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By J. L. Huisman, G. Schouten

After pyrometallurgy and hydrometallurgy, bio(hydro)metallurgy is the latest development in the ongoing search for efficient and economic metal winning processes. In addition to bioleaching, other biotechnology-based applications are getting more and more accepted. In this paper a number of proven and commercial processes will be presented that can be applied for nickel and cobalt recovery and refining. These processes are based on the ability of biomass to convert the redox state of sulphur compounds under ambient conditions. They can be applied to recover sulphate from effluents or SOx from off gases and convert it to H2S or dissolved sulphide that can be reused in production or effluent treatment. Not only does this minimize the costs on resources but it also reduces waste production and improves the quality of discharges even to the point where reuse becomes feasible.

Jan 1, 2005

By M J. Daniel

Comminution is the science of size reduction of brittle materials. It is integral to mineral extraction and is one of the most energy intensive processes in the mining industry. There are a number of tests used to quantify the strength of ore, which are then used to size the AG / SAG mill in circuit design. The calculated energy utilized for breakage in these devices is based on the assumptions that the materials treated are of average shape and that the processing equipment is designed to break the ore as efficiently as possible under the given operating conditions. In drop weight tests, it was found that shape significantly influences the measured rock strength. Controlled experiments with variations in blends of rock shape show that mill throughput increases with the addition of weaker shaped rocks.

Jan 1, 2012

By S. Sillitoe

In mining, as in other business and engineering enterprises, efficient operation depends upon how well and how quickly the lines of communication can function. Mines have used the telephone on and between levels for many years, but in the hoisting shaft maintenance of physical wire connections for communication with the moving cage or skip has been found, for all practical purposes, impossible. A most natural solution was, therefore, the code-bell or buzzer signal system between fixed levels, and this has been standard practice throughout the mining world for many years. However, this system has serious limitations which make it impossible to signal a cage between levels in the shaft, and it requires crude, hazardous or costly methods for signalling during daily shaft inspection. Radio signalling overcomes these difficulties, because the communication medium is never broken and the cage-tender or shaft inspector can safely signal to, and receive signals from, the hoistman at any time from any position in the shaft, whether stationary or in motion. In addition to both audible and visual code signalling, two-way telephone communication and slack cable alarm are facilities made possible in recent commercially developed equipment.

Jan 1, 1949

By L. Voisin, K. Itagaki

In the reductive smelting of the copper concentrate like a blast furnace operation using coke as fuel and reductant or in processing the copper concentrate which contains coal in the bulk, a sulfur-deficient matte phase often coexists with an iron base alloy in the bottom of the smelting furnace. This alloy is generally called furnace residue or speiss when considerable amount of arsenic or antimony is contained in the alloy and in the extreme case of reducing condition the alloy is saturated with carbon. As a fundamental study to know the behavior of some precious metals such as silver, gold and platinum between the sulfur-deficient matte and the furnace residue or the speiss which are in equilibrium under reducing condition, the phase relations and distribution of precious elements in the Cu-Fe-S-As and Cu-Fe-S-Sb systems saturated with carbon were determined at 1473 K by a quenching method.

Jan 1, 2007

By Joseph J. Poveromo

The blast furnace today continues as the primary production method of hot metal in large-scale steel production. The blast furnace process has been the target of repeated attempts to replace it with various process options, including direct reduction and coke-free smelting reduction. While these new technologies are being adopted in appropriate niches, the blast furnace has responded to the challenge by being amenable to continuous improvement. I will review the role of the blast furnace, major developmental and improvement trends, and then list the current important issues in ironmaking. I will outline the challenges to be faced by the blast furnace to maintain its position as the primary hot metal production process. The material presented here is an update of earlier presentations made in Stockholm, Sweden, 1996, Duluth, 1998 and Chicago, 2000.

