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By V. I. Ryaboy, V. P. Kretov, I. V. Ryaboy, E. D. Shepeta

This paper studies the features of known and newly synthesized dialkyldithiophosphates and reagents with thioamide groups when separating copper-containing and arsenic-containing minerals in the flotation of skarn-scheelite-sulphide ore at the Primorskaya concentration plant. The optimization of dialkyldithiophosphate collectors was based on the study of their surface activity at the liquid-gas interface and estimated hydrophobic abilities. The flotation experiments show that the selectivity of action of the reagent increases with an increase of its surface activity and a reduction of hydrophobic ability when separating chalcopyrite and arsenopyrite. IMA-225-5 was proposed as a more efficient dialkyldithiophosphate collector, which increases the recovery of copper by 2.8% compared to the industrially used collector IMA-I413. Selection of the optimal structure for reagents with thioamide groups (derivatives of thionocarbamate and thiourea) was carried out according to their acidity and the presence of hydrophilic particles in their structure. Calculations were performed depending on the pH of the solution of chalcopyrite to determine the optimum reagent sorption and to further optimize the structures of these reagents. The tests with reagents with thioamide groups show an increase in copper recovery by 3-4% together with a significant increase of arsenic content compared to IMA-225-5. As a stronger collector with thioamide groups, it was recommended to use sample 234, which belongs to the thiourea derivatives. IMA-225-5 was recommended for industrial tests at the Primorskaya concentration plant. Thus, this study has shown that using dialkyldithiophosphate is more appropriate if it is necessary to increase the selectivity of separation of copper-containing and arsenic-containing minerals, and using reagents with thioamide groups, or their combinations with dialkyldithiophosphates, is more appropriate if it is necessary to increase the recovery of copper or the quality of copper concentrate with less selectivity of the process.

Jan 1, 2016

By V. Estrada, G. Aguilera

"Since the most of mineral processing are wet, and for more specific applications where it is necessary to increase the purity through leaching and / or concentration, the proper dispersion is the first, and perhaps more crucial stage in the whole chain of processing. This specific process is based on the formation of a dispersion or suspension of mineral, trying to make the mixture as homogeneous as possible, and with specific rheological conditions. Sometimes it is not enough agitation to make it happen, so that chemical additives are used as an aid. However, the addition of chemicals strongly alters the viscosity and other rheological properties of the suspension factor to consider for subsequent steps to ore beneficiation. In other hand, in a process where no chemicals used often employ large quantities of water to achieve dispersion. But if an efficient chemical agent, which optimizes said dispersion through a specific physicochemical effect on the particle surface is used, also it can generate rheological advantages, besides achieving rational use of water and increase the recoveries of the product main about also optimal costs. The aim of this work is to find the optimal rheological conditions for a dispersion of kaolin as study case, looking for stability, best disaggregation, viscosity and pseudoplasticity.To find the optimal additive, the evaluation parameters were: 1) Best degree of dispersion of the suspensions according to the analysis of the flow curve; 2) Best level of disaggregation of particle chemical analysis delaminated by Particle Size Distribution; and 3) Best thixotropic rheological parameters and pseudoplasticity. Finally the optimum additive as one that meets the best combination of parameters is proposed.INTRODUCTIONKaolin is a clay material formed by altering of feldspar composed mainly for kaolinite. Depending on the application, the kaolin as raw material must be refined and processed because the ores of clays contain usually a lot of impurities derived of its sedimentary source, such as feldspar, mica and quartz (Torres, et. al., 2011). According to the experience on the plant floor and the publication of several scientific papers, it is known that the dispersion is a crucial stage in mineral processing (Greene, Duke, & Hunter, 1965) (Raghavan, et. al., 2004), not only because of the disaggregation of particles, besides because of the humectation of them. Is clear that disaggregation of particles give to the suspensions rheological stability, and the humectation improves the effect of further processes like grinding or chemical treatment. The dispersion process involves making a suspension of the mineral with a solvent which is usually water, to obtain a homogeneous dispersion, with the aid of energy of stirring. Sometimes is not enough the agitation (even with high energy) for this to occur, so is necessary the use of dispersing substances which introduce ions and molecules as modifiers of chemical potential, forcing the molecules of the material to disperse. Sometimes their use even could affect the pH of the suspension in a non-desirable condition. (Flores, 2013)."

