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By Ian Sherrell, Michael Pirie, Riddhika Jain

"Conventionally, direct reduced iron (DRI) mixed with char from rotary furnace discharge is cooled down before separating the char via magnetic separator. The DRI must then be reheated for further downstream processing (i.e. smelting). Outotec has developed the PyroMagTM specifically to conserve thermal energy during this separation process. DRI is cleaned by feeding hot particles directly after reduction onto a rotating surface just above a stationary magnet assembly. This allows hot feeding of the clean DRI to the downstream equipment which renders the entire process more energy efficient.Continuous testing of the PyroMagTM was performed to verify design and separation. Because the use of DRI/char was not practical for test use, the pilot plant testing was conducted using a magnetite/sand mixture heated up to and beyond the Curie temperature of magnetite. The separation was efficient for both cold and hot processing with recoveries varying from 98.6% to 99.74%. As expected, the recoveries decreased to as low as 83.99% as the temperature was increased beyond the curie temperature of magnetite (585°C). Long term separation was thermally efficient and sustainable.INTRODUCTIONMagnetic drum separators are widely used in the mineral processing industry. These low to high intensity magnetic separators are used to concentrate various magnetic material, such as iron ore, and less magnetic materials, such as ilmenite and garnet from silica and other contaminantsThere are multiple classes of magnetism based on the effect that each material displays while in and out of a magnetic field. In a simplified fashion, which is more appropriate for mineral processing, the magnetic susceptibility of a mineral is used to define it as being ferromagnetic, paramagnetic or nonmagnetic. In this respect, minerals with varying degree of magnetic susceptibility can be selectively separated with different types of magnetic separation equipment in different stages of a process flow sheet. The lower strength magnets are employed early in the process to remove highly magnetic fractions. Later stages utilize greater magnetic fields for capture of less magnetically susceptible material."

Jan 1, 2016

By J. Scrimgeour

"The word ""instrumentation"" has expanded from its original meaning, which in engineering perhaps referred to measuring apparatus alone. In its broadest form, it now includes sensors, display instrumentation, standard pack-aged controllers and, most recently, the use of stored program computers for on-line process control. The paper traces the evolution, in tutorial form, of the successive application of mechanization, measurement instrumentation, automatic control, central operating systems, programmed control, process computer control, direct digital control and, finally, hierarchies of computers used for process control and corporate management as a fully integrated business system. In the field of industrial minerals, the cement industry has seen the most widespread acceptance of these techniques. Computer control has been accepted as the way of life for the blending of chemical materials and for on-line control of the cement kiln. Accordingly, the cement application is selected for further presentation in the paper. This illustrates the trend progressing from control of single loops on process variables toward the objective of total control of the product quality. The economic justification for instrumentation, centralized control, automatic control and computer control is .discussed with reference to savings in fuel, maintenance, operating labour, depreciation, power and product quality improvements."

Jan 1, 1967

By F. Rashchi, A. Ghahreman, J. Moghaddam, S. Karimi

"In this work, the kinetics of ferric-ferrous redox reaction on a passivated sphalerite electrode is studied by the application of chronoamperometry method in 0.5 mol L-1 H2SO4 solution. The electrochemical behaviour of ferric and ferrous couple was investigated on two sphalerite minerals acquired from two different geological regions (Iran and Canada). The carbon paste electrode (CPE) of sphalerite was initially prepared and passivated in 0.5 mol L-1 H2SO4 solution and after reaching the steady-state condition, ferric and ferrous sulfate solution was added. The registered current density differences between the current density of the passivated electrode and that of the electrode in the iron salts added solution were interpreted for kinetics of ferric-ferrous reduction-oxidation reaction. The equilibrium potential for ferric-ferrous couple on sphalerites surface was about 500 mV vs. Ag/AgCl. The exchange current density (i0) for ferric-ferrous redox reactions on the sphalerite samples had the same magnitude of 10–6 A cm–2. The electrochemical impedance spectroscopy (EIS) measurements at 550 mV vs. Ag/AgCl illustrated that sphalerite oxidation was controlled by two charge transfer process in both of Fe-free and Fe-containing solutions. The charge transfer resistance remarkably decreased when Fe salts added to the 0.5 mol L-1 H2SO4 solution, owing to the ferric-ferrous redox reactions being the predominant reactions on sphalerite surface.INTRODUCTION Direct atmospheric leaching processes for sphalerite concentrates are performed by reduction of an oxidant (e.g. ferric ion and oxygen) and oxidation of sphalerite to zinc ions. Oxygen could be an oxidizing agent as well, but the concentration of oxygen is very low in the solution. The role of ferric ions is predominate in this oxidation (Babu, Sahu, & Pandey, 2002). The oxidation reaction for sphalerite in the presence of ferric in can be presented as follows (Lampinen, Laari, & Turunen, 2015):"

