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By A. I. A. Salama, M. W. Mikhail, R. J. Mikula

"The Coal Research Laboratory (CRL) of CANMET along with other research organizations in coal-producing countries envisage major benefits from computer applications in coal preparation, Some of these benefits are greater system flexibility, improved coal preparation plant performance efficiency and efficient utilization of manpower, all of which result in economic benefits. Computers can be applied for both on-line and off-line purposes; this paper focuses on the on-line applications from the process control point of view.A critical discussion of the different analog and digital process control systems is presented. Recent developments in Great Britain, West Germany, Poland and Australia on automation and instrumentation using on-line measurements of coal ash and moisture contents are identified.The CRL research and development strategy aimed at achieving on-line computer control of an automated coal preparation plant is presented.IntroductionIn the past twenty years an enormous progress in the area of computer technology has been noticed. Computer applications in industrial processes offer greater system flexibility, improved plant performance efficiency and efficient utilization of manpower. Significant computer control development in mineral processing has already been achieved. Although progress has been made in the area of computer applications in coal preparation, more effort is needed to utilize the full potential.The computer applications in coal preparation can be viewed as off-line and on-line. Considerable progress has been reported in the area of off-line computer applications, especially in the areas of modelling, performance evaluation/prediction and statistical analysis. However, only modest progress in on-line applications has been reported(1-7). This paper will focus on: online instrumentation and process control applications, different analog and/or digital control systems, on-line automation and instrumentation in other countries and CRL strategy toward pilot plant automation."

Jan 1, 1985

By Margaret Armstrong, Normand Champigny

"In order to define the ore/waste boundaries as finely as possible, mine planners often insist on kriging very small blocks (relative to the spacing of the available sample grades). These kriged estimates for very small blocks are over-smoothed. For several simple sampling patterns the relation between the block size and the variogram range, and the kriging results were studied. Meaningful estimates of individual blocks are obtained when the variogram range is large compared to the block size and the sample spacing. For a variogram range less than half the sample spacing, the kriged block estimates were found to be uncorrelated with the actual grades. The over-smoothed estimates should not be used for calculating recoverable reserves IntroductionNowadays most mining companies know that the geostatistical estimation method, kriging, gives the best estimates of individual block grades. As most mining engineers and geologists are now familiar with the basics of geostatistics, the definitions of the variogram and of kriging will not be repeated here. An appendix containing definitions and mathematical formulae is given at the end of the article for the sake of completeness.Even though it is well known that the kriged estimates for very small blocks are over-smoothed, mine planners who want to define the ore/waste limits as finely as possible (especially for selective underground mines), are often tempted to krige very small blocks. So we ask how small is ""too small""? Clearly ""smallness"" cannot be expressed in yards or metres. It depends on the nature of the orebody under study and this is reflected in the variogram model chosen to describe it.To answer this question, the changes in four key parameters are studied:• the kriging variance,• the variance of the estimated grade,• the slope of the linear regression of the true but unknown grade on its estimated value, and• the coefficient of correlation between the actual grade and the estimate;as a function of the block size and the variogram range. (Definitions of these four parameters are given in the appendix). Ideally the kriging variance should be low while the variance of the estimated grade should be equal to the dispersion variance of the blocks. The slope should be l.0, and so should the correlation coefficient.These four parameters have been calculated for several simple 2-D examples. The effect of using kriged block estimates that are too heavily smoothed are shown, and the dangers of trying to use these estimates for predicting recoverable reserves for small blocks (i.e. selective mining units) are pointed out."

Jan 1, 1989

By J. Dufour

Although the recovery of nitric and hydrofluoric acids from stainless steel pickle liquors has been solved by several methods, such as solvent extraction, acid retardation, evaporation or pyrohydrolysis, metals (mainly iron, chromium and nickel) are usually obtained as a waste or by-product that has to be disposed. Alternatively, the treatment requires a high liquor flow to be economical, as is the case for pyrohydrolysis. A new process has been developed for metals recovery, that produces metal oxides with a low fluoride content. This new technique is based on a selective precipitation mechanism, which produces nickel hydroxide with a purity of 90%, separate from a mixture of iron and chromium oxides and hydroxides suitable for recycling. The reaction mechanism is based on the precipitation of fluoride compounds of iron and chromium, K2FeF5 and CrF3. For this purpose, free fluoride must be added as potassium fluoride. Also, solid fluoride compounds are hydrolysed, releasing free fluoride. A part of the fluoride is recycled to the selective precipitation operation and the remainder is fed to the acid recovery stage. Nickel does not react in this operation; it remains in solution giving a high separation yield.

