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By P. Belley

Prior to 2006, the filtration unit for leached sludge treatment (filter press) permitted the filtration, washing and drying of cake to 17% (w/w) moisture. That year saw moisture content abruptly increase to 20% (w/w), drastically changing the rheological properties of the cake. The cake became sticky and agglomerated. This led to major disruptions of operations and plant capacity (cake release and cake conveyor problems, complicating the subsequent steps of the process). The conditions for the filtration, washing and drying, were simulated to ease cake unloading without aggravating dust emissions (moisture about 17% (w/w)). All of the laboratory tests yielded a moisture content above 17% (w/w). Therefore, we concluded that the moisture problems were not due to a recipe change in primary material, but to an operational problem in the filter press. Through the laboratory results, the filter press operating conditions (washing ratio, drying pressure and drying time) were optimized to enable a reduction in cake moisture to 17% (w/w).

Jan 1, 2007

By M. Ye. Shulgina, M. L. Bolotin, S. A. Prokopev, Ye. S. Prokopev

Iron ores concentration at Russia’s operations is carried out using conventional flow sheets. They comprise the two-four stage grinding followed by one-two stage magnetic separation. This results in the maximum recovery of magnetite to concentrate and the tailings generation. The final concentrate is generated only during the last stage of magnetic separation. Technologically, this flow sheet layout is not effective at recovering the liberated magnetite grains during grinding to the resulting concentrate. Advanced models of magnetic separators do not allow for the selective separation of the tailings and the portion of the resulting iron ore concentrate. Magnetic product which is the ore mixture of the liberated magnetite grains, high grade and low grade intergrowths is directed to the next grinding stage. In this case, regrinding of the liberated magnetite occurs. In addition, the performance of hydrocyclones during classification in closed grinding circuits is poor. Their classification efficiency does not provide the material separation in accordance with the size. In this case, simultaneous separation in accordance with the density occurs. The quartz particles with the size of 300 mm have similar velocity and trajectory like the particles of magnetite with the size of 60 mm. As a result, light and coarser intergrowths report to the overflow and free heavy magnetite grains report to underflow and return to regrinding (“the density effect”). This resulted in a significant increase of a mill circulating load, the decrease in the feed throughput and higher power consumption. In this connection, the development of iron ore concentrate stage recovery with the focus on gradual liberation of the intergrowths is getting much attention. Gravity concentration technique, particularly, spiral separation is effective at solving the problem of stage recovery not only the dump waste product but also high grade magnetite concentrates at the early concentration stages. This can be attributed to a significant difference in magnetite (4.9-5.2 g/cm3) and host minerals (quartz 2.7 g/cm3) densities, which is the principal during gravity concentration. The test work on concentration of various products samples from current operations (the mills discharges, concentrates from various stages of wet magnetic separation and cyclones underflows) was carried out. Spiral separators SV-500 and ShV-500 manufactured by Spirit LLC were used for the test work. High grade iron ore concentrate (69.05% Fe) was generated during primary wet magnetic separation concentrate concentration using a spiral separator. During the concentration of mills discharges the content of iron in the resulting concentrates and middlings of wet magnetic separation II stage was 64.5% and 64.6%, respectively. The recovery of iron to the concentrates of spiral separation was 33.6-42.0%. The studies presented demonstrate that by using spiral separation for iron-bearing ores concentration, you can separate magnetite liberated grains at the early concentration stages, decrease their regrinding and circulating loads in grinding circuits. This process is able to improve the overall recovery and economics of iron ores concentration process.

Jan 1, 2016

By D. Bernard

Over the last decades, the wrought aluminum casting industry has made significant progress with regards to process consistency by the introduction of new technologies in the field of liquid metal processing and casting. These technologies, combined with the application of best practices, have led to increases in productivity as well as better process performances and product quality. The competition in the addedvalue aluminum products (by opposition to P1020 production) is, however, very strong and involves players that did not hold a major role five years ago but who are now exerting a strong competitive pressure on our industry even sometimes from far abroad. There are still technical and technological challenges remaining in the different areas of aluminum casting production, amongst which metal pre-treatment, furnace operations, in-line treatment and casting hold a predominant influence. The comprehension of the contribution of each individual process step to the entire process chain is a key element and must be considered in future process optimisations. This paper presents the technological position of the casting industry and tries to highlight areas where further progress can be made.

