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By M. R. Julien

"The geomechanical behavior of rocksalt shows very distinctive features. The response of this most ductile of all low porosity rocks is dominated by inelastic processes that are strongly time- and historydependent. These characteristics must be taken into account when analyzing underground openings. Different constitutive models have been proposed and used for this purpose, and this paper presents the general formulation and applications of one of these. The SUVIC model relies on a unified approach with internal state variables producing mixed hardening to represent the inelastic behavior, which lead to specific solutions for plasticity and creep. The model equations have been implemented into a finite element code to perform numerical analyses. Simulations results are presented to show that this model captures essential aspects of rocksalt behavior under simple and complex laboratory testing conditions. Simulations are also conducted to analyze the response of underground openings. INTRODUCTIONPredicting the response of man-made excavations in rocksalt can be quite a challenge as it requires a reliable constitutive model to represent the material behavior. This softest of all low porosity rocks shows a highly non-linear inelastic behavior, very sensitive to history and rate effects (e.g. Senseny et al., 1993; Cristescu & Hunsche, 1997; Julien, 1999; Wittdke, 2014). The many deformation (micro) mechanisms acting locally in rocksalt make the construction of appropriate constitutive equations quite complex. Nonetheless, there have been significant progresses made over the last two decades or so; many of these developments have been included in a series of specialized Conferences Proceedings (Ghoreychi et al., 1996; Aubertin & Hardy, 1998; Cristescu et al., 2002; Wallner et al., 2007; Bérest et al., 2012)."

Jan 1, 2015

By H. Wotruba, K. Neubert

Dual-energy X-ray transmission (DE-XRT) imaging is known from safety luggage inspections at airports. The use of DE-XRT technology for sorting applications in the primary raw materials industry has been the subject of numerous investigations. Beside other metal ores, X-ray transmission sorting is already used for the preconcentration of tungsten ore, gold ore and coal. The applicability of DE-XRT sorting is limited to ore types where differences in metal concentrations are measurable, based on an interpretation of X-ray images. Metal contents in particles occur in large varieties in terms of concentration, grain sizes, spatial distribution and mineralogy and therefore influence the X-ray absorption. As a result, each ore has to be tested individually for its suitability for DE-XRT sorting. The objective of current research at the Department of Mineral Processing (AMR) at RWTH Aachen University is to assess parameters influencing the detectability of rare earth oxides. Two approaches were followed: (1) Practical test work, based on artificial ore samples of defined compositions and (2) Computer-based simulation of absorption features of identical particle compositions. In total, more than 300 artificial samples of various compositions and metal grades were produced and X-ray images from DE-XRT sorting were analyzed. Results from the DE-XRT sensor were put into correlation with metal grades and particle sizes, to analyze influences and limits on the detectability of rare earth oxides. In addition, a new approach was tested in which the X-ray absorption of particles of various compositions was determined based on a Monte Carlo (MCNP) simulation. During the simulation, similar compositions, as used for the artificial samples, were tested and the X-ray absorption behavior during DE-XRT sorting was determined. A comparison of results from both approaches is used to assess the applicability of the MCNP-simulation for the prediction of the X-ray attenuation behavior during DE-XRT sorting.

Jan 1, 2016

By J G. Brady

This paper discusses the ceramic products used in the construction industry in Canada, as well as the main raw materials used in their manufacture. The products include the! following: (1) clay prorlucts -such as facing brick (glazed and unglazed), common brick, facing tile (glazed and un-glazed), terra cotta, load-bearing tile, non-load-bearing tile, structural clay floor tile, quarry tile, drain tile, sew-er pipe, conduits .and flue liners -which are made mainly from domes-tic common clays and shales and from domestic or imported stoneware clays and low-grade fire clays; (2) floor and wall tiles of the whiteware type, which are produced from ingredients such as kaolin, ball clay, feldspar, nepheline syenite, talc, pvro-phyllite and wollastonite; (3) glass products -the major ones being sheet glass, plate glass and mineral wool (glass wool, and rock or slag wool) -which are made from such materials as silica sand, soda ash, salt cake, feldsspar, nepheline syenite, dolomitic limestone, high-calcium limestone. borax and (for rock and slag wool) various rocks or slags;