Jan 1, 2016

"5.1. IntroductionThe sample preparation requirements for bulk analyses of platinum-group elements (PGE) are different from the requirements for ore microscopy and in-situ analyses. It is necessary that the initial sample collection results in as representative a sample as possible for both types of analyses. Ingamells (1980) believes, however, that sampling is always imperfect and that there is no such thing as a truly representative sample. Once collected, the usual low content and irregularly dispersed nature of the PGE require that samples for bulk analyses be made as uniform as possible, whereas in samples for ore microscopy and in-situ analyses the PGE must be concentrated. Because of the generally high specific gravity of platinum-group minerals (PGM), certain precautions must be taken, such as mixing the sample material in the bags prior to opening.5.2. Preparation forBulk Analytical MethodsThe principal factors that determine the size of the sample required for a bulk analysis are grade, heterogeneity and grainsize. Initially, the grade and sample heterogeneity can only be estimated and a sampling methodology is developed with experience. It is essential at all times, however, that the assayers have information about the source of the sample and the purpose for the analysis. Information on the grain-size, which can only be obtained through mineralogical analysis, is also very important for PGE analyses, but, unfortunately, is often ignored.5.2.1. Samples fromUnconsolidated DepositsConcentrations of PGE may occur in eluvial deposits as well as in a large variety of alluvial deposits, including those of fluvial and glaciofluvial origin. These deposits are often difficult to map and sampling is further complicated by the wide range, from sand-size to boulders, of the non-POE-bearing constituents, and by the irregular distribution and shape of the ""pay streaks"". PGE concentrations in unconsolidated deposits are largely composed of resistant Pt-Fe and Os-Ir-Ru alloys (cf. Cabri and Harris, 1975 and Raicevic and Cabri, 1976), thus making comminution to the usual-150 to -200 mesh somewhat unreliable, due to the malleability of these alloys."

Jan 1, 1979

By F. R. Erick Mulder

"AbstractTwo bottom-hole samples have been taken from two new completions in the Turner Valley field, Royalite Lowery No. 8 on the west flank and Royalite No. 73, which was deepened into a lower fault block, on the northeast flank. From the bottom-hole oil of Royalite Lowary No. 8 a synthetic sample was prepared to simulate the original fluid in the reservoir, saturated at the gas-oil contact conditions. The sample from Royalite Lewery No. 8 has been shown to be the original fluid present at this well and represents the oil phase near the oil-water contact in• the reservoir. Complete chemical analysis, P.V.T., and viscosity data have been obtained on these reservoir fluids, which represent the range of saturation from the gas-oil to the oil-water contact in the Turner Valley oil structures. Sampling techniques and the application of the analytical data to reservoir conditions and field operations are discussed. Super-compressibility curves for an average separator tail gas have also been prepared. These data have not been available before. They will be of fundamental value in futu.re reservoir engineering studies of this field and will also serve as a guide in determining operating practices."

Jan 1, 1950

By William Ferguson, Claude Deveau, Wade Hazel, Stephen R. Young, Allen Lussier, Robert Copeland

