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By I. Filippova, L. Filippov

"The by-product potential of light rare-earth elements (LREE, La, Ce, Nd) and rare-metals (W, Nb, Sn) within the St Austell kaolin deposits (UK) is related to the kaolinisation process, which liberates the accessory heavy minerals of the host granite in the clay matrix and allows their separation in the waste streams. As a consequence these minerals are pre-concentrated in the micaceous residue which displays relatively high LREE content (around 170 ppm) hosted by monazite which is mainly distributed (up to 95%) in the -100 µm fraction. A combined gravity/flotation concentration flowsheet, starting with classification of the residue into 3 size fractions (+150 µm, 150-53 µm and -53µm) was developed. This study presents the results of the clay-rich -53 µm size fraction beneficiation by flotation using sodium oleate and hydroxamate as collectors.The effect of dispersant addition during de-sliming operations on flotation efficiency was also investigated. The LREE grade in the floated product obtained with sodium oleate increased from 3370 ppm to 5350 ppm and recovery from 30% to 80% with dispersant which is attributed to clay coating. Comparison of flotation performance and Falcon Ultra-Fine (UF) concentration of monazite to previous results obtained with Falcon Semi-Batch (SB) gravity concentrator on the unscreened raw residue clearly shows that flotation of the fine residue is more efficient than Falcon UF and Falcon SB. Indeed Falcon UF produced high recoveries (87-95%) but with almost no enrichment (1.3-1.4 ratios) whereas Falcon SB concentration of unscreened residue produced higher grades (up to 0.6 % LREE) but with low recoveries (17-22 %). These preliminary results show that LREE can be pre-concentrated suggesting that the micaceous residue stream (and the associated tailings dams) could be considered as a potential resource for these metals."

Jan 1, 2016

By D. R. Nagaraj, Napoleon Tercero, Raymond Farinato

"Several studies conducted recently have shown that molybdenite flotation from Cu-Mo ores is adversely impacted in sea water at pH >~ 10.0 irrespective of the pH modifier; under the same conditions Cu sulfide flotation is relatively unaffected. This has been attributed to the presence of Mg2+ ions and their hydrolysis products in the sea water which adsorb and precipitate on molybdenite surfaces as Mg(OH)2. However, why and how Mg(OH)2 impacts only molybdenite flotation in the complex flotation pulps containing a multitude of minerals is not understood. The work presented in this paper probes the interface and interphase regions near the edge and basal planes of natural molybdenite (MoS2) in aqueous solutions and flotation pulps, particularly in the presence of copper ore pulp and added Mg2+. Differences in interaction of metal ions and their hydrolysis products (Mg2+, Mg(OH)+) were measured on the two faces of this anisotropic mineral. How those differences relate to molybdenite floatability and the impact of aqueous solution chemistry are discussed.INTRODUCTIONWater resource management is an important sustainability challenge in mineral processing. In view of the shortage of fresh water in many parts of the world, mineral processing plants are evaluating alternative sources. Seawater flotation has received much attention recently and there have been several important studies reported in the literature, particularly for the processing of Cu-Mo ores (S. Castro, 2012; S. Castro, Rioseco & Laskowski, 2012; S. Castro et al., 2012; Laskowski & Castro, 2012; Ramos, Castro & Laskowski, 2013; S. Castro & Laskowski, 2013; Laskowski, Castro & Ramos, 2013; Nagaraj & Farinato, 2014; S. Castro, Uribe, & Laskowski, 2014; Veki, 2013). The main conclusions from these studies on Cu-Mo ores in seawater at elevated pH were: a) flotation recovery of Cu sulfides is either unaffected or only marginally reduced, b) molybdenite recovery is adversely affected in seawater at pH values necessary for rejecting pyrite (i.e. pH > 10 to 10.8 depending upon particular system), and c) the precipitation of Mg2+ in seawater as Mg(OH)2 is responsible for the adverse effect on Mo flotation. In order to further investigate the individual effects of Mg2+ and Ca2+ on molybdenite depression in Cu-Mo ore flotation, Nagaraj & Farinato (2014) conducted flotation tests wherein individual metal ions were spiked into tap water during grinding of Cu-Mo ores. They showed the strong adverse effect of Mg2+ addition on Mo recovery and, to a lesser extent, on Cu recovery when pH > 9.5. Under similar conditions, Ca2+ had virtually no effect on either Cu or Mo sulfide flotation. Figure 1 below shows the previous results for Cu- Mo ores in tap water and the effect of addition of Ca2+ and Mg2+ ions. Note that in seawater the adverse effect of Mg2+ on Cu recovery was much smaller than that in tap water (Nagaraj & Farinato, 2014; Figure 4a and 4b and Table 4 therein)."