Jan 1, 2006

By M. Lebeuf, A. Dumais, C. Farsangi, N. Singh

The Nunavik Nickel project began ramp-up of a new ore body (Expo) in November 2014. This new deposit is significantly more competent than the previous ore type milled (i.e., the plant moved from a feed with a BWI of 12.2 kWh/t to predominantly material with a BWI of 19.6 kWh/t). Despite circuit changes made in advance of the Expo ore ramp-up (grinding media size, mill loading/power draw, and cyclone configuration) the throughput of the plant was bottlenecked at 90% of targeted throughput with multiple stoppages to grind-out the primary mill due to excessive circulating loads. During this time, the secondary milling circuit was under-utilised: therefore the focus for debottlenecking plant production became increasing the product size of primary milling. Given the scope of changes already made to the circuit, it was decided to test the mill in open circuit. The milling changes were modelled using the Molycop Tools package to identify potential problems. In the modelling and plant trial it was apparent that the ball size in the secondary grinding circuit was inadequate, resulting in pebbling. The power draw of the secondary mill was brought up to minimize pebbling and the average ball size was increased. The switch to open circuit primary milling permitted a significant augmentation in plant tonnage. While the overall grinding efficiency decreased using the open circuit configuration, the ability to increase throughput made it the clear operating choice.

Jan 1, 2016

By R. Laucournet, E. Billy, M. Joulié

Today Li-ion batteries are considered as one of the most attractive available energy storage solutions. However in order to overcome environmental, legislative and economic issues, the management of used batteries has to be considered and mainly the recycling. The present paper deals with the recycling of used Li-ion batteries and the recovery of high value metals from active materials of electrodes. Lithium nickel cobalt aluminum oxide (NCA) and lithium manganese nickel magnesium oxide (LMNM) cathodes, which contain most of valuable elements typically used in the composition of active materials for Li-ion batteries are investigated by a hydrometallurgy route. The process is divided into two steps: the materials leaching and the elements recovery by a selective chemical separation. Some experimental parameters (acid nature, concentration, time and temperature) are studied to determine the most efficient conditions of dissolution. Then, the valuable elements such as nickel, cobalt and manganese are selectively recovered with a high efficiency close to 100 % and with a high purity by precipitation. By this study, an adaptable hydrometallurgy process can be defined according to the composition of Li-ion batteries to recycle.

Jan 1, 2014

By Andrzej Luszczkiewicz, Magdalena Duchnowska, KGHM Polska Miedz S. A., Witold Pawlos, Jan Drzymala, Alicja Bakalarz, Przemyslaw B. Kowalczuk

Numerous data in the literature confirm that the chemical composition and consumption of grinding media influence electrochemical properties of flotation suspension as well as effectiveness and selectivity of upgrading processes. During a milling process, attrition of grinding media is observed. Depending on the susceptibility to abrasion, the grinding media influence, to a different extent, the redox potential, pH as well as flotation efficiency. As a result, different upgradeability of sulfide minerals is observed. The paper presents laboratory scale flotation results, obtained for the copper sulfide ore from Polkowice Region of KGHM Polska Miedz S.A. in Poland ground in the presence of forged steel, highchrome iron and stainless steel as the grinding media. The investigated flotation feed contained 36 g/t (ppm) of silver and 1.86 % of copper. Several flotation tests were conducted using fixed amount of frother and a mixture of sodium ethyl and isobutyl xanthates as the collector at three different doses of 75, 100 and 125 g/t. A comparison of the obtained results confirmed that the application of grinding media with different chemical compositions influenced the electrochemical properties of the suspension and recovery of silver and copper in the final concentrate. The highest values of redox potential were observed for the stainless steel as the grinding medium. Moreover, in the presence of this type of grinding media, regardless of the collector dosage, the best silver upgrading was observed. For the forged and high-chrome iron media, the recovery of silver depended on the collector dosage. It is indicated that higher levels of the redox potential, together with smaller amount of iron released from the grinding medium, improve the flotation of the silver-bearing mineral compounds from the copper sulfide ore.