"LocationSometimes known as the Bernie Lake mine, the mine is located about 180 km east-northeast of Winnipeg on the northwestern shore of Bernie Lake, close to the Nopiming Provincial Park and the Manitoba-Ontario boundary. The mine is accessed from Lac du Bonnet which is linked to the provincial road system.Brief Description of OperationTantalum Mining Corporation of Canada Ltd. operates an underground mine employing ramp access, room and pillar mining, and shaft hoisting for the production of tantalum, lithium and cesium minerals. Daily campaigned crushing of the tantalum and lithium ores supply separate concentration circuits. Tantalum recovery employs conventional gravity equipment together with recently developed centrifugal concentration methods. All tantalum concentrates go to Cabot Performance Materials for the production of tantalum chemicals and metal. Lithium minerals are recovered using heavy medium separation and silicate flotation to produce spodumene and montebrasite/amblygonite concentrates. The lithium concentrates are shipped worldwide for use in ceramics, specialty glass and mold powders. Cesium processing involves the dry grinding of pollucite as feed stock for the recently built on-site chemical plant dedicated to tl1e production of cesium formate, a high-density drilling fluid for use in the oil industry."

Jan 1, 2000

Energy benchmarking is widely applied across industries to determine the potential to improve energy performance. Unlike the many technologies for which energy benchmarks and efficiency rating systems are already in maturity, benchmarking of mining processes is still in its infancy. Benchmarking energy usage in mining operations, where energy costs are high and represent a significant portion of overall operating expenses, is challenging due to the uniqueness of each mining operation. Mines vary in terms of geology, geographic setting, ore body geometry, mineralogy which impact the mining method, material handling, processing and waste management. In order to gauge the opportunity for reducing the energy intensity of individual operations and also to compare the energy performance of operations on a global scale, the deployment of new benchmarking methodologies, models and frameworks is necessary. As a step towards the establishment of an accurate framework for benchmarking the energy consumption of mining operations, comminution, one of the more energy intensive mining sub-processes, was selected as the focus of a new energy benchmarking method. The methodologies and processes used to onset fragmentation in a rock mass to the crushing or grinding of rock to a size that is suitable for economic extraction are predominantly dependent on the ore properties. For this reason, site specific factors, such as the size reduction requirements and ore hardness were included in an energy benchmark model so that the energy performance of comminution processes at different operations could be normalized and compared on a global scale. Single particle compression breakage has been identified by several prominent researchers in the field of comminution as the upper limit of energy utilization in size reduction processes. For this reason single particle compression breakage was proposed as the basis of a work index for ores to be used as an input for the benchmark model. Overall, the new method showed that the energy benchmark for mineral comminution can be normalized and subsequently compared for a range of mining operations once the ore hardness has been appropriately characterized.

Aug 1, 2013

By J. Güntner

A significant portion of Outotec's business relates to the application of fluidized bed for processing a wide range of industrial materials, including gold ore and gold concentrate. As part of the former Lurgi and Boliden organization, our division constructed the first industrial reactor for roasting sulphur-bearing materials in 1950, based on the principles of fluidized bed technology. This process, when combined with efficient heat recovery and off-gas treatment and its conversion to sulphuric acid, became the standard for processing sulphur-bearing ores. In the last 60 years we have delivered more than 265 plants and developed (in addition to the standard fluidized bed solution) variants of the fluidization technology, such as the circulating fluidized bed and the bubbling fluidized bed. This paper describes the different options of the fluidized bed technology for gold roasting reflecting on main process design criteria.

Jan 1, 2011

By J. O. Marsden

Over the past decade, the copper industry has been through an extended downturn followed by several years of sustained high copper price. A number of new technologies have been developed over the past 10 years aimed at reducing costs by decreasing energy, labor, and materials requirements, or by increasing metal recovery. The energy intensity of different copper extraction routes and different technologies varies considerably and this has a significant impact on the economics of extraction. Based on average ore grade materials, the total energy for the extraction of copper typically varies from about 24-26 MJ/lb (6.7-7.2 kWh/lb) for the mining, crushing, milling, flotation, smelting and refining route to about 14¬16 MJ/lb (3.9-4.5 kWh/lb) for the mining, crushing, heap leaching, solution extraction and electrowinning route. New technology developments are providing opportunities for significant reductions in energy consumption for copper extraction, representing energy savings up to 20-25% in some cases. In addition, in many cases, these new technologies have introduced environmental, safety and health benefits over the incumbent technology. Some of these technology developments have been more successful than others, and many hold great promise for application in the coming decade. This paper provides an overview of the technology developments that have occurred, and explores the underlying reasons behind successful implementation.