Jan 1, 2016

By E. Tulcanaza

Mining companies normally establish exploration and research programs originated with actions in embryonic stage. At their early stages of development, these exploration and technological activities are subject to uncertainties that need, first, to be resolved, deciphered or, at least, mitigated for information reporting; and later, for valuation reporting. Under these circumstances, these exploration activities follow a sequence of development phases that range from exploration work to the profile, conceptual, and finally to basic engineering phases and construction. For information reporting, the International Template for Reporting of Exploration Results, Mineral Resources and Mineral Reserves integrates the minimum standards being adopted by the relevant professional bodies in Australia, Canada, South Africa, Chile, USA, UK, Ireland, and other European countries which set up the Committee for Mineral Reserves International Reporting Standards (CRIRSCO, www.crirsco.com). These standards are based on the progressive collection of relevant information to reduce present and future uncertainties over time under a context of transparency, materiality, and technical competence. For valuation reporting several procedures have been disclosed and applied. However, in the last decades financial instruments such as real options, decision analysis, and games theory have developed into a niche of great potential for mine valuation applications. The objective of this paper is to provide a summary of the information reporting standards prepared by the Chilean National Commission for the Qualification of Competent Persons in Mineral Resources and Mineral Reserves and show a procedure and an application of real options to the valuation of the sequential development phases of a mine asset from the exploration stage through up to full development.

Jan 1, 2007

By S. Kaiman

This paper describes flotation test work conducted over the past several years at the Mines Branch, Ottawa, on the radioactive quartz-pebble conglomerate ores of the Elliot Lake area of Ontario. The purpose of this work has been to produce a uranium flotation concentrate for sub-sequent leaching operations. The results of earlier investigations are summarized and correlated with the results of mineralogical studies of the ores and flotation products. The results of recent pilot-plant investigations by flotation, as well as by gravity concentration followed by flotation of the gravity tailings, are given. The principal collector used for uranium flotation was a tall oil fatty acid, and the indicated total cost of all reagents ranged from 21 to 31 cents per ton of ore treated.

