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By A. F. Matheson

"The Jellicoe is the most westerly mine in the Little Long Lac area with a record of gold production. The property is largely covered with overburden and the ore deposit was found by diamond drilling along the projected strike of a gold bearing zone at Magnet lake 1 ½ miles to the east on the property of Bankfield Consolidated Mines, Limited. In 1940-41 Jellicoe mined the whole orebody of approximately 14,000 tons, recovering 5,620 ounces of gold.The vein is in light-coloured greywacke. A mile-long dyke of fine-grained quartz feldspar porphyry 5 to 10 feet in width lies 100 feet south of the vein. A similar, even longer dyke lies 700 to 800 feet north of the vein. Some narrow diorite dykes are also rather closely associated. The porphyry dykes are gold bearing, but not ore. The vein material is quartz and silicified and brecciated greywacke. Mineralization consists of native gold, pyrite, arsenopyrite, and some sphalerite."

Jan 1, 1954

By O. Moselhi

Material can be seen as the fuel needed to execute the project from inception to completion. Material installed provides good indicators of progress achieved onsite vis-a-vis project schedule performance. It correlates well with the role of the schedule performance index (SPI) of the earned value method (EVM). Material is recognized to have a significant impact on achieved progress for physical completion of project activities. This paper presents a study on the development of material status index (MSI) in support of the EVM. Unlike the SPI, the newly developed index account for the criticality of project activities. This is carried out considering the total float of each activity, percent float (i.e. the ratio of float to activity duration) and the total float of the path on which the activity is located. MSI, can independently and jointly with SPI provide root causes behind problems encountered during project execution. In turn MSI can reveal material related factors behind the performance detected by joint interpretation of the two indices. MSI serves to provide added value in alerting management to take corrective actions. While SPI and MSI may have different values, they can jointly augment and enrich the captured project status based on EVM. To demonstrate the capabilities of the developed MSI method, it is implemented on a case study. The case encompasses the construction schedule of a hydro power station constructed in northern Quebec. Different scenarios are adapted from the real case to demonstrate a set of practical aspects of the developed index. The results generated from the analysis of the case study illustrate the useful features of MSI beyond those of the traditional SPI on two fronts; causation and the considerations of criticalities of actives.

Aug 1, 2013

By Dallas W. Davis

"Since May 1980, New Brunswick has called separate tenders for the right to explore and develop several potash prospects, as well as areas underlain by Alberta oil shale. These tender calls had in common the provision for a basic ad-valorem royalty, combined with sharing of cash flow after exceeding a 15-20% discontinued cash flow rate-of-return threshold. In the case of potash, the bidding variable was a share of cash flow, but for oil shale it was exploration expenditures committed, with the cash flow sharing to be negotiated at the time of application for a production lease. The Millstream potash occurrence, previously discovered by government drilling, received five bids (21.1% highest), the Dorchester ""grassroots area"" with four surmised drill targets apparently received no bids, and in the case of oil shale there were only two bids on the one block previously subjected to the most exploration.It is concluded that New Brunswick will not be successful in awarding the potash or oil shale rights in return for a comparable level of basic royalty and cash flow share as in the case of Millstream, unless it spends money in discovering prospects or sharing the exploration risk with companies. The approach is likely to work for oil shales only if current exploration proves the existence of much high-quality material or a definite trend of real increases in the price of oil is again established. Undoubtedly, it continues to be desirable to assure an on-going stable investment climate through award of potash and oil shale rights under terms which provide for a return that the public and future governments will consider fair. This could mean that some form or risk sharing with companies would be advisable."

Jan 1, 1983

By S. Rash Ahmadi

Thin brittle coatings are deposited or developed on component surfaces for different reasons. In many practical applications the coatings are stressed by externally applied loads. Under such conditions, coating failure can occur. In this paper the probability of the extension of surface crack in coated materials due to cylindrical sliding indentation is analyzed. Contact loading problems typically result in multi-axle and strongly inhomogeneous stress fields near the contact surface. This property which strongly affects the stress intensity factors is taken into account in the failure analysis. Edge cracks were selected to model the actually accruing surface flaws. A suitable method is described for calculating the contact stress fields in coating and substrate. The coating is idealized as a brittle-elastic layer of uniform thickness, which is bonded to the surface of a half space. Method of linear elastic fracture mechanics are then used to calculate the load required to cause fracture in the coating.

