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By C. Arson

"Optimizing hydraulic fracture injection parameters in order to maximize hydrocarbon extraction and to avoid extensive borehole spalling is still an open issue. In this paper, the Differential Stress Induced Damage (DSID) model is employed to simulate the anisotropic damage distribution around pressurized boreholes drilled in fractured shale. The loading path is purely mechanical: excavation and fluid injection are simulated by stress relaxation followed by pressurization. We investigate the effect of pre-existing fracture orientation, in-situ stress and injection pressure on the propagation of anisotropic damage during pressurization. Finite Element results indicate that (1) damage initiates and develops when the ratio of two in-situ stress component deviates from 1, and the magnitude of damage is proportional to this stress deviation; (2) For a given in-situ stress field, damage initiates for a certain threshold of injection pressure, and the damage zone extends as the injection pressure increases; (3) A pre-existing fracture only affects the damage zone locally; the orientation of that fracture does not affect the damaged zone, which is controlled by in situ stress and injection pressure.INTRODUCTIONHydraulic fracturing is used to increase shale permeability and to enhance hydrocarbon extraction. In order to maximize the extraction ratio and to avoid wellbore spalling and clogging during fluid injection, the parameters related to injection for each particular site need to be optimized. Therefore, it is necessary to clearly understand how shale responses upon excavation and pressurization.It is well known that breakouts grow in the direction of minimum compression and that plastic deformation around wellbores tends to arrest breakouts (Zoback et al., 1985). Laboratory acoustic emission tests revealed that fractures propagate along the direction of maximum compression stress, and fractures (breakouts) are surrounded by the Excavation Damaged Zone (EDZ), in which rock properties are weakened by the presence of micro cracks (Eberhardt et al., 1999; Martino et al., 2004). The anisotropy from orientated foliations and cracks may influence the development and propagation of fractures and breakouts (Everitt et al., 2004). Sonic televiewer logs proved that during hydraulic fracturing, fluid injection further alters the stress distribution (Evans et al., 2005). Shale natural fabric strongly affects the evolution of the EDZ around boreholes."

Jan 1, 2015

By J. G. Mieczaniec

"A key element for a successful mining operation is the grinding circuit. It must be reliable, maintainable and must perform to or above design capacities for 95% of the time. Once chosen and installed major modifications are either prohibitive or very expensive. The selection of mills and drive system is probably the single most important decision made within the concentrator complex.Economic studies revealed that the optimum expansion for Lornex was a 68070 increase in plant throughput. This indicated that the new mill would have to be larger than the existing 32-foot mills.The Lornex ore has a wide range of hardness which has a great influence on mill throughput (Table 1). To smooth out the fluctuations, a blending program ha s always been in effect at the mine, coupled with ball charge control for the primary mills. As can be appreciated, an optimum balance is difficult to achieve. A sudden change to so ft ore with a high ball charge puts the mill into jeopardy with a constant speed drive.The blending philosophy would continue after the expansion, but with the addition o f a second primary crusher, it was envisaged to have the new mill process harder ore to maintain production targets. In theory, the new mill would have a proportionally larger ball charge than the existing mills.This scheme makes the new mill vulnerable for processing so ft ore for a fixed speed mill. Thus, variable speed seemed an attractive option.In early 1979 prominent mill manufacturers were invited to submit proposals for the new mill. Fixed and variable speed mills were to be considered with mill size ranging from 32-foot to 36-foot diameter. The proposals were to include the drive, ball charge, % critical speed, couplings, gears, etc. - the complete package. The recommendations were variable with most manufacturers submitting several alternatives. Recommended mill speed varied from 68% to 78% critical. The concept of variable speed was becoming more attractive, Lornex ultimately decided on a twin DC motor drive system for a 34-foot diameter mill.After start-up it was discovered that best throughput occurred at 78% mill critical speed or top speed of the drive motors. The motor speed range was adjusted upward from 186 to 200 rpm. Today the mills operate at 79% critical or a motor speed o f 193.5 rpm.Clearly the selection of the variable speed mill allowed the flexibility to optimize throughput."