Jan 1, 2006

By A R. Bullis

Metal Mines Limited (Bancroft Division) was incorporated m 1964 to take over the assets of Faraday Uranium Mines Ltd., including their uranium deposit near Bancroft. Ontario. This paper outlines the geology of the Bancroft area, and. then go on to describe the principle rock types m the mine workings, especially the pegmatite, which is the host rock for the uranium mineralization. The structure and mineralogy of the orebodies are thoroughly covered, and, after a summary of the production and ore re-serve figures, the paper concludes with suggestions for further exploration work. Location and History M ETAL Mines Limited, Bancroft Division, is located in Faraday township, Hastings county, Ontario. The main production shaft and concentrator are about: Y2 mile north of Highway 28 and about 5 miles west of the village of Bancroft (Figure 1). The presence of radioactive minerals in the Ban-croft-Wilberforce area has been known since the early 1920's. Uraninite was found at the Richardson deposit near Wilberforce in 1922, and some attempts were made to produce radium from the deposits of the area between 1929 and 1931.

Jan 1, 1965

By L. M. Lowe, D. B. Chambers, D. G. Feasby

"The presence of the naturally occurring radioactive elements uranium and thorium in rare earth (RE) resources can present challenges in achieving regulatory and social acceptance. The discovery and awareness of radioactivity in mineral resources radioactivity typically generates strong public intuitive responses that may be project prohibitive; a significant proportion of such resources contain radioactivity.The objectives of this paper are to demystify the presence of uranium and thorium in RE resources and to demonstrate how a RE project can be safely developed, operated and closed from a radiological perspective. Radioactivity in RE resources is principally thorium-based. Thorium is interesting and challenging from a metallurgical perspective – one of those stubborn metals commonly assessed as refractory. Thorium is difficult to mobilise into solution and easily precipitates out. Thorium is a common element in the earth’s crust – about 10 ppm on average, and natural geophysical systems conclusively demonstrate its immobility. Specific mine tailings contain elevated levels of thorium, but the contained thorium is neither a significant ecological nor a personal hazard.Waste management for a hard rock rare earth project includes the management of mineral processtailings, waste rock, and metallurgical residue. Proven strategies are available for tailings and waste rockfor all climate conditions. The management of the metallurgical residues is potentially more challenging.Example robust strategies for addressing these challenges are presented.A potential way to reduce the radioactivity of rare earth metallurgical wastes is to selectively remove uranium and thorium. Uranium oxide is readily marketable, but its concentration as a byproduct typically triggers extensive regulatory processes. Thorium is presently not marketable, but may be so in the not-too-distant future with the development of thorium-based nuclear energy. The pro’s and con’s of uranium and thorium byproduct recovery are summarized."

Jan 1, 2016

By Ali Montaser

Hauling trucks are important part of equipment fleets for large earthmoving operations such as those encountered in dams and highway construction projects. This paper presents an automated methodology for tracking and estimating productivity of hauling trucks fleet operations in near-real-time. Recent advancement in automated site data acquisition technologies made their use in tracking and monitoring of construction operations feasible. However, these technologies fail to track hauling truck fleets due to the change in the cut and fill locations from one cycle to another; making tracking and progress reporting difficult and inaccurate. In addition, there is very little work done utilizing data sensed directly from equipment, for example sensing when truck dumping bed is raised during the dumping process. The technologies deployed in the developed method are Radio Frequency Identification (RFID) and equipment control sensors. Low cost passive RFID tags are attached to hauling trucks and fixed RFID readers are attached to loaders or excavators. The read range of the used RFID tag is centimeters, to be activated only when a loader with an attached RFID reader is loading a truck. On the other hand, control sensor is connected to the truck control system and operated by the motion of its movable bed. The function of control sensors is to record the signal time when the truck operator gives order to the truck control system to raise or lower truck bed. The captured data is then transferred wirelessly from the RFID reader and control sensor to a computer housed in one of the temporary offices onsite and subsequently to the main server in the contractor?s head office. Fusing the data captured from RFID reader and control sensor is used to identify loading, travel, dumping and return time that constitute the hauling truck cycle time. The collected data is analyzed and processed automatically, without human intervention, to calculate the productivity of the hauling truck and to report it directly to onsite personnel. Relational database is developed to support the implementation of the proposed method. The developed database is used to process the data captured by the RFID and the control sensor to calculate the productivity achieved in cutfill operations in near-real-time. The developed methodology is expected to facilitate early detection of discrepancies between actual and planned performances.