Jan 1, 2016

Cominco began investigations about ten years ago relative to noise abatement in underground operations. As a result of intensive research, this study has advanced so that the practice now has wide application. Automotive mufflers are used on vane-type blasthole diamond drills. Exhaust hoses are attached to longhole percussion drills. Hand-held drills, such as airlegs and stopers, are equipped with mufflers which are either part of the drill, as received from the manufacturer, or are light rubber de-vices developed, fabricated and installed by Cominco. Ear defenders are in general use. The paper reviews details of practices employed, and assesses the success achieved. Noise is generally associated with some of the basic equipment used in mining. About ten years ago, in order to improve on this situation. The Consolidated Mining and Smelting Company of Canada Limited began investigations relative to noise abatement in its underground operations. As a result of intensive research, this study has advanced to the point

Jan 1, 1964

By R. P. Zahn

The need for quantitative mineralogical data to characterize ore types before they are processed is becoming increasingly necessary. Mineralogical data (modal abundances, grain size, liberation/locking characteristics, mineral textures and associations) can provide invaluable information to facilitate the identification of metallurgical issues that may arise during processing of a particular ore. This paper will discuss the use of QEMSCAN analysis in conjunction with bench scale flotation test work to determine metallurgical characteristics for several ore types that will be fed to the Morenci concentrator upon commencement.

Jan 1, 2007

By E. Best

In 2003, Phelps Dodge Mining Company decided to pursue the design and construction of a Central Analytical Laboratory to provide chemical analyses for their Arizona and New Mexico operations. This centralized approach was selected in place of refurbishing six (6) older laboratories that operated at the various Phelps Dodge sites, and which would not have permitted full automation and use of robotics. The new lab was designed by the Process Technology Center (PTC) Material Characterization Group in cooperation with IMP Group. The Central Analytical Service Center (CASC) encompasses fully automated sample preparation of blast holes and geological samples weighing up to 15 kg/sample. The CASC also includes the first "wet chemistry module" worldwide to be operated by robotics systems to perform Total Cu, Acid Soluble Cu, and Quick Leach Tests (QLT), and a fully automated lab for electrowon copper cathode. The new lab also offers flexibility for handling specialty samples and analyses by either semi-automated or manual mode. Data handling and transfer is accomplished using the commercially available StarLIMS system. Commissioning was accomplished within five (5) months of startup during which the CASC also handled 86% of a full production load. The 24/7 lab operation has already exceeded its design capacity, has achieved considerable savings in operating cost, reduced sample preparation errors, and significantly increased analytical quality.

Jan 1, 2007

By Vishal Shukla, Prateek Singh, D. P. Chakraborty

"Continuous thickening by an operation called sedimentation is the separation of suspended solid particles from a liquid stream by gravity settling. The primary purpose of thickening is to increase the solids concentration of the feed stream. High rate thickeners are designed specifically to maximise the flocculation efficiency. A detailed investigation has been carried out to understand the influence of ore type and operating parameters such as bed level, bed mass, rake arm torque and flocculent concentration on thickening operation. Tata steel’s Noamundi plant data shows that variation in ore type, and operating parameters are major contributors to fluctuation in thickener performance. A lot of research has been done earlier on thickening operation but effect of ore type and operating variables by using plant data was never touched before.In this context, the performance of thickener was evaluated by daily data to study the influence of ore type and operating variables on thickener operation. Investigation shows that friable ore % in feed mix is proportional to slime density because friable ore is porous & brittle in nature. As a result, friable ore generates more fines/ultrafine during communition process in wash plant. Increase in flocculant concentration and bed mass is showing a positive change on high rate thickener performance Investigation shows that optimum bed mass and flocculant concentration is required to achieve desired pulp density in thickener underflow at different feed pulp density (g/cc).INTRODUCTIONOver the years, Iron Ore Beneficiation at Tata Steel, Noamundi has seen varied changes. Depletion of high grade iron and with increasing iron ore throughputs coupled with lowering of the hard ore a subsequent increase in slime generation, slime management and clear water requirement for wet Plant has thrown up myriad challenges. To overcome these challenges, many improvements initiatives were taken by Tata Steel in last decade. One of the major changes is the recent High Rate Thickener commissioning at Tata Steel Noamundi to cater the high iron ore throughput requirement. Slime reporting to Thickener has increased from 1.4 MTPA 2.5 MTPA over the last few decades. The above changes further aggravate the poor settling and dewatering characteristics of the slurry which is being feed to HRT. Considering the above mentioned constraints and stringent environmental implication proper water management has become a major challenge to reckon with. The thickener is used to increase the concentration of the suspension by sedimentation, accompanied by the formation of a clear liquid. In most cases the concentration of the suspension is high and hindered settling takes place."

