Search Documents

By S. Mostaghel, Fariba Azgomi, Steven Goodman, M. Oliazadeh

"It is known that copper loss to the slag phase can be in the forms of chemical dissolution and mechanical entrainment. The contribution of each mechanism to the total Cu-loss depends on different parameters and may vary significantly. To reduce emissions to the atmosphere and to shorten the converting cycle, most industrial processes are aiming at production of high matte grades. Increased oxygen-to-sulfur potential, required by these processes, results in a highly oxidized slag, which in turn leads to an increased concentration of the chemically dissolved copper in the slag phase. Hence, slag cleaning processes are becoming increasingly important for economic viability of the smelting operations. Hydrometallurgical, pyrometallurgical, and mineral processing routes have been used for copper recovery from slag. The current article reviews a trade-off study evaluating two of the commonly used methods (namely flotation and electric slag cleaning furnace) by comparing the technical pros and cons, operability/maintenance requirements, and capital/operating costs of the operations.INTRODUCTIONLarge volumes of smelter and converter slags are produced by copper smelters around the world. It is estimated that for production of each ton of metal 2.2 tons of slag is produced (Gorai, Jana, & Premchand, 2003). Considering the current pressure on the mining and metals industry for “zero-waste, sustainable and environmentally friendly” extraction of metals, it is absolutely essential for metal producers to improve their efficiencies in order to remain competitive. To meet these objectives, almost all metal producers, from steelmaking plants, ferroalloys, base and precious metals producers, are trying to reduce their metal losses to the slag phase. In particular, copper producers are aiming to produce higher matte grades in their smelting furnaces to reduce the converting time and improve their overall throughput. Copper smelters need to minimize their copper/precious metal losses to the slag phase before final landfilling/use of slag. The current article, therefore, briefly reviews the copper loss to the slag phase, methods of metal recovery from the slag and then presents a trade-off study conducted for a green field flash smelter of the sulfide concentrates. A comparison was made between two of the major process routes for metal recovery from slag, namely slag cleaning furnace and flotation."

Jan 1, 2016

By S. Perez

Core drilling is a fundamental process in the mineral exploration industry. As deep exploration in hard rocks is accelerated due to the depletion of near ground mineral resources, deep-drilling operations need to reduce their reliance in operators experience and begin to implement new technologies in order to increase efficiency and cost-effectiveness of the overall process. Currently, lack of real-time information on the bit/rock interaction is a major problem. Therefore the mechanism behind the acoustic emission, which is a proven technique for remote monitoring, generation in mechanical rock cutting must be understood in order to provide real time information about the rock. This paper aims to identify the influence of mineral composition of granitic rocks on the acoustic emission (AE) during rock abrasivity test with a single contact tool and to evaluate the feasibility of AE as a means to infer Cerchar Abrasivity Index (CAI). Single contact tool will provide precise and accurate description of the source of AE. To provide constant grooving speed Cerchar apparatus was modified to monitor AE during rock/tool interaction. Tests on the modified Cerchar apparatus are carried out under the static load of 70N and cutting speed of 1 mm/s. A Scanning Electron Microscope (SEM) is utilized to visualize the groove in the rock and to identify the mineral composition through Back-Scattered Electrons (BSE) reflected from the rock sample. Based on the microscope images, it was found that biotite shows a larger groove area and plate-like fractures accompanied with burst-type AE signal, whereas plagioclase and quartz, which are characterized by similar hardness and BSE brightness, possess shattered-like fractures and more continuous-type AE signals. In addition, a-value of the Gutenberg-Richter scale has been found to well correlate with Cerchar Abrasivity Index (CAI).

Jan 1, 2015

By Y. G. Yaroshenko, V. Y. Baldin, Y. M. Gordon

The manufacture of sulphuric acid from the off-gas of pyrometallurgical processes in the production of heavy metals is one of the common methods of effective recycling of sulfuric anhydrite. The new Impact-Inertial Devices with the rectangular contact channels (IIRCh) and the internal circulation of liquid allow the injection of an absorber into the phase's interactive cell by utilizing the gas stream energy and by this way increasing the sulphuric acid yield and reducing the power consumption. These devices have the following advantages: simplicity of design, smaller size, low capital expenses, absence of irrigating system, high operational reliability, simultaneous cleaning of solid, gaseous and liquid impurities and also cooling of gases etc. The IIRCh efficiency is almost 18 % higher and they require 1.3-2 times lower energy when compared with Venturi Absorbers. Also the elevation of spraying nozzles or injectors is 1.5 times lower in the IIRCh case.

