet processing and required drying of the final material. The process requires little if any pre-treatment of the material other than grinding and operates at high capacity ? up to 45 tonnes per hour by a compact machine. Energy consumption is low, approximately 1 kWh/tonnes of material processed. Since the only potential emission of the process is dust, permitting is typically relatively easy. In contrast to the other available electrostatic separation processes that are typically limited to particles greater than 75 µm in size, the ST belt separator is ideally suited for separation of very fine (<1 µm) to moderately coarse (500 µm) materials with very high throughputs. The triboelectric particle charging is effective for a wide range of materials and only requires particle ? particle contact. The small gap, high electric field, counter current flow, vigorous particle-particle agitation and self-cleaning action of the belt on the electrodes are the critical features of the ST separator. The high efficiency multi-stage separation through charging / recharging and internal recycle results in far superior separations and is effective on fine materials that cannot be separated at all by the conventional electrostatic techniques. Since 1995, this triboelectric process has been extensively used for the beneficiation of coal fly ash with eighteen separators in place and over 100 machine-years of operation at locations in the US and Europe. The technology has been also successfully applied to the beneficiation of a variety of minerals including calcium carbonates, talc, and potash.

Nov 1, 2011

By Simon C. Dominy, Alwyn E. Annels, Paul Wheeler, Suzanne P. Barr, G. Simon Camm

Abstract-Narrow veins are an important world-wide source of silver, tin, uranium and particularly gold. To potential financiers, this style of mineralization is viewed as high risk because of the often relatively small resource involved and high cost of estimation. In many cases diamond core drilling will not enable resource estimation beyond the inferred and indicated categories. Exploratory underground development is required to define measured resources. The definition of geological and grade continuity are major factors in narrow vein assessment. A measured resource must be based on strong geological and grade continuities. Narrow veins, generally less than 3 m wide, are complex geological phenomena, which commonly display unpredictable geometry and grade distribution. Variations in structural continuity, dip, strike, width, mineralogy and specific gravity are common. Veins may be composite, with ore-grade mineralization restricted to a specific structural domain. Branches, intersections and braided zones are common features. Potentially high-grade zones are often localized within ore shoots, which are surrounded by barren/low-grade regions. Resources must be determined as closely as possible to reality and reflect the distribution of the commodity in the rock. Estimation has three main requirements: (1) geological study to determine orebody nature; (2) estimation of tonnage and grade, and (3) the presentation of this information using a classification that is clear, unambiguous and bankable. Estimation methods employed are either classical or geostatistical; however, classical methods are often used because of the difficulties in applying geostatistics. Grades generally show a strong positively skewed distribution testifying the presence of high-grade values. Problems exist in the applicability of cutting outlier values risking over- or underestimation of grade. It is generally believed that where resource estimates are in error, poor geological control is usually the cause. Overestimation can lead to the closure of a mine through lost revenue and capital. An understated estimate can result in an opportunity missed for profit and/or greater economies of scale. Definition of reserves involves the consideration of economic and engineering data, to decide which part of the resource is economically mineable. Geology plays a similarly important role at this stage in the assessment of likely mining method, dilution, recovery etc. Throughout resource/reserve estimation, it is crucial that the amount and quality of the data and the geologist’s experience are relevant. The impact of geological understanding on estimation is often undervalued or assumed to be of lesser importance than finding grades and tonnages. This paper discusses the geology of narrow vein deposits and the importance of geology in their evaluation.