Jan 1, 1985

By R. Erpelding

High Pressure Grinding Rolls (HPGR) are said to be a good option in new grinding circuits. Due to their low energy consumption compared to other grinding systems such as SAG milling, there is a strong incentive to check their behaviour for certain ore types. With rising energy prices the operation will become even more beneficial in future. As published in the past, the HPGR is claimed to increase the liberation of the valuable mineral component within an ore. An investigation at the research centre of Polysius was conducted to substantiate the liberation behaviour in finish grinding operations. A pilot scale HPGR test unit (POLYCOM MAGRO) with a roll diameter of 950 mm and processing capacity of 80 t/h was used. Grinding tests were completed with a screen and a two stage drying air separation process (SEPOL). Analysis included standard screen analysis, fractional XRF and modern MLA technology. A technique was developed to oppose the amount of produced slimes (resuming bad flotation) against the positive effect of producing high mass fraction at flotation-easy sizes. The paper shows how effective the use of a dry grinding separation could be in terms of production of mass of liberated metal.

Jan 1, 2012

The 2-4D window shown above is the base startup window which allows you to begin a new project. ??Setting up the project is the first step ??The next step is to setup the properties to be used in this project

Feb 1, 2008

By P. E. Cavanagh

"The Davis tube test has been used for many years as a laboratory method for determining the magnetic iron re-coverable from a magnetite iron orebody. This paper de-scribes a method for determining the recoverable iron from ores of the Labrador Trough type, with the usua1 flow sheet utilizing spirals followed by magnetic separation.The mechanical structure of a metamorphosed iron ore, resulting from recrystallization over long periods of time, is the basis for the laboratory method developed. Similarities between the structures of such recrystallized ores and the structure of annealed and recrystallized steel are noted.A laboratory technique to determine the size of the different grains of gangue and iron ore minerals is de-scribed and the application of this information to arrive at recommended grinding techniques and flow sheets is demonstrated. The use of the method to determine recoverable iron in such ores is compared to actual iron recovery in the pilot-plant and commercial concentrations of the same ore.The use of a specified lower limit of recoverable iron as determined by this method, in order to design open-pit limits, achieves practical results when compared to designing a pit based on an arbitrary lower limit of total soluble iron. The Ungava Iron Ore deposits are used in giving an example of the resulting pit design changes."

Jan 1, 1968

By Maxim Martel, Karolan Tremblay

Westwood Mine has experienced several episodes of increased seismic activity. While current geotechnical characterizations such as RMR, GSI, and Q' index can identify the general rock quality and zones at risk of convergence, they fail in identifying zones at risk of seismic activity. Previous research at Westwood Mine has shown a correlation between seismicity and areas with strong rheology contrasts. To characterize this contrast, 300 UCS tests were analyzed with their associated geochemical data, and statistical analysis and regression were performed using IOGAS software to establish a relationship between resistance and geochemistry. UCS-generated data with XRF results were transferred to Leapfrog Geo to create a block model of intact rock strength. This block model dataset was used to perform a competency contrast block model, and back-analysis of specific seismic sectors at Westwood Mine were conducted to validate the model. The purpose is to develop an established geomechanical tool capable in identifying areas with greater seismic risk associated to a change in the rock strength characteristics. By identifying those areas, mitigation measures can be implemented to minimize impact of seismicity on the operation.

Jan 1, 2023

By P. R. A. Andrews, R. K. Collings

"There are more than thirty-five deposits or occurrences of celestite in Canada, chiefly in Newfoundland, Nova Scotia, New Brunswick, Ontario and British Columbia. Deposits of economic interest are the Lake Enon and MacRae deposits in the Loch Lomond district of Cape Breton Island, Nova Scotia. Two Cape Breton deposits were operated from 1969 to 1976 by Kaiser Celestite Mining Limited, which supplied an upgraded celestite concentrate to an associated strontium carbonate plant at Point Edward, near Sydney.The MacRae deposit is of current interest because of its possible development for strontium carbonate production using the ""black ash"" process. This process involves chemical leaching, rotary kiln calcining with petroleum coke, washing and treatment with carbon dioxide.Celestite is the basic material used in the manufacture of strontium chemicals, principally strontium oxide, carbonate, nitrate, chromate, chlorate, chloride, sulphide and phosphate. Strontium chemicals, in turn, are used in the manufacture of glass and ceramics, in pyrotechnic devices, in the production of strontium metal and in other metallurgical applications. Recently, strontium ferrites have been introduced into permanent ceramic magnets."