Jan 1, 2016

By S. Rash Ahmadi

Welding is highly reliable and efficient metal joining process. In welding the metal adjacent to the weld joint is subjected to severe thermal conditions. As a result, complex changes in metallurgical structure occur in this region. These changes in structure depend on the material and the temperature history experienced. Friction stir welding (FSW) is relatively a new welding process in which, heat is generated by friction between the tool and the workpiece. The amount of heat conducted into the workpiece determines the quality of weld, residual stress and distortion of the workpiece. The objective of the current work is to study the transient temperature in a friction stir welding. So, a three dimensional transient analytical model is used to study the thermal distribution during the welding. Heat input from the tool shoulder alone is considered in the model. The process parameters like axial load, welding speed and tool rotational speed, used in actual FSW process are taken to build the model. This analytical model is very useful for select the optimized affected parameters in friction stir welding. The model illustrates the comprehensive equation including actual affected parameters in FSW and it can be used for different materials. In addition to the above the thermal history finds application in design of welding tools.

Oct 1, 2011

By C. Jewell, G. H. Rupay

"67 - 2:15-3:00Regeneration of Hydrochloric Acid from Waste Pickle Liquor Using a Fluidized Bed Reactor System. G. H. RUPAY and C. JEWELL, Dominion Foundries and Steel Ltd., Hamilton, Ont.The disposal of acidic waste liquors from pickling processes has always been a problem for the steel industry. With increased awareness toward environmental control and the problems acidic wastes create, processes utilizing recovery and regeneration of the waste acids are becoming more popular. This paper describes the Keramchemie/Lurgi process for regenerating hydrochloric acid from waste pickle liquor using a fluidized bed reactor system. The process parameters are outlined, together with a brief description of the equipment. This is followed by a discussion of the operating problems and concludes with economic data."

Jan 1, 2000

By R. J. Fruehan

Oxygen steelmaking (OSM) is not only the dominant steelmaking process but defines the structure of the industry. There are a number of myths regarding the future of OSM, which are false. These myths include that the EAF will become the dominant process in the near future, it is less costly to produce steel in an EAF and OSM is a mature technology and no new developments are occurring. These myths are shown to be false. Selected new developments are discussed such as post combustion, recycling of waste oxides, slag splashing and sensors.

Jan 1, 2004

By Yongjie Bu, Wei Sun, Zhiyong Gao, Yuehua Hu, Hongbiao Tao, Runqing Liu, Central South University