Jan 1, 1997

By Gwenaële Petit, Ulan Massimkhanov, Gilles Joubert

For its Zuuvch Ovoo uranium deposit in Mongolia, Badrakh Energy (partly owned by Orano Mining) is working on the prefeasibility study for exploitation by ISR (in situ recovery). As part of this project, Orano built a 2-cell (each cell is constituted of one producer well located in the center and surrounded by six injection wells in an hexagonal pattern) and a processing pilot plant that will be used to demonstrate the operability and economic viability of an ISR process. Another main objective of this pilot trial is to demonstrate the ability of Orano’s modeling tools to predict the ore behavior under given leaching conditions. To model uranium production by ISR, Orano uses HYTEC, a reactive transport computational software, which was adapted for its existing operation in Kazakhstan (Katco) to predict uranium recovery and reagent usage based on operating conditions. In order to perform similar simulations for this new deposit, Orano engaged in a comprehensive program including ore sampling, detailed characterization, and metallurgical testwork. The mineralogical conclusions were used to prepare a simplified geochemistry for the ore, in particular carbonate and reactive clay grades, uranium mineralization and penalizing elements such as pyrite. Then, bottle roll leach tests were used to characterize dissolution kinetics for smectite clays. Eventually, column leach test results such as pH, free acid, and uranium recovery were modeled on HYTEC to improve the fit of some of the dissolution kinetic parameters. Parameters fitted using metallurgical test work results will now be used as inputs for predictive model at the pilot scale, in order to anticipate operational results and help with operating decisions for production ramp up.

Jan 1, 2020

The importance of understanding the behaviour of cemented paste backfill (CPB) within the framework of the effective stress concept is highlighted in this paper. Only through an understanding built on this concept can problems such as barricade loads, the rate of consolidation and arching, be fully understood. The critical importance of the development of stiffness during the hydration process, and its impact on factors such as barricade loads, is used to illustrate why conventional approaches that implicitly ignore the effective stress principle are incapable of capturing the essential components of CPB behaviour.

May 1, 2007

By W. R. Smith

Introduction No commercial deposits of silica sand are known to occur in British Columbia, so all requirements for foundry and other uses must be imported. During the war, nearly 5,000 tons per year were used, all originating in Illinois and delivered to local consumers for about $12.00 per ton. Present requirements are somewhat less, but the cost is still of the same order. The relatively high cost of silica sand in British Columbia is not only a serious item for present consumers, but might be a deterrent to the establishment of a glass industry, should this be contemplated at any time. The present investigation was undertaken in an attempt to provide a cheaper source of silica sand within the Province. In 1936, a large number of beach and bank sand deposits in the lower coastal region of British Columbia were examined by the British Columbia Department of Mines, and samples were analyzed chemically and mineralogically. The deposits over the whole area proved remarkably uniform in mineral composition, consisting essentially of quartz, feldspar, ferromagnesian minerals, rock fragments, and various accessory minerals, and differing only in the relative proportions of the various constituents. In no case did the quartz content of any sand exceed about 40 percent and the average was of the order of 20 to 30 percent.

Jan 1, 1947

By J. I. Gazzarri

A model of solid oxide fuel cell AC impedance behaviour has been developed and is used to simulate the frequency response of a single cell with and without mechanical damage. The results indicate that the presence of mechanically induced damage within the components of a solid oxide fuel cell can be detected by comparing the frequency response of the undamaged cell with that of a cell in which in-plane cracking or delamination has occurred. The presence of such defects manifests itself as a new semicircle in the Nyquist impedance diagram of the full cell. A parametric study reveals the resolution capabilities of the method in terms of the geometrical characteristics of the defects.