Jan 1, 1991

By J. C. Ingles

"A new technique is in the process of revolutionizing inorganic chemical analysis. Galled atomic absorption spectrophotometry, it combines the use of a special light source, a flame, and the equipment of conventional spectrophotometry, to provide a quick, reasonably accurate method for the determination of a large number of elements.This paper outlines the principles on which it is based, describes the commercial instrumentation"" available for exploiting it, and. summarizes current applications in process metallurgy."

Jan 1, 1966

By L. V. Bell

"The gold deposits of the Caribou mine are representative of those of the Province of Nova Scotia as a whole. The ore shoots within the deposits, in common with those elsewhere within the Province, are associated usually with interruptions or irregularities in the broader and uniform fold structures. The structural factors localizing ore deposition as applied more specifically to the Caribou mine are demonstrated chiefly by the close relationship of the two principal ore shoots, known as the main orebody and the 'high-grade' vein, with a pitching drag fold developed in the southeast limb of the major northeast-southwest trending anticlinal fold or elongated dome that constitutes the primary structural feature of the Caribou gold district. It is of interest to note that the evidence indicates that this drag fold, in common with other folds subsidiary to the primary fold, formed as a result of movement similar in nature to that which caused the primary fold itself. Presumably, therefore, these folds are coincident in time.The property described here as the Caribou mine is an amalgamation of two adjacent properties formerly known as the Ross and the Nova Scotia Gold, but which since 1934 have been controlled and operated as a unit by The Consolidated Mining and Smelting Company of Canada, Limited. The Caribou mine is situated in the Caribou gold district about 45 miles to the northeast of the city of Halifax and about 6 miles to the north of the Moose River gold district.The history of mining at Caribou dates back to 1867. The first recorded gold production is for 1869. From 1869 to 1933 the gold produced from the mines of the Caribou district aggregated 47,249 oz. from 93,234 tons of ore treated. The grade of the ore on the basis of the gold actually recovered from the district would thus average 72 oz. gold a ton, which, as will be noted from the following, is precisely the grade of the ore treated from the Caribou mine during operations by The Consolidated Mining and Smelting Company. These operations commenced in September, 1934, and milling on a commercial basis was under way during 1938. Since that time production, apart from a short period in 1945 during which efforts were concentrated on development work, was continuous to early in 1947, when the mine closed down owing to exhaustion of the known orebodies. Gold produced from the Caribou mine by The Consolidated Mining and Smelting Company from September, 1934, to the close of 1946 aggregated 43,205 oz. from 90,754 tons of ore milled; the grade of ore treated averaged 0.50 oz. gold a ton. The indicated average grade of O.S oz. gold a ton for the ore of the Caribou district throughout its mining history ranks somewhat higher than the 0.37 oz. a ton average for the ore milled to date from the several gold districts throughout the Province as a whole according to the production statistics of the Provincial Department of Mines."

Jan 1, 1954

By LUKE O. LINDOE

A major clay products industry in the Medicine Hat area since before 1910 has maintained a continued interest in the clays of the Cypress Hills. For the first forty years the materials used were local red-burning Cretaceous and Pleistocene clays and sands and high-quality stoneware clays of the Whitemud Formation at Eastend, Saskatchewan. Recently a much broader spectrum of raw materials has been brought into use. Including the exposures of the Eagle Butte structure, the Cypress Hills present a 1200 m section of clay-like sediments. Of this 1200 m about 94 per cent, the high montmorillonite shales of the Upper Cretaceous, can be considered useless, or nearly so; the remaining six per cent, all fresh-water beds, presents a wide variety of potentially useful materials. The development of these clay resources is complicated by deep surface creep on the south flank of the Cypress Hills, by largescale slumping on the north flank and by a structural complex in the Eagle Butte area.