Jan 1, 2017

By Fazel G. Jahromi, Ahmad Ghahreman

"Atmospheric leaching of arsenical sulfide concentrates, and especially enargite leaching, is one of the major challenges within the current hydrometallurgy research area. One of the recent processes developed for sulfide ore treatment is atmospheric leaching in the presence of AF 5, a novel carbon based catalyst, in chloride media. The quantification of different ion concentrations during enargite and chalcopyrite leaching in the presence of AF 5 were measured and the copper recovery rates of 97% and 96% were achieved. The objective of this study is to shed light on the leaching mechanism of the sulfide minerals. Based on the speciation of iron and copper by different titration methods, the AF 5 catalyst first reduced ferric and cupric ions and then oxidized ferrous, cuprous and arsenite ions. The oxidation behavior of the catalyst enhanced the leaching results. The AF 5 catalyst also caused in situ precipitation of scorodite in leaching experiment. The speciation of ions in the chloride media were simulated by Phreeqc software and the dominant species in the leaching solution were determined.INTRODUCTION The hydrometallurgy of copper has been used for several decades and is still under development for more complex copper sulfide minerals due to their refractory nature. Most of the world copper reserves are in the form of chalcopyrite; and enargite is known as a major contaminant. Pyrometallurgical processing of enargite is problematic due to arsenic release and tight environmental regulations (Peacey, Gupta, and Ford n.d.). On the other hand, lower recoveries in the hydrometallurgical processes make most of these processes impractical. Several leaching processes have been developed for the leaching of copper sulfide minerals. Some of the common treatment methods for copper sulfide minerals are pressure oxidation leaching (POX), CESL, Activox, Albion process, atmospheric ferric sulfate leaching, Dynatec, Galvanox, and Hydro copper process (Barr, Defreyne, and Mayhew 2005; Conner and Anderson 2013; D.G. Dixon, Mayne, and Baxter 2008; Hyvärinen and Hämäläinen 2005; Palmer and Johnson 2005; Rohner, Bartsch, and Ngoviky 2012). Generally it is not viable to dissolve copper sulfide minerals at ambient pressure in mild acidic media and dissolution of these refractory minerals requires harsh conditions in the presence of oxidant materials (Biswas and Davenport 2002). Ferric ions have been used as an oxidant in different media in copper sulfide leaching processes. U. S. Bureau of Mines’ Reno Metallurgy Research Center in 1969 (Haver and Wong 1971) investigated ferric chloride leaching of chalcopyrite. Dutrizac and Macdonald (1972) studied ferric sulfate leaching of enargite. Based on this study, 50% of the copper was recovered at 80-85 ºC after 7 days of leaching. Cupric ions can also be used as an oxidant. Parker, Paul, and Power (1981) stated that cupric/cuprous couples are more effective than ferric/ferrous couples in chloride media because they are rapid and reversible. The Hydro Copper process leaches copper sulfide minerals in chloride solution catalyzed by cupric ions. In this process, copper dissolves as cuprous ions in presence of cupric ions (about 10 g/L) (Hyvärinen and Hämäläinen 2005)."