"The flotation behavior of O-isopropyl-N-ethyl thionocarbamate (IPETC) and pH for chalcopyrite and galena was studied through pure mineral test, adsorption quantity determination, solution chemistry calculation and Materials Studio simulation. The results show that the recovery differential value of chalcopyrite and galena is about 20% when pH of the pulp 9.5 and IPETC is 7×10-4 mol/L, the flotability differences of the two minerals is significant. There is competitive adsorption between OH? and IPETC on mineral surfaces, it lead to galena flotability is lower than chalcopyrite flotability. IPETC can remove the hydration layer on mineral surface and adsorb on active sites for collector adsorption, minerals have a better hydrophobicity.INTRODUCTIONCopper and lead are two of the most widely used metals in industrial and living, their applications include building construction, various metal alloys, heat and electricity, machine manufacturing (Zhang et al., 2014). Chalcopyrite and galena are the major source of copper and lead, normally they associated with each other. With the growing use of these resources, high grade and dissemination large particle sizes minerals are less and less, the use of low grade and complex dissemination minerals have to be paid more attention (Chen, Ye, & Li, 2010; Liu, Sun, Hu, & Wang, 2009). As the special properties and complex composition of copper-lead sulfide ore, flotation separation of chalcopyrite from galena effective is a research emphasis and difficulty point in mineral processing (Bruckard, Sparrow, & Woodcock, 2011).In the separation process of chalcopyrite and galena, it is rather important to choose effective collector (Huang, Wang, & Liu, 2014). Enlarging and using the two mineral flotability will be a good basis and start in flotation (Reyes-Bozo et al., 2014). Qin et al. (2013) made a great deal of research on flotation separation of copper/lead concentrate, collector O-isopropyl-N-ethyl thionocarbamate (IPETC), butyl xanthate (BX) and ammonium dibutyl dithiophosphate (ADTP) were investigated, BX and ADTP floated both chalcopyrite and galena well, specific adsorption appeared in the surface of mineral, the problem was the collectors were not selective enough, however IPETC showed better selective."

Jan 1, 2016

By R. Roufail

"Energy consumption in stirred mills has been studied, in the last couple of decades, on a macro scale. Effective operation and meeting particle size required for downstream operations used to be the main objectives behind energy utilization of stirred mills. In this paper, three energy terms are defined to assist in understanding the breakage mechanism for various types of minerals versus mill operation. The types of minerals studied had diverse physical and mechanical properties that are summarized as specific gravity, hardness and crystal structure. The minerals utilized in this study were quartz and galena. The effect of quartz and galena mix has been addressed as well as Lead-Zinc ore sample from SAG mill discharge. The energy input to the mill is function of the agitator speed, therefore three agitator speeds were evaluated, 1000, 1500 and 2000 RPM, respectively. The energy terms studied are specific energy (kWhr/ton). Effective energy is the ratio between net energy and total energy consumed by the mill. Last type of energy is the specific breakage energy, which is the net energy consumed by the mill per one-micron breakage. Results showed that specific energy and specific breakage rate are functions of mineral type, while effective energy is only function of mill input power (agitator speed).INTRODUCTIONGrinding is the largest energy consuming component of a mineral processing operation and typically consumes about 50% of the total energy used at a mining operation (Botin, 2009). Over the last two decades, stirred mills have been extensively utilized in mineral processing operations due to increased mineralogical complexity of ore bodies. Stirred mills grind particles to less than 10 µm by applying a high power intensity. The technology has been the focus of several research studies to investigate mill energy and grinding mechanisms. Becker, et. al. (2001) studied the relationship between different types of energy including input energy, specific energy, volume/mass specific energies, to stress intensity and final product particle size. Other studies such as by Kwade (1999), Kwade and Schwedes (2002), Blecher et al (1996), Partyka and Yan (2007), Stender et al (2004), focused on mill design and/or stress intensity distribution. Peukert (2004) studied the effect of mechanical properties of the grinding media and ground material on the comminution process."