Oct 1, 2011

By J. W. Matousek

"More copper concentrates are treated in flash smelting furnaces than by any other process, and such furnaces are located in most of the world's major copper producing areas. Except for perhaps two furnaces treating chalcocite-type materials, little difference is seen between the grades of the concentrates being smelted. Within individual smelters, even less variation in feed grades is found. This is both accidental and intended. Many furnaces treat concentrates from captive ores, and these tend to be of relatively constant composition over long periods. Toll smelting operations blend concentrates to ensure delivery of feeds of fixed compositions to their furnaces to avoid upset conditions. Matte grades vary between flash smelting furnaces, but most commonly, these are the result of differences in operating practices rather than because of differences in concentrate grades. This paper reviews an industrial flash smelting test in which the copper content of the furnace feed was intentionally altered over a wide range. IntroductionExcept in a few copper mining regions of the world, the principal copper mineral is chalcopyrite (CuFeSz). This results in the almost universal production of concentrates containing 25070 to 30% copper (and similar amounts of iron and sulphur). Many operators of copper flash furnaces spend their entire metallurgical careers smelting concentrates of essentially fixed grades. This is true both of smelters treating concentrates from captive mines and those processing concentrates on a toll basis. From the production staff's point-of-view, the less variation in grades seen by the furnace, the better. Fixed analyses of concentrates and constant feed rates produce consistent quantities of matte at a consistent grade for processing by the converters. The result is, even in smelters treating a variety of concentrates, efforts are expended in sampling and blending to ensure feeds of relatively uniform compositions being sent to the furnaces."

Jan 1, 1993

By Junto Nishiwaki, Shinji Kumai

"Mechanical and physical properties of the impact welded dissimilar metal joints are controlled by joint interface morphology. An intermediate layer (IML) is often formed at the joint interface and this deteriorates the interface quality in some metal combinations. Numerical and experimental studies were performed in order to examine the formation mechanism of the wavy interface and intermediate layer for explosive welded Al/Cu dissimilar metal joints. The impact welding process consists of (1) high-speed oblique collision of metal plates, (2) metal jet emission and large deformation and temperature increase at collision point and (3) rapid cooling at the joint interface. Euler-Lagrange coupling method, smooth particle hydrodynamic (SPH) method and modified laplacianFoam (LF) method were linked together to simulate a series of processes from (1) to (3), and the final interface morphology including the formation of IML was reproduced. The wavy morphology (wave-height, wavelength) and the position and composition of IML formed at the joint interface of Al/Cu joints were quantitatively in good agreement with those reproduced by numerical analysis. Our simulation results are useful for the control of the interface morphology, reduction of the amount of IML, and improvement of the mechanical properties of the impact welded dissimilar metal joints.INTRODUCTIONImpact welding is a kind of solid state joining method providing extremely high joint strength for both similar-and dissimilar metal combinations. Explosive welding and magnetic pulse welding are representative methods to achieve the impact welding. By a high-speed oblique collision between two metal plates, a metal jet is emitted from the collision point. The metal jet can remove any oxide films and contaminations on the plates and produce an active refreshed surface. Consequently, good metallurgical bonding can be achieved even for dissimilar metals (Crossland, 1982). Solid metals deform like fluids under the high pressure condition at the collision point and characteristic wavy interface is formed. In addition to the wavy interface, an intermediate layer (IML) is often formed at the joint interface in some metal combinations. Elimination or reduction of the amount of IML at the joint interface is desired since the excessive IML formation along the joint interface causes a large reduction in physical and mechanical properties. Formation of IML is considered to result from characteristic thermal history at the joint interface including partial melting due to the local temperature increase and successive rapid cooling behavior at the joint interface. In order to control the IML formation at the joint interface, it is necessary to reveal both heating and cooling processes at the joint interface. However, it is impossible to observe the phenomenon occurring at the joint interface and also difficult to investigate the temperature change at the joint interface directly during the impact welding. Therefore, simulation or numerical analysis is indispensable to overcome this problem. In the present study, the explosive welded Al/Cu joint, which is prone to form IML at the joint interface, was selected for the research. By using a newly developed numerical analysis method, not only the formation process of wavy interface, but also the local temperature increase and successive temperature decrease at the joint interface were reproduced. The formation process of IML was investigated by using both numerical analytic and experimental results."