Jan 1, 2017

By Veronique Falmagne

"In 1987 the only knowledge available of the Ansil orebody was that it was high grade, deep and relatively small . High stresses were also anticipated because there had been rockbursts during shaft sinking and destress blasting had been necessary (Fig. 1). From the design, through the development and now in the mining stage, rock mechanics and microseismic monitoring have been used to maximize recovery and safety and minimize dilution. Examples are given of the use of a microseismic monitoring system in the early stages o f mining. This paper also presents a review of the mine's in situ stress measurement campaign, cable bolting practice and backfill procedure.The Design PhaseAfter the initial mapping and classification work, preIiminary numerical modelling was performed using assumed stresses of ov = oH and oH = 3ov• The empirical Mathew's analysis was then used to optimize stope dimensions based on geomechanics data available at the time (Bawden et 01., 1988; Falmagne, 1987; Potvin et 01., 1988). Because of high stresses predicted by numerical modelling and a brittle, strong and relatively unfractured host rock which was believed to be rockburst prone, it was decided to mine without temporary or permanent pillars. However, in order to satisfy production rates, the orebody had to be broken up into two horiwns separated by a triangular pillar (Fig. 2). The final mining sequence is shown in Figure 3.The Development PhaseAt this point, based on work accomplished to date, including mapping and observations from drifting and modelling, the following problems were identified: (1) flat backs in the hangingwall andesite were thought to be highly stressed; (2) flat backs in weak massive sulphide ore would also be subjected to high stress and be difficult to support; (3) the felsic dyke was noted as a "" stress raiser"" , because activity increased as drifts approached it; and (4) chlorite coating of joints in the hangingwall was thought to be an important factor in reducing their stability."

Jan 1, 1991

By N. Manopulo, J. Maier, L. Tong, C. Becker, P. Hora

The contribution presents a new finite element approach in which the common updated Lagrangian formulation is replaced by a spatial flow formulation applying a special arbitrary Lagrangian-Eulerian for-mulation (ALE). The description separates spatially the process in a die inside zone and in a profile zone. For the description of the inside zone, where the filling process occurs, a special Euler time independent mesh is applied. By this formulation the mesh has to be generated only once, which simplifies the generation of spatially optimized meshes. For mapping of the material flow during the filling process the method uses a flow surface traction method as applied in casting simulations. A further strength of the new method is the computational efficiency which allows the modelling of extrusion process with the highest complexity with a response time of 12 hours, which is important for the industrial optimization process.

Jan 1, 2015

By F. Mohamm

"Recent changes in regulations and scientific advances concerning selenium bioaccumulation have placed greater importance on non-biological treatment systems for selenium control. Mining wastewater contains hexavalent selenium (selenate) as the predominant aqueous species and possibly small amounts of tetravalent selenium (selenite). Non-biological removal of selenite is accomplished readily and cost effectively by ferric co-precipitation and adsorption using ferric oxyhydroxides sourced from ferric salts or iron anodes in electrocoagulation cells. Selenate on the other hand is difficult to remove. It is often incorrectly assumed that electrocoagulation is suitable for removing both selenite and selenate. Selenate removal efficiency by electrocoagulation is low and the amount of waste residue produced high. In contrast, BioteQ’s Selen-IX™ process removes selenate very efficiently and produces a much smaller amount of stable residue. The process combines selective ion exchange with electro-reduction of selenate in electrocells that physically resemble electrocoagulation cells but are designed and operated differently. This paper summarizes four years of pilot scale demonstration on a wide range of mine waters and discusses the key benefits and limitations of Selen-IX™. The pros and cons of combining ion exchange with electro-reduction in comparison to direct electro-reduction of selenate are also reviewed.INTRODUCTION Selenium in Mining and Mineral Processing Effluents Similar to sulphate and metals, selenium presence in mining and mineral processing wastewater originates from minerals contained in the mined deposits. Therefore, no organoselenium species are typically present in these kinds of waters and inorganic species including selenite (SeO32-), selenate (SeO42) and elemental selenium account for the majority, if not all, selenium present in these streams. Elemental selenium is not always present in mine water but is often contained in smelter wastewater. To comply with new environmental regulations, a successful water treatment plant must remove selenium from all these forms effectively and economically without generating by-products that are difficult to dispose of or manage. Elemental selenium can be dealt with using filtration or gravity separation in clarifiers often assisted by flocculants and/or coagulants. Mine impacted waters typically contain other forms of suspended solids which are removed from water in this way. Once the solids are removed, the selenium species that remain untreated are the dissolved forms. In mining waters this is mostly selenate with small fraction of selenite. In smelter wastewater, the majority could be selenite. It is well established that tetravalent selenium is readily removed from water by using ferric iron co-precipitation at pH > 4 (NAMC SWG, 2010). Ferric hydroxide/ferrihydrite solids act as the adsorbent for tetravalent selenium when it is in one of the ionic forms of biselenite or selenite. This treatment for tetravalent selenium is highly efficient. Therefore, tetravalent selenium removal is generally not an issue and is often easily incorporated into lime neutralization or unit operations such as electrocoagulation used for removing other metals present in mine impacted waters. Another option of dealing with tetravalent selenium is sulphide precipitation in acidic pH which produces SeS2 and can separate selenite from other metals and/or sludge produced at neutral to alkali pH."