Jan 1, 2016

By K. E. Waters, E. R. L. Espiritu, G. R. da Silva

"Rare earth (RE) elements are essential components of emerging green technologies. The increase in demand for these applications have driven the search and development of new rare earth deposits such as the Niobec project in Quebec, Canada. This deposit consists primarily of dolomite with significant amount of RE minerals bastnäsite and monazite, the primary sources of RE elements. Due to the minerals’ fine liberation sizes, flotation is commonly used as a concentration method. To develop an efficient process, the electrokinetic properties of the minerals must be understood. In this study, the surface properties of bastnäsite, monazite (RE minerals) and dolomite (a common gangue mineral) were investigated by zeta potential measurements. These measurements are affected by various ions present in solution; for bastnäsite, monazite and dolomite, some of these ions are H+, OH-, PO43- and CO32-. Dolomite, being a sparingly soluble mineral and a primary component of the ore, may be the greatest contributor of these ions in solution in the form of CO32- ions. Thus, different sources of CO32- ions (from dolomite dissolution and from Na2CO3) were investigated. The research work aims at elucidating how these reagents may influence the minerals’ surfaces. The results have shown that dolomite supernatant and sodium carbonate greatly affect the electrokinetic properties of each minerals. The addition of dolomite supernatant have resulted to relatively similar zeta potential of the minerals; while, sodium carbonate have affected them differently. These observations could be useful in efficient flotation of bastnäsite and/or monazite from bastnäsite-monazite-dolomite system.INTRODUCTIONThe increase in the demand for rare earth (RE) elements has driven the search and development of new deposits. Out of 53 rare earth projects in the world, 19 can be found in Canada (Hatch, 2015). These include the Niobec project of Magris Resources Company in Quebec. This deposit contains a significant amount of rare earth minerals (such as bastnäsite and monazite), with carbonates (such as dolomite) as the primary gangue minerals."

Jan 1, 2016

By T. A. Chepushtanova, I. U. Motovilov, V. A. Luganov, G. D. Guseynova

"Kazakhstan has significant reserves of oxidized nickel ore with low nickel content. Processing of such ores is effective via pyrometallurgical technologies such as smelting to ferronickel or matte with consecutive extraction of metals from melting products. There are also many options for direct hydrometallurgical processing. However, they do not provide high nickel recovery.We studied extraction of nickel and cobalt by using combined technology of low-grade ore processing from the Shevchenko Kazakhstan deposit, which includes smelting to poor matte followed by hydrometallurgical processing of the matte. The nickel content in the initial ore was 0.75–0.9%. Pyrite concentrate of Sokolov-Sarybai Kazakhstan deposit containing 0.17% cobalt and 0.06% nickel had been used as a sulphidizer at smelting.As a result of the study, we were able to extract up to 98% of the nickel and up to 80% of the available cobalt. Obtained matte contained 3.1% nickel, 0.29% cobalt, 71.6% iron and 24.3% sulfur. Matte leaching was carried out by hydrochloric acid. The iron content in the pregnant solution was 170–185 g/dm3. Nickel and cobalt precipitation from the pregnant solution was carried out by hydrogen sulfide. Initial matte or cast iron was used as neutralizers during the process. Practically complete precipitation of nickel was achieved at 3–5% excess of neutralizer at 333–343°K in 4 hours; up to 95% of cobalt precipitation was achieved in 50% excess of neutralizer at 363°K in 8 hours. The purified solution contained 200–600 mg/dm3 of nickel, 80-100 mg/dm3of cobalt and 175–185 g/dm3 of iron. The purified solution allows to obtain iron oxides by high-temperature hydrolysis, and to regenerate hydrochloric acid.As a result of non-ferrous metals precipitation we obtained sulfide concentrate with concentration of Ni up to 25% and concentration of Co up to 5.5%. The technology is recommended for semi-industrial testing."

Jan 1, 2016

By V. G. Papangelakis, M. Cheung, M. Dry

The high pressure acid leaching of laterite was modelled and simulated using a combination of two commercially available software packages, namely Aspen Plus 11.1 and the OLI Stream Analyzer. New kinetic parameters for the acid-controlled metal dissolution and precipitation reactions at temperature were first determined from previous experimental data on the leaching of limonite. A grain model with cylindrical pellets was used to model the solid-liquid dissolution reactions. Precipitation reactions were modeled via aqueous equilibrium chemistry. A dedicated thermodynamic database previously developed at the University of Toronto was used in conjunction with the OLI software to model the solution chemistry and calculate the concentration of hydrogen ions in solution at the leaching temperature. Mass balances were handled by Aspen Plus. The simulation gave good predictions of nickel dissolution under industrial and laboratory conditions, for the dissolution of limonite and limonite/saprolite blends. Computational