Jan 1, 2005

By Mohammad Noaparast, Babak Fotoohi

"Due to certain advantages in (semi-)Autogenous-Ball mill circuits in most of the high-throughput ore grinding units of mineral processing plants, much attention is paid to optimize the mill performance. Despite the maturity of the grinding mill mechanical design, there had been made less attention to the efficiency of the grinding media in the past. In this research, the possibility of establishing a relationship between liner/lifter wear rate and variations in the composition of the iron ore (from Chadormalu mine) is investigated.Measurements and determination of liner/lifter wear rates and patterns concluded in recognition of critical liner segments exposed to much abrasion during the ore grinding. After metallurgical analysis of liner materials and correlation of wear rate with the ore composition, the homogeneity in the metallurgical microstructure of the alloyed steel (such as the uniform distribution and amounts of the constituent phases) was determined as the most influential factor in the response of the liner/lifter to the variations in the ore composition. Magnetite with greater abrasion index than hematite, in finer particles, is responsible for additional abrasion of liners; hematite with greater work index exists in the mill with larger particle sizes, thus it could produce wear on liner parts with less tolerance to impact as is the situation for martensitic steels.INTRODUCTIONThe mineralization in Chadormalu plutonic iron ore deposit is consisted of mostly magnetite, hematite, martite, apatite, quartz and carbonates. The average composition of the ore is presented in Table 1. In the processing circuit, the gyratory crushed ore reduced to 30 cm would finally be the feed to three similar 32’ semi-autogenous mills in parallel processing lines. The pulp in the mill would have the characteristics mentioned in Table 2. The quality of the mill output has its direct effect on the downstream processes either physically or chemically (e.g. in cycloning or flotation respectively). In order to take advantage of optimum performance for these circuits, a close control of the ore grinding conditions is necessary; because any shortages in throughput, liner/lifter damage or changes in ore composition could bring the unexpected casualties. In this work, it has been attempted to find (possibly) a reasonable relationship between variations in ore characteristics together with liner quality and the amount of wear rate in different liner/lifter segments of a semi-autigenous mill. Liner/lifter segments are supplied by three different domestic steel making companies. The alloy structure of the liners/lifters is made up of pearlitic chromoly steel."

Jan 1, 2005

By J. Miettunen

"The lining of a grinding mill has an important role in creating the conditions for the grinding process. The main purpose of the lining is to transfer the energy taken by the mill motor to the contents of a mill. The power draw curve of the mill, if measured with sufficiently short intervals, describes how well the lining works in lifting and mixing the material to be ground.The power draw curve can also be used for determining the volumetric filling of a mill. This new measuring technique was developed at the Pyhasalmi concentrator in 1989-90. The measuring device with its PC-connections offers an excellent tool for controlling volumetric mill filling, for maximizing throughput and for research purpose (e.g. process studies, mill linings design).The paper describes the new method and the results achieved at Outokumpu's concentrators.INTRODUCTIONVarious methods have been developed for measuring mill load; weighing, noise, etc. Weighing is one of the most reliable methods but installing the sensor to existing mills is often difficult. Besides the load measurement does not indicate the volumetric filling if the specific gravity of the mill feed fluctuates. Noise measurement has often failed with its sensitivity to various disturbance sources.As known, the power draw measurement is one of the most accurate measurements in grinding circuits and therefore it has been utilized in sophisticated control, e.g. in power peak seeking algorithms for maintaining maximum grinding efficiency.About 10 years ago power oscillation measurement was developed at Pyhasalmi concentrator. In this method the amplitude of the oscillation caused by the lifters was measured. The oscillation amplitude and the mill filling has quite a good correlation and together with the power draw measurement it could be used for maximizing mill throughput (Koivistoinen and Miettunen, 1989). The main difficulties in this method were that the dependence between mill filling and the amplitude is unlinear and that the dependence also is individual for each mill.The method developed during 1989-90 is also based on the power oscillation but on its phase shift. In principle level of the material in a mill is measured. The method has been successfully used for maximizing throughput at Pyhasalmi and Enonkoski concentrators and at Harjavalta slag concentrator."