Jan 1, 1963

By M. Al Mukhtar, D. Hoxha, X. Brunetaud, D. P. Do, C. Auvray, L. Michel

"Mechanical behavior of rock joints is often the key factor governing the response of complex structures constructed in fractured rock masses such as underground openings or of objects assembling various stones blocks such as historical building walls or damaged marble statues. This paper aims at developing a theoretical model to describe the behavior of fresh joints based on the description of their morphology. The main idea of the model is to establish a link between the effective contact surface of joints and the frictional coefficient. Beginning from a chosen level of joint surface description where a joint is considered as “smooth”, the model describes the added friction with respect to the increase of the contact surface of the joints and the distribution of stress in these contacts. The model developed initially for asperities with regular geometry is firstly compared with existing models and then applied on fresh artificial joints. For that, healthy artificial joints have been characterised using in one hand classical CNL shearing tests and in another hand the morphology of joints. The joints surfaces are digitized before testing using a high resolution laser scanner (Konica Minelota Vivid 910) allowing to obtain a precision up to 10µm. From these scanned surfaces the morphology of joints is characterised on the profiles running in the direction of shearing and a mean value of friction is calculated using the developed model. This calculated value is then compared with that obtained from CNL shearing test and a good approximation is notedINTRODUCTIONThe role of the mechanical behavior of rock joints on the overall response of fractured rock masses is well established in many fields of engineering activity going from the stability of underground constructions (Souley M, Hoxha D, Homand F 1999), rock slope stability (Einstein H.H. Veneziano D., Baecher GB., O’Reilly K.J, 1983, Jaeger 1971), various rehabilitation of masonry construction, damaged stone artworks restoration (Michel L., Do D.P, Coignard B, Hoxha, 2014) and so on. In the same time the characterisation of the behavior of joints and their modeling is nowadays a dynamic field of research or/and investigations and many alternative approaches have been proposed (Barton, N.R. and Choubey, V. 1977, Tatone, S.A. Bryan, Grasselli Giovanni 2010, William C E. 2007). While empirical relations of shear strength with various parameters of the joint morphology are the most used in practice because of their simplicity (Barton. and Choubey, 1977, Barton 1973, Bandis S., Lumsden A. C. and Barton N. R. 1983) many other models of joint strength are developed based on mechanistic considerations (Haberfield CM, Johnston IW. 1994), multiscale approaches (Yang Z.Y., Di C.C., Yen K.C. 2001, Fardin N., O. Stephansson, Lanru Jing 2001) or micromechanical ones (A. Serrano, C. Olalla, R.A. Galindo 2014) to mention just a few of research trends on rock joints modeling."

Jan 1, 2015

By M. Kucharski

The model of the Outokumpu direct-to-copper process deals with a steady-state process the parameters of which do not depend on time. To give a prediction for the process outcome, "a modified black box" method, which ignores most of the chemical reactions in the furnace, was used. This method takes input and output parameters into consideration. The presented model describes the Outokumpu direct-to blister process in the form of the set of linear equations which give mass and enthalpy balances as well as the distribution of elements between blister copper and slag. However, only major substances where quantities in the feed charge exceed a certain level (for example 0.5 kg/ lMg of smelted concentrate) are taken into consideration. Minor elements are distributed among slag and metal phases in a different way. Some of the equations are derived from distribution coefficients. The value of distribution coefficients can be calculated from plant production data.

Jan 1, 2007

By A. Koster, V. Maurel, S. Dezecot, Szmytka. F.

The aim of this work is to clarify the role of microstructure heterogeneity in the initiation and growth of cracks in a lost foam cast A319 for low cycle fatigue (LCF) loading condition. Because 2D analysis fail to establish the scenario of damage events, this study is based on 3D in situ analysis using synchrotron X-ray tomography during LCF test performed at 200°C. If X-ray tomography is now an established technique to study damage development in 3D, its application for relatively high temperature cyclic tests has never been done so far. Initial 3D observations of damage show that the cracks that lead to fracture initiate near large pores and propagate into the hard particles 3D network of the eutectic regions.