Jan 1, 2004

By David Sanscartier, Elizaveta Petelina, Alexey Klyashtorin

This paper provides an overview of the radiological risk mitigation approach applied by the Saskatchewan Research Council (SRC) for the remediation of 35 legacy uranium mine sites in northern Saskatchewan where uranium exploration and extraction took place in the 1950–60s. Mining activities resulted in an irregular increase of the gamma radiation dose rate (up to 18 μSv/h). The radiological objectives for the sites include a gamma dose rate at a spot (<2.5 μSv/h above local background), and the dose rate averaged over a hectare (<1 μSv/h above local background). These objectives are generally achievable at the impacted sites through the installation of shielding soil cover. This method may be impractical for site areas with rough terrain (e.g., steep slopes) and/or difficult access. A risk assessment approach is applied to determine if these areas can be safely left uncovered or if additional mitigation measures should be implemented. The risk assessment approach is based on two factors: (i) the ambient radiation dose rates collected through gamma surveys, and (ii) actual land use data collected through various surveys of activities of local community members at the sites. Exposure scenarios based on four land uses are applied to estimate a potential annual dose load for members of the public. The estimated doses are compared with the criterion of 0.3 mSv/a recommended by the Canadian Guidelines for the Management of Naturally Occurring Radioactive Materials (NORM). If the criteria are not satisfied, a mitigation plan is developed, and post-remediation gamma levels are modelled using GIS tools to evaluate the performance of the proposed mitigations. The proposed approach allows the team to optimize resources for the site remediation so that public exposure to NORM are as low as reasonably achievable after remediation.

Jan 1, 2020

By Northeastern University, B. Y. Cui, B. Y. Wang, D. Z. Wei, W. G. Liu, Z. C. Guan, S. L. Gao

To recover iron values from low grade ores by reverse froth flotation method, further research on cationic collectors used in reverse flotation of iron ores is launched to promote the utilization efficiency of iron ores. In this paper, one new cationic surfactant, bis(2-hydroxylethyl) dodecylamine (BHD), that could be dissolved in water easily was used as collector for quartz flotation. Flotation results indicated that BHD shows stronger collecting performance on quartz than hematite. The maximum recovery of 96.30% to quartz is obtained at a collector concentration of 20.0 mg/L in the pulp pH range from 5 to 7. This collector can be used to float quartz from hematite. And optimal separation results with 86.59% iron recovery and 66.60% iron grade to synthetic sample were achieved at a collector concentration of 20.0 mg/L and pulp pH of 5.02 when hematite and quartz were mixed at a mass ratio of 3:2. The adsorption mechanism of the collector on quartz surface was investigated by XPS analysis, infrared spectroscopic analysis and zeta-potential measurements, which revealed that electrostatic attraction and hydrogen bonding adsorption occur between collector and quartz surface.

Jan 1, 2016

By K. O. J. Sidwell

STRATMAT LIMITED, through its subsidiary, the Strategic Manganese Corporation, controls two adjoining iron-manganese properties five miles west of Woodstock, New Brunswick. One is a staked property of 77 claims traversed by one trunk highway, several secondary roads, and a branch line of the Canadian National railway. The other property, a 20-square-mile Concession immediately to the north-east, is also traversed by an excellent network of roads. Both proper-ties are situated in gently rolling farmland. The deposits were discovered in 1836 by Dr. C. T. Jackson. The first attempt to exploit them was made in 1848 when a blast furnace was erected with a capacity of 7 tons per day. The ore was mined by a series of deep trenches that followed the folds of the enclosing slates. In the late years of operation, bog iron ore from Burton and Maugerville, in Sunbury county, was used in conjunction with the Wood-stock ore. An additional 5-ton furnace was erected in 1863 and mining was carried on intermittently until 1884. No further extensive work was done until 1953. During the period of activity, approximately 70,-000 tons of ore are said to have been smelted ( 1). During these earl y operations the Iron Ore Hill and Moody Hill deposits were partially opened, with the ?bulk of the furnace feed being mined from the Iron Ore Hill workings. The low tenor and apparently limited extent of the deposits, the high. ?content of phosphorus, and the increasing scarcity of fuel, were the chief factors that brought the enterprise to an end.