Jan 1, 1991

By Simon C. Dominy, Alwyn E. Annels, Paul Wheeler, Suzanne P. Barr, G. Simon Camm

Narrow veins are an important world-wide source of silver, tin, uranium and particularly gold. To potential ?nanciers, this style of mineralization is viewed as high risk because of the often relatively small resource involved and high cost of estimation. In many cases diamond core drilling will not enable resource estimation beyond the inferred and indicated categories. Exploratory under-ground development is required to de?ne measured resources. The de?nition of geological and grade continuity are major factors in narrow vein assessment. A measured resource must be based on strong geological and grade continuities. Narrow veins, generally less than 3 m wide, are complex geological phenomena, which commonly display unpredictable geometry and grade distribution. Variations in structural continuity, dip, strike, width, mineralogy and speci?c gravity are common. Veins may be composite, with ore-grade mineralization restricted to a speci?c structural domain. Branches, intersections and braided zones are common features. Potentially high-grade zones are often localized within ore shoots, which are surrounded by barren/low-grade regions. Resources must be determined as closely as possible to reality and re?ect the distribution of the commodity in the rock. Estimation has three main requirements: (1) geological study to determine orebody nature;(2) estimation of tonnage and grade, and (3) the presentation of this information using a classi?cation that is clear, unambiguous and bankable. Estimation methods employed are either classical or geostatistical; however, classical methods are often used because of the dif?culties in applying geo-statistics. Grades generally show a strong positively skewed distribution testifying the presence of high-grade values. Problems exist in the applicability of cutting outlier values risking over- or under-estimation of grade. It is generally believed that where resource estimates are in error, poor geological control is usually the cause. Overestimation can lead to the closure of a mine through lost revenue and capital. An understated estimate can result in an opportunity missed for pro?t and/or greater economies of scale. De?nition of reserves involves the consideration of economic and engineering data, to decide which part of the resource is economically mineable. Geology plays a similarly important role at this stage in the assessment of likely mining method, dilution, recovery etc. Throughout resource/reserve estimation, it is crucial that the amount and quality of the data and the geologist’s experience are relevant. The impact of geological understanding on estimation is often undervalued or assumed to be of lesser importance than ?nding grades and tonnages. This paper discusses the geology of narrow vein deposits and the importance of geology in their evaluation.

Jan 1, 1997

By F. E. Lathe

The method of feeding blast-furnaces to be described below is simply the application of well-known principles, and an attempt to carry that application to its logical conclusion. It does not involve radical changes in equipment, nor does it require unusual skill on the part of the furnaceman. In fact, much of its value lies in its very simplicity. Before giving details of the method it will be well to consider briefly the conditions under which it was used at the Nickelton plant of the British America Nickel Corporation, in the Sudbury district, before that plant closed down. The Sudbury nickel ore consists chiefly of pentlandite, chalcopyrite and pyrrhotite in a gangue of norite or greenstone. The proportions of sulphide and gangue vary widely in different mines, the former constituting about 45 per cent of the total in the British America sorted ore. The gangue is fairly uniform in analysis, carrying about 55 per cent Si02, 18 per cent A120 3, 13 per cent FeO and smaller quantities of CaO, MgO, Na20 and K20. The ore has been frequently described as refractory, a word which seems suitable when one considers the many unsuccessful attempts to smelt it pyritically, as well as the high percentage of coke normally used at all the plants in the district.

Jan 1, 1925

By Peter Mitschke, Friedrich Rosenstock, Heinrich Meiler

"The development of the Centrifugal Mill jointly by Chamber of Mines (Johannesburg) and LURGI GMBH (Frankfurt) had been described by L. Kitschen e.al. during the 14th IMPC at Toronto in October 1982. Further investigations, using a 55 kW semi-industrial mill, installed at LURGI's Research Laboratories, were concentrated on efficiency and wear in grinding.The test results showed, that efficiency increases when increasing the ball load between 60 and 80 % by volume. Furthermore, the efficiency is increased by speeding up the mill, thus increasing the centrifugal force to up to 14 times the force of gravity. Applying these findings to grinding of a Canadian iron ore spiral concentrate, a saving in grinding power of 30 % was experienced, when comparing with ordinary wet ball milling.Investigations of several shapes of the grinding chamber cross section and linings and several types of materials showed, that no increase of liner or ball wear will occur compared to conventional ball mills when choosing suitable lining patterns. 1. DEVELOPMENT OF THE CENTRIPUGAL MILLThe centrifugal mill was developed with the aim of finding a grinding unit that can operate at a higher power concentration than the conventional tumbling mills.LURGI felt the necessity for such a mill in connection with a hydrometallurgical process developed at the beginning of the seventies, which incorporated an activating grinding step as one of the essential process features. At that time, the Chamber of Mines in Johannesburg was investigating possibilities of underground wet grinding and preconcentration of gold ores aiming at a decrease of mining costs by reducing the quantities, especially for mines operating at depths up to 3600 m, by changing over from rope hoisting to hydraulic transportation systems. After the Chamber of Mines had initiated the development work on its own, in 1974 a cooperation between the two organisations was started."