Jan 1, 2015

By W. D. C. MacKenzie

IT IS almost exactly fifteen years since the discovery of the Leduc oil field and, as this luncheon is part of the Thirteenth Annual Technical Meeting of the Institute's Petroleum and Natural Gas Division, it seems, therefore, a singularly appropriate time to discuss the theme which the program committee has suggested for the occasion -the progress of the Canadian oil industry during the fifteen years since the discovery of the Leduc field. As you will see, I plan to take a few minor liberties with this suggested theme. I shall present ample evidence of growth and progress, but, at the same time, I want to refer to some areas where progress has been anything but conspicuous and to see what can be learned from these areas for the future. The achievements of the Canadian oil industry since the Leduc discovery in 1947 have been substantial, and the public is relatively familiar with the more spectacular developments.

Jan 1, 1962

By Takao Oishi, Go Ohara, Toru Kitazaki, Masahiro Tanaka

"The High Pressure Acid Leach (HPAL) plant for nickel-cobalt mixed sulphide production at Coral Bay Nickel Corporation (CBNC) in the Philippines has been in operation since 2005 with a capacity of 10,000 t/year of nickel. Subsequent to the commissioning of the second plant in 2008, the production capacity increased to 22,000 t/year of nickel (Llerin et al., 2011). CBNC’s annual nickel production reached more than 24,000 tons of nickel in 2014. The concepts to achieve this capacity are the high availability and the reciprocally flexible operation of both plants. The availability depends on some factors, such as the control of impurities in the process and the equipment condition, to mention a few. In the HPAL process, it is not only the autoclave operating conditions that affect nickel extraction but also the impurities in the ore greatly influence it. The major element in the ore is iron and most of this iron is precipitated as Fe2O3, while the rest remains as Fe2+ or Fe3+ sulphate in solution. These ions in solution reduce the availability, so it is important to control the formation of iron ions by controlling the impurities in feed ore as well as the HPAL conditions. This paper presents the general HPAL process and the behaviour of impurities, focusing on iron behaviour in the HPAL process.INTRODUCTIONCoral Bay Nickel Corporation ProfileCoral Bay Nickel Corporation (CBNC) was founded on April 2002, as a joint venture of four companies; namely, Mitsui Corporation (18%), Sojitz Corporation (18%), Nickel Asia Corporation (10%) and Sumitomo Metal Mining Corporation (SMM) with a controlling stake of 54%. Aside from its capital share, Nickel Asia Corporation also supplies the ore and limestone for the High Pressure Acid Leach (HPAL) plant located in Rio Tuba, Philippines, as shown in Figure 1 (Tsuchida, 2008). The objective of the CBNC project is to produce 22,000 t/year (original design) of nickel and 1,500 t/year of cobalt, as sulphide, by the treatment of nickel laterite ore which is a low grade nickel oxide ore in the Philippines (Mines and Geosciences Bureau, 2014). The sulphide product has been exported as a raw material to the SMM Nickel Refinery in Japan for 30 years. The product of this plant, a mixed (Ni/Co) sulphide, is shipped to the SMM’s Nickel Refinery in Niihama, Japan. SMM Corporation provides the technology and management personnel to the plant. SMM Corporation also supplies the sulphuric acid, which is the main reagent for the HPAL process."

Jan 1, 2016

By M. Nagamori, A. J. Plumpton

"Commercial HCl-leaching of magnesite and serpentine yields highly concentrated aqueous solutions containing 25 mass % to 33 mass % MgCl2. The partial molar enthalpies and heat capacities, the ionic activities of Mg2+ and Cl–, and the Raoultian activity of H2O have been assessed for the concentrated MgCl2-H2O solutions at temperatures of 348 to 373 K. These thermodynamic data are used to calculate the pH of aqueous MgCl2 solutions saturated with a Mg-bearing mineral such as magnesite, serpentine, brucite, forsterite, enstatite or talc. On the basis of these thermodynamic data, technico-economic aspects are discussed as to neutralization with pulverized MgCO3, water evaporation from the MgCl2 solutions, and ore composition including such minor constituents as CaCO3, FeCO3 and Fe3O4. IntroductionA major magnesium electrolytic reduction plant operates in Quebec, where another will begin its production in the year 2000. One uses imported magnesite ore as raw material, while the other will utilize local asbestos tailings (serpentine). Both processes produce a concentrated salt solution of 25 mass % to 33 mass % MgCl2 by leaching the ore with concentrated hydrochloric acid. Thus, the two processes differ mainly in the HCl-leach and related operations. After the HCl-leach of the ore, the serpentine process yields about 25 times more wet cake to filter and wash than the magnesite counterpart. A comparative cost-engineering study with respect to slurry filtration and cake washing has been published elsewhere (Blackburn and Nagamori, 1994). By contrast, the present study considers the thermodynamics and technicoeconomics of the HCl-leach itself for both ores."