May 1, 2003

By E. H. Mulligan

THE ERRINGTON B-I mine is located on the Errington orebody of Steep Rock Iron Mines, Limited, at Steep Rock Lake, Ontario. In 1946, this orebody entered the shipping lists of the Lake Superior iron ranges as an open-pit operation. During the period 1946 through 1953, the mine produced a total of 9,000,000 tons of iron ?ore. In 1950, as the mine approached the economic limits for open-pit operations, ground was broken for an underground development to exploit the deposit at depth. The mine is designed for an ultimate production of 1,500,000 tons per year by the block-caving system of mining. The initial shaft is 1,200 feet deep and will produce or-e from the 700 and the 900 levels. The 1,100 level will be used as a drainage level and as a haulageway for waste rock, which is hoisted to surface by skip. Ore from the two production levels moves by a system of ?ore passes to a crushing plant located below the 900 horizon and is hoisted from this point to surface by conveyor belt. At the present time, all material handling on the levels is by tramming, but as tram distances increase conveyor haulage will probably be installed. The initial stage of the Errington B-1 development is expected to produce 6,000,000 tons of ore over a period of four years. The second stage will require deepening of the shaft and development of lowe1? production levels. The conveyor hoisting plant will be extended to serve these new levels. We visualize the mining of this orebcdy down to 2,500 feet by these methods.

Jan 1, 1956

By P. Taskinen, A. Jokilaakso

The Flash Smelting Process for copper and nickel production has been one of the most successful new metallurgical process developments in the 20th century. The experimental data from laboratory scale investigations of studies has produced information and insight into the reaction mechanisms and kinetics of the flash reactions of copper concentrates. Advanced computer models coupling chemical reactions with a Computational Fluid Dynamics (CFD) software became possible with the development of commercial CFD software together with increased computing power. Currently, there are both experimental and CFD modelling, including also CFD–DEM coupling (Discrete Element Method), studies ongoing for investigating the kinetics of matte – slag reactions in the flash smelting furnace (FSF) settler. The ultimate goal of the modelling work is to develop a comprehensive FSF model for studying the behavior of changing raw materials, both primary and secondary, and distribution of their elements between the matte, slag, and gas phases. The use of User-Defined-Functions (UDF) is one way to digitalize metallurgical knowledge and experimental information to be used for supporting process experts and development of artificial intelligence applications in metallurgy. In this paper, a review of the development of the FSF reaction shaft modelling and experimental investigations, and the current work for the settler reactions’ experiments and modelling are presented. INTRODUCTION The Outotec Flash Smelting process (Bryk, Ryselin, Honkasalo, & Malmström 1958) has been used in the copper and nickel industry for 70 years with continuous support from experimental investigations by many research groups in academia, among others Jorgensen and Segnit (1977); Jokilaakso, Suominen, Taskinen and Lilius (1991), Chaubal and Sohn (1986), Kim and Themelis (1986), and in industry Mäkinen and Jåfs (1982); Kojo, Lahtinen and Miettinen (2009); Tuominen, Pienimäki and Fagerlund (2016). It has been developed also for pyrite and lead smelting (Asteljoki, Sulanto & Talonen, 1984). A schematic illustration of the FSF and other main parts of the process is depicted in Figure 1. Also, two and three dimensional physical water or gas models have extensively been used in product and process development (Lilja & Rajainmäki 1995). During the recent decades, computer based models have increasingly been adopted in the FSF research and development (Ahokainen & Jokilaakso, 1998); Ahokainen, Jokilaakso, Taskinen & Kytö, 2006; Hahn & Sohn, 1990; Jorgensen & Elliot, 1992; Zhou, Zhou, Chen & Mao, 2014; White, Haywood, Ranasinghe & Chen, 2015) to name a few, but also in supporting engineering and sales of the technology (Miettinen 2017). Even though the reactions of the sulfidic concentrate particles have been included in the reaction shaft modelling, the complete FSF model with both gas-solid/drop and molten slag/matte drop has so far been and still is too demanding for today’s computer hardware.