Jan 1, 1985

By Alain Langlais, Caroline Boudrias Chapleau, Claude Bazin, Ahmed Bouajila

"Slurry «viscosity» has been recognised for several decades as a variable that significantly influences the operation of grinding mills. This paper describes an instrument that can be used in a laboratory or a plant to measure and monitor the flow properties of mineral slurries. Laboratory results obtained for two different ore samples are consistent with results obtained during a full scale trial. The results provide a basis for analysing the effect of the solids concentration and particle size distribution on the slurry flow properties. Grinding tests were also conducted in an attempt to link the grinding efficiency to the rheological properties of mineral slurries.INTRODUCTIONThe flow properties, or incorrectly called «viscosity», of a slurry influence the operation of mineral processing devices. Work has been conducted for instance to assess the effect of this variable on the operation of hydrocyclones (Kawatra et al. 1996; Klimpel, 1982a) and dense media separators for coal (Napier-Munn, 1996). However, most of the research effort has been oriented toward the grinding processes which is still the most energy demanding operation for ore dressing (Fuerstenau et al., 1995).Results of investigations of the influence of slurry flow properties upon grinding performances are presented regularly in the literature since 1950. In the 70's, most of the research work was conducted with the aim of using slurry flow properties for the control of grinding mill and to analyze the effect of that variable upon the population balance model breakage and rate functions (Austin et al., 1984; Hemmings et Boyes, 1977). In the 80's, most of the litterature dealing with slurry rheology was devoted to the use of viscosity modifiers to adjust the slurry flow properties, allowing an increase of grinding mill throughputs (Klimpel, 1982b; Fuerstenau et al., 1985). Although laboratory and pilot plant results show the benefits of adding these modifiers to the slurry, few plants have published results concerning the advantages of such addition (Fuerstenau et al., 1985). It is felt that the use of these modifiers introduce operating difficulties with the concentration circuits, especially flotation (Kawatra et Eisele, 1988)."

Jan 1, 2003

By F. Flynn, P. Downey, G. Ritson

"Bell Creek Mill which has been in continuous operation since 1987 has undergone numerous operational changes in the past three years. The addition of over 2. 5 million tons of resource at over 13 git from Hoyle Pond Mine precipitated an expansion program for the Bell Creek Mill. This paper discusses the major changes that have occurred over the past two years to increase throughput and efficiencies. In addition, the refractory ore treatment options are also discussed.IntroductionThe Bell Creek Mill is located in the Timmins Goldcamp approximately 8km NE of porcupine Ontario. (Fig I.)The mill was originally constructed by Camamax in 1987 to treat the Bell Creek ore at a design throughput of 350tpd. The flowsheet (Fig 2.) consisted of two stage crushing, grinding, thickening, leach and drum filtration with gold recovery by Merrill Crowe.As ore depleted at Bell Creek, the Mill was purchased by Falconbridge to process ore from their Hoyle Pond property. Kinross purchased the Hoyle Pond property and Bell Creek Mill from Falconbridge in 1992.The successful exploration program at Hoyle Pond has led to several expansions and process design changes, with further changes planned over the next twelve months.In 1994, the mine produced 61,865 oz. of gold at an average cost of 197US$ per oz. In 1995 production was 91, 611 oz. at a cost of 187US$ per oz. Projecting the nine months ended September 30, production for 1996 will be 155,000 oz. at a cost of 165US$ per oz.In early 1997, the CIP expansion will be complete, with a target of 175,000 oz. at a cost of 176US$ per oz for 1997. The mill throughput will have increased from 400tpd to 1500tpd between 1994 and 1997.The changes to Bell Creek since 1994 have been numerous with very little of the existing equipment still in operation. The total cost of the expansion to date is 15 million C$. This paper discusses the major projects carried out during in this time. The focus will be to highlight the justification of each project, the design and engineering, some of the initial start-up problems and solutions.Figure 3 shows a plan of the existing mill facility together with the various additions that were carried out."