Jan 1, 1957

By K. Ogawa, T. Yokoyama

Hydraulic fracturing technique, an applied technique to cause tensile fractures to rock by injecting water pressure to a certain closed section of the borehole, is a measurement method of in-situ rock stress. This technique has the highest track record for techniques used in sub 1000 meter. A feature of this technique is comparatively simple and easy for in-situ stress measurement, because the measurement is applicable when a drilled borehole is available. The predominant advantage of this method is that elastic constants such as Young’s modulus and Poisson’s ratio are not required for determining the value and direction of initial stress. The factors to determine the stress state are the water pressures of re-opening and shut-in of fractures around the borehole wall and its directions. With conventional methods, however, the accuracy of the derived stress states from the observation equations was often adversely affected by the lack of consideration of the remaining water pressure in fractures and insufficient stiffness of the pressurization system. We have developed a new hydraulic fracturing system based on a new test method concept overcoming these defects, and applied to a 300 meter deep borehole in granite. The most important improvement of the new system is an employment of a syringe pump which enables an accurate flow control of fluid with less than 1ml/min in the pressure of 30MPa. Therefore the new test system has a quick response for pressurising in the interval zone, and the measured data was confirmed extremely accurate.

Jan 1, 2015

By A. A. Rafiei, J. A. Finch

A previous study comparing n-pentanol and the polyglycol Fl50 showed that the two reagents could give the same gas holdup but with different size bubbles. The finding implies that bubble rise velocity depends on the surfactant (frother) type. A study using bubble swarms supported the frother type effect but bubble interactions were a possible confounding factor. This study resolves the question by measuring the rise velocity of single bubbles of 0.8-2.5mm diameter over a distance :::: 300cm in n-pentanol and F 150. It is shown that at typical frother concentrations used in flotation that the rise velocity in n-pentanol remains comparable to that in water alone while in Fl50 the velocity is significantly reduced. The results confirm the suspected impact of frother type. It is illustrated that in n-pentanol the rise velocity does not reached terminal; while in Fl50 it does and this is the source of the velocity difference. Advances

Jan 1, 2009

By Finley A. Campbell

"Nickel-copper sulphide deposits associated with basic rocks in the Quill Greek area and the White River area in the Yukon Territory have been studied and compared from the view-point of their general geology, structural geology, and the mineralogy of the ores. The relative amounts of the major constituents, magnesium, iron and calcium, and the minor constituents, nickel, cobalt and chromium have been determined spectrographically for two cross sections of the basic rocks at Quill Creek and one at White River. These data, along with petrologic and field evidence, were used to determine the sill and dyke-like character and nature of the basic intrusions. Loss on ignition is employed as a measure of the degree of serpentinization. The distribution determined shows that the serpentinization does not appear to have greatly influenced the inferred original distribution and lithophile associations of magnesium and nickel. The cobalt content may have been altered.The nickel content of the serpentinized peridotites ranges from an average of 0.36 per cent in one section to an average of 0.24 per cent in each of the other two sections studied. The cobalt averages 0.0038 per cent in the samples from the two Quill Creek sections and averages 0.0042 per cent at White River. These results have been compared with other available data.The sulphide ores are later than both the peridotite and gabbroic rocks and may be co-magmatic with them. There is no evidence in these areas to support an origin by lateral secretion; on the contrary, the alteration associated with the ores, the mineralogy and spatial relationship to basic and ultrabasic rocks, indicate the ores are derived from a basic magma."

Jan 1, 1960

By Matthew A. Baumann

Tooth wear on mining shovels presents a challenge for productivity. A shovel with worn teeth suffers from increased digging forces, longer fill times, and an increased likelihood of lost or broken teeth and adapters. Efficient maintenance planning relies on knowledge of tooth decay rates and patterns. A fully automated wear monitoring system can record detailed logs of tooth wear, permitting G.E.T. personnel to optimize maintenance scheduling. Studies have demonstrated that planned tooth change-outs result in significantly reduced costs as compared to unplanned maintenance. A machine-vision-based tooth-wear monitoring method is introduced. A rugged camera is installed on the boom of cable shovels, or on the stick of hydraulic shovels. The images are processed using a photogrammetric algorithm to determine the individual tooth lengths. Tooth length data is collected at intervals during shovel operations, forming a profile of the current wear state, speed of decay, wear pattern, and expected lifespan of teeth. A case study in a South American mine on a Komatsu PC8000 hydraulic front shovel is presented. Tooth wear is tracked over a 6-day period and wear rate statistics are computed for 6 teeth. This validates the system and provides an example of how wear patterns can be recorded and analysed by an automatic system. Armed with this data, mine personnel can reduce the cost and lost time due to unplanned maintenance, and observe the effects of mine conditions and operator behaviour on tooth wear.