Jan 1, 2018

By David L. Huston, Wouter Bleeker, Bruce E. Taylor, Ron Cook, Bob Stewart, Elizabeth R. Koopman

"Abstract-Detailed oxygen isotope mapping of rhyolites in and around the Kidd Creek mine indicates that the orebodies are associated with relatively low (<12‰) whole rock values that extend up to 200 m laterally from ore. The zone of low d18O values is overlain stratigraphically by a carapace of higher (>13‰) values that extends up to 1.5 km laterally from and 300 m to 500 m above ore. Immediately above the stratigraphically highest orebody this carapace is cut by a zone of lower d18O values extending from the ore zone. Zones of higher d18O values also occur in massive rhyolite bodies that occur in the footwall of the orebodies.The zone of low d18O values partly coincides with a Na2O depletion anomaly associated with hydrothermal alteration, except that the Na2O depletion anomaly has a greater lateral extent, and the low d18O anomaly extends farther into the stratigraphic hanging wall. These data suggest that d18O mapping may detect hanging wall alteration above massive sulfide bodies more effectively than conventional lithogeochemistry. Zones of high d18O values, which define zones through which large quantities of low-temperature hydrothermal fluids have passed, may also have usefulness in exploration.Oxygen isotope variations at Kidd Creek record three stages of a hydrothermal system that evolved in temperature with time, as follows: (1) an early, low-temperature event that produced rocks with high d18O values, (2) a high-temperature event that produced rocks with lower d18O values, and (3) a later, low-temperature event that also produced rocks with high d18O values. The high d18O sig- nature of the massive rhyolite was recorded during early-stage, low-temperature (<200°C) alteration, and was probably preserved owing to decreases in permeability associated with low-temperature silicification. The low d18O signature of cherty breccia and chloritite was recorded during the thermal peak at >300°C. High d18O values in the carapace above the deposit were recorded as the hydrothermal system waned."

Jan 1, 1995

By John G. Henning

Low quality rock is encountered in many manifestations in underground hard rock mines, ranging from weak and poorly consolidated rock to highly altered or foliated rock. Lateral mine developments driven in low quality rock pose on-going challenges to a mine operator, as ground stability issues, such as caving of under-supported ground, drift closure due to surface deformation or buckling processes, and degradation of exposed rock surfaces are a persistent concern. For many operators, ground support design is an iterative process, as support practices are refined with time. Using case studies from a variety of underground hard rock mines, this paper reviews techniques for the classification of low range rockmasses and examines the rationale and effectiveness of adopted ground support systems.