Jan 1, 2007

By Z. D. Hora

"There has been a number of new developments in British Columbia's industrial minerals field over the past few years. Several new industrial operations were started to diversify the line of British Columbia mineral production by magnesite, perlite and fuller's earth. Industry activities and geological projects have identified occurrences of rare earth minerals, niobium, kaoline, fireclay and zeolites. The Geological Survey Branch significantly improved its database on industrial minerals. New geological concepts based on recent work are opening a number of new opportunities f or further industrial minerals' exploration and development in British Columbia.IntroductionTraditionally, the value of industrial minerals produced in British Columbia in any given year comprises between 100/0and 15% of the combined value of minerals, coal, petroleum and natural gas. Over the years a wide variety of industrial minerals has been produced , often with different levels of marketings success. For some products, such as dimension stone and clay or shale products, initial strong demand gradually dissipated; for others such as asbestos and magnesite, new discoveries or new industrial activities created demand and new markets . In some cases, such as fluorite , talc, pyrophyllite and perlite, wider use has been prevented by small size, poor quality or remote location of the deposits. Also, British Columbia , with 2.6 million inhabitant s, provides only a limited market and the industry therefore has to look beyond provincial borders."

Jan 1, 1990

By Carl O. Nickle

"IntroductionIF I WERE ASKED what are the two most important single factors in shaping the growth of Canada to date, and in building its future, the answer would be: first, the treasure house of natural resources on and below the surface over the length and breadth of our country; and two, the pioneering spirit and 'get up and go' of many of our people. The two factors are inseparable. Without the pioneering spirit, the natural resources of land, forest, stream, and the subsurface would have continued •to be useless,. Idle assets. With the pioneering spirit, Canada's natural resources have been and are creating economic revolutions.Western Canada oil and natural gas rank high on the list of such revolutions. Calgary, your meeting place today, is the birthplace of this economic revolution, one that has already sharply altered the economy .of the middle half of Canada, particularly that of Alberta; is increasingly making its weight felt on the economy of all Canada; and is helping re-shape world thinking on sources of vital petroleum supply for both peace and war. Calgary is today the 'operation headquarters' for the great bulk of a huge exploration and development programme that now extends over a quarter of a million square miles of Canada's West. As a Calgarian, •therefore, I am particularly happy to have this privilege of talking about oil and natural gas to members of the C.I.M.M., who play a key role in the development of all Canada's varied natural resources."

Jan 1, 1952

By Raymond S. Suglo

Increasing depths of mining coupled with the mechanization of most underground mining operations have led to growing complexities in the mine environments with the production of large amounts of gaseous and particulate contaminants. Over 100,000 lives have been lost due methane gas and dust explosions in coal mine workings in both the US and Canada since 1900 when the methane concentrations exceeded stipulated levels in some workings. There is therefore the need to constantly assess and evaluate the performance of the existing mine ventilation systems to maintain safe and acceptable mine environmental conditions in workings to meet the requirements of federal, state or provincial laws. This paper uses the results of continuous monitoring of methane concentrations conducted in selected development headings in coal mines in North America to assess the effectiveness of existing auxiliary ventilation systems in the control of methane gas concentrations in the headings. The results show that the average quantities of fresh air required to dilute, disperse and remove methane concentrations within set levels of one minute varied from 5.43 m3/s in Heading #11 (Condition 2) to 27.97 m3/s in Heading #10 (Condition 1) and this represented about 12 to 26% of the quantities required to dilute methane concentrations to safe levels within one minute under Condition 1 and 32 to 139% under Condition 2. The average dilution times in the headings studied were less than 8 minutes. The forcing efficiencies of the auxiliary systems in the headings studied ranged from poor to excellent implying that the auxiliary ventilation systems were capable of controlling the methane concentrations below statutory levels but may not be able to cope with large and unusual methane concentrations in the headings. This study is important to prevent methane gas and coal dust explosions in coal mines and thus avoid any loss of lives and property.