Jan 1, 2017

By J. M. Goris

"Researchers at the U.S. Bureau of Mines are conducting research on cable-type ground supports to assess their material and support properties and to provide design criteria for implementing cable supports as a workable roof control system under various underground mining conditions. Much of this work involves laboratory assessment of the material and support properties of cable supports using both conventional and birdcage steel cables. Included in this assessment are single and double cables, effects of changes in embedment length on support strengths, water-cement ratios, use of breather tubes, and pumpability and water-bleeding properties of grouts.IntroductionSince cable supports were introduced in the early 1970s, considerable research has been conducted in laboratories and at mine sites to understand their behaviour. The U.S. Bureau of Mines began a laboratory evaluation project in 1985 at the Spokane Research Center (SRC) to study the behaviour of cables supports under uniaxial loads so that the effects of various cable support components, such as grout and breather tubes, could be identified. Other objectives were to compare the behaviour of various types of cables and grouts and to collect meaningful data for numerical analyses. Pull tests were conducted to determine how cables supports reacted under uniaxial loads and how they failed when ultimate loads were exceeded. Such data are essential for the development of numerical models for analyzing rock mass behaviour when the rock is supported with cables.Test ProgramBecause each cable support can be composed of either single or double cables as well as a breather tube, pull tests were designed to include a variety of samples containing these components. A series of samples containing a single conventional cable, a neat cement grout having a water-cement ratio of 0.45, and no chemical additives was selected as a standard (Table I). Then one component in the system, such as the presence of a breather tube, was changed, and results of tests compared to results obtained for the standard samples to determine what influence that component might have on the behaviour of the support system. If significant changes in test data occurred, they could be attributed to that one component. To control the quality of the samples, the physical condition of the cables and tubes were monitored closely, and compressive and tensile strengths as well as flow properties were determined for the grout used in each test series."

Jan 1, 1991

By C. Piribauer, E. Feichtenhofer, A. McEneaney

"As part of a major diversification project, RHI AG, through its plant in Drogheda Ireland, has developed a Caustic Calcined Magnesium Oxide (CCM) for use in the Cobalt (Co) & Nickel (Ni) hydrometallurgical extraction industry. In the course of the project, the company investigated the chemical and physical properties of a number of different Magnesia’s used in Co & Ni hydrometallurgy applications and has been able to determine the important parameters for a successful Magnesia for this application. A number of live plant trials have confirmed the results of this testwork and the company is now proceeding to produce this product in commercial quantities at Premier Periclase Ltd., the RHI AG plant in Drogheda, Ireland. This paper will outline the development work conducted by the company and highlight the important chemical and physical properties that make a successful CCM. Much of the research was conducted at the RHI Technology Centre in Leoben, Austria. In addition, a number of external laboratory studies were conducted on behalf of RHI AG. The result of this work has allowed the company to develop a Magnesia product with optimised properties for use in the Cobalt and Nickel hydrometallurgical extraction process.INTRODUCTION Premier Periclase is part of RHI AG, a globally operating supplier of refractory products, systems and services, headquartered in Vienna, Austria. The company produces Magnesia from seawater at its plant in Drogheda, Ireland. While the main focus is on production of refractory grade Dead Burned Magnesia for the steel industry, the plant also produces a number of different grades of Caustic Calcined Magnesia as well as Magnesium Hydroxide products. As part of a major project to diversify the company’s product base, the use of CCM in the Cobalt (Co) & Nickel (Ni) hydrometallurgical extraction industry was investigated. One of the company’s highly reactive grades of Caustic Calcined Magnesia was found to be particularly suitable for this application. In an effort to understand what makes a successful Magnesia for hydrometallurgy the chemical and physical properties of different Magnesia’s used in Co & Ni hydrometallurgy were investigated. This paper and conference presentation outlines the findings of this process."

