Search Documents

By S. Kashani-Nejad

The kinetics of the thermal decomposition of samples of Mg2(OH)3Cl.2H2O that were obtained by a novel leaching technique applied to a commercial magnesium electrolysis feed were investigated under ambient atmosphere. Thermogravimetric (TG) Analysis showed that decomposition of Mg2(OH)3Cl.2H2O exhibited a single intermediate stage wherein crystalline water was lost at roughly 108 °C. Conversion of the resulting Mg2(OH)3Cl to MgO, HCl and 1120 occurred at temperatures above 398 °C. Thermal decomposition of anhydrous Mg2(OH)3Cl was seen to be consist of two stages. Both stages exhibit first order kinetics with respect to the weight percent of Mg2(OH)3Cl remaining in the sample. However, the rates of decomposition in the two stages were significantly different. Detailed analysis of the kinetic data suggested that the rate of decomposition of Mg2(OH)3C1 was controlled by the rate of removal of the gases released. The change in decomposition rate during the course of the experiments was explained by HCI being released in stage 1 and followed by release of H2O in stage 2.

Jan 1, 2004

The principles and utility of in-situ coal gasification are discussed, and a first field test conducted by the Alberta Research Council in 1976 near Forestburg, Alberta, is described. The test was carried out in a 12-ft subbituminous coal seam under 60 feet of cover. Within this seam, a 30 by 60-foot block , containing approximately 650 tons of coal, was delineated by four injection/production holes which were oriented to take advantage of the natural fracture system in the coal. Linkage between holes was established by reverse combustion and gasification was accomplished by injecting air into the ignited coal. No steam was injected but operating pressures were adjusted to utilize formation waters for partial carbon -steam gasification. The coal gasification runs lasted six weeks and gasified an estimated 900 tons of coal ,' during sustained periods of gasification, a fuel gas with heating values of between 110 and 150 Btu/scf was obtained. Plans are now being developed for excavating the test site and inspecting the subsurface cavities created by gasification.

Jan 1, 1977

By Laura A. Sanders

Mineral scale formation is prevalent in numerous mining operations. Such scale formation can occur in the direct-contact heat exchangers ahead of an autoclave. In these heat exchangers, the incoming slurry comes into contact with steam in a stage-wise fashion, which is re-circulated from the downstream flash vessels to heat the slurry in stages ahead of the autoclave. Calcium sulfate scaling causes severe problems in mining operations where increased temperatures are involved due to rising temperatures promoting calcium sulfate scaling through a decreasing solubility. In a number of these operations, the scale formation can occur in the presence of mineral solids, where fine-grained charged particles are at concentrations in excess of 35%. Scale prevention is not difficult in standard aqueous systems; however, the presence of solids leads to significant deficiencies in the prevention of scale due to the adsorption of the polymer onto the charge solids instead of the polymer interaction with the scale. Therefore, a technical solution to prevent mineral scale build up occurring in presence of pulp slurry in mining operations is needed. Several novel antiscalant technologies were developed and evaluated which provided a substantial improvement in the scale prevention in such systems.

May 1, 2013

By Clemens Kuhnert

"Nickelhütte Aue GmbH is specialized in the recycling of waste materials containing non-ferrous metals. We treat nickel, copper, cobalt, vanadium, molybdenum and precious metal containing materials like spent catalysts, ashes, dusts, grindings, liquids, slurries and sludge's as long as they contain one or a combination of the above mentioned metals. In our pyrometallurgical works we produce non-ferrous metal concentrates suitable for further treatment in our hydrometallurgical plant where we refine Ni-, Cu-, Co- and V-chemicals. Our production is based on synergy effects due to the combination of pyro- and hydro-metallurgy. As an example we can mention our heat recovery system and internal recycling of by-products. Furthermore, the use of alternative fuels instead of fossil fuels contributes to the economic and environ-mentally friendly treatment system.INTRODUCTION Nickelhütte Aue GmbH (NHA) can look back on nearly 400 years of tradition as a pyrometallurgical works and recycling company. The existence since its foundation in 1635 as a blue dye works shows responsible and successful action in the past. Therefore, we see highest customer service, minimization of interferences with nature by closing material cycles and maximized health and occupational safety protection by avoiding injuries and diseases, still as our future duties. These duties are evaluated and monitored by an integrated management system that meets the standards of DIN EN ISO 9001, 14001, 50001 and BS OHSAS 18001. We commit ourselves to the observance of all juridical and customized demands. The management and the department managers perceive their model function. We require responsible action from all employees. To protect the continuity of our enterprise, we will also perform in future continuous improvement of products and their quality, as well as steady progress in the areas of environment protection, health protection and industrial safety. Equally the effectiveness and propriety of the management system is checked and developed regularly. In order to obtain the objectives resulting from this policy, our company determines activities and measures by involving all employees."