May 1, 2001

By H. Gharahbagheri, S. Shafiei Zadeh, H. Hassan Nejad, Reza Roostaazad

In this paper, dissolution of vanadium from mining residue, in which vanadium is associated intimately with magnetite ore, was investigated via both bacterial ( aerobic and anaerobic) and fungal activity. Although bacterial activity was tangible, it could not reduce and dissolve vanadium in both aerobic and anaerobic experiments. However, in fungal leaching, after 30 days about 36.9% and 29.7% of vanadium was dissolved for a pulp density of 10 and 30 g/l, respectively. At the end, the concentration of metabolites usually produced by fungal activity was optimized and oxalic acid was chosen as the main agent for the leaching process.

Jan 1, 2014

By Turgut Yalcin

"In this study, potential benefits of focculant usage were explored in the processing of mill tailings by hydrocyclones. Tests conducted on copper-nickel mill tailings have demonstrated that, under suitable conditions, flocculation could significantly enhance solid-liquid separation in hydrocyclones. For example, at a feed pulp density of approximately 9%, focculant-assisted hydrocyclone produced an underflow with over 98% solids recovery, compared to a recovery of less than 53% with conventional hydrocyclone. However, feed pulp density was found to be a critical factor, and tailings with pulp densities of greater than about 15%required a two-stage hydrocyclone operation where the focculant-assisted hydrocyclone was employed at the second stage to process the overfow of a conventional hydrocyclone.The underflow and overflow products obtained from the focculant-assisted hydrocy-clone may be discharged into tailings dams in the same manner as those produced by gravity thickeners. The focculant-assisted hydrocy-clone would, however, provide a higher throughput."

Jan 1, 1996

By Xiaolin Cheng, A. J. Sinclair

"Abstract - Norm calculation procedures originally designed principally for igneous rocks are very rigid in their application and, in general, do not utilize important alteration minerals. For instance, volatile components are essential constituents of many metasomatic rocks but either are not used or are not used effectively in determining normative minerals by the CIPW norm or Niggli-Barth norm procedures. Our approach to determining norms for metasomatic rocks allots all major, minor and volatile constituents to a set of standard normative minerals which are commonly observed as products of hydrothermal alteration. A useful procedure is to have a metasomatic norm approximate the mode as closely as possible. Petrographic information helps to provide the necessary mineralogical constraints. With the recognition of an immobile component and knowledge of sampling and analytical errors in lithogeochemical data, it is possible to recast norms into amounts of alteration minerals relative to a given amount (100 grams) of parent rock. Combining these results with the calculations of absolute loss or gain of individual chemical constituents and considering errors (e) for an appropriate confidence level, an overall (net) material exchange equation can be presented as follows:SMineralparent rock ± e + SConstituentgained from solution ± e= SMineralaltered rock ± e + SConstituentlost from wall-rock ± ewhere all items have extensive units (e.g., grams). The model includes the initial and final mineralogy of rocks (evident in the field) as well as gains and losses of specific elements. Only those constituents whose calculated losses and gains are significantly different from zero are retained in the above model, and only the normative minerals with abundances significantly different from zero are included in the model (equation). One advantage of the chemicomineralogic model is that parent rock and product are modeled in mineralogical terms that are familiar to and easily usable by exploration geologists."