Jan 1, 2017

By Ahmad Ghahremaninezhad, Denver H. Cowan

Much of today’s gold is locked within sulphide minerals. These sulphide minerals, including pyrite, need to be subjected to oxidative pre-treatment in order to leach the refractory-gold using traditional methods. Typically autoclaves employing high temperatures between 180?225 ºC, and extremely high pressures between 1,500?3,200 kPa, are used for the oxidative pre-treatment. However, the autoclaves themselves are very expensive, costly to operate and maintain, and produce excess sulphuric acid. This paper studies the atmospheric oxidation of pyrite in ferric sulphate solutions. In general, pyrite oxidation under atmospheric pressure can result in high elemental sulphur production, i.e. less acid generation. Activated carbon has displayed an ability to catalyze the process, achieving reasonable kinetics. The reaction kinetics were investigated by altering acidity of the leaching solution, temperature, catalyst ratio, sparged oxygen and agitation. A combination of X-ray diffraction, scanning electron microscopy, optical microscopy, X-ray fluorescence, inductively coupled plasma mass spectrometry (ICP-MS), and atomic absorption spectroscopy (AAS) were used to monitor the kinetics of the process and elemental sulphur yield. The purpose of this investigation was to determine optimal operating conditions that maximized kinetics of the atmospheric oxidation while maximizing elemental sulphur yield.

Jan 1, 2015

By Pura Alfonso, Teresa Escobet, Hernan Anticoi, Eduard Guasch, Josep Oliva, Sarbast A. Hamid

"The liberation modelling of mineral particles using mineral liberation analysis have been used in the past to model comminution and concentration processes. In this work this concept has been taken a little further, using comminution and concentration for applying the mineralogical characteristics of particles. This approach is shown using the image analysis, mineral liberation analysis and the distribution density functions for liberation modelling. The work focused on the effect of comminution on mineral liberation for liberation modelling. To model this, effect the mineral liberation of the particles using distribution density and the cumulative distribution was linked to the image analysis of the ore particles. These properties have been estimated by statistical measures such as the distribution density and liberation grade, which were extracted from MLA data and images analysis, using proper image analysis and techniques based on MATLAB software. A comparison of different tungsten ores of liberated particles, has been introduced and evaluated by estimated results and image analysis.INTRODUCTION The chief economic minerals of tungsten are wolframite [(Fe,Mn) WO4] and scheelite(CaWO4), and approximately two-thirds of the world tungsten reserves consist of scheelite deposits (Lassner and Schubert, 1999). Tungsten has unique properties and is widely used in various industrial high strength and high temperature applications. It occurs coarsely aggregated in low grade ores. Most of tungsten ores, particularly scheelite, wolframite and ferberite, occur in deposits with very low content of WO3 (0.1–2.5%) that is not economically viable to apply directly metallurgical methods to extract tungsten (Martins, 2014). Tungsten is considered as a critical metal by the European Union by the economic importance and also the high supply risk (European Commission, 2014; Chakhmouradian et al., 2015).Currently, scheelite is playing an increasingly important role in tungsten industry because the mineral reserve of wolframite is getting depleted after gradual exploitation and utilization (Min et al., 2016). In mineral processing, the liberation of valuable mineral from the gangue determines the efficiency of subsequent separation processes. The liberation characteristics of an ore are primarily dependent on its texture, the association of mineral in the host matrix of gangue minerals, and to some extent on the grinding process (Zhang and Subasinghe; 2013)."

Jan 1, 2017

By J. Worden, D. Hughes, S. Smart, H. Zughbi

The enterprise wide optimization (EWO) of steelmaking and manufacturing is a multi-level, hierarchical problem which spans higher level corporate planning and scheduling through to the lower level operations of processes that produce and manufacture steel. External and internal system dynamics combined with process unit co-ordination create complex changing circumstances for the enterprise. This paper presents a scoping study as a prelude to enterprise wide considerations at an integrated steelworks to help inform the choice of appropriate model types and optimization techniques. The hierarchical, multi-level structure of the enterprise and the important spatial-temporal scales to consider are defined. Insights into the system were gained by analyzing a large set of dynamic operational data. Over two years of data were subject to both univariate and multivariate analysis with the intent of understanding the complex interrelations of energy flows on site, the inherent system dynamics of the energy network, system operational modes, aspects of planning and scheduling and the coordination between major processing units. This analysis was further used to evaluate the performance of the system in regards to energy utilization and understand the potential economic benefits derived from improved operational decisions.