Aug 1, 2013

By E. You

The concentrator at Kennecott Utah Copper currently has 4 lines with a configuration of one SAG mill feeding two ball mills. The slurry that reports to each ball mill will vary resulting in an unequal load of material. This configuration contains two separate sumps that receive material from a distribution box relying solely on natural slurry flow to feed each sump. The unequal split to each mill results in one mill receiving a greater amount of material. This will result in the equipment on one mill reaching limitations that may affect product quality and the operation of the equipment near maximum. The parallel mill in this condition will often have additional capacity that can be used but cannot be utilized due to the unequal split. The major consequences of this issue result in reduced throughputs and metal recovery. To resolve this condition an advanced control strategy was implemented to control the split in April of 2002 using equipment that was in place.

Jan 1, 2007

By Y. M. Zhao, C. L. Duan, Z. F. Luo, X. L. Yang

"Fine coal beneficiation in a dry way is considerably imperative for the efficient utilization and conservation of coal resource in drought regions, especially for China. In this study, a continuous vibrated gas-fluidized bed separator was established and developed based on the results of laboratory batch separation results. The fluidization behavior and the effects of several main parameters including superficial air velocity, vibrational parameters, bed height and separating time were systematically investigated. The results showed that the bed expansion increased linearly with the superficial air velocity and theoretically, higher bed expansion benefited the hindered settling process of fine coal particles. However, larger superficial air velocity would induce intense fluctuation in bed surface and a poor performance of density segregation. The conveying velocity of particles was mainly determined by the vibration angle and a predicted model was established by the nonlinear regression analysis. A theoretical model of bed height distribution was established and this model fitted the measured value well. The beneficiation performance of this separator was evaluated by separating -3+1 mm Wuhai fine coal. The results showed that the probable error, E, is 0.225, indicating a continuous vibrated gas-fluidized bed separator could achieve a satisfactory performance.INTRODUCTIONFine coal beneficiation in a dry way is considerably imperative for the efficient utilization and conservation of coal resource in drought regions, especially for China. Meanwhile, it is also conducive to environment protect and low-carbon, green development of coal sector. In recent years, the increasing academic interest in the field of fine coal dry beneficiation has been aroused in most of big coal countries. In summary, recent processes of fine coal dry beneficiation are, according to their processing principles, mainly classified into two categories: dense medium beneficiation (Dong et al., 2015; Fan, Chen, Zhao, & Luo, 2001; Luo et al., 2008; Macpherson, Iveson, & Galvin, 2011) and improved pneumatic beneficiation (Patil & Parekh, 2011; Yang, Zhao, Luo, Song, & Chen, 2013; Yang, Zhao, Luo, Song, Duan, et al., 2013; Zhao, Zhao, Chen, & Luo, 2015). The former deploys artificial dense medium, such as magnetite powder and fine sand, to form a stable gas-solid suspension with certain density under the function of the upward fluidizing air flow and in some case, the external force field like vibration and magnetic field. Generally, it is believed that the process of air dense medium fluidized bed (ADMFB) is suitable for separation of coarse coal (-50+6 mm) and can't obtain a satisfactory result for fine coal separation (Luo, Chen, & Zhao, 2002; Luo et al., 2008). However, some recent laboratory efforts (Patil & Parekh, 2011; Zhang et al., 2014) attempt to find an improved performance for fine coal beneficiation in ADMFB with some modifications. The point of these works is to use a comparatively shallow bed and finer magnetite powder with appropriate size distribution. It is known that fluidization of finer magnetite powder is prone to arouse adverse fluidization properties such as channeling and slugging. Thus, the external force is introduced to an ADMFB in order to improve the fluidization quality of a magnetite powder bed. Some recent literature on air dense medium magnetically stabilized fluidized beds (Fan et al., 2001; Luo, Zhao, Chen, Fan, & Tao, 2002; Song, Zhao, Luo, & Tang, 2012), air dense medium vibrated fluidized beds (Luo et al., 2008) and Reflux Classifier (Macpherson, Iveson, & Galvin, 2010) reports that the separation efficiency, namely the probably error E value, of dense medium separation of fine coal ranges from 0.066 to 0.07, indicating a good separation performance. But, the main unresolved problems of dense medium beneficiation are located in the processes of product purification and medium recovery and are urgent to be solved befor"