Jan 1, 2019

By G. Molloy

The purpose of this paper is to demonstrate the value of applying continuous improvement, in particular 5S and standard work, in an underground environment. 5S and standard work are two aspects of Lean manufacturing that have been applied in many industries. At Vale Canada Limited, the focus is to first stabilize the process, commonly through the use of 5S, standard work and other continuous improvement techniques. In parallel with building an engaged workforce, these approaches aim to incrementally stabilize and improve a process. 5S is an employee-driven, systematic methodology to reduce waste in all its forms through attaining, maintaining, and improving workplace organization. Identified as a foundational part of any improvement process, 5S aims to remove wastes that impact on the overall efficiency of the area. Standard work is used to formulate a common approach to how tasks are carried out to ensure consistency. Standardization involves identifying, establishing, and following the best method. The aim is to eliminate the variation that can occur when there is not a pre-defined established standard. Demonstrating the value of 5S and standard work in an underground environment will be achieved by first understanding the overall concept of Operational Excellence and continuous improvement as practiced within our operations. The paper will then cover a real application of 5S and standard work within the underground environment at Thompson, Manitoba.

Aug 1, 2013

By L. Contretras

This study has as an objective to analyze and to propose actions to improve the quantity and quality of the graduate education in the area of mining industry, specifically of mining engineers, metallurgists, geologists, to satisfy the expectations of professionals in the mining industry. Included are an analysis of the present scenario and the future demands in countries like Chile and proposed plans for the Establishment of Educational Initiatives, country policies and market forecast, vis-a-vis the experience of Australia, South Africa, United Kingdom, Canada and the United States of America.

Jan 1, 2007

By R. Sharma, I. Miskovic, S. Miskovic

Solvent extraction (SX) is a widely used method for the extraction of copper from pregnant leach solutions or other ionic solutions in hydrometallurgical applications. About 17% of total refined copper production worldwide is produced using SX followed by electrowinning (EW). Conventional SX units, such as mixer-settlers, consume a large amount of extractant, offer poor process control and yield low extraction efficiency. Extraction efficiency is poor due to low specific interface area, crud formation, emulsification, and slow phase separation stage. Micro solvent extraction (micro-SX) is a rapidly developing technology that provides an opportunity for improved process control, higher extraction efficiency, lower residence time and, as such, has a potential to reduce the environmental footprint of SX operation. In this research, extraction of copper ions in an acetate buffer media is investigated using D2EHPA with kerosene as a diluent. Chemical factors such as extractant concentration and ionic concentration of aqueous phase are varied to determine the optimum conditions. Subsequently, the extraction efficiency and reaction time of new micro-SX reactors are compared against previous bulk SX studies. Extraction in the microfluidic reactor was observed to be faster with a residence time more than an order of magnitude lesser than bulk SX. This study forms a prelude for developing new modular micro-SX units which will enable continuous, effective, and safe operation on a large scale. In future studies, numerical and analytical models validated through this work will help eliminate rigorous experimentation and enable faster design and fabrication of micro-SX units. INTRODUCTION Conventional industrial solvent extraction (SX) units such as mixer-settlers, extraction columns present various disadvantages. Low specific interfacial area, crud formation, and emulsification in industrial reactors lead to long extraction times and severely hamper extraction efficiency (Priest et al., 2011; Chen et al., 2017). Microfluidic extraction considerably improves upon the current extraction practices by (1) creating a large surface to volume ratio that enables rapid mass transfer across the interface, (2) better process control, and (3) easier separation of phases (Kashid, Renken, & Kiwi-Minsker, 2011; Ciceri, Perera, & Stevens, 2014). These factors establish micro-SX as a crucial mode for process intensification. Although, a micro SX unit has significantly low processing volume than conventional extraction methods, their throughput can be increased via massive parallelisation (‘numbering up’), which is an area of active research (Darekar, Singh, Mukhopadhyay, & Shenoy, 2016a; Kriel, Woollam, Gordon, Grant, & Priest, 2016).