Jan 1, 1997

By M. G. Lipsett

One challenge in applying information technologies in Mining is building a business case. In Mine Maintenance, there is a complex flow of information that contributes to making informed business decisions. By understanding those information relationships and the cost of wrong decisions, analysts can estimate the value of information flow. Developers can then ensure that systems deliver key information in an accurate and timely way. In this paper, general maintenance decision-making is discussed, with examples of how model-based analysis can improve the information delivered to decision makers.

May 1, 2001

By A. R. Barnes, N. O. Lotter

Recoverable economic copper sulphide minerals such as chalcopyrite, bornite, chalcocite and covellite often occur together in varying proportions in the major copper-bearing ores, and have individual flotation requirements and characteristics. Pyrite also occurs in these ores to varying extents as the sulphide gangue, and is problematic because of its natural tendency to float quickly and easily. In a bulk sulphide float, selectivity against pyrite is desirable, particularly if it does not host other paymetals such as gold or silver. At the same time it is a requirement to float all of the copper sulphides despite their electrochemical differences. The electrochemistry and semiconductor properties of these minerals are reviewed, together with implications for flotation with and without collector addition. Mixed collector systems for the improved flotation of these sulphides are proposed as a solution. The use of xanthate and dithiophosphate in the collector suite allows the co-existence of dixanthogen and free dithiophosphate radical because the latter has a higher redox potential requirement than xanthate to oxidise to the dithiolate. Because some of these minerals require dixanthogen, and others, free thiolate, to generate surface hydrophobicity, a bulk flotation of all the species becomes possible in the overlapping area of Eh and pH between the two dithiolate equilibrium lines on the Pourbaix diagram. The arsenic-signature copper minerals are added to the study, since many copper operations encounter arsenic as a penalty element in the saleable concentrate. It is shown that the addition of arsenic to the copper and iron sulphides alters the semiconductor and electrochemistry properties, and in turn, its flotation characteristics. The degree of mineral association and liberation between these minerals can be a complicating factor due to textural associations, and should also be considered in the process as a next step.

Jan 1, 2016

By P. Srinivasan

Corrosion is a major operational problem in amine-treating plants causing significant expenditures each year, Corrosion may become more severe when the amine plants contain process contaminants ? namely heat-stable salts. The heat-stable salts enter the plants with feed-gas streams and makeup-solution, and/or are produced within the plants by reactions of alkanolamine and available carboxylic-acid anions, This work investigated interaction corrosion effects that may exist in amine-treating plants containing a mixture of heat-stable salts, The investigation was experimentally carried out in a 5 kmol/m3 monoethanolamine (MEA) solution containing 0,20 mol/mol carbon dioxide (CO2) loading at 80°C under atmospheric pressure using carbon steel 1018, Six heat-stable salts, including formate, oxalate, bicine, acetate, thiosulfate and chloride, were tested with a series of salt combinations, Potentiodynamic Polarization, Tafel Extrapolation, and Cyclic Polarization were used for revealing corrosion behavior, determining corrosion rate, and examining the pitting tendency, respectively, Results show that thiosulfate induces the most corrosive environment when present either individually or in the form of salt mixtures.