Jan 1, 2017

By Daan Maijer, Wade Marquardt, Robert MacKay, Steven Cockcroft, Farzaneh Farhang Mehr

"To comply with the new Corporate Average Fuel Economy (CAFE) standards, the automotive industry is aiming to reduce weight and increase the power and efficiency of small displacement engines through the application of forced induction technologies. As an example, there are now several 2.0 litre turbocharged engines in production, producing in excess of 240 hp. To meet the need for improved fatigue properties in the engine blocks used in these high-output engines, a new water-cooled chill technology is under exploration at UBC in partnership with General Motors and Nemak. A series of experimental techniques were used to assess the capability of the new chill to extract heat from an A319 casting in the vicinity of the main bearing bulk head. The results show that this method has the potential to achieve a reduction in secondary dendrite arm spacing thus meeting the new microstructural specifications for these engines.INTRODUCTION The automotive industry is working to meet the stricter efficiency requirements laid out within the CAFE (Corporate Average Fuel Economy) regulations (Bastani, 2012; Cole, 1995; Mackay, 2011; Miller, 2000), while at the same time not sacrificing performance. One approach is to increase the use of lightweight materials, which leads to a decrease in the overall vehicle weight and fuel consumption (Cole, 1995; Mackay, 2011; Miller, 2000). Other approaches include smaller displacement engines and gas-electric hybrid drivetrains. However, one trend that is becoming clear, is a greater emphasis on force induction gasoline engines. This allows for weight reduction to be achieved with smaller displacement engines without sacrificing performance. One consequence of this approach is that the engine block materials are subject to higher in-service thermal and mechanical cyclic loads (Cole, 1995; Miller, 2011; Heysler, 2001) The fatigue properties of an alloy are strongly affected by a number of the, as-cast, microstructure features including, Secondary Dendrite Arm Spacing (SDAS), porosity and eutectic lamella spacing (including intermetallic ß-Al5FeSi platelets) (Mackay, 2010a; Mackay, 2010b; Viet-Duc, 2015; Casellas, 2005). It is generally accepted they can act as fatigue initiation sites and that a reduction in their size will result in an improvement in fatigue performance. For a given alloy chemistry, one of the key parameters affecting the length scale of all three is cooling rate (Mackay, 2000)."

Jan 1, 2017

By P. Müller, W. J. Przybylowicz, V. M. Prozesky, D. de Bruin

"Abstract -The common style of gold mineralization in the Basal Reef and other auriferous conglomerates of the Witwatersrand Supergroup comprises clusters of gold grains occurring interstitially to quartz and pyrite pebbles as well as gold accumulations attached to the surface of and infilling hairline cracks and fractures in round, compact, detrital pyrite. The latter textural association is generally interpreted as a result of remobilization of originally detrital gold during regional metamorphism and related hydrothermal fluid circulation. There is general agreement that, although gold solubility was Iow, ore modification occurred during the metahydrothermal event, but uncertainty exists about the magnitude and scale of gold remobilization .Micro-textural and chemical investigation of compact round pyrite and associated gold accumulation has established that gold is preferentially deposited on chemically heterogeneous pyrite surfaces. Combinations of alternating high- and low-As zones in pyrite result in mixed np-type conductivity accompanied by electron exchange and the reduction-driven deposition of gold at the cathode. This mode] does not explain gold accumulations which are not immediately linked to chemical heterogeneities and it is inferred that an additional control on the deposition of gold was exerted by physical defects which lead to zones of increased charge density and/or areas of focussed conductivity. The inferred precipitation mechanisms suggest that submicrocopic physical and chemical controls are the important factors that determined the sites of gold nucleation and that precipitation mechanisms based on physicochemical changes of the hydrothermal system were not involved. The Basal Reef contains on average close to 5% of round, detrital, chemically zoned pyrite which provides a large number of electrochemically active pyrite surfaces. The extremely effective electrochemical precipitation mechanism together with the low solubility of gold in Witwatersrand fluids is the main reason for the spatially restricted remobilization of gold in the conglomerate reefs."