Jan 1, 1966

By O. Hungr, V. Gischig, G. Preisig

Deep-seated landslides are characterized by slow time-dependent movements induced by constant gravitational creep, and periods of acceleration associated with stress changes within the rock and the preexisting fracture network. Natural stress changes are typically caused by seasonal variations in surface temperatures and groundwater pressures, but also by rare and more violent events such as earthquakes. These processes are responsible for cyclic loading and unloading that leads to rock mass damage, fatigue and progressive failure with time, and may explain sudden, unexpected rock slope acceleration phases. In this work, we present a set of distinct-element models to investigate and compare the role of hydromechanical fatigue and seismic fatigue in the history of a deep-seated landslide. Hydromechanical fatigue arises from the fluctuation of pore pressure in fractures accompanying periods of significant groundwater recharge. In alpine areas, there are usually one or two cycles per year associated with snow melt and intense rainfall periods. In the presence of a deep confined aquifer within the rock slope, the amplitude of pressure fluctuations may reach values of 0.25-0.5 MPa. Hydromechanical models considering such pressure changes are able to reproduce observed slope accelerations-decelerations phases. Substantial accelerations may occur even in the absence of a cycle of exceptional amplitude, depending on the current state of fatigue. At a given time, one or more fractures may be critically-stressed, and a small change in applied stress is enough to cause local failure and induce a crisis of enhanced slope acceleration. This is augmented if the rock slope contains planes of weakness associated with its tectonic history, glacial debuttressing, etc. The corresponding behaviour is analogous to laboratory experiments on rock and metal fatigue. Similar fatigue effects have also been proposed for repeated earthquake events in seismically active regions. Unlike hydromechanical stress changes that occur in a more localized portion of the rock slope, those induced by passing seismic waves involve the entire rock mass. Moreover, the frequency and amplitude of stress perturbations due to earthquakes are different than those induced by pore pressure variations, although both likely contribute in combination to the degradation and progressive failure of large deep-seated landslides when both are present. The results presented illustrate that: (1) assessment of slope stability near critical infrastructure (e.g., hydroelectric reservoirs) should not only consider static stability, but also failure mechanisms related to fatigue that evolve over time and may result in an apparently stable slope progressing towards a critical state due to relatively small but repetitive stress changes; and that (2) characterization of fatigue processes affecting a deep-seated landslide requires multiparametric continuous monitoring at different observation points.

Jan 1, 2015

By W. N. B. Armstrong

CORROSION of metals, for the purpose of this talk, may be divided into two general classes, namely, atmospheric and chemical. Atmospheric corrosion is caused by the natural agents -water, air, salt, and temperature -as well as by the agents arising from industrial operations which pollute the atmosphere. Chemical corrosion affects metals in refineries and chemical plants where severe conditions exist due to .acids, alkalies, salts, solvents, gases, ?steam, etc. A special condition is encountered on road equipment and motor vehicles due to the large amounts of corrosive salts which are used on our roads in the winter. Exposure to corrosive conditions such as those referred to above causes metal to be destroyed and, therefore, it has to be protected. The non-metallic or organic coatings used to protect the metal are themselves destroyed ultimately by these same conditions. Since all types of organic coatings do not have the same kind and degree of resistance to degradation, a particular kind of -coating must be used for a particular set of conditions in order to obtain the maximum benefit. In ?addition to the above mentioned agents, organic coatings are degraded ?by sun-light, which is probably the severest single factor in the breakdown of organic coatings exposed outdoors. We can divide organic coatings, in a general way, into the following classes: (1) Conventional coatings, and (2) Special coatings.

Jan 1, 1958

By C. Stapel, P. D. Roberts, D. G. Jones, W. G. Macdonald, R. J. De Meijer

"Abstract-Measurement of natural radioactivity has been used in both a qualitative and a quantitative way in mineral exploration, particularly in the search for uranium. In the last five years, the Kernfysisch Versneller Instituut (KVI) and British Geological Survey (BGS) have designed, built and tested a new detector system that greatly improves quantitative applications in mineral exploration, especially on the seafloor and in the nearshore zone. The new system is an enhancement of an earlier BGS design. The major improvements comprise the use of a highly sensitive ?-ray detector, together with new data processing, from which concentrations of natural radionuclides may be deduced in real time. After laboratory analysis of samples, these concentrations can be converted into mineral percentages. Once the mineralogy of an area has been characterized, this conversion can also be done in real time.Thus far the system has mainly been used to map heavy-mineral concentrations in coastal subtidaland intertidal sediments. For such work the multi-sensor detector probe is towed on the seafloor and various parameters are recorded continuously. The probe contains, in addition to the gamma-ray detector, a water-pressure sensor (giving water depth) and an acoustic device to measure bottom roughness. The system, when used together with high-precision positioning systems such as D-GPS, enables the production of detailed maps of bathymetry, bottom roughness, and seafloor radioactivity or mineral distribution. These maps allow mineral concentrations to be readily correlated with seabed topography and sediment type. In the same way, ?-ray detectors could be used advantageously during dredging operations to provide on-line assessment of the mineral content of the dredged sediment as well as to guide the direction of dredging. Additionally, the same technique could be used to monitor the subsequent fate of a dredge spoil after dumping on the seafloor.Natural radioactivity arising from potassium and the thorium and uranium decay series has potential use for the fast and reliable assessment of siliciclastic and phosphatic impurities in limestones. Detection of such impurities may preclude the use of the limestone for chemical or cement production.Apart from its use in exploration, the technique has significant potential in mineral processing, particularly of heavy minerals. It can be applied as on-line quality control in dry and wet separation processes and for process control, by using decisions based on the results to control valves and other instrumentation. In addition, it can also be used in environmental monitoring of waste arising from mineral extraction and processing. In conclusion, the technique described has a diversity of applications in exploration, mining and mineral processing."