Jan 1, 1984

By Peter A. Bevan

"In massive and semi-massive deposits, it is essential to take samples continuously for specific gravity determination as well as for assays of the various metals of interest. Failure to use specific gravity in mixed deposits of high density contrast will result in incorrect determinations of the average grade.Graphs and linear equations of specific gravity against the grade of one metal are not considered accurate enough in a multi-mineral deposit, but appear to be very satisfactory in a theoretical one-sulphide/gangue mix. Specific gravities based on base-metal values only in massive sulphide deposits will result in underestimating the effect of low grade areas on the average grade and also cause a reduction in the calculated tonnage.IntroductionBy definition, a base-metal assay is the percentage of metal by weight contained in a sample, whether it be a soil or silt sample, a grab, chip or channel sample, or a section of diamond drill core.In those cases where there is a series of contiguous samples, say in diamond-drill core, the average grade may be required of the various assays that are above a desired or required cutoff grade.Internal low grade or waste can be included if the assays one side or the other are used to ""carry"" the lower grade material and the resulting average grade is above the cut-off grade. To determine the average grade, the individual assays are ""weighted"" by multiplying these values by their respective lengths, adding up the cumulative assay times length and dividing by the total length. This method is essentially a weighting by volume, because the core diameter is constant and is common to all the samples being considered for estimating the average grade . If some of the core samples have much higher specific gravities than others, and the specific gravities are not used in the weighting process, the resultant average grade will be over-estimated or underestimated, depending on the grade of the heavier sections. When core assays of approximately the same specific gravity or weight are averaged by length, the error in the weighted estimation of the average grade is negligible."

Jan 1, 1993

By Harold L. Gibson, David H. Watkinson

"Volcanogenic massive sulphide deposits of the Noranda Camp cur throughout the Noranda Shield Volcano but are concentrated and along the margins of the Noranda Cauldron. The deposits are realized along synvolcanic faults that also accommodated subsince and controlled the location of eruptive centres. Deposits within e 3 000 m thick Mine Sequence formed during a period of active volcanism and subsidence coinciding with the onset of two cauldron subsidence cycles. The Noranda Cauldron was a restricted site of 10malously high heat flow and structural permeability that favoured e development of a high-temperature hydrothermal system. Metals may have been derived from leaching of aquifer rocks by convecting a water or directly from a shallow underlying magma chamber, now presented by the Plavrian Pluton, that was at its highest position !thin the crust during cauldron subsidence. The deposits formed rough a combination of sulphide precipitation from exhaled fluid td replacement at and below the seafloor in a manner analogous to ose on the modern seafloor.RESUMESi les dépôts de sulfures massifs volcano gènes du camp minier de ~uyn-Noranda sont présents dans les différentes parties du volcanluclier de Noranda, ils se trouvent concentres toutefois, en plus ·and nombre, sur le pourtour de la caldeira (cauldron) de Noranda. ~s dépôts sont localises le long des failles synvolcaniques qui ont cilite la subsidence et contrôle la position des centres d’éruption.~dépôts situes dans la séquence des mines (3 000 m d’épaisseur) sont formes durant un épisode d' activité volcanique et de subsiden qui coïncide avec l' amorce de deux cycles d' affaissement de la rldera (cauldron) de Noranda. Celle-ci Jut le site exclusif d’unflux : chaleur anormalement élevé et d’une perméabilité d’origine cucturale qui ont favorise le développement d’un système hydrothermal a haute température. Les métaux proviennent soit directement d’une chambre magmatique situee afaible profondeur, so it d’un lessivage des roches de l’aquifère par l’eau de mer circulant par convection. Cette chambre magmatique, représentée maintenant par le pluton de Flavrian, se trouvait à son niveau le plus élevé dans la croute au moment de l’affaissement de la caldeira (cauldron). Les dépôts se sont constitués par un mecanisme combinant remplacement et précipitation de sulfures à partir des fluides exhalatifs, au niveau ou au-dessous du plancher océanique, de la même manière que se forment de nos jours, les dépôts de sulfures massifs au fond des océans."