Jan 1, 2016

By K. Adham

Iron chloride pyrohydrolysis (ICP) is used as an efficient way to fix iron as an oxide, for sale as a by-product or for safe disposal. Iron chloride is reacted with water at elevated temperatures to yield iron oxide and hydrogen chloride. Both the steel industry and synthetic rutile producers make extensive use of ICP. Two technologies are available for ICP: fluidized bed (FB) and spray roaster (SR). Both technologies are energy intensive. Here, fluid beds and spray roasters are compared with respect to their fuel and electrical energy consumptions. Roaster size and oxide product characteristics are also considered. Process models are prepared, using the METSIM® software, and specific energy consumptions are compared. The results will help the industry decide which technology best suits its goals and at what energy cost.

Jan 1, 2006

By R. D. Brown

In the spring of 1977, Revenue Canada announced its intention to proceed in 1978 with a plan to impute a taxable benefit on interest-free and low-interest loans provided to employees. Such loan arrangements are often an important aspect of the compensation packages provided by many companies to their employees. Since the original announcement, there have been many submissions to Revenue Canada opposing this change, and the Finance Minister has now brought down a compromise solution with the introduction of a proposed amendment to the Income Tax Act. The amendment, which would not take effect until the 1979 taxation year, would require an employee, a shareholder or a related person to include a benefit in income measured as the difference between the interest on any such loan computed at bank prime rate and any interest actually paid. Only the amount of such a benefit in excess of $500 in a particular year would be required to be included in income. Of particular interest is the exclusion from these benefit rules of loans up to $50,000 in respect of the purchase of a house on the relocation of an employee and loans provided for the purchase of shares of an employer corporation.

Jan 1, 1978

By A. de Ville d’Avray, G. Guezennec, P. Wavrer, E. Braak

The aim of the European CEReS project was to develop an innovative copper recycling route based on the coprocessing of coal production waste by bioleaching and printed circuit boards (PCBs) from Wastes of Electrical and Electronic Equipment (WEEE). Coal waste is processed by bioleaching in stirred tank reactors, and the resulting bio-lixiviant solution is used to extract copper from PCBs pre-treated by catalytic cracking. Copper is then extracted using solvent extraction, stripping and electrowinning. The whole process flowsheet combines thermal, biotechnological, physical and hydrometallurgical operations. Once the process concept has been validated at laboratory scale, a simulator of the whole process has been built in the USIM PAC software platform. The tool enables to improve the analysis of the results of the lab-scale experiments and to design industrial-scale scenarios by simulation. The results of such simulations allow to estimate the economical interest and to perform environmental impact assessment. After presentation of the CEReS project objectives and main results, the paper describes the methodology used to build the simulator and define the scenarios corresponding to feasible process routes. The main results of the simulations are then presented with technical, economic and environmental point of views. INTRODUCTION Because of rapid technological innovations in the electronics industry, electronic waste represents the fastest growing waste stream in the world, especially in developing countries (Işildar et al., 2018). Meanwhile, the global copper demand is expected to go on rising in the future. As significant amounts of copper are present in end-of-life printed circuit boards (PCBs), it becomes a necessity to develop efficient copper recycling routes. Metal refining from e-waste is traditionally performed by pyrometallurgical processes. However, the hydrometallurgical processing of PCBs, which has been shown to be technically feasible at laboratory scale with a wide range of leaching reagents, could be a less energy intensive and more flexible alternative (Tuncuk et al., 2012). However, a large amount of leaching reagent is required to leach the metals from PCBs.