Jan 1, 1997

By C. Stapel, P. D. Roberts, D. G. Jones, W. G. Macdonald, R. J. De Meijer

"Measurement of natural radioactivity has been used in both a qualitative and a quantitative way in mineral exploration, particularly in the search for uranium. In the last ?ve years, the Kernfysisch Versneller Instituut (KVI) and British Geological Survey (BGS) have designed, built and tested a new detector system that greatly improves quantitative applications in mineral exploration, especially on the sea?oor and in the nearshore zone. The new system is an enhancement of an earlier BGS design. The major improvements comprise the use of a highly sensitive ?-ray detector, together with new data processing, from which concentrations of natural radio nuclides may be deduced in real time. After laboratory analysis of samples, these concentrations can be converted into mineral percentages. Once the mineralogy of an area has been characterized, this conversion can also be done in real time.Thus far the system has mainly been used to map heavy-mineral concentrations in coastal subtidal and intertidal sediments. For such work the multi-sensor detector probe is towed on the sea?oor and various parameters are recorded continuously. The probe contains, in addition to the gamma-ray detector, a water-pressure sensor (giving water depth) and an acoustic device to measure bottom roughness. The system, when used together with high-precision positioning systems such as D-GPS,enables the production of detailed maps of bathymetry, bottom roughness, and sea?oor radioactivity or mineral distribution. These maps allow mineral concentrations to be readily correlated with sea-bed topography and sediment type. In the same way, ?-ray detectors could be used advantageously during dredging operations to provide on-line assessment of the mineral content of the dredged sediment as well as to guide the direction of dredging. Additionally, the same technique could be used to monitor the subsequent fate of a dredge spoil after dumping on the sea?oor.Natural radioactivity arising from potassium and the thorium and uranium decay series has potential use for the fast and reliable assessment of siliciclastic and phosphatic impurities in limestones. Detection of such impurities may preclude the use of the limestone for chemical or cement production.Apart from its use in exploration, the technique has signi?cant potential in mineral processing, particularly of heavy minerals. It can be applied as on-line quality control in dry and wet separation processes and for process control, by using decisions based on the results to control valves and other instrumentation. In addition, it can also be used in environmental monitoring of waste arising from mineral extraction and processing. In conclusion, the technique described has a diversity of applications in exploration, mining and mineral processing."

Jan 1, 1997

By N. J. Shackleton, N. A. Chapman, V. Malysiak, C. T. O’Connor

In this study, the effect of using conventional crushing and high-pressure grinding rolls (HPGR) in combination with dry or wet milling was investigated using a base-metal sulphide (BMS) sphalerite and a platinum group mineral (PGM) ore to determine how these processes affect the flotation performance. In sphalerite, irrespective of the crushing procedure (HPGR or conventional), dry milling resulted in the highest grades and recoveries of zinc, whereas in PGMs, similar treatment produced the poorest results. The results were investigated further by the effect of factors such as percentage liberation and particle size on the flotation results.