Jan 1, 2019

By Frands Jensen, Erik Eriksson

"Haldor Topsoe’s Wet gas Sulfuric Acid (WSA) technology has been proven in a number of industries converting sulfurous gasses to concentrated sulfuric acid. In the metallurgical sector plants have been delivered handling SO2 gasses from copper, zinc, molybdenum, and lead ore. WSA has high energy efficiency and allows autothermal operation from feed gas strengths as low as 3.0% (volume). Recent variants of the WSA process have been developed that allow very high SO2 conversion efficiencies of over 99.9%. This paper describes the technology, its advantages and industrial achievements.The WSA technology is well suited for production of concentrated sulfuric acid of commercial quality from the sulfur dioxide (SO2) gas that inevitably emerges from the metallurgical processes. Some of the features that make the WSA technology attractive for this application are:- High SO2 conversion rates (up to 99.99%)- High energy efficiency leading to a low autothermal point (~ 3% SO2)- No need for gas cooling and drying to produce concentrated sulfuric acid- No production of waste- Very low cooling water consumptionThis paper describes the WSA process principles and highlights features that make this process attractive for handling SO2 gases."

Jan 1, 2014

By William Petruk, Donald Leroux, Michael Cooper

"Brunswick's primary flotation circuit (CuPb) produces a low grade concentrate containing considerable amounts of undesirable sphalerite and pyrite. To determine the cause of the poor selectivity, a series of Quantitative Mineralogical Analyses (QMA) were performed on several CuPb circuit streams. It was observed that significant fractions of sphalerite and pyrite reporting to the concentrate was liberated, meaning that their depression was not complete. The study highlighted the need for some R&D efforts to be spent in sulphide flotation fundamentals.IntroductionThe viability of many mining projects strongly depends on the performance of their concentrators. More than ever, competitive grade concentrate and high metal recoveries are criteria of paramount economic importance. The selectivity of solid/solid separation processes used in concentrators must be maintained at high levels or continuously improved.Flotation is the solid/solid separation process used by most base metal producers. In spite of its low operating cost, flotation remains a very complex process. To make it selective, precise reagent dosages and electrochemical conditions must be maintained. The difficulty in controlling flotation lies in the numerous heterogeneous reactions that can take place between the different solid, liquid and gaseous phases involved. This complex chemistry makes flotation selectivity difficult to understand and, therefore, to improve from a theoretical point of view.Brunswick Mining and Smelting, near Bathurst N.B., operates a 10500 tpd concentrator which produces four concentrates through five stages of sequential flotation (Figure I). Various reagents are added at key process stages while the ore undergoes different electrochemical conditions. Although the selectivity is important at all stages, the performance of the very first separation, the CuPb circuit, is the most critical. It is here where mineral misplacement to the wrong stream has the greatest economic consequences."

Jan 1, 1996

By J. W. Smith, J. G. Eacott, D. H. Napier

"Three hydrometallurgicat processes (Noranda chloride leach, B. C. Research biological leach and Sherritt-Cominco activated oxygen leach) and the Noranda pyrometallurgical process have served as the basis for design projects in the final year of the chemical engineering program at the University of Toronto. Each member of a team of five or six students devotes about 200 hours to the project and the final report is expected to include an economic analysis.None of the processes has been developed to full- scale plant, nor, in the case of the B.C. Research and Noranda processes, were pilot plant data available. Nevertheless, the designs developed provide a useful basis for a preliminary estimate of capital and operating costs and for a preliminary assessment of project feasibility.This paper discusses the approach used in the design projects with respect to engineering and economic aspects, and outlines the educational features and benefits of such a program as well as some of the problem areas that arise.IntroductionAs part of the undergraduate degree course in chemical engineering at the University of Toronto, students devote some 200 hours to a design project in their final year. Hydrometallurgical processes, not yet proven at the commercial scale, have been selected for study. The students are required to develop laboratory and / or pilot scale results into a conceptual plant design, using sound engineering principles. Capital and operating costs are then determined and a preliminary feasibility study and economic analysis are carried out."