Jan 1, 2019

By G. Fuentes, J. Viñals

"The nature and basic kinetics of the hydrothermal reactions of bornite, covellite pyrite and enargite with copper sulfate solutions were investigated, as a previous study on the behavior of the bulk Chilean copper concentrates. The reaction of bornite produced digenite at 160 °C and djurleite above this temperature. Covellite was transformed to digenite at < 200 °C and to chalcocite (Q and M) at > 200 °C. The pyrite reaction was significant at > 200 °C and extensive at 240 °C, enargite reacts only above 240°C and produces digenite. The hydrothermal treatment of Chilean Codelco-type copper concentrates with hydrothermal reactions was similar to those obtained from pure mineral samples.INTRODUCTIONStudies on the hydrothermal enrichment of chalcopyrite concentrates were begun by MacGauley and Roberts (1951), Roberts et al. (1953) and MacGauley and Schaufelberger (1956). In the 1970's these processes were reexamined by McKay et al. (1972), and Johnson and Coltrinari (1976), but it not was until the 1990s when the kinetics, mechanisms and full engineering aspects were studied by Barlett, (1992), Jang and Wadsworth, (1994) and Peterson and Wadsworth (1994). The main objectives were to solve some important problems in the copper pyrometallurgy: The increase of the smelting capacity, the reduction of the iron slag – and associated copper losses – as well as the reduction of sulfur emissions. The present rise in copper demand and price implies the production and subsequent treatment of very impure concentrates. Thus, a significant increase of environmental problems can be expected in the copper pyrometallurgy. The previous purification of concentrates can reduce the processing of wastes containing hazardous heavy metals in the copper refineries and the hydrothermal treatment can be an alternative which combines both enrichment and purification. On the other hand, Chuquicamatatype concentrates (Viñals et al., 2004a) contains digenite (Cu1.8S), pyrite (FeS2), chalcopyrite(CuFeS2), b ornite (Cu5FeS4), covellite (CuS) and sphalerite (ZnS) as the main mineral components, with minor amounts of enargite (Cu3AsS4), galena (PbS) and molybdenite (MoS2)."

Jan 1, 2012

By Jerry Gagnon, Matt Burr, Timothy Ellis, Abbas Mirza, Larry Webb

"The mechanical properties of RSR anode alloys (lead-calcium-tin, 009+ and lead-strontium-tin) were investigated as a function of time with an objective of developing lead anodes for use in high temperature electrolytic processes such as in copper liberator cells and in cobalt and nickel electrowinning. At a temperature of 70 oC, the mechanical properties of rolled RSR lead-calcium-tin (PbCaSn) alloy currently used in copper electrowinning decreased gradually while the mechanical properties of rolled RSR lead-strontium-tin (PbSrSn) decreased relatively quickly and stabilized at low strength levels. Cast PbSrSn started off as the weakest alloy but its properties remained stable with time. Rolled RSR 009+ anode alloy showed improvement in ageing properties over the other alloys tested. However, its mechanical properties did not stabilize in the study timeframe of 284 days. Further investigations are planned to study the effect of alloying elements on mechanical properties of RSR 009+ anode alloy over several years as a function of time at 70 oC. The mechanical properties will be evaluated to determine the time at which they stabilize. Comparative plant trials with rolled RSR PbCaSn and RSR 009+ will also be performed in copper liberator cells and in cobalt and nickel electrowinning tankhouses to determine their mechanical and electrochemical performance at temperatures of 65-75 oC.INTRODUCTIONLead-based alloys are the primary anodes used in the electrowinning of copper, zinc, nickel, cobalt and manganese from sulfate-based aqueous systems. Lead anode technology has evolved over the years migrating from pure lead and lead-antimonial alloys to the present day PbCaSn alloys for copper and PbAg and PbCaAg alloys for zinc electrowinning (Prengaman, Ellis and Mirza, 2010). It has also migrated from cast to rolled microstructures in search of improved mechanical properties and higher corrosion resistance. Although great strides have been made in the development of new lead anode alloys and production processes for lead anodes to be used in copper electrowinning, the industry still has some unresolved issues. These relate to the necessity of having higher mechanical properties especially for the lead anodes in liberator cells in copper electrorefining and for cobalt and nickel electrowinning as these tankhouses operate at temperatures of 65-75 oC compared to 40-45 oC in case of copper electrowinning."

Jan 1, 2016

By J. L. Gartshore

PRACTICALLY all of Quebec's chrysotile asbestos production derives from twelve mining and milling operations located in the "Eastern Townships" area of the province. The annual output of these twelve operations exceeds one million tons of chrysotile asbestos, valued at over one hundred million dollars, and is shipped to manufacturers spread over all six continental areas of the world. A total of approximately twenty million ton of asbestos ore yearly, or about seventy-five thousand tons a day, is mined. Individually, the operations vary in size from about two thousand tons to thirty thousand tons per day. Removal of waste rock and overburden to develop these ore tonnages varies greatly from one mine to another, but would probably average out at about a one to one ratio.