Jan 1, 1994

By F. R. Nogas

"Because of the elements of uncertainty and instabilitp associated with single-enterprise communities, there is increasing interest in the alternatives to developing additional new communities of this nature. Gulf Minerals Canada Limited has chosen a unique alternative means to accommodate employees at a new uranium mine/mill complex at Rabbit Lake in Northern Saskatchewan. Gulf has adopted a fly-in program which moves their staff from a 450-mile radius, in and out of the on-site facilities, on a 7-day rotation."

Jan 1, 1976

By R. F. Tylecote

"The closure of the iron and steel making plant at Consett in Durham in 1980 marked the end of an era-a long era in the world's iron and steel making history. Iron had been smelted in the Tyne-Wear area of the United Kingdom since before the Roman period, but apart from evidence of smithing in the Roman period, the historical evidence for iron production on a large scale dates from the 14th century.The paper describes sites in the area that first worked the bloomery process and then, in the 16th century, as did most of Europe, graduated to the blast furnace process. The main emphasis is on the early introduction of coal to iron making at the end of the 18th century and the use of the steam engine to render integrated sites possible.IntroductionIron has been smelted in the Tyne-Wear area of the United Kingdom since before the Roman period, but apart from clear evidence of smithing in the Roman period, the historical evidence for iron production on a large scale dates from the 14th century. Like many other countries, the United Kingdom benefitted from the visits of foreign observers, such as Jars, Svedenstierna, de la Houliere and Dufrenoy, who left detailed records. In modern times, information gained from excavations of iron and steel making sites has supplemented the historical record.Natural ResourcesUp to the end of the 19th century, the industry was wholly dependent on its own resources. Iron ore, limestone, wood, coal and water power were all found a short distance away from the main valleys of the Tyne and Wear. The main sources of iron ore were the coal measures, with rider ores from the lead vein s in Alston and Weardale, and carbonate ores from shale horizons in the Carboniferous limestone. Good coking coal was available from West Durham and reasonable coal from the Tyne valley and Northumberland limestone. Limestone was plentiful."

Jan 1, 1983

By E. T. Turner

Introduction 1n assembling material for this paper on Wood Refuse Burning 1 turned first to the records of our early studies of the problem in order to learn how and why certain basic decisions were arrived at and also how it came about that the completed central steam plant differed so much from the original plans. It may be of interest, therefore, to outline the engineering problems as they presented themselves in the early part of 1948, and to indicate the economies involved. Although the principle of using wood refuse as boiler fuel instead of burning it to waste was quite sound, and in fact the practice had been in use for a long time in the boilers of many lumber companies, there was some guesswork as far as Hollinger was concerned in deciding how best to handle the large quantities of wood refuse involved and as to the type of boiler equipment necessary to .burn it efficiently. These problems will be examined first. Hollinger Boiler Equipment in 1948 Hollinger had four separate boiler houses, at Main, No. II, and No. 19 shafts, and a small unit at the compressor plant for heating purposes. Main and No. Il boiler houses operated all the year round; No. 19 and the compressor plant only in the winter. At Main there were four 36-year-old HRT boilers with total available h.p. of 500, at No. II, three 30-year-old HRT boilers with 195 available h.p., and at No. 19 two old field-type locomotive boilers capable of producing 95 h.p.

Jan 1, 1951

By Grant J. Goddard

"The Iron Ore Company of Canada (IOC) has been in operation for over 30 years. Today, and in the future, technology and its application will play an ever more critical role in the company’s business success.The Carol Mining and Concentrating (CMC) division of IOC is energetically applying technology today to enhance performance and results, and is aggressively exploring opportunities to apply technology to support improved business results in the future.A critical area of focus is the application of technology to maintenance management performance. CMC has taken a “back to basics” approach to the fundamentals of maintenance management in 1995 and 1996. In parallel, the mine is aggressively implementing its Vision 2000 maintenance integration plan. This plan is targeted at levering the energies applied to sound maintenance management fundamentals as the company moves to a fully condition based maintenance approach.This paper discusses some of the strategies, key technologies and objectives of theVision 2000 maintenance integration plan at the mining operations of IOC."