Jan 1, 2015

By F. C. Robles Hernandez

This paper presents the results of the electromagnetic semi-solid treatment of the 319 aluminum foundry alloy, Various levels of structure modification were achieved controlling the AC current used to create the Electromagnetic Field, thus manipulating the intensity of the field, The level of grain refinement, partial modification of the Al-Si eutectic, as well as cellular dendrites were observed, A quantitative analysis of the structure was performed using Image Analysis (IA) techniques. In addition a novel Thermal Analysis methodology was developed for the on-line determination of the microstructure modification level.

Jan 1, 2004

By R. B. Nourse, S. F. Gwynn-Jones, S. Nikolic, M. L. Bakker, I. McDougall, H. Joubert

"Tenova Pyromet’s core furnace knowhow and expertise has been built within the ferroalloy and nickel/platinum group metal (PGM) industries with the supply of electric furnaces for a number of nickel/PGM operators, including Eastplats, Lonmin, and Anglo-Platinum in South Africa, Mineraçào Serra Da Fortaleza in Brazil, and Norilsk Nickel in Russia. Tenova Pyromet has also supplied the electrode columns and associated electrode equipment – the heart of the electric furnace technology – for cobalt recovery in furnaces in Zambia and the Democratic Republic of the Congo. The quantity and size of projects undertaken by Tenova Pyromet has provided the opportunity to continuously improve furnace designs and the scope of supply, culminating in the most recent nickel/PGM project currently under construction at Northam Platinum. Through this innovative culture, the Tenova Pyromet Base Metals Initiative was formed in 2015 to develop the Novasmelt™ Furnace; a next generation optimised Top Submerged Lance (TSL) furnace design. The combination of Tenova Pyromet’s advanced Novasmelt™ product with our industry leading electric furnace technology are discussed with reference to applications for nickel and cobalt production. Flowsheet arrangements are compared summarising potential capital savings, operating requirements and achievement of downstream product quality.INTRODUCTION Tenova Pyromet is a leading player in the field of smelting technology development and equipment supply. Tenova Pyromet is the result of the union of three furnace suppliers under the Tenova banner: Techint Technologies (Tagliaferri), Core Furnace Systems Corp (Lectromelt) and Pyromet Technologies. The furnace experience of the combined groups dates back over a century with the earliest Lectromelt going into production in the early 1900s. Throughout the modern era, Tenova Pyromet has developed a reputation for providing dependable innovative smelting technology, high quality equipment and sound project execution to a worldwide client base with customer plants operating in Europe, Southern Africa, North America, South America, Russia, Kazakhstan, the Middle East, South Korea, and India. Tenova Pyromet’s core knowledge and expertise was developed in the South African ferroalloy, base metals, and platinum group metals (PGM) smelting industries. Tenova Pyromet has spent considerable effort on development and has contributed significantly to improve the state of the smelting industry. Tenova Pyromet’s electrode columns have become widely renowned and are now providing significant benefits, especially in increased furnace availability, to many smelting furnace operators. The electrode column is the heart of the furnace as it delivers a controlled amount of electrical energy, at an optimum depth in the burden/bath, to the smelting process. Every furnace is custom designed to the specific operating range and optimal operating point of that furnace and process"