Oct 1, 2010

By P. C. Holloway, M. J. Collins, K. R. Buban

Historically, there has been little incentive to process copper-arsenic concentrates by leaching, rather than via established smelting operations. However, with ever tightening environmental emission standards and more arseniferous concentrates being produced, increasingly sophisticated and upgraded off- gas handling facilities are required in smelting operations, generating greater quantities of challenging metallurgical dust. In this context, oxidative pressure leaching offers distinct advantages. The current state of pressure leach technology delivers high extractions from copper concentrates, while producing an environmentally stable process residue, without atmospheric emissions of sulphur dioxide or arsenic. However, as was shown in an earlier study, copper extractions and environmental leach residue stability are impacted negatively by arsenic levels above 2.5 to 3.0 wt%. In further studies on pressure leaching of copper concentrates, Sherritt has developed process conditions that allow even highly arseniferous (> 7 wt% As) feed materials to be converted into environmentally stable residues, with excellent copper extractions. At the same time, pressure leach residues can be generated that are amenable to silver recovery via direct cyanidation, without pre-treatment by lime boiling or hot curing. The results of pilot plant test work are discussed. INTRODUCTION As the production of copper has expanded over the years, resource exploitation has extended beyond relatively clean, high grade and easily accessible ores, and copper sulphide concentrates increasingly come with higher levels of contaminants, such as As, Hg, Sb and Bi, and lower copper and sulphide sulphur concentrations. However, as concerns on the impact of the emission of such contaminants into the natural environment have mounted, import/export restrictions have made the trading of copper concentrate more difficult, and, in particular, the export of concentrates with greater than 0.5 wt% As; under ever tightening environmental emission standards, these lower quality concentrates can be a significant strain on the off-gas handling facilities in smelting operations. The processing of arsenic bearing copper concentrates is, therefore, an increasing challenge as copper producers seek to exploit more complex mineralization and to extend the life of their operations. In this environment, processing arsenical copper concentrates with high temperature pressure leaching (>200°C) must be considered as an alternative to pyrometallurgical processing. Leaching kinetics for copper minerals at these temperatures are rapid and acid is generated for potential use in heap leach operations. Pressure leaching of copper concentrates eliminates gaseous emissions of arsenic and sulphur, while generating environmentally stable residues, as measured by the Toxicity Characteristic Leach Procedure (TCLP) (Kalanchey et al., 2007). Both medium and high temperature pressure leaching of copper concentrates have also proven themselves technically on an industrial scale (Marsden et al., 2004) with high copper recoveries.

Jan 1, 2019

By I. Colquhoun

Current practice tends towards "integrity as an afterthought". That is, integrity is treated as an isolated aspect of operations and maintenance. In fact, this works quite well. But it would work so much better and with less uncertainty if integrity management measures were introduced at the design phase and addressed the entire life-cycle of the pipeline asset. The talk will address the measures and metrics that can be implemented on a new pipeline during design to optimize integrity and deliver a comprehensive operating manual and integrity management program for the pipeline system. This deliverable should describe the risks to be assessed and monitored, and the actions to be taken to control these risk adequately. Properly executed, integrity by design will provide a good working estimate of the life-cycle integrity management costs and maximize system reliability.

Jan 1, 2005

By M. J. Dry, G. B. Harris

"This paper presents basic chemistry and operating conditions for the hydrolysis of ferric chloride into solid hematite and gaseous hydrogen chloride, and shows how this unit operation can be applied in chloride hydrometallurgy to regenerate strong hydrochloric acid and reject iron without also rejecting valuable metals such as nickel, copper and cobalt. Two examples are used to illustrate the hydrolysis technology and compare it to existing technology. The first is the regeneration of spent steel pickling acid, comparing hydrolysis to conventional pyrohydrolysis. The second example is the processing of a hypothetical low grade nickel laterite, comparing the novel chloride hydrolysis route to conventional sulphate HPAL technology.INTRODUCTION Whilst, in many respects, the control and removal of dissolved iron from chloride leach solutions can resemble the manner in which it is done in sulphate systems, chloride chemistry additionally offers the ability to achieve the same objectives in different ways (Harris, 2014). Conventionally, iron is oxidised to its ferric state (if necessary) and then precipitated with a base, usually magnesia where the feed is a laterite and lime where it is a sulphide, since calcium will precipitate sulphate formed during leaching. One method for controlling iron is to form FeOOH, either ß-FeOOH (akaganéite), a-FeOOH (goethite), or a mixture thereof (Fillipou and Choi, 2002). However, if akaganéite is formed, the precipitate will contain a significant chloride component (as high as 7% Cl), leading to chloride losses and difficulty in satisfactorily disposing of the residue. Washing chloride from akaganéite is almost impossible due to the propensity of the solids to undergo peptization. The conventional approach requires the addition of a base, but it is based to some extent on controlled supersaturation precipitation (Demopoulos, 2009), which produces a more uniform and crystalline material and is far more attractive than, for example, the turboaeration process proposed by Great Central Mines in their chloride copper process (Raudsepp & Beattie, 1986)."