Jan 1, 1995

"Previous studies on the effect of polytetrafluoroethylene addition during chalcopyrite leaching under conditions similar to those of the CESL process have reportedly resulted in complete leaching of the copper without the need for grinding of the flotation concentrate. However, these studies employed a pulp density of only 1% and finely sized PTFE particle that required the use of high impeller rotation rates that are not sustainable at an industrial scale. This paper explores the performance of 1/8” diameter balls of PTFE, that readily sink in the leach solution, on leaching performance at impeller rotation rates and ore pulp densities more typical of industrial practice. Possible routes for separation of the PTFE from the leach residues and their regeneration for recycling back to the leaching stage are also discussed.INTRODUCTIONChalcopyrite, CuFeS2, is the most important primary sulfide source of copper. While pyrometallurgical smelting of chalcopyrite remains the only widely accepted route for treating chalcopyrite concentrates, several medium temperature pressure oxidation processes are claimed to be economically feasible (Muir & McDonald, 2007). Among these, the CESL process has been extensively piloted and demonstrated at the prototype scale. The overall process chemistry of the CESL process may be summarized as follows (Marsden & Wilmot, 2007):4CuFeS2 + 5O2 + 4H2SO4 ? 4Cu2+ + 4SO4 2- + 2Fe2O3 + 8S0 + 4H2O (1)4CuFeS2 + 17O2 + 2H2SO4 ? 4Cu2+ + 10SO4 2- + 4Fe3+ + 2H2O (2)Though copper extractions of over 95 % are achieved, the CESL process requires extra grinding of the concentrate (Muir & McDonald, 2007). This is because leaching is conducted at temperatures around 150 °C, where the elemental sulfur produced is molten and grows thicker on the mineral’s surfaces as oxidation progresses, creating an increasingly large barrier for mass transport. In addition, the sulfur is sticky and tends to cause the mineral particles to agglomerate, effectively halting further oxidation of the particles that end up embedded within the agglomerates. Consumable surfactants, such as ligin sulfonate, have been shown to be effective at avoiding agglomeration, but they are not effective at removing sulfur from the minerals. Hence, their use does not obviate the need for fine grinding."

Jan 1, 2012

By V. Feldman, I. Holl, J. Zampini

"The Renard Mine, 100% owned by Stornoway Diamonds, is located approximately 250 km north of the Cree community of Mistissini and 350 km north of Chibougamau in the James Bay region of north-central Québec. The project benefits from a large and growing resource, good mining conditions, strong social acceptance, a modest environmental footprint, and the development of direct-to-mine road infrastructure. Construction began on July 10, 2014; following the completion of a 946 million CAD project financing transaction. Now completed, the mine is the first diamond mine in Québec, and one of only six in Canada, employing approximately 500 people. First ore was delivered to the plant approximately 5 months ahead of schedule on July 15, 2016. Commercial production was declared on January 1, 2017. In general, the project ramp up has been characteristic of a type 1 McNulty curve. One of the challenges during production ramp-up was a redesign of processed kimberlite dewatering (replacing the dewatering centrifuge with two stages of hydrocyclones and a dewatering screen). A processing opportunity captured by Stornoway was the design and installation of an ore sorting facility which rejected free waste rock from the valuable host rock; kimberlite. Through tackling both challenges and opportunities, Stornoway has realised and is now exceeding their original design tonnage.PROJECT DESCRIPTION Stornoway Diamond Corporation (Stornoway) was established in 2003 resulting from to a plan of arrangement between Northern Empire Minerals Ltd. and Stornoway Ventures. In 2011, Stornoway acquired 100% interest of the Renard Mine. The construction of the Renard Mine began in 2014 and achieved full production in 2017 [1, 2]."

Jan 1, 2019

By R. Q. Honaker

A significant problem in ultrafine particle classification is the significant amount of submicron particle by-pass to the coarse particle stream. In classifying cyclones, submicron particle by-pass to the underflow stream can be reduced by decreasing water recovery. Past studies have shown that a reduction can be realized when the feed solids concentration is increased or the apex diameter is reduced. However, both adjustments tend to increase the particle size cut point and negatively affect classification efficiency due to the impact on slurry rheology. The addition of a viscosity modifier to the feed stream of a classifying cyclone improved the classification performance and decreased the particle size cut point over a range of feed solids concentrations. The detailed test program investigated the use of the modifier in conjunction with varying apex diameters to identify conditions that minimize ultrafine by-pass. With small apex sizes, roping conditions were readily eliminated by the addition of viscosity modifiers. The addition of the modifier had no deleterious effect on froth flotation performance, which commonly serves as a downstream separation process. The fundamental and practical benefits of viscosity modifiers in classification processes are discussed in this publication.