Jan 1, 1986

By B. Van den Bogaert, K. Binnemans, T. Van Gerven

Europium is one of the most critical rare-earth elements due to the limited supply of this element combined with a high demand for red lamp phosphors. Therefore, the recycling of europium from end-oflife lamp phosphors has become increasingly important. Photochemical reduction of europium(III) to europium(II) and subsequent removal from rare-earth mixtures by precipitation as EuSO4 is a very selective and efficient method to recover europium from binary europium/yttrium solutions. It is shown that full separation of europium and yttrium is feasible from laboratory prepared non-equimolar Eu/Y mixtures up to a ratio of 1/20, which reflect the composition of red lamp phosphors. Optimal conditions were determined at pH 4 with isopropanol as a radical scavenger, which is a less harmful and toxic compound than the commonly used formic acid scavenger. Europium removal efficiencies of more than 95% were achieved, with a purity of 98.5% of the EuSO4 precipitate. The irradiance of the used light source, expressed in mW/cm2, has a large impact on the illumination time needed to remove europium from the solution. It is observed that higher irradiance results in a shorter induction time, i.e. a period during which virtually no europium is removed, and a faster removal rate once the induction time has passed. The photochemical separation technique was applied to recover europium from leached industrial red lamp phosphor (YOX) powder, with a Eu/Y ratio of 1/30. Europium recovery of 50% was reached with a purity of 96%, proving the feasibility of this method for the recycling of europium from end-of-life lamp phosphors.

Jan 1, 2016

By Brian K. Ayres

Inco Limited, Ontario Division is currently in the process of decommissioning the Whistle Mine site located near Sudbury, Ontario, Canada. The most significant component of site decommissioning involved relocating approximately 6.4 million tonnes of acid-generating waste rock to the open pit from two adjacent stockpiles. An engineered cover system was designed for the backfilled pit to reduce the long-term production of acid rock drainage. Geochemical modelling was conducted to assess the effectiveness of various cover options on the longterm water quality of the backfilled pit. Results obtained from performance monitoring of cover system field trials at the site and estimated full-scale construction costs were used to select an appropriate material for the cover system barrier layer. The two-dimensional soil-atmosphere model VADOSE/W was used to develop a calibrated model of covered waste rock based on field data obtained from the cover trials, which was subsequently used to predict net percolation and oxygen ingress through various cover system alternatives for site-specific climate conditions. Erosion and landform evolution numerical modelling was completed to assist in designing the runoff management system and final landform for the pit cover system. The potential impact of various physical, chemical and biological processes on the sustainable performance of the pit cover system was also considered in the design process. This paper provides an overview of the design and construction of the backfilled pit cover system.

Apr 1, 2005

By Laxman M. Amaratunga

"The fine fraction of tailings is usually excluded from the backfill process and generally disposed on the surface in tailings ponds. Because of the ever increasing demand for fine grinding in the extraction process for improved liberation of valuables in the ore, increased production of fines in the tailings has resulted. The negative impact of surface impoundment of tailings on the environment is well known. Amaratunga and Annor (1989) first presented a concept of fine tailings agglomeration for backfill.This paper presents the development of the novel cold-bond tailings agglomeration (CBTA) technology for non-reactive fine gold mill tailings. For cold-bond agglomeration regular portland cement was used as a binder. In order to cut costs, alternate binders such as lime, and blast furnace slag cement were examined. The effects of binder dosage, curing time, and agglomerate size on the fracture load strength of the agglomerate were studied.Fine tailings agglomerates are mixed with coarse tailings or non-agglomerated fine tailings to make high density fill compositions to be used as underground backfill. Alternatively, the agglomerates can be used as aggregates for surface applications. The paper discusses the environmental and operational benefits of this total tailings utilization and disposal technology.IntroductionIn Canadian mines, mill tailings are probably the most commonly used material for backfill. However, only the coarse fraction of tailings is desirable for use as hydraulic fill or high density fills. The fines are disposed on the surface in tailings ponds since they are unsuitable for underground backfilling owing to the following factors:i) slow settling ratesii) longer percolation timeiii) excessive consumption of binder due to drainageiv) poor compactionFor improved value liberation more milling operations have resolved to fine grinding in their comminution circuits. Gold milling operations driven by down stream leaching processes grind their ores excessively fine. In general, gold mines use hardly any tailings for backfilling. This can result in periodic short falls and the need to search for alternate backfill material from other sources. Apparently, the gold producers are the most identifiable sector which suffer from a shortage of backfill materials ( Amaratunga and Annor, 1989)."