Jan 1, 1962

By C. O. Brawner, J. Kalejta II

"The classical approach to control rock fall and ravel in open pit mining has been to use catch benches. The width and volume of benches is most dependent on the bench height, size of loading equipment, blast damage to the face and mining regulations. This was compatible with open pit slopes of less than approximately 45 degrees.As our understanding of rock mechanics and blasting control has improved over recent years, much steeper rock slopes can be developed at many open pit mines. However, narrower benches result in less rock fall capacity.The transportation industry has been very successful in using catch fences to protect highways throughout North America and Europe for years. The authors recommend that cable and ring net fences have a potential major application in open pit mining to allow steeper rock slopes with significant economic benefit. This paper outlines the application, design and operation of catch fences in surface mining for specific conditions. Typical case examples are presented."

Jan 1, 2002

By Richard N. Zimmer

This paper discusses the installation of corrugated steel linings in bored raises at Inco&apos;s Thompson Mine. The procedure for the installation of these linings is outlined and the relative advantages are compared with conventional methods of ground support. Future trends in the use of corrugated steel products are then discussed.

Jan 1, 1978

By F. Doxey

Introduction Numerous papers have been written dealing with the construction and functions of, and the environmental conditions created by, Diesel locomotives. Therefore, it is not my intention to attempt to deal with these phases of Diesel transportation other than to make reference to them in ?relation to and in connection with actual operation. The rapid expansion of industry during recent years and the necessity of products being made available at competitive prices in home and world markets has made the demand for cheaper coal a very serious factor for the coal industry. This condition has meant each coal producing country looking into ways and means whereby greater productivity and reduction in cost could he achieved. Surveys made show that, in addition to face mechanization, savings, in some cases substantial, can be made in transportation. Ventilation The most efficient mines are in-variably the well ventilated ones, for it is true that, where there is good ventilation, there are usually good roads. These combined factors are very essential where Diesel locomotives are used. Good roadways and track allow speed, and good ventilation dilutes rapidly any disagreeable exhaust gases. Locomotive Development In the older types of auxiliary rope haulage, coal hauled per haul-age hand is usually very low.

Jan 1, 1951

By I. O. Ojala

Detailed knowledge of velocity-depth trends is essential for constructing well-to seismic ties, determining background velocity and generating synthetic seismic traces for interpreting seismic amplitudes in terms of porosity, lithology and pore fluid type. The acoustic properties of shales are of particular importance in the exploration setting as shales constitute more than 80% of sediments and rocks in siliclastic environments. Seismic and sonic log data may be used for estimating overpressure in shales in order to maintain borehole stability during drilling. In addition, velocities in shales can be used for predicting its mechanical properties and hence, borehole collapse. Despite of the apparent importance of understanding shale acoustics, sonic logs in shales are frequently unavailable or unreliable especially for older wells. Hence, it is essential to compute pseudo-velocity logs from other available information. This can be accomplished by using empirical relationships or rock physics transforms. In this study we have compared the predictive power of resistivity (Faust 1951, Hubert 2008) and porosity based models (Wyllie 1956, Holt & Fjær 2003) for computing synthetic P-wave velocity logs using wireline log data from mudstone intervals at three North Sea wells. The wells 6507/2-1, 6507/2-2 and 6507/2-1 are located at the Haltenbanken area at the Norwegian Sea. The wells targeted hydrocarbon potential at the upper Cretaceous and lower Tertiary sandstone sequences. The sandstone beds are overlain by thick Tertiary and Cretaceous sequences of mudstones. Since our primary goal is to model acoustic velocities in shale, we used wireline data from the Nordland (NL), Rogaland (RL) and Hordaland (HL) groups that are mainly composed of mudstone. The mudstone beds were identified from the well log data by using natural gamma log, sonic and resistivity data as well as information from the Norwegian Petroleum Directorate website. The volume of shale was estimated from the natural gamma log and the data points with values higher than 0.65 were discarded. Similarly, the data points with shale volume less than 40 % were discarded. Furthermore, exceptionally high resistivity values amounting to more than 6 Ohm m were not included in the analysis. Porosities were determined from the density log assuming 2.7 and 1.05 g/cm3 for matrix and fluid densities, respectively. The depth that was used for calculating Vp from Faust (1953) was the depth below mudline in order to the compare of well data from wells that have been drilled at different depths (Hubert 2008).