May 1, 2011

By N. Behnood, W. Pascheto

"Laboratory wear tests are important tools that can be used for the evaluation of materials for wear applications and mitigation of wear problems in the mining industry. However, laboratory test parameters must be fully characterized and test results must be carefully interpreted if a material selection is to be made. Failure to do so may lead to erroneous conclusions. Suitable lab-oratory tests are valid only if they reflect the field conditions to which materials are subjected. Therefore, it is important to know, in detail, the field conditions, as well as the wear test techniques being considered. It is important to recognize the limitations of the various wear tests and the wear test data published in the literature. This work will review present wear testing technology, including the various wear tests avail-able, wear test equipment and test limitations. Several wear test procedures will be related to common equipment used in the mining industry.IntroductionThis paper will concentrate on non-lubricated wear mechanisms, because they are the most costly to the mining industry. Very frequently we are faced with the task of selecting materials for wear applications or improving existing systems that are giving poor performance. There are plenty of examples in the literature of practical wear cases and ranking of materials for wear applications. It is also very common to find materials manufacturers’ data -sheets listing wear tests results by comparing their materials performances against those of competitors. Much of the published wear data lack the description of the type of wear test, test parameters and the type of wear mechanism to which the data should be applied (if any).Before considering wear test data for a specific problem one should ask which type of wear mechanism is involved? What type of test and what test parameters were used to produce the results? Even if the type of wear tests and parameters are known, how accurate and useful are the published wear data? How are the results related to a particular type of wear? It is important to point out that even the standardized wear tests, such as those in ASTM standards, have limitations. Such limitations are recognized and clearly spelled out in the standards themselves. Basically, wear tests may lead to erroneous results if the test is not able to repro-duce the same wear mechanisms encountered in the field. Therefore, the use of published results may be helpful, as a starting point, but may be of little value for a final material selection.This work will discuss the main types of non-lubricated wear mechanisms encountered in the mining industry. In addition, it will discuss the many wear tests available and their correlation with the various types of wear mechanisms. The limitations of several standardized wear tests and the limitation of using published wear data will also be discussed."

Jan 1, 1997

By Jing Chai

The Cenozoic unconsolidated strata with the thickness of 100 to 240m in the east area of China are composed of clay, sandy clay and hardpan, etc. Numerous shafts of the coal mines in these areas have been damaged to various degrees since 1987, with the main reason for this being the subsidence of the super-thick unconsolidated strata. To prevent the continuing settlement deformation of unconsolidated strata caused by groundwater removal, long-term water injection through multiple boreholes controlled the settlement deformation of unconsolidated strata. A new type of fiber Bragg grating (FBG) sensing system was successfully used for real-time strain monitoring of the unconsolidated strata during water injection at a coal mine in China. A mathematical model for the compression settlement induced strain calculation is proposed which can assist understanding of the effect of water injection on the ground. With the increase in water injection, the unconsolidated strata compressed state was improved by the transition of the stress state from compressive to tensile stress. The wavelength change of fiber Bragg grating sensors corresponded with the trend of the water level in the same strata. Engineering practice indicates that these sensors can normally, safely and reliably survive conditions associated with hydrous unconsolidated strata. The FBG sensing can be used for continuous lifetime monitoring of the system, starting with real-time monitoring during low-pressure water injection process of multi-borehole. The results will give important guidance for water injection and mastering stratum subsidence.

Aug 1, 2013

By R. ZapataN.