Jan 1, 1994

By B. N. Church, A. R. Pettipas

"The second vertical derivative method of processing aeromagnetic data from low level helicopter surveys yields results correiatable with the known geology and may be utilized to indicate possible targets for future exploration in the Silver Queen and Equity Silver mines areas, near Houston in central British Columbia . The principal zones of alteration associated with mineralization, known from detailed mapping, are further delineated and extended in a way not possible by a cursory examination of the original magnetic data.IntroductionThe second derivative method of processing aeromagnetic data is a long established procedure used to enhance the short wavelength content of the magnetic fields. Some recent exam pies of the use of the second derivative technique have been published by Chandler (p. 385), Sun Yunsheng et al. (p. 424) and Yarger (p. 223) in Hinze, 1985. According to theory, the ""second vertical derivative"" is closely related to the rate of curvature of magnetic (or gravity) fields and is particularly useful in resolving and sharpening local anomalies. The contours on second derivative maps may coincide with important features such as lithological boundaries, faults and mineralized zones.In the Houston area, central British Columbia, aeromagnetic data supplied by local mining companies provide a ready base for analyses. Examples are data sets for the Silver Queen and Equity Silver mines centred 35 km and 34 km south and southeast, respectively, from Houston (Fig. 1), (Cochrane, 1970 and Church, 1985)."

Jan 1, 1990

By Zhang Wei

"Pulang Copper Mine is located in Shangri-La county, Diqing Prefecture, Yunnan Province, with currently defined copper reserve of 4.8 million tonnes of copper metal and an average grade of 0.34% Cu. The mineralized zone in a dome shape is 2,300 m long, 600–800 m wide, and 1,000 m high. At present, the project is at a construction phase, with a first-stage mining and processing capacity of 12.5 million tonnes of ore per year. Ore haulage is planned via a drift and ore pass development system. The cavability of mineralized rock is classified into three types (II, III, IV), with type III accounting for more than 98% of the total reserves. The cavability of the orebody is generally considered to be good and block caving mining method is planned. Semi-autogenous grinding and ball milling are adopted for the mineral processing. The tailing dam construction method is a center-line method.INTRODUCTIONAs the China's largest underground nonferrous mine, Pulang Copper Mine is located in the northeast of Shangri-La County, Diqing Prefecture, Yunnan Province, China. It is 62 km northeast of Shangri-La city. Shangri-La County is a Tibetan-dominated, multiple-ethnic region, with a population of approximately 163,000 in 2009. The county is rich in mineral and water resources, thriving with tourism. Its economy is also dominated by agriculture. To date, the defined copper reserves at the Pulang Copper Mine is 4.8 million tonnes of copper metal at an average grade of 0.34% Cu. In addition, it contains a gold reserve of 145 tonnes, a silver reserve of 2,754 tonnes, a molybdenum reserve of 0.19 million tonnes, and a sulphur reserve of 10.5 million tonnes. The first-stage mining and processing capacity is planned at 12.5 million tonnes of ore per year. When it ramps up to this production rate, the mine will produce copper concentrate containing 50,000 tonnes of copper and molybdenum concentrate containing 968 tonnes of molybdenum. A drift and ore pass system is planned for ore haulage and mining method is a block caving method. Semi-autogenous grinding and ball milling are considered for mineral processing. A center line dam is adopted for the tailing dam construction (Feng, 2010; Feng, Li, & Wang, 2011; China Enfi Engineering Corporation, 2014)."