Jan 1, 2006

Lonmin RoM ball mills are treating two types of feed ore produced by conventional mining and mechanised mining methods. It was reported that reduction in mill throughput was observed when treating the mechanised mining ore. Detailed grinding surveys were conducted for troubleshooting. Ore samples were collected for breakage characterisation using a JKRBT based on different particle density components. XRD analysis was conducted to investigate the association of minerals with density components. The plant surveys and the breakage characterisation tests all suggested that the two mining methods did not significantly affect either the ore breakage properties or the RoM mill performance. Instead, the mill discharge open area exerted a remarkable influence on mill throughput. The RoM ball mill operated at Lonmin K4 Concentrator has been proven to be a versatile mill that performed stably with variations in feed size distribution and feed ore changes by different mining techniques. The reasons are elucidated by the multi-component breakage characterisation and the plant surveys data.

Jan 1, 2012

Stellite-6 coatings were formulated on two Ni-base superalloys, namely Superni 75 and Superni 600, by a shrouded plasma-spray process, and the oxidation behaviour of these coatings has been investigated in air and in an aggressive environment of Na2SO4- 60%V2O5. Accelerated oxidation tests were conducted in a silicon-carbide tube furnace under cyclic conditions at an elevated temperature of 900°C for 50 cycles. Each cycle consisted of 1 h heating and 20 min cooling in air. A thermogravimetric technique was used to approximate the oxidation kinetics. The corrosion scales were characterised by XRD, SEM/EDAX and EPMA analysis. It has been observed that the coatings nearly followed the parabolic rate law of oxidation. Overall weight gain conceived in air was just 51% of that in the aggressive environment in the case of coated Superni 75, whereas in case of coated Superni 600, the cumulative weight gain in air was found to be one-third of that in the Na2SO4-60% V2O5 atmosphere. Furthermore, the coating showed very good adherence to both of the substrates during the course of air oxidation, whereas some superficial cracks were observed near the edges of the specimens during the molten salt induced oxidation. XRD analysis revealed the presence of phase-like CoO, CoCr2O4 and Cr2O3 in the oxide scales, which are reported be protective against high-temperature oxidation. The XRD results were further supported by SEM/EDAX and EPMA.

Jan 1, 2005

By Saeid Akhavan

Accumulative roll bonding (ARB) is a severe plastic deformation process for achieving ultrafine grains in metallic sheets without changing the sample dimensions. In this study, ARB process was carried out on 5083 aluminum alloy sheets up to 6 cycles. In this process, the surfaces of the strips to be joined are roughened and cleaned and then stacked. After stacking, the specimen is roll-bonded by rolling using a 50% reduction. The rolled specimen is cut into two halves, and the above-mentioned procedure is repeated for several times. Microstructural characterizations were analyzed by transmition electron microscopy (TEM). Tension and Vickers hardness tests were performed on produced sheets for evaluating their mechanical properties. Moreover the texture parameter of the ARB-ed samples was calculated using their XRD patterns and the related equation. Additionally, the texture evolution during the ARB process was demonstrate by analyzing the measured pole figures and orientation distribution functions (ODF) and skeleton lines. The results indicated that at the early stages of ARB process, grains were subdivided by deformation induced boundaries. After several ARB cycles continuous recrystallization resulted in a microstructure covered with small recrystallized grains with an average diameter below 100 nm at the end of four cycle. Texture analysis revealed fiber textures have been discovered with continiuose of the ARB process cupper. Brass, S and dillamor textures identify which their differences are in intensity of ARB process. Results indicated conformity between mechanical evolutions and texture evolutions during ARB process.

Oct 1, 2011