"In the following report, Altonorte Smelter owned by Xstrata will explain its experience with its denominated furnace called ""Continuous Altonorte Reactor"" since started up in March 2002. The Reactor is the main and only smelting furnace since the operation of Reverb Furnace was stopped (15 days after the start up of the Reactor) and it can be operate with dry concentrate for injection by tuyere and wet concentrated via Garr Gun when the injection system fails. From the started up of the Reactor, three operational campaigns have been carried out where in each one they have been increased their smelting throughput and availability. The flexibility reached by the technology bath smelting has allowed a high level of smelting of concentrate and revert materials. The high availability of the Reactor and overcoming problems that were considered of high complexity like the extraction of white metal and slag, refractory campaign, etc. has allowed the Altonorte smelter to project to smelting 1,200,000 tonnes per year with its only Reactor in next year."

Jan 1, 2007

By K. Sawamukai, S. Ogasawara, D. Umenai, T. Tsuruta

"Removal of cobalt, strontium or cesium ion from the aqueous solution containing each metal ion only using microorganism was examined. Arthrobacter nicotianae which had a high ability to remove cationic metal ion was used for the removal of each metal. The removal of cobalt, strontium or cesium using A. nicotianae cells was affected by the solution pH, concentration of metal ion, and cell amount. The effects of above mentioned factors on the removal of each metal and time course of strontium from the solution containing each metal only using A. nicotianae cells were reported in this paper. INTRODUCTIONRadioactive elements, such as cesium, iodine, strontium, plutonium, barium, cobalt, lanthanum, yttrium, and tellurium, were detected around Fukushima Daiichi nuclear power plant, which was damaged by the magnitude 9.0 earthquake and the tsunami followed.The removal of radioactive elements from contaminated sources is a worthwhile subject to investigatein terms of environmental control. Research efforts have been especially concentrated on studying microorganisms that remove uranium including bacteria (Andres et al, 1993, Hu et al, 1996, Marques et al, 1991, Strandberg et al, 1981), actinomycetes (Byerley et al, 1987, Friiss and Myers-Keith, 1986, Golab et al, 1991), fungi (Byerley et al, 1987, Galun et al, 1983a, Galun et al, 1983b,Tsezos and Volesky, 1981, White and Gadds, 1990) and yeasts (Strandberg et al, 1981, Schmate II et al, 1978).We have investigated removal and recovery of uranium from aqueous systems using microorganisms isolated from uranium mines. We identified some strains of bacteria with extremely high uranium removing abilities (Sakaguchi et al, 1996), and thus, the microbial biomass may be considered as an adsorbing agent for the removal and recovery of uranium and heavy metals present in aqueous systems around Fukushima Daiichi nuclear power plant.In the present study, we screened various species and strains of bacteria, actinomycetes, fungi, and yeasts for their ability to adsorb uranium (Tsuruta, 2002). Basic features affecting uranium adsorption?co-existing cations and anions, cell amounts, pH, and the adsorption time course?by Arthrobacter nicotianae cells, which adsorbed the largest amount of uranium, were also investigated. In addition, we examined the removal of an other actinoid element, thorium ion, which may be present with uranium in refining effluents.In this paper, the removal of cobalt, strontium, or cesium from the solution containing each metal ion using A. nicotianae cells is discussed."

Jan 1, 2012

By Rhual L. Guerguerian

MINING has been practised by mankind for over sixty centuries (1). In 1876, the "ball mill" was patented, and during the century that followed rotary grinding developed to the state where individual machines are treating tens of thousands of tons of ore per day. This paper gives a brief description of design practices prior to the availability of advanced facilities, followed by modern analytical design development at Dominion over the past ten years.

Jan 1, 1978

By Liu Liu

In the recent 10 years the rapid development of Chinese steel industry has attracted the attention of the world. The technological progress of converter steelmaking has played an important role in this process. First of all, slag splashing has been extensively adopted by Chinese steel companies in various sizes of converters from largest to smallest ones, and even including those using special hot metal containing V and Ti. Remarkable metallurgical results have been achieved. Up to now the average converter campaign life has reached nearly 10,000 heats, and the longest exceeds 30,000 heats in three melt shops. Based on this process, the long-life combined-blowing converter steelmaking technology has been developed. Slag splashing has been used to form a gas permeable "slag mushroom" on the top of bottom nozzles to protect the nozzles. In order to keep the effective bottom blowing, furnace bottom thickness control technique has been developed to prevent the furnace bottom growth. It makes the service life of bottom nozzle the same as the converter campaign life (average 10,000 heats and longest > 30,000 heats). The complete combined blowing was ensured through out the furnace campaign. Concentration product [C][0] is in the range of 0.0023 ~ 0.0030%, the T.Fe in the slag is lowered by 4 ~ 6%, and the [0] in steel is decreased by 100 ~ 250 ppm.