Jan 1, 1990

By R. Bainbridge

"IntroductionTHE LEAD SMELTING Department of The Consolidated Mining •and Smelting Company of Canada, Limited (Cominco), at Trail, B.C. treats materials from numerous sources for the recovery of lead, •and, of secondary importance, for the .recovery of sulphur as S02• The Department's sintering section has a .capacity of 1,500 tons daily. This section is being replaced by •a new charge-•handling and sintering plant with a daily capacity of 2,000 tons of finished sinter. Materials handled in the sintering section comprise concentrates, ores, and fluxes from Company mines and from 'custom' (independent) producers, together with intermediate products from various plants of Cominco'•s Metallurgical Division, all of which must be treated to, make up a chemically balanced charge of a predetermined lead content for the sintering plant.As received, 80 •per .cent of these materials are finer than 200 mesh, and one-quarter of the tonnage (dry basis) is a slurry .at 30 to 40 per cent moisture. This slurry, a -residue from the electrolytic zinc operation, was, for many years, partially dried before being mixed with other dry materials to make up the sinterplant charge.Some experimental work carried out in 1937 indicated that the metallurgy of the sintering operation could be improved by adopting a technique of 'wet-mixing' followed by controlled drying and nodulizing."

Jan 1, 1953

By Dennis Z. F. Mraz

"Because rock salt and pot ash formations contain particles capable of elastic deformation, the material has usually been compared with various rheological models containing elastic elements. Extensive laboratory testing of salt and potash samples resulted in various theoretical conclusions based on conditions quite different from those in a deep mine. It is felt that sufficient data have now been collected from underground measurements and observations to demonstrate the inelastic behaviour of salt masses in a deep mine. The conditions in deep salt strata can be defined as near hydrostatic, because the acting pressures are very high compared to the negligible elastic limit of the salt. The pressure field and creep around the single opening is a function of its shape, size and age. The same factors, together with extraction, determine the behaviour of the mining a rea. The application of the correct analytical method in mine design can significantly improve the excavation techniques and predetermine the long-term behaviour of openings."

Jan 1, 1973

By E. Lehtila, J. J. Talja, R. Jahila

Kopar Oy is acknowledged for engineering and manufacturing of robust systems for bulk material handling, especially at power plants and non-ferrous smelters. We have over thirty years of experience with systems specifically designed for hot and abrasive conditions, aiming at low cost of ownership, low operational expenses and high availability. Although Kopar has numerous applications in mechanical conveying, there is an increasing number of pneumatic conveying applications at copper smelters. They relate to conveying of concentrate, and primary and secondary flue dusts. Challenges of pneumatic conveying for concentrate are mechanical and do relate to broad particle size distribution and high abrasivity of the concentrate and the silica. Therefore, special attention shall be paid to system design and ceramically lined bends in the pipeline. Challenges of pneumatic conveying of primary flue dust relate predominantly to material stickiness and poor flowability which are mainly due to fine particle size and formation of sulphates and furthermore, crystalline water. Additional challenges of secondary dust, the white converter dust, are primarily due to the extremely fine 0.1–1.5 µm particle size and problems which come with this. Effect of material characteristics like size distribution, morphology and chemical composition in pneumatic conveying are discussed in detail. INTRODUCTION Fine materials like concentrate, feed mix, flue dusts (from waste heat boiler and electrostatic precipitator) and secondary dusts need to be conveyed at smelters. Both horizontal and vertical conveying and combination of those are used. For the purpose, both mechanical and pneumatic conveying are applied. Most widely used equipment are drag chain conveyors and various combination of pneumatic systems, e.g. air lift, dense-phase and dilute phase pneumatic conveyors. Kopar has 30 years’ experience with multiple material handling systems. Furthermore, acquired companies like Elmomet Oy and SITE Oy (both currently fully merged and integrated into Kopar Oy) have even longer history, especially in pneumatic conveying. It is commonly known that the finer the dust the more difficult it is to be conveyed pneumatically. Sulfates with crystal water makes it all even more difficult, if not ineligible. Challenges related to pneumatic conveying of various fine materials is discussed in detail in the paper.