Jan 1, 2012

By P. M. May, V. Gella

The deportment and speciation of trace elements during mining and minerals processing is becoming an area of increasing concern with regards to potential health and environment risks. The use of chemical modelling can enhance our basic understanding of the deportment and speciation of trace metals under conditions present in gold processing solutions, and assist in laboratory and field investigations. In this paper, we report the results of chemical speciation modelling using the JESS software package for the trace toxic elements Pb, Cd, Hg, Se and Te in cyanidation solutions of varying salinity and relate the models to experimental data. The speciation of mercury is examined in detail.

Jan 1, 2011

By S. M. C. Santos

Preliminary bench-scale studies were carried out on the leaching of a zinc sulphide concentrate from Somincor, Portugal, and the purification of the resulting pregnant solution using solvent extraction techniques. The sulphide concentrate contained 36% Zn, 36% S, 2% Fe and 4% Cu. The leaching was carried out with sulphuric acid in the presence of ferric sulphate as the oxidant. Important leaching parameters, such as the effect of reaction time, the solid-liquid ratio, temperature and concentrations of acid and oxidant, were investigated. After leaching, the recovered solution was contacted with an organic phase containing Acorga 5640 to remove the copper. Subsequently, the removal of iron from the leaching solution was achieved with a mixture of Cyanex 272 and TBP. This solvent mixture was relatively selective for iron over zinc. The stripping of the loaded solvent was performed with 200 g/L H2SO4. Six countercurrent extraction stages achieved a separation of about 99% of the iron from the leaching solution. The iron-free leachate can be further treated to recover minor metals by cementation, and finally, zinc by liquid-liquid extraction. The advantages of the suggested process relative to the traditional jarosite process are discussed.

Jan 1, 2006

By Richard K. Komarek, Antonios Zavaliangos, Roman T. Dec

Current industrial compacting and briquetting practices are largely based on trial-and¬error techniques. This paper introduces a two dimensional finite element model of compacting/briquetting process in the roller press. Compared with other modeling techniques used in the past, finite element method offers the most versatile approach because it incorporates adequate information about powder behavior, geometry and frictional conditions and offers predictions for the density distribution, velocity field, stress distribution, roll force, roll torque and other important process variables. More over, when the model includes elasticity, it offers predictions on the internal stress state in the briquet after its exit from the pressing zone. This enables to perform realistic computer experiments which are helpful for establishing the pressing system design, forming cavity geometry and process conditions necessary to produce compacted or briquetted product with the desired properties.

Jan 1, 2004

By O. G. Olvera, D. G. Dixon, E. Asselin, L. S. Quiroz

Dissolution rates of chalcopyrite (CuFeS2) were calculated using electrochemical impedance spectroscopy (EIS). The calculated dissolution rate decreased by a factor of 3.2 after the electrode was passivated. The results presented in this work indicate that the reduction of Fe3+ was the rate-controlling step for fresh CuFeS2 electrodes while the transport of cations within the passive film limited the dissolution rate for the passivated electrode. The transfer of cations at the electrode/electrolyte and passive film/electrolyte interfaces did not affect the dissolution rates of the fresh and passivated CuFeS2 electrodes, respectively. The catalytic effect of pyrite (FeS2) on the dissolution of CuFeS2 continued after the passivating treatment. The contact of fresh and passivated CuFeS2 electrodes with different FeS2 particles resulted in increased dissolution rates, due to an increase in the reduction rate of Fe3+.

Jan 1, 2014

By A. J. Baer

"DEFINITION OF THE REGION AND ITS BOUNDARIESTHE EXPOSED PART OF THE GRENVILLE PROVINCE is the southeastern part of the Canadian Shield, characterized by crystalline rocks with K-Ar ages of about 1,000 million years. Its Canadian portion is bounded on the southwest by Georgian Bay •and by Paleozoic sediments south of a line passing through Orillia and Kingston, on the southeast by the St. Lawrence River valley and the north shore of the Gulf of the St. Lawrence, on the east by the coast of Labrador and on the northwest by the Grenville front, a linear tec-tonic feature that is a metamorphic transition zone and/or a fault. Rocks located to the southeast of the front have younger K-Ar radiom€tric ages than rocks located to the northwest of it.The region is formed of complexly deformed and highly metamorphosed crystalline rocks and in part differs from other areas of the Canadian Shield by the presence of large amounts of crystalline limestone and bodies of anorthosite."