Jan 1, 1996

By A. Banerjee, J. P. Weiler, J. Jekl, J. T. Wood, R. Berkmortel

"The work presented here is part of an ongoing project designed to develop predictive capabilities of the local mechanical properties, and thus, structural behaviour of a thin-walled high-pressure die-cast AM60B magnesium alloy component. This work focuses on developing correlations between process parameters and local microstructure. Numerical simulations of the die filling and solidification behaviour of the AM60B component were used to estimate local process parameters such as solidification rate, temperature gradient, filling velocity, etc. These estimated parameters were used to establish semiempirical correlations with measured VALUES (of the local microstructure measured in regions throughout the component of different solidification conditions. INTRODUCTIONHigh-pressure die-cast magnesium alloys are experiencing increasing use in structural automotive components. A strength-to-weight ratio comparable to steels and its ease of castability allow for these alloys to be utilized in such capacities as instrument panel beams, seat and door frames, and engine cradles, among others (Gjestland and Westengen, 2007). However, the current use of these alloys is limited due to variations in local mechanical properties. These local property variations restrict part designers to assume lower than actual properties, resulting in larger sections, thus diminishing the light-weighting advantages of magnesium alloys. If these local property variations could be predicted, part designers would be able to optimize die-cast magnesium alloy components and fully take advantage of the light-weighting capacity of these materials.The work presented here is part of an ongoing project aimed at developing predictive capabilities of the local mechanical properties, and bulk mechanical performance, from variations in local microstructure, and ultimately from local process parameters in die-cast magnesium alloys. This project, unique in its nature, is based upon the results determined from fifty sequentially cast AM60B magnesium alloy instrument panel beams provided by Meridian Lightweight Technologies (shown in Figure 1)."

Jan 1, 2012

By J. Lammers, D. Adams

Most pressure oxidation operations introduce oxygen through a large multi-use nozzle in the vapour space of the autoclave. Sparge pipes extend inside the vessel to the point of discharge below the compartment agitator. However, two zinc pressure leach operations have successfully used a bottom entry oxygen sparge system for a number of years. Recently, the concept has been used in a whole ore gold pressure oxidation operation as well as a copper pressure leach plant. Both of the latter operations also introduce cooling water for temperature control through the same sparge pipe. This paper addresses the benefits of the bottom entry system with regards to autoclave performance and the positive effects on agitator performance.

Jan 1, 2004

By M. Sukhram

In the year 1992, T.A. Utigard published a paper titled "The measurement of the heat-transfer coefficient between high temperature liquids and solid surfaces." In that work, he instrumented an agglomerate of materials with thermocouples to infer the heat transfer coefficient of a high temperature liquid on a solid. The purpose of that research was to help in the design and operation of metallurgical reactors. Since that time there have been many researchers that have worked to characterize heat, mass, and momentum transfer phenomena in high temperature metallurgical processing operations. This paper presents results from the author’s experience with instrumenting thermocouples in copper elements coated with carbon to infer velocity of high temperature liquid metals. It also presents a methodology to determine velocity of a high temperature liquid by inferring the local heat transfer coefficient at a solid-liquid interface

Jan 1, 2015

By Seong-Ho Ha, Shae K. Kim, Young-Ok Yoon

In the this study, surface segregation of Mg and Ca with Mg addition range from 5 to 10wt% in Al-Mg alloys with Mg+Al2Ca master alloy and its effect on the oxidation resistance were investigated. The addition of Mg+Al2Ca master alloy as the Mg alloying element led to the surface enrichment of Mg and Ca during high temperature oxidation. As a result of the oxidation test by TGA, the oxidation resistance of all the examined alloys was significantly improved with increasing Al2Ca content. The weight change of Al2Ca added Al-5Mg and Al-7.5Mg alloys indicated the complete oxidation resistance during the whole oxidation test time, while a slight weight increase was shown in the case of Al-Mg alloys even with Al2Ca addition. The improvement of the oxidation resistance in Al2Ca added alloys may be attributed to the formation of the protective oxide layer mixed with CaO and MgO on the surface.

Jan 1, 2015

By Michel Lefebvre, André Piché

Every organization performing R&D is faced with the challenge of introducing new technologies to its operations. Difficulties must be overcome if companies are to realize the benefits anticipated from such developments. This paper outlines the difficulties encountered in transferring to operations various technologies developed at the Mining and Exploration Division of the Noranda Technology Centre. The approach used in the selection of a privileged partner for the technology transfer, the criteria motivating the choice and the process followed to establish the partnership are presented.