May 1, 2009

By G. V. Theja, V. B. Maji

Large infrastructure projects like tunnel excavations, underground constructions face innumerable risks. For successful completion of these projects, it is essential that we foresee and understand risks that could occur during different phases of the project. One of the risks affecting underground excavation projects is the inaccurate performance prediction of TBMs. As this could severely affect the project, resulting in lower advance rates and could also result in changing the excavation machine or method, due to difficulties in excavation, thereby increasing the overall cost of tunnelling. This makes performance prediction of the TBMs as one of the crucial aspects in tunnelling, as a precise estimation of its performance is required for planning and estimation of time and cost of the tunnelling projects. This performance prediction of TBM is a challenging geotechnical problem that is intricate and complex in nature, this is possibly due to the fact that TBM performance prediction involves understanding the rock fragmentation process in wide range from micro-scale (i.e. the interaction of surface of rock material and cutter tip) to macro-scale (including the interaction of rock mass and TBM). Thus in order for the performance prediction model to be efficient, parameters of both TBM specifications and ground conditions have to be considered. Various models have been proposed by researchers since the early phases of TBM application, these studies resulted in the development and improvement of numerous penetration prediction models. Most of these models consider the geotechnical parameters that are input to the model to be consistent along the TBM drive and neglect the uncertainties in parameters that occur. And so to improve the predictive capability of these models and to incorporate the above uncertainties, the penetration rate is modeled as a stochastic variable depending on the geotechnical and TBM parameters, its statistical distribution is determined and is used to characterize the penetration rate instead.

Jan 1, 2015

By R. Khanna, K. Hyun Ko, A. J. Berkovich, J. Hook

"The co-pyrolysis of synthetic polymer polyethylene terephthalate (PET) and agricultural wastes (naturally occurring polymer-macadamia nut shell) was investigated in the temperature range 473K to 1273K using a horizontal furnace with an aim to understand their thermal degradation under isothermal conditions. In-depth characterization of pyrolysis residues was carried out using x-ray diffraction (XRD) and solid state nuclear magnetic resonance (NMR) for carbon structure, and through determination of the concentration of unpaired electrons using electron paramagnetic resonance (EPR). In previous studies, it has been found that PET thermally decomposes ~ 650K-700K, releasing (~80 wt % of initial weight) gaseous products due to random chain scission. In the case of macadamia nut shell, three types of byproduct can be obtained from pyrolysis: char, tar and gaseous products. In the co-pyrolysis of macadamia nut shell with PET in 50-50 wt% ratio, total product weight ratio could be modified with the addition of PET acting as a hydrogen source. This is because a recombination of thermal cracking products of cellulose could be suppressed by hydrogen from PET, which will later lead to an enhancement of tar formation. In addition, pyrolysis around 673K is sufficient for bond cleavage to occur in cellulose and lignin leading to the formation of negatively charged activated carbon with high surface area, providing bonding sites for volatiles evolving from PET. Therefore the co-pyrolysis may be able to enhance the product yield (tar/char/solid carbon residue) along with a reduction in the release of gaseous products. During the co-pyrolysis, temperature was found to have a significant influence on the kinetics of thermal degradation and solid residual by-products after co-pyrolysis.INTRODUCTIONPlastics are being used worldwide in a wide range of applications in the modern society; their usage has resulted in increasingly a massive waste problem. The production of most synthetic plastics requires hydrocarbons that are produced from petrochemicals derived from fossil oil and natural gas, a non-renewable source (Speight 2011). Currently, plastic manufacture utilizes ~4% of world oil and gas production, and it is expected to drive further increases in petroleum demand by 1-2% due to their large volume of manufacture (Hopewell, Dvorak et al. 2009). Landfilling and incineration of plastic waste are the two main routes to plastic waste management (Encinar and González 2008). In Australia, only 10% of waste plastics were recycled in 2006 (White and Hyde 2011). This means that large amount of fossil fuels from plastics has either been simply burned for energy recovery or buried in the ground. There is an urgent need for developing alternative avenues for recycling waste plastics. Our group at UNSW has carried out extensive research on the recycling of waste polymers as carbon resource in steelmaking including slag foaming and carbon dissolution from waste plastics into liquid steel at 1600°C; the effect of basic plastic characteristics such as chemical composition, structure, bonding network etc. was examined (Sahajwalla, Rahman et al. 2009)"

Jan 1, 2012