Jan 1, 1970

By L. P. Chrismas

"IN 1975, Nova Scotia produced 1.8 million tons of coal with a FOB mine value of $47.6 million. Of this total, about 30 per cent or 600,000 tons was coking coal and the remainder was steam and industrial-grade coal. The Nova Scotia Power Corporation consumed 630,000 tons in three generating stations and 570,000 tons were sold to Sydney Steel for making coke for its steel operations. Exports, principally to Great Britain, comprised 370,000 tons in 1975 in addition to the 300,- 000 tons shipped to other provinces for use by cement and pulp and paper companies. In 1975, just over 100,000 tons of coking coal were imported into the province from Alberta. Before 1975, low-volatile coking coal was traditionally obtained from the United States. In 1975, production came from seven individual mines and one project involving reclamation from mine dumps in Pictou County. Of the seven producers, four are owned by the Cape Breton Development Corporation, a federal Crown corporation; the remaining three are small independent mines, but, even though small, they are sizeable contributors to the economies of their local areas. After 101 years of continuous operation, Devco's Princess mine was closed in 1975. The Nova Scotia coal industry, in terms of value, accounted for about half of total mineral production in 1975. The industry provides jobs for 3,000 men and women. It is also significant that in 1975 Nova Scotia produced about 6.5 per cent of Canada's total coal production of 28.3 million tons. Detailed statistics on Nova Scotia's coal industry appear in the Appendix."

Jan 1, 1976

By V. V. Zubkov

The systems of geophysical monitoring have been already put into operation at coal mines and ore mines. Since at present it is rather difficult to conduct mine experiments; it is necessary to start a new step in joining of geomechanics and seismic. The linking geomechanical and geophysical monitoring at coal mines and ore mines today became possible due to progress in development of numerical methods of modeling of stress state and technology for processing of seismic information. This paper describes one potential step in linking geomechanical and seismic monitoring at coal mines and ore mines.

Aug 1, 2013

By L. Magne, A. Pinto, M. Maldonado, J. A. Finch

Estimation of gas holdup from electrical conductivity measurements has been used in lab and industrial installations. The approach is based on the application of Maxwell's model, which relates the concentration of a dispersed phase in a continuous medium to measurements of the electrical conductivity of the dispersed phase, continuous medium and the resulting mixture (dispersion). When applied to inferring the collection zone gas holdup in a three phase system and to facilitate real-time on-line measurement, the slurry is assumed to behave as the continuous medium and gas bubbles as a nonconducting dispersed phase. This article derives an equation for estimating gas holdup in a three phase system, eliminating the assumption that the slurry behaves as a continuous medium but rather as a dispersion of non-conducting solid particles in water. In this formulation only water behaves as the continuous medium in the sense of Maxwell, and gas holdup in a three phase system is then calculated from the application of the Maxwell model twice: (1) to determine solid content in a two-phase system, and (2) to determine solid plus gas holdup in a three phase system. To validate the new equation and quantify the errors incurred by assuming slurry is the continuous phase a laboratory flotation cell was instrumented to continuously measure the conductivity of two and three phase dispersions with known solids contents. As the amount of gas in a lab flotation machine is difficult to measure directly or by another indirect technique such as using pressure signals, 2.5 mm dielectric plastic spheres having a density of ca. 1.3 g/cm3 were used instead of air bubbles for validation. Experimental results demonstrated that the continuous medium assumption underestimates gas holdup and that the resulting bias error increases linearly with the solid content and decreases with the magnitude of gas holdup.