Jan 1, 2016

By A. G. Pathan

Rock and soil mechanics investigations were carried out in block VIII at Thar Coalfield, Pakistan. Most of the strata were mainly composed of sand, with an average content of 67.68 %. Laboratory studies of rock and soil samples from drill hole GT-01 revealed that the strata in block VIII are very weak with an average uniaxial compressive strength of 3.59 MPa, an average tensile strength of 0.68 MPa, an average Young?s Modulus value of 0.234 GPa, an average cohesion of 129.19 KPa, and an average friction angle of 55.47°. Slope stability analysis, based on a probabilistic approach, was carried out using Slide-V software. Monte Carlo simulations have been applied to investigate the probability of failure in the slopes of an open pit lignite mine in block-VIII. From the slope stability investigation, it was found that the probability of failure is 0 % at a slope angle of 16°.

Aug 1, 2013

By J. P. Rajot, H. Mouzannar, M. Bost

"The design of rock foundations may need to evaluate shear strength of rock-concrete interface by performing laboratory direct shear tests. A series of tests were carried out on specimens for different values of the spacing free of encapsulating material about the shear plane and different values of normal stress. Different kinds of failure were observed and not necessarily at the rock-concrete interface. The spacing free of encapsulating material appeared to be of significant influence on the test results. A mechanical analysis is presented which illustrate the influence of the loading conditions in the direct shear box on the failure mechanism. INTRODUCTIONThe design of rock foundations subjected to significant lateral loads requires defining the value of the shear strength of the interface between rock and cast in place concrete. Verifying the stability against sliding of strip footings subjected to inclined loads (SETRA, 2009) or concrete gravity dams (CFBR, 2013) are common examples where design modelling approaches imply the shear strength, sometimes the deformation behavior, of the rock-concrete interface, more or less assumed as a failure plane.Defining the behavior of rock-concrete interfaces relates to tribology. Many studies have been conducted to improve the representation of this behavior (e.g., Johnston & Lam, 1989; Kodikara & Johnston, 1994; Gu, Seidel & Haberfield, 2003; Saiang, Malmgren & Nordlund , 2005; Fishman, 2008; Eltervaag, 2013; Gutierrez, 2013), raising many questions. The behavior appeared to be influenced by many factors such as the geometry of the interface which is not planar, the roughness of the natural rock, the rock mineralogy and the concrete formulation. In addition, the study of the shear strength of rock-concrete interfaces involves considering the two different deformation behaviors of both rock and concrete. Finally, the observed failure mechanism is strongly influenced by the initial cohesion due to adhesion between the two materials when concrete is directly cast onto rock."

Jan 1, 2015

By M. Moats

World copper refining tankhouse practices have been surveyed. This survey is a supplement to previous surveys that have been carried out in the 1987, 1991, 1995, 1999, 2001 and 2003. On a world basis, process technology trends include the further installation of automated electrode handling systems including permanent cathode systems, automatic anode preparation and cathode handling machines, section switches, fully automatic cranes and polymer concrete cells. General plant process control has increased with more automation of material handling in the copper refining tankhouse. The general trend for most greenfield copper refining projects remains in eastern Asia.

Jan 1, 2007

By P. L. Schwartz

The present method of shipping potash to the myriad of consumers is inefficient, not only because of the extreme and unpredictable nature of seasonal demand, but also because railway car turnaround times are very lengthy. The Floating Train system employs unit trains of potash operating from Saskatchewan mines to distribution warehouses located throughout the six corn-belt states of Minnesota, Iowa, Wisconsin , Illinois, Indiana and Ohio, transshipment points at Thunder Bay and the U.S. waterway network, and, where applicable , large consumers. These unit trains would "float", meaning that they would not originate at the same mine nor terminate at the same warehouse on each trip . They would " float " freely among the origins, destinations and participating railways. The potash would be shipped uniformly throughout the year and usually stored in warehouses located within the six states. It would be subsequently delivered to consumers within a 75-mile radius. Distribution warehouses and rolling stock would be provided by a new company, Potash Distribution Limited, consisting of major potash producers and the Canadian railways. Potash Distribution Limited would be responsible for the distribution of potash from the origin through the warehouses to the final consumer. The additional costs of providing warehouse space and outbound delivery will be offset by the reduction in both rail rates and "peaking" expenses.