Jan 1, 2019

By W. H. MacLean, S. Liaghat

The Key Tuffite is a thick (0.3 m to 6 m) and laterally extensive (-10 km) cherty, sulfide-bearing tuff unit in Archean greenstones in the Matagami mining district in northwestern Quebec. It lies at the contact of the Watson Lake Group and overlying Wabassee Group volcanic rocks, and is host to major Zn-Cu volcanogenic massive sulfide deposits. The tuff component is highly altered and its volcanic precursors are not identifiable by petrographic means. The tuff is mixed with a volcanic exhalative component comprising chert, carbonate and sulfides (pyrite, pyrrhotite, and minor sphalerite and chalcopyrite). The normative mineral composition of the Key Tuffite is 33% quartz, 28% sulfides, 16% sericite, 8070 carbonate, 6% chlorite and 9% other minerals. In the vicinity of the Bell Allard and Orchan mines, the precursor tuff components are identified using immobile major and trace elements, as Watson Lake tholeiitic rhyolite (Zr/Y = 1.5 to 3.5, LaN/ybN = 1.7 to 2.8, SiO2 = 72.5 ± 1.2 wt %, and Wabassee calc-alkaline andesite (Zr/Y = 9, LaN/YbN= 4 to 8, SiO2 = 56% to 65%). Immobile element computation techniques were used to calculate mass additions and losses in the conversion of the tuff to the Key Tuffite. Average net amounts of FeP3 (27% total iron), Si02 (14%), Cao (8%), S and K2 (+ 2%), were added, Nap was removed (-2.8%), and MgO was over-all unchanged. Total net mass change was +63%, which comprises mainly exhalative additions, but also includes changes owing to hydrothermal alteration of the tuff component.

Jan 1, 1992

By K. Meshinchi Asl

In this study the effects of T4 and T6 heat treatments on microstructural characteristics of AZ91 alloy containing Rare Earth elements have been investigated. Formation of intermetallic Al1 1RE3 needle shape particles which have a good thermal stability reduces both formation of ß(Mg17A112) and discontinues precipitation in AZ91 alloy which are dominated at the grain boundaries and are responsible for poor mechanical properties specially in elevated temperatures. For AZ91-RE samples both T4 and T6 heat treatments led to a continuous precipitation of ß particles at the grain boundaries after aging. However, in AZ91 samples (with no Rare Earths) precipitation was discontinuous at grain boundary areas. This type of precipitation is one of the main reasons of poor mechanical properties of this alloy at elevated temperatures.

Jan 1, 2007

By Derek Harvey

"The paper briefly describes the development of the Eickhoff ESA60 roadcutter which is based on the old and well used principles of the shearer loader. It is intended to show that the machine offers a viable alternative to the normal methods used for driving roadways and also for coal production . References are made to installations currently operating in Europe with applications ranging from roadway drivage to pillar recovery. The paper also looks at possible applications in Canada.IntroductionThis paper is an attempt to show how the principles used in mechanical cutting, conveying and roof support are being applied to a development system capable of catering to a variety of situations and conditions. It is also intended to illustrate how the same system can be used as a total mining system for the mining of many minerals.In order to give some sort of time perspective to the age of the principles, reference can be made to an article in Coal Mining & Processing which states:- During World War II the Germans developed the "" panzer"" or armoured face conveyor.- After the war the English developed power cutters or trepanners that were mounted on the face conveyor, this then developed into the shearer.- The first shearer was produced by the Anderson Company in England in 1950 and shortly after that the Eickhoff Company started manufacturing shearers in German y.- The first hydraulic roof support was produced in 1954 by Gullick.This is a potted history of the three major components of the new system, i.e.:- Mechanical cutting element based on the shearer.- Transport element based on the panzer.- Optional roof support based on the hydraulic face supports.It can therefore be said that since the "" youngest"" of the elements was produced in 1954 the principles of the system in respect of the rapid change in mining equipment are in fact old.Of the three major components the most important is the cutting element since the major benefits of the system are to be obtained from this."