Jan 1, 2017

By Jean-Paul Drolet

"The ultimate aim of the Law of the Sea Conference, held under the auspices of the United Nations, is to ensure that all aspects of the use of the sea are covered by international law. The question facing the nations of the world can be stated as: "" Who will control and benefit from the use and the wealth of the sea?""The United Nations Conference on Law of the Sea - known as UNCLOS - which reconvened in New York during the latter part of August 1978 was the third such Conference in the UN's history. The concepts of sovereignty over the territorial sea and freedom on the high seas have remained fundamental to the international law o f the sea until our time. The legal regime based on these two concepts developed initially from state practice meant that the unilateral actions taken by one or more countries were eventually accepted and followed by others.It was not until 1958, during the first Geneva Conference on the Law of the Sea (pursued in a second Conference in 1960) that the Law of the Sea was codified and modified to a certain extent by the then independent nations of the world in the four multilateral conventions on territorial sea and contiguous zone, continental shelf, high seas, and fishing and conservation of living resources.A third Conference got under way many years later when the members of the UN met in New York at the end of 1973 for preliminary discussions . This meeting stemmed largely from the need to fill gaps in existing international legislation which did not cover the new uses of the sea. The Conference was subsequently reconvened a number of times - in Caracas (1974), in Geneva (1975) and twice in New York (1976) for what was called "" substantive negotiating sessions."" A sixth session was held in New York in 1977; a seventh, held in Geneva at the beginning of 1978, recessed and reconvened in New York at the end of August 1978. This is what is referred to, in international jargon, as the seventh session of the Third United Nations Conference on the Law o f the Sea. The following dates are the principal markers of a saga which began some twenty years ago with the purpose of regulating the use of the oceans."

Jan 1, 1981

By T. Johnson, K. Lambrych, D. Kelley

Materials for construction of equipment used in hydrometallurgical plants are selected based on a combination of their ability to perform as required in aggressive process environments as well as their cost. As a material of construction, fiber reinforced plastic (FRP) has been shown to provide equal if not improved durability relative to alternative materials such as corrosion resistant alloys at a considerably lower cost. This is particularly true in the case of equipment used in acid leaching processes for copper, cobalt, nickel and rare earth elements. The selection and extensive use of FRP over alloys in new hydromet plant construction in North and South America illustrates this advantage of FRP effectively. This paper will compare corrosion performance and cost of plant equipment fabricated with stainless steel alloys and FRP made with Epoxy Vinyl Ester thermoset resins. Real world case histories for FRP piping, storage tanks, extraction vessels, and electrowinning cells combined with laboratory based corrosion studies will be reviewed to demonstrate how FRP materials are selected for hydrometallurgical equipment.

Jan 1, 2015

By W. Curlook, L. M. Pidgeon

THE PURPOSE of this investigation was to study part of the ternary system Co-Fe-S. Jensen ( 1) established the solubility limits of sulphur in pyrrhotite. The compound with 61.7 per cent Fe, corresponding to a formula Fe12S13, was found to melt congruently at l,192°C. Hulsmann and Weibke(2) determined the Co-S phase diagram from O to 35.2 per cent S. The solubility limits of sulphur in the com-pound Co(l-x)S were not determined. The initial object of the present in-vestigation was to determine the composition at which the compound Coci-xiS melted congruently. Once this was ascertained, it was decided to investigate the ternary system Co-Fe-S from the region of 100 per cent Co(1-x) S to the region of 100 per cent Fe12S13.