Jan 1, 2005

By S. Banisi, M. Poorkani

The Sarcheshmeh copper deposit contains 1 billion tones of ore averaging 0.7% copper and 0.025% molybdenum. It is located southeast of Iran and currently processes 41,000t/d. Molybdenite as a by-product is recovered in two separate stages. First, a bulk coppermolybdenum concentrate is produced and in the second stage these two are separated. The recovery of molybdenite in the first and second stages is 65% and 85-90%, respectively. The yearly production of molybdenite concentrate varies between 3500 and 4000 t. Sodium sulphide is used as the depressant of the copper and iron bearing minerals which due to a rather high consumption (17.7 kg/t) constitutes one of the major cost items of the plant (i.e., 58% of total reagents cost). A detailed laboratory scale study showed that replacing air with nitrogen could reduce the consumption of sodium sulphide (i.e., H2S or mineral origin). Nitrogen for the plant was supplied from an oxygen plant used for the smelter through a 1400 m long pipeline. The existence of the oxygen plant at the Sarcheshmeh complex was a key factor in the implementation and success of this project. After using nitrogen in the plant for a period of twenty one months, the consumption of sodium sulphide was reduced from 17.7 to 14.2 kg/t at constant metallurgy. The reduction was lower than expected which was mainly due to the type of sodium sulphide used and the lack of any automatic instrument to control the depressant (sodium sulphide) dosage. The latter in turn caused the operators to overuse sodium sulphide in order to reach and maintain the target metallurgy (i.e., higher molybdenite recovery along with lower copper content of the concentrate).

Jan 1, 2005

By Don Thompson

Canada’s oil sands are a controversial topic and virtually every newsmaker and layperson seems to have an opinion about this 179 billion barrel resource. The oil sands represent 97 per cent of Canada’s remaining oil reserves, but misinterpretation and misrepresentation of the facts are threatening development of a resource that generates significant employment and tax revenue for Canadians. Join Don Thompson, president of the Oil Sands Developers Group, as he dispels the top ten myths about Canada’s oil sands and presents an alternative perspective on an industry that can play a critical role in North America’s economic recovery.

Jan 1, 2010

By J. R. Levin, E. J. Schelter

"We present some of our recent efforts in the development of predictive, directed oxidation chemistry of cerium(III) complexes under non-aqueous conditions. The electrochemistry of cerium(III)- alkali metal heterobimetallic aryloxide complexes is reported and compared with cerium aryloxide complexes that are kinetically stabilized by hydrogen bonding cations that span between the complexed aryloxide ligands. Comparative electrochemical measurements reveal differences between the heterobimetallic complexes and the hydrogen-bonded complexes.INTRODUCTIONThe rare earth elements comprise the lanthanides, La–Lu, and the element yttrium (Aspinall, 2001). Rare earth ores such as monazite, LnPO4, and bastnäsite, LnFCO3, typically bear mixtures of light rare earths: La–Sm while monazite, LnPO4, contains mixtures of heavy rare earths (Eu–Lu) (Cotton, 2006). Pure rare earth elements typically are isolated using a liquid-liquid separations process.(Bautista, 1995) The hydrometallurgy of these elements is a difficult problem because the separation factors between neighboring rare earths, which are predicated on the small differences in the sizes of the trivalent ions, are quite small (Cox, 1992). The element cerium, with its 4f1 electronic configuration in the trivalent state, is unique among the rare earth elements due to a relatively accessible 4f0 electronic configuration. The accessibility of the 4f0 configuration underlies the chemistry of cerium(IV), the only rare earth ion with molecular chemistry in the tetravalent oxidation state (Cotton, 2006). Cerium is trivially separated from mixtures of light rare earths by making use of its unique oxidation chemistry. In an effort to extend separations chemistry by oxidation reactions to other rare earth elements such as terbium and praseodymium, the solution electrochemistry of well-defined cerium complexes is of interest."

Jan 1, 2012