Jan 1, 1985

By James R. Hein

Manganese nodules form at the sediment surface of abyssal plains throughout the global ocean at water depths of about 4000-6500 m. The nodules form a continuum from purely hydrogenetic (all metals from seawater) to purely diagenetic (all metals from sediment pore waters), which will determine which metals of potential economic interest are enriched in the nodules. Another important factor in metal enrichment is whether diagenesis in the bottom sediment is oxic or suboxic. There are several nodule fields in the deep ocean that have received much attention with regards to economic potential, the most important being the Clarion-Clipperton zone (CCZ) in the NE Pacific, where the International Seabed Authority (ISA) has signed 12 contracts for exploration areas, each spanning 75,000 square kilometers. Those nodules are rich in nickel (mean 1.3 wt. %), copper (mean 1.1 %), and manganese (28%), with moderate amounts of cobalt (mean 0.2%), molybdenum (587 g/t), and lithium (129 g/t). A conservative estimate is that there exists 21,100 million dry tonnes of nodules in the CCZ, yielding more manganese, twice the nickel, three times the cobalt, and four times the yttrium than the entire land-based reserve base (economic plus marginally economic plus subeconomic reserves) for each metal. Total rare-earth elements (REEs) as oxides average 0.09% in CCZ nodules, a potential byproduct even at that grade because the heavy REE complement averages 26%, compared to less than 1% for the large land-based carbonatite REE deposits. The price for HREEs is much greater than for the light REEs. For comparison, the REEs in deep-ocean ferromanganese crusts are 3 to 5 times greater than nodules and the HREE complement averages 18%. Of the 12 CCZ contracts, 7 are with States (China, France, Germany, Japan, Korea, Russia, and a group of States (IOM); and 5 are with companies: G-Tec Sea Mineral Resources NV, Nauru Ocean Resources Inc. (NORI); Tonga Offshore Mining Ltd (TOML), UK Seabed Resources Ltd (Lockheed UK), and Marawa Research and Exploration Ltd. Three other nodule fields that have received attention are in the Peru Basin, which has nodules very rich in manganese (34%) and lithium (mean 311 g/t), the Penrhyn Basin (Cook Islands Exclusive Economic Zone), with nodules very rich in cobalt (mean 0.4%); and the Central Indian Ocean Basin (CIOB), where India has an exploration contract with the ISA. CIPB nodules have mean nickel, copper, and manganese contents of 1.1%, 1.0%, and 24% respectively.

May 1, 2013

By Rakesh Kumar, Rajabrahma K., A. K. Verma, V. Mukesh

"In this study, laboratory investigation as well as numerical investigation is carried out to ascertain the transition from one mode to another for Semi-circular bend setup. Laboratory investigation is carried by varying the span length (s/2R); crack length (a/R); notch angle (a); and notch thickness (t). The specimen consists of cement, sand and water mixture in a ratio of 1:1:0.5 by weight and are prepared as per the ISRM standards (2014). Tests are conducted by a servo controlled universal testing machine at a strain rate of 0.2 mm/ min. The results are collected in terms of failure load, crack mouth opening displacement (CMOD) and images of crack initiation and propagation.Image analysis of laboratory tested samples shows that crack initiates at the notch tip when the notch inclination angle is 0°. As the notch angle increases (i.e. 30° and 60°) the fracture begins to initiate behind the notch tip. The direction of crack propagation in front and back side of the sample is same for notch inclination angle is 0° whereas it differs more and more as crack inclination increases. The transition represents the change in mode of failure from mode I (0°), mode II (30°) and mixed mode I/II fracture (60°).Finite element method used to find the transition based on MTS failure criterion. The inclination of notch is varied like 40, 42, 44, 45, and 50 deg and FEM analysis shows that the transition from mode-I to Mode-II take place at 49 deg. The same procedure can be extended to find the transition from mode-II to mode-III."

Jan 1, 2015