Jan 1, 1999

By George P. Demopoulos, Yan Zeng, Zhibao Li

Precipitated silica is marketed with a rising demand as reinforcing filler in the rubber industry and as a potential raw material for the synthesis of lithium-ion battery electrodes. Due to an awareness of the environmental impact of the existing processes for the production of precipitated silica, a green and sustainable process was proposed by using sodium bicarbonate (NaHCO3) as an alternative to sulfuric or hydrochloric acid in the precipitation reaction with sodium silicates. The use of NaHCO3 allows for better control of the supersaturation and pH to form silica with desired quality. Additionally, Na2CO3 solution as the process by-product is recyclable because it could be recovered to produce NaHCO3 by absorbing CO2. The solubility of sodium metasilicate nonahydrate (Na2SiO3·9H2O) in the Na-CO3-HCO3-OH-H2O system was measured using a dynamic method in the temperature range from 288.15 to 308.15 K. It is found that the solubility of Na2SiO3·9H2O decreases with increasing concentration of either Na2CO3 or NaOH over the investigated concentration range. With the aid of the OLI platform, a chemical model for the Na2SiO3-Na-CO3-HCO3-OH system was established with newly obtained interaction parameters of the Bromley-Zemaitis model by regression of experimental solubility data. The new model predicted the solubility of Na2SiO3·9H2O in multi-component systems with good agreement and was used to conduct a preliminary feasibility study of the new process.

Jan 1, 2015

By M. Abdellatif

Successful demonstration of The Mintek Thermal Magnesium Process (MTMP) was achieved in November 2004 at the pilot-scale, About 30 tons of magnesium producing recipe was smelted in the DC arc furnace over a continuous operation of 8-days, Twenty-two furnace batching-tapping operations were carried out at a feed rate of 525kg/h and a smelting temperature of 1600-1700°C, The MgO content in the produced slag was as low as 6,7%, and averaged 9,2% MgO, resulting in an overall magnesium extraction of 77%, which reached 87% during good operating periods, Magnesium vapour was extracted at a rate of 70-85kg/h and was delivered to the condenser that was operated at 680-720°C, The magnesium was captured in the condenser crucible in a liquid state, allowing its prompt tapping, More than 3500kg of crude metal were produced over 15 on-line metal tapping operations, On average, a condensation efficiency of 85% was achieved during the entire testwork, which peaked at 87% during steady operations, The quality of the crude metal was similar to, if not better than, that of the Magnetherm's crude magnesium, A pre-feasibility study has indicated that the MTMP has the potential for lower capital and operating costs as compared to the electrolytic process, and therefore Mintek and its consortium partners are exploring opportunities for a commercial production facility.

Jan 1, 2006

By M. Pawlik, E. Arinaitwe, V. Ferrera

A series of flocculation tests were performed on dilute quartz suspensions with the use of five polyacrylamide-based flocculants of similar molecular weights but of different degrees of anionicity. The tests were performed as a function of ionic strength and pH. The macromolecular conformation of flocculants in solution was assessed through intrinsic viscosity measurements under the same physicochemical conditions as those of the flocculation tests. It was generally found that the flocculating efficiency of the polyacrylamides correlated with their ability to coil or stretch in solution. Polyacrylamides with the degrees of anionicity on the order of 10-18% showed the highest flocculating efficiency in terms of the settling rates of the flocculated solids and the residual turbidity of the resulting supernatant. At the same time, these most effective flocculants were also found to exhibit the greatest tendency to coil and stretch in solution. This result suggests that the flocculating power of a flocculant is determined not only by its ability to adsorb onto (and bridge) fine particles but also on its ability to conform to the size of the resulting floes.