Jan 1, 2005

By Liang Zhen, Jian-Tang Jiang, Guo-Ai Li, Xiao-Ya Wang

"Deformation behavior of 2A97 aluminum alloy containing coarse secondary phases was studied using uniaxial hot compression (HC, 340–490°C, 0.4001–1 s-1). The flow stress could be described by a Zener-Hollomon parameter in hyperbolic sine function with the hot deformation activation energy of 237 kJ/mol. Based on the experimental data and dynamic materials model, processing maps were generated to demonstrate the hot workability of the alloy. The coarse secondary phases experienced dissolution by varying degree under different deformation temperature, which producing different effects on the microstructure evolution. When deformed at relatively low temperatures, a mass of fine grains shaped up in the original grains and grain boundaries, and the dominating deformation mechanism was believed to be dynamic recrystallization. As the deformation temperature rising to 490°C, most secondary phases disappeared and few recrystallized grains were observed, indicating that the secondary phases dissolved sufficiently along with dynamic recovery occurred during the hot deformation. Particle stimulated nucleation related to the coarse secondary phases was believed to promote the recrystallization and the recrystallization behavior was sensitive to deformation temperature.INTRODUCTION Al-Li alloys has received much attention as new promising structural materials in the aircraft and aerospace industries, due to their lower density, higher elastic modulus and improved fatigue crack growth resistance in comparison with the conventional commercial aluminum alloys (Ou Ling, 2015). 2A97 alloy is one of the 3rd generation Al-Li alloys targeting at comprehensive improvement of aviation aluminum alloy and applications for wing spars and ribs to other internal structures for transport aircraft. Al-Li alloys are usually formed by hot deformation, either by rolling or extruding. The deformation behavior and resulted microstructure evolution during the forming process mainly dominates the formability of the alloy and the serving performances as well. Therefore, the deformation behavior and microstructure evolution at elevated temperature need be made clear for optimizing the hot processing parameters and controlling microstructure evolution."

Jan 1, 2018

By G. Morin, G. Marin, M. C. Parr, J. Carignan

"Investment casting offers many advantages for the near net shape production of complex geometries, however, molten titanium reacts with most of the refractories used in investment casting shelling systems, which leads to the formation of an oxygen contaminated surface layer. This layer, called alpha case, is 0.1 to 0.6 millimeters in thickness according to the casting section size and must be removed either by mechanical or chemical milling processes. Alpha case removal processes affect casting tolerances and may contaminate the part intended for medical applications (e.g. embedding of abrasive grit media in the alloy). A shelling system based on an yttria prime slurry has been developed and was found to almost suppress the mold metal reaction. Yttria is an expensive refractory, but slurry life was found acceptable for small castings using a closed container and flow coating process instead of conventional pattern dipping. Alpha case depth has been determined for Ti6Al4V by metallographic techniques and microhardness measurements on different step block casting cross sections. Alumina and yttria second prime stuccos were evaluated in this study. The shelling system minimizes finishing operations in the production of casting for medical applications.INTRODUCTIONTitanium investment castings have been in the commercial market since the beginning of the titanium era in the mid 50’s. Investment casting is a cost effective way to produce complex parts for medical, aerospace and chemical processes applications. Investment casting of titanium is difficult due to the high reactivity of titanium with air and refractories used for shell mold building especially for the face coat. Melting is done under vacuum and no shelling system has been proven effective to suppress the mold-metal reaction yet. The main issue with the mold-metal reaction is the formation of an oxygen enriched zone at the surface of the castings named alpha case (Frueh et al., 1997; Kim, 2002; Saha, 1986). The alpha case is brittle, reduce the fatigue life in service of the parts and must be removed by chemical milling.For industrial purposes, calcia partially stabilized zirconia based slurries have become widely used in titanium investment casting for primary coats due to a combination of limited metal shell reaction. Calcia stabilized zirconia slurries have an acceptable shelf life and offer an interesting production window. Our experience shows that a resulting alpha case depth is 280 micrometers for a casting section of 6.35 mm in thickness is typical with such a shelling system (Morin, 2013)."

Jan 1, 2016