Jan 1, 2016

By W. B. Timm

Introduction In preparing this paper on Recent Developments in Gold Milling Practice, the idea occurred to me that possibly the best way to deal with the subject would be to take you in thought on a visit to the principal gold mining camps of the Dominion, starting at the east and finishing up in the west, and noting, as we go, the outstanding improvements that have been made in the last few years in the practice of gold milling. Before beginning this tour, I desire to emphasize the debt this country, and particularly our mining industry, owes to that body of trained and experienced men, little heard of, but who, working quietly on their problems, are responsible for these improvements. The metallurgists, to whom I refer, have solved many difficult problems for the mining industry, in connection with the treatment of our complex ores; for instance, the silver-cobalt ores of the Cobalt district, the gold ores of the Porcupine district, the gold-telluride ores of the Kirkland Lake? district, the copper-gold ores of Noranda, the arsenical-gold ores of the Beattie mine, the copper-zinc ores of Flin Flon, and the lead-zinc ores of Kimberley. In doing so, they have maintained the high technical standards of the profession, and the practices thus evolved are noteworthy for their high degree of efficiency. When the price of gold increased from $20.67 to $35.00 an ounce, what had formerly been thought to be a low tailing became almost an ore, so that the metallurgists are now busily engaged upon the problem of putting this railing back in its proper place of being a tailing once more, or from its value, at the present price, of anywhere from 50 cents to a dollar or so per ton, to a few cents per ton. Owing to the changing prices of the metals in the world's markets, still greater improvements in metallurgical practices are imperative. An important contributory factor towards improvement in ore dressing is the aid furnished by the microscope in the examination of ores and mill products. By making possible the determination of the mineral constituents of the ore, their association, and grain size, it gives the investigator a knowledge of his problem, before he does any actual test work. In the Mines Branch laboratories at Ottawa, its use has enabled us to predict how an ore should respond to various methods of treatment.

Jan 1, 1935

Presentation Overview Corporate Overview Kutcho Project History Exploration Development Permitting Capstone -Pursuit of Value Building a mid-tier copper producer focused in the Americas Two operating copper mines; Cozamin& Mintomines High grade and low cost 2010 forecast: 80-85 million pounds of copper in concentrates Total Cash Costs* of ~US$1.10/lb to US$1.20/lb of payable copper produced Significant by-products of gold, silver, lead & zinc Growth potential Further expansions at existing Cozamin& Mintomines High grade copper development: Kutcho project, BC Investments in Nevada Copper & Silver Wheaton 100% North American assets Low risk ?Canada & Mexico ?Conventional operations

Oct 1, 2010

By D. A. Wheeler, Rémi Tremblay

"INTRODUCTIONDuring the last few years, through Column Flotation Company of Canada ltd, the Centre de Recherches minérales has worked on the column flotation of coal, phosphate, feldspar, talc, graphite, copper, lead-zinc and diamond ores. The operating companies and prospective deposits were located in Canada and in other countries. Since these projects were financed by the concerned mining companies, all results remain confidential unless we obtain permission to publish. Three companies have graciously allowed us to use their information which I will describe in this text. These are the Polkowice copper mine in Poland, the North Coast Industries ltd graphite deposit and a talc company which preferred to remain anonymous. I will also describe our 2 inch column which was used for all tests. Data is also given on how to scale-up the 2 inch column to industrial size.Figure 1 presents a schematic of a flotation column. Feed, at a controlled rate and pulp density, enters at about 1/4 of the height of the column from the top. A controlled rate of air is bubbled into the bottom of column through a fine-holed sparger. The column volume between the feed point and the top of the sparger is called the recovery zone. Tailings, at a controlled rate, always slightly greater than the feed rate, discharges from the bottom of the column. This difference in feed and tailings flowrates is called the bias. The floated mineral is carried through the recovery zone on air bubbles which rise into the cleaning zone which is that column volume between the feed point and the overflow at the top. As the bubbles rise in this zone they are washed of gangue material by wash water which enters over the top of the froth layer. The froth layer is maintained at a given depth during flotation but this depth will depend on the froth cleanliness, for quite a bit of cleaning by wash water is accomplished in this layer."

Jan 1, 1988