Jan 1, 1997

By V. Gregoire

THE DEVELOPMENT by the Iron Ore Company of Canada of the Quebec-Labrador mining project, which eventually led to 'Iron Ore in 1954', involved, from the start, several distinct undertakings. Among them, the most important were: The construction of a 360-mile railway, linking Knob Lake with Seven Islands. The erection of a railway terminal, and harbour facilities, at Seven Islands itself. The building of an entire townsite at Schefferville (formerly Knob Lake) The construction of two hydroelectric plants; and, finally, The development of a sufficient number of orebodies to enable a production of 10 to 15 million tons of ore a year. Since these phases of the project have already been the subject of previous discussions, this paper will not elaborate further on them but will rather concern itself with a brief outline of the Company's current mining practices.

Jan 1, 1958

By H. J. Chalmers

THE H.B. MINE and concentrator are located in the Nelson Mining Division of British Columbia, on the north side of the Sheep Creek valley about seven miles southeast of the town of Salmo. It is an operation of The Consolidated Mining and Smelting Company of Canada, Limited (Cominco), which has its metallurgical plants at Trail, about 25 miles west. The property was originally staked about 1907 by Horton and Benson, whose names are commemorated in the designation "H. B." Up until 1927, a considerable amount of development work was done in the upper levels by various companies. Cominco purchased the ?property in 1927 and carried out intermittent work until 1946. Following this, an extensive surface diamond drilling programme and a subsequent underground exploration were undertaken. Sufficient ore was outlined 'to warrant the construction of a 1,000: ton concentrator. This was started in April, 1952, and completed by the spring of 1953. However, because of adverse base metal market conditions, operation was deferred until May, 1955.

Jan 1, 1957

By J. Convey, S. L. Gertsman

"THE EXPANSION of steel capacity is seldom spectacular. It may be for this reason that the remarkable progress made in Canada has not been generally recognized. In 1950, Canada's output of steel ingots amounted to 3,270,000 tons ( l ), which is a ll8 per cent increase over the tonnage produced in 1939. It can therefore be readily seen that Canada's growth curve for steel production is climbing at a rate paralleling her growth as a nation. It is by no means •an exaggeration of its importance to consider the steel industry as the cornerstone in the economic structure of Canada's manufacturing activities. From the humble diaper pin to the giant members of massive bridges, fortifications, and other steel structures, steel accompanies us as a necessary and inescapable companion in our journey through life. The Age of Steel has a literal meaning, and refinements in the manufacture of the products of steel are adapting it to more and more varied uses as time passes.The integrated iron and steel works of Canada fall into two natural geographical divisions. One has its base on the Great Lakes and draws its supply of •coal and some of its ore from the United States. In this division lie the works of the Algoma Steel Corporation, at Sault Ste. Marie, at the junction point of lakes Huron, Superior, and Michigan; and the works of The Steel Company of Canada, at Hamilton, on lake Ontario."

Jan 1, 1952

A direct comparison has been undertaken between laboratory wind tunnel experimentation and computational fluid dynamics simulation of a 3D manufactured analogue for a body of fractured broken rock, created with CAD/CAM techniques. Detailed descriptions of the ?design? of the analogue (using a discrete element analysis multi-body simulator), its manufacture (using computer aided design and 3D printing technology) and the laboratory experimentation (inserting the physical analogue into a laboratory scale wind tunnel) are presented. The agreement of the results of direct experimental observations on the manufactured analogue with the values from CFD simulations of those experiments justifies the utilization of a CFD environment for the practical investigation of geometric factors controlling air flow and heat exchange in complex assemblages of broken rock blocks. The ultimate goal is described, that of developing functional relations between bulk properties of such assemblages (such as their porosity and bulk density) and the low-level geometric factors that dictate the air flow behaviour, such as the equivalent perimeter length of the cross-sectional area available for flow, or average flow path tortuosity. A practical application area of the work in the mining context is also described; equivalent continuum air flow and heat transfer constitutive models developed on the CFD tool from such functional relations are useful in characterization of seasonal heat storage in large scale bodies (approximately 1 km3) of broken rock.

Aug 1, 2013

By R. R. Culbert

Several thousand parts per billion of uranium are present in some alkaline lake and ground waters of the Okanagan region, British Columbia. To a major extent the uranium content of these highly anomalous waters is controlled by their levels of dissolved bicarbonate. In lakes, dissolved bicarbonate and the organic content of the sediment largely control the partitioning of uranium between sediment and water. This relationship is found to a lesser extent in alkaline creeks, and transported geochemical anomalies in soils appear where uranium-bearing alkaline ground waters have encountered organic materials. There is a possibility that young, near-surface deposits (with very low radioactivity) are forming from these uraniferous waters.

Jan 1, 1978