Jan 1, 2016

By K. Barbetti, J. Avraamides

"The processing of gold ores with high silver contents can provide operational challenges, such as high cyanide consumption, retardation of gold leaching and competition during adsorption stages of carbon-in-pulp/leach/column (CIP/CIL/CIC) circuits. In particular, the silver, which is about 1.5% of the value of gold, competes with gold during carbon adsorption due to its higher concentration in many Ag-Au ores, potentially leading to gold solution losses. Fresh and partially fouled (barren and regenerated) activated carbons were evaluated at various Ag:Au ratios and total metal concentrations with regard to the adsorption kinetics and equilibrium loadings. Conventional Freundlich isotherms were found to be highly inaccurate for predicting equilibrium loadings in the competitive adsorption environment. An integrated model, which incorporates competitive adsorption kinetics with a modified competitive adsorption isotherm model has been developed and validated using plant and laboratory data. The model performance and some of its salient features will be discussed.INTRODUCTIONThe processing of gold ores with high silver contents can present a range of operational challenges, such as high cyanide consumption, retardation of gold leaching and competition in carbon adsorption circuits. Silver is often present at significantly higher concentrations than gold in many gold-silver ores and competes with gold in carbon adsorption circuits, limiting the gold loading rate and capacity, resulting in gold solution losses and reduced gold recovery.Curtin University’s Gold Technology Group has evaluated fresh and partially fouled (barren and regenerated) activated carbons at various Ag:Au ratios and total metal concentrations to determine the adsorption kinetics and equilibrium loadings for gold and silver. Conventional Freundlich isotherms were found to be highly inaccurate for predicting equilibrium loadings in the presence of both gold and silver.An integrated model, which incorporates competitive adsorption kinetics with a modified competitive adsorption isotherm model has been developed and validated using plant and laboratory data. This paper describes the model performance and some of its salient features."

Jan 1, 2016

By Hajime Miki, Gde Pandhe Wisnu Suyantara, Ahmed Mohamed Elmahdy, Hidekazu Matsuoka, Kyushu University, Tsuyoshi Hirajima

"Selective flotation of chalcopyrite and molybdenite was studied using various surface treatment methods such as electrolysis, ozone treatment, and plasma. Oxidation via electrolysis method indicated that only chalcopyrite surface is affected by electrolysis due to conductivity difference with molybdenite. Oxidation treatments and XPS analyses indicated that chalcopyrite became hydrophilic due to deposition of oxidized iron on its surface. Various oxidizing methods also showed that chalcopyrite was selectively oxidized and this can apply selective flotation of chalcopyrite and molybdenite. The possible mechanisms are proposed in this work based on surface analyses and thermodynamic calculations.INTRODUCTIONCopper sulphide minerals often associate molybdenite (MoS2) which is one of the most important by-products (Wills, 2006). It is important to recover molybdenite perfectly not only since molybdenite is valuable mineral, but also contamination of molybdenite into copper concentrate or contamination of copper mineral into molybdenite concentrate indicates penalty for both concentrate values (Wills, 2006). Conventional separation of copper sulphide and molybdenite has been achieved with sulphide bulk flotation followed by selective molybdenite flotation with NaHS addition since NaHS works as a depressant for copper sulphide. However, this current process shows imperfect molybdenite recovery and depressant such as NaHS needs to be used under specific flotation plant since it might be environmental contaminant. Hirajima et al., (2014) have been studied selective flotation of molybdenite and chalcopyrite (CuFeS2), which is the most important copper mineral, with plasma pre-treatment. They reported that plasma pre-treatment process followed by washing treatment can improve molybdenite floatability and depress chalcopyrite. This result is attributed to surface oxidation and selective conversion of chalcopyrite and molybdenite wettability. It may be hypothesized that another surface oxidation methods could give a similar result as plasma treatment process. To test this hypothesis, in this study, as comprehensive study of oxidation effect, various oxidation methods such as electrolysis, ozone, and plasma were investigated. Electrochemical measurements, thermodynamic calculations to predict the chemical reactions happened during the process, various surface analyses, and flotation experiments were carried out."

Jan 1, 2016