Jan 1, 2009

By H. V. Kinsey

"IntroductionTITANIUM is probably the most widely publicized metal today. Much has been written, both in the lay press and the technical press, about its properties and potentialities. In view of the fact that Canada possesses large quantities of titanium-bearing ore, and could conceivably become a major producer of metallic titanium, it was felt that a paper dealing mainly with the physical metallurgy of titanium would be of interest to this Institute. This paper is concerned chiefly with the useful properties of titanium and its alloys and the fundamentals governing the modification of its properties by alloying.Physical Properties of TitaniumTitanium belongs to a family of metals that have been termed 'gas sensitive' (I), because their mechanical properties are altered by certain gases which they readily absorb and retain. Other metals of this group are zirconium, hafnium, vanadium, columbium, tantalum, and chromium. Titanium has a strong affinity for oxygen and nitrogen and once it has absorbed these gases they cannot be removed either by melting in vacuum or by any degassing agent. These gases, when present in excess of about half a per cent oxygen plus nitrogen, render the metal brittle and useless as a structural material.Some of the typical physical properties of titanium are listed in Table I along with those of common structural metals for comparison."

Jan 1, 1953

By Ian S. Leslie

Seismic monitoring systems for mining operations are being utilized more than ever before in the characterization of rock mass response to underground and open pit mining. This paper provides a review of the use of microseismic monitoring for rock mechanics applications at mines throughout the world. Some practical considerations for the installation of these systems are presented along with techniques for optimizing seismic array coverage. Case studies and installation examples are also provided. Recent applications of advanced seismic analysis techniques are discussed including the determination of event mechanisms, mapping of maximum peak particle velocity (PPV) and seismic hazard fields, and the use of source parameter data for large event re-entry protocol.

Jun 1, 2012

By R. M. Berry

A brief outline of refining methods used to (1) upgrade yellowcake to nuclear purity and (2) convert the uranium to the chemical and physical forms required by the fuel fabricators is presented. The uranium hexafluoride (UF6) production facility now under construction at Eldorado, Port Hope, is discussed. Technological improvements in uranium refining are considered.

Jan 1, 1969

By Dawei Yu, Kinnor Chattopadhyay

In the nickel industry, molten slags produced from a Pierce-Smith converter contain significant amounts of valuable metals in the forms of oxides and physically entrained matte droplets. A slag cleaning step, which takes places in an electrical slag-cleaning furnace, is therefore required to recover the valuable metals as a common practice. Utilization of a waste material from aluminum industry (i.e. spent potlining) as a flux to improve the slag cleaning in terms of both the metal recovery and the operation efficiency was studied by simulation with FactSage program. Results show that the addition of SPL could substantially reduce the slag viscosity due to its fluoride values, thus accelerating the settling of matte droplets. The carbon value in the SPL could also help increase the metal recovery by reducing the valuable metal oxides followed by settling.

Jan 1, 2015

By D. M. Doyle

"In this paper I will summarized the Falconbridge Nickel Mines1) energy costs and consumption data by fuel, process, cost centre and estimate our future costs and consumption patterns 2) detail the distribution of electrical energy 3) distribution of other forms of energy 4) describe present and planned energy conservation schemes; and 5) discuss economic justification and responsibility.There is sufficient material in this presentation to warrant several technical papers, however we felt that an overview of all our data and endeavors on the subject, would be most beneficial to those companies formulating energy conservation plans. The data briefly referred to in this slide presentation can be found in the technical paper.Over a five year period, total energy costs will vary between $63 and $94 MM depending on the future rate of energy cost escalation. An unrealistic 32% reduction in energy consumption is required to hold our own in the years ahead whereas an attainable 10°;, reduction in energy consumption would save $9 MM over this five year period.Total energy consumption, tonnage of ore delivered to plants and their ration BTU’s per ton of ore, are graphed for the years 1973 through 1976 and forecasted for the 1980’s. In 1974 we along with other member companies of the Mining Association, determined our purchased energy per ton consumption rate and set, as our goal, a 20% reduction by 1980. The dotted lines calculated from the energy audit, based on 1976 data shows there is a potential for a 10% increase in energy per ton. This could result from a lower than forecasted mining rate and operation of the new roasting, electric furnace and acid recovery facilities installed for environmental considerations at designed capacity."