Jan 1, 2004

By X. Shi

Magnesium, the lightest structural metal, has not yet been considered as a serious contestant for automotive use due to its weaknesses in corrosion. Electroless nickel-boron alloys are well known for their corrosion resistance and hardness. An electroless nickel-boron layer was successfully deposited first on the chemical conversion pre-treated AZ31 alloy and also on the Ni-P coating which was deposited on the conversion coating. The electroless bath contained nickel sulphate and dimethylamine borane (DMAB) as main salts and the samples were activated by a 5 g/L AgNO3 solution before the electroless plating process. The presence of the conversion coating between the nickel coating and the AZ31 substrate acted as a barrier and prevented corrosion of the alloy. The morphology of the nickel-boron layer was studied using SEM. The crystal structure and the composition were examined by EDS and the hardness was measured. The corrosion behaviour of the nickel-boron layer deposited on the conversion coating and on the Ni-P coating was studied using potentiodynamic polarization in a 0.5M NaC1 solution. A saturated standard calomel electrode was used as a reference electrode. The results show that the nickel-boron coatings had a significantly better corrosion resistance than the AZ31.

Jan 1, 2006

By A. J. Petrina

"At Craigmont Mines Limited, Merritt, B.C., tests were begun in March, 1965 to evaluate the use of shotcrete as a method of ground support m development headings; previously, ail drifts had. required support, which was accomplished mainly by timber and occasionally by the use of rockbolts. The tests demonstrated conclusively the effectiveness of shotcrete for supporting Craigmont's ground. Gradually, the use of timber for ground support was virtually eliminated in favour of shotcrete. This paper describes the equipment used, the operation of the equipment, pertinent cast data and opera ting details. Also discussed are other uses developed for the shot-creting equipment, the use of reinforcing bar rockbolts, and a method used at Craigmont for lining long vertical ore passes with steel plate and concrete as part of the raising cycle."

Jan 1, 1968

By B. K. Mishra, P. Patnaik, B. C. Tripathy, I. N. Bhattacharya

Cobalt is an essential metal considering its numerous industrial applications. The demand for the metal is increasing due to its wide range of use in, for example, rechargeable batteries and as an alloying element in super alloys. Cost effective production of Co is critical. Electrowinning from aqueous sulphate solutions is the preferred technology available for the production of Co. Attempts are being made to produce uniform, smooth and bright deposits of cobalt metal. Use of organic additives in the electrolytic bath improves current efficiency and deposit morphology of the metal. We investigated the effect of quaternary amines TEABr, TPABr and TBABr during cobalt electrowinning from aqueous sulphate solutions. Among the additives studied, TEABr yielded the best results. Smooth and bright deposits of cobalt were obtained at low concentration of TEABr (10 mg/L) maintaining a very high current efficiency of 99.6%. X-ray crystallography indicated that (100) is the most preferred plane of crystal growth.

Jan 1, 2014

By F. W. Guernsey

Of all the elements, sulphur occupies a place by itself. It is mined in situ, in such quantities and of such purity that, as regards the tonnage produced, it is the first of any element on the list. Iron and coal the great tonnage producers, are combinations of elements, while sulphur is mined and marketed almost chemically pure. It is sold, in large quantities, commercially, calling for a purity of 99.5 per cent while for medicinal purposes, the Pharmacopoeia requires only 99 per cent. purity. It is a very common commodity, and like many common things is of extreme importance, in the progress of our civilization. The substance has been known from the earliest times, the word sulphur being derived from the Sanskrit Culvari", hence the Latin Sulphur. Commercially it is also called brimstone, this word being a derivative of the Anglo-Saxon Bryne Stane or burning stone. From our younger days, we have been more or less familiar with the mineral. On the spiritual side being threatened, if we did not behave ourselves, with an ultimate consumption in a lake of fire and brimstone, (which in moments of reflexion was not pleasant to contemplate) while our bodily ills were taken care of by inward applications as a spring medicine. In both instances, the effect required, was generally attained. Sulphur occurs in nature, both free and in the combined state, it being estimated that it forms, over one tenth of one per cent of the first ten miles of the earths surface. (I do not know who did the estimating and it is not guaranteed).

Jan 1, 1923