Jan 1, 1953

By Nessetech Consulting, L. A. Cisternas, E. D. Galvez, S. H. Kuan, L. H. Saw

"In Malaysia, there were two rare earths processing plants namely Asian Rare Earth (ARE) and the Malaysian Rare Earth Corporation Plant (MAREC) in Perak, which were operated until 1992 and were subsequently closed due to problems pertaining to disposal of large amount of radioactive waste. Recently, Lynas Advanced Materials Plant (LAMP) has become one of the largest rare earths processing plant in the world producing rare earth elements (REE) in Gebeng, Pahang. The primary raw material is lanthanide concentrate (LC) which is imported from Mount Weld mine in Australia and shipped to Malaysia. LC is produced from lanthanide ore after mining and mineral processing. The ore has a lower impact than Bayan Obo, Mountain Pass and adsorbed clay deposits, given the small footprint of the mine itself and the remoteness of the location. The type of ore being mined (rare earth phosphates: carbonatite, monazite) may have higher thorium content than bastnasite ore from the Chinese or American mines but still far below radiation concerns. This paper was written to review the processing flowsheet at the Lynas Advanced Materials Plant (LAMP), the environmental impact associated with the processing of the said ores and the sustainability of the operation.INTRODUCTIONRare earth minerals are one of a set of 17 minerals or chemical elements which consists of yttrium and scandium, as well as the 15 lanthanide elements (lanthanum, cerium, praseodymium, neodymium, promethium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, and lutetium). Despite their importance, rare earth minerals rarely exist in economically viable concentrations and they are usually difficult to extract. Rare-earth minerals create strong magnets when added to magnetic elements such as iron, and are useful for the production of electronics systems as well as electric cars. They are also used extensively in automotive catalytic converters, fluid cracking catalysts in petroleum refining, wind turbines, phosphors in colour televisions and flat panel screens, displays for mobile phones and laptops, rechargeable batteries, and various medical devices. The elements are typically split into two subgroups: the cerium sub-group of ‘‘Light’’ rare earth elements (LREEs) which includes La to Eu and the yttrium sub-group of ‘‘Heavy’’ rare earth elements (HREEs) which include the remaining lanthanide elements, Gd to Lu, including yttrium (Gupta and Krishnamurthy, 1992; Jordens et al., 2013; Trifonov, 1963). Scandium, however, when it is classified as a rare earth element, is not included in either the LREE or HREE classifications (Gupta and Krishnamurthy, 1992; Jordens et al, 2013). Half of the world’s 110 million tons of reserves exist in China while other sizable deposits are found in Russia, United States, Brazil, India, Australia, Canada, and Greenland. The countries known to be actively mining REE are China, Russia, India, Brazil and Malaysia (Hao et al., 2015). Among these countries, China has the largest REE production, accounting for more than 93% of global supply (Yap, 2015). The critical metal report (Moss et al. 2011) listed 14 economically vital raw materials that are prone to supply disruption and concluded that supply disruption would threaten the goal for cleaner transport and sustainable energy since rare earth metals are used in products using green technology, such as hybrid/electric vehicles, carbon capture systems, wind power generation, low-energy lighting, and energy efficient flat-screen displays."

Jan 1, 2016

By K. Baris

Methane (CH4) present in coal seams, generally known as Coalbed Methane (CBM), Coal Mine Methane (CMM) or Coal Seam Gas (CSG), is a major energy source, as it is the primary constituent of natural gas. At the same time, released methane is a potent greenhouse gas (GHG) and a major safety hazard in underground mining operations. Therefore, a considerable effort has been undertaken to develop coal bed methane extraction and utilization technologies that can achieve both environmental and safety benefits. Countries with significant coal reserves and gassy seams, i.e., USA, Australia, Canada, China, India, Poland and Germany have developed mature methodologies and practices to extract, before and during mining, and utilize significant amounts of methane from coal seams. Nevertheless, on a global scale, methane recovery remains untested and many technical and economic challenges require urgent attention. The research presented in this paper, sponsored by the United States Environmental Protection Agency (EPA), is focused on the Zonguldak Basin, the only hard coal region in Turkey. The basin is known to contain very gassy coal seams and consists of three major regions: Armutcuk, Zonguldak and Amasra. Among the three, the Amasra coalfield is considered as the most favorable for CBM recovery, as it comprises of deeper coal seams and where a private company, Hema Enerji A.S. (Hema) is already developing coalbed methane production facilities. This study aims at developing a reservoir model to predict the potential CBM recovery from the CBM-2 well, the only producing CBM well drilled by HEMA Enerji A.S in the Amasra coalfield. History matching was utilized to model the 15-day production data and uncertainty analysis was performed to estimate the optimum values for the reservoir parameters. The produced model yielded an average production rate of 143 m3/day for 10 years. The total amount of CH4 to be produced during this period was 0.53 million m3. Furthermore, the total amount of GHG to be avoided was estimated at 6585 tCO2e.

Aug 1, 2013

By Bob Drew, Goran Vukovic, Bojan Zivanovic, Klaus Gamweger

Reaction bath temperature is a major factor in processing liquid metals and in many applications where a balance between process duration and temperature has to be found to run a procedure efficiently. Also extremes of temperature can decrease the output of a process if too cold or even make it impossible, conversely overheating can be detrimental to both the product and furnace integrity. With the help of the new online temperature measurement system very accurate monitoring of the process is possible in contrast to the current routine practice where the temperature is measured periodically with dip thermocouples. The system works with a digital, fiber optic pyrometer, which is embedded in a refractory housing. Installation in the lining is possible below liquid level as nitrogen is blown to keep the system open and to ensure continuous sight from the optical head of the pyrometer to the molten metal through the tuyere. This permanent temperature measurement gives optimal process control with the potential of taking appropriate actions at an early stage enabling proactive process control. Therefore energy savings and even process endpoint detections can be realized.

Jan 1, 2015