Jan 1, 1978

By J. Walker, G. E. Kim

Since May of 2000, Mogas Industries, in partnership with F.W. Gartner Thermal Spraying Co. and using the services of Perpetual Technologies, has invested time, energy, and resources towards developing novel ball valves for high-pressure acid-leach (HPAL) service. In addition to developing new valve designs, an aggressive coatings development effort has been undertaken to improve the protective quality of the coatings so as to enhance the performance and extend the life of valves in severe HPAL conditions. In 2001, Mogas Industries qualified and applied a nanostructured titanium oxide (n-TiO2) coating for gold and nickel/cobalt HPAL services. The n-TiO2 coating provided dramatically superior protection against abrasive and erosive wear, fared very well against high-pressure autoclave corrosion testing, and has performed well in HPAL service.

Jan 1, 2004

By Paul Guliov

Industrial clays, including a variety of bentonites and kaolinbased clays in southern Saskatchewan are hosted by Late Cretaceous and Early Tertiary sediments. Ofparticular significance are the deposits of swelling bentonite in the Cretaceous Bearpaw Formation and the kaolinitic clays of the Cretaceous Whitemud and Paleocene Ravenscrag Formations. Swelling bentonite is currently produced in the Wilcox-Truax area by Canadian Clay Products Inc. and yields at least seven different commercial products for a variety of applications. Kaolinitic plastic clays, including ball clay, stoneware and earthenware clay, as well as kaolin in southern Saskatchewan, have a long history of development and use. Products include common and face brick, refractory bricks and other shapes, chinaware, pottery, sewer pipe, chimney flue linings and tiles. Currently clay production is for out-of-province brick manufacturing and for pottery. Recent research and improved technology combined with expansion in certain areas of the global clay industry generally hold promise for a resurgence of a clay-based industry in Saskatchewan. Products of particular promise include: clay tiles; kaolin fillers and extenders; and aluminum as well as related by-products from kaolinitic clays based on the carbochlorination process.

Jan 1, 2001

By Luc Harnois, Gabriel Voicu, Marc Bardoux, Robert Crépeau

"Abstract-Detailed petrographical and geochemical studies have been carried out on the igneous and sedimentary rocks in the Omai area, part of the Paleoproterozoic Barama-Mazaruni greenstone belt, Guyana. The stratigraphic succession at Omai begins with basalts, associated with mafic-ultramafic intrusives and poorly-sorted conglomerates; these are overlain by andesites and quartzfeldspar porphyries, with pelites and tuffaceous sediments at the top. The volcanic-sedimentary succession was intruded by a quartz-monzodioritic stock (Omai stock) and granophyric rhyolite dikes. Several generations of mafic dikes were intruded discontinuously from the Mesoproterozoic to the Permo-Triassic. Volcanic rocks range in composition from subalkaline basalt to high-silica rhyolites, with a gap between 60% to 70% SiO2, which suggests the suite is bimodal. Major, trace, and rare earth element criteria were used to subdivide the rocks into tholeiitic and calc-alkaline types. The tholeiitic rocks are characterized by flat to moderately sloping chondrite-normalized REE patterns. On the basis of immobile trace-element ratios, the tholeiitic mafic rocks from Omai have characteristics of immature intra-oceanic island arcs, or of E-MORB basalts affected by a strong arc signature, as is commonly reported for back-arc basin basalts. The andesites, quartz-feldspar porphyries, rhyolites and quartz monzodioritic stock are calc-alkaline, with strongly sloping REE patterns, enrichments in the large-ion lithophile elements, and depletions in the heavy REE and high-field-strength elements, features which are typical of more mature island-arc settings.At Omai, two types of gold-bearing veins can be distinguished: vein sets (± stockworks) and tension veins, both post-dating the regional metamorphic peak at the level they were emplaced. The relationship between the gold mineralization and its host lithologies does not seem to be genetic. Rather, the emplacement of mineralization was strongly influenced by the rheological contrasts between the intrusive/subvolcanic bodies and the volcanic/sedimentary country rocks. These contrasts helped to focus the regional stress upon the more competent intrusive subvolcanic bodies, resulting in brittle fracturing, and therefore in greatly enhanced permeability to hydrothermal fluids. The Omai gold mineralization can be classified as late tectonic, with its emplacement controlled by the last brittle to brittle-ductile stages of the Trans-Amazonian orogeny."

Jan 1, 1997