Jan 1, 1978

By I. H. Warren

"An analysis of form-coking processes is presented in terms-of their fundamental mode of operation and their relationship to other coking processes. Their possible future role in cokemaking is assessed. IntroductionAny consideration of prospects and possibilities for form coking must commence with the iron and steel industries-their likely future growth pattern on a world and regional basis and the potential direction of future developments in iron and steelmaking technology.From the numerous estimates which have been made of the future consumption of steel, it would appear that a growth rate of 3lllo between now and the year 2000 is likely. Radical changes in steel making technology are unlikely to be commercially adopted on any significant scale during the next twenty years . However, widespread commercialization inter alia of continuous casting and direct reduction, growth of electric furnace steelmaking and a decrease in coke rates will all contribute to a growth rate for metallurgical coke that certainly will be less than that of steel."

Jan 1, 1980

By G. F. Warning

"THE H. B. Mine is situated on the north side of Sheep Creek valley, about six miles southeast of Salmo, B.C. It is the most northerly producer along a belt containing a number of zinc-lead deposits, including the Jersey mine of Canadian Exploration Limited, 3 miles to the south, and the Reeves MacDonald mine, 12 miles to the southwest. The important zinc-lead producing area around Metaline Falls, Washington, lies 23 miles to the south. Two prospectors, Horton and Benson, located and staked the oxidized outcrops in 1.907. The property was named the H.B. after the two discoverers. Exploration by a number of operators failed to locate any sulphide orebodies until 1946, when Cominco began a geological study followed by surface drilling which was successful in locating extensive sulphide mineralization. A program of underground exploration revealed sufficient ore to war-rant mill construction. A 1 ,000-ton mill was completed by 1953, but due to low metal prices production was deferred until May, 1955. To September 1, 1959, 1,900,000 tons of zinc-lead ore have been milled; present milling rate is about 1,250 tons per day. Concentrates are trucked to the Trail Smelter, a distance of 35 miles."

Jan 1, 1960

By C. G. McLachlan

Professor H.E.T. Haultain: To me from time to time the urge comes to say the agreeable thing as well as the disagreeable in commenting on the work of others. It is a prerogative of age. I don&apos;t apologize. To myself I justify my action as based on a long experience of the matters with which I deal, and I like to tell myself that I have a certain responsibility in such matters on account of my detached position. This Noranda article is a very fine contribution concerning Canadian milling, and I am surprised that no word of commendation or thanks has appeared concerning it in the BULLETIN. There is altogether too much written in these days by men rushing into print, concerning laboratory work, that has not been tied into, nor has resulted in application in the field. The authors of this paper have not rushed into print. The preparation of this paper was evidently an uncongenial task. If the authors had been that way inclined, it could have spread over several lengthy papers. It is an important article because it represents an enormous amount of work in the laboratory and the mill, extending over a period of sixteen years, and resulting in fine metallurgical and economic results with a very difficult and involved problem. It is a fine article because it is so well prepared and presented. It deals with an unusual ore condition, but there is much in it of use to every cyanide millman. It leaves very little room for criticism, though there may be differences of opinion in regard to some of the chemistry phases with which I am not conversant. I am struck by the enormous amount of persistent, painstaking, conscientious research work involved, and in the careful, sincere way in which the methods and difficulties have been described. Persistence and sincerity are the key note of the effort. It should have a good educational effect on the rising generation of millmen, and it should continue for long as a work of reference, and a spur to others. There has been an important by-product, the training and development of the young men engaged in the work. Three of them became superintendents of important mills. One was sought for important work in Africa, another has joined a large research organization in the United States.

Jan 1, 1946

By Erwin L. Zodrow

"This paper is based on a statistical analysis of the Smallwood iron ore mine (6). In this mine, the prediction of magnetite is especially difficult because of strong trends. Recognizing the statistical limitations of the sample data, the paper approaches the basic statistical analysis of the magnetite by endeavouring to obtain a first approximation of its sample density function. The knowledge of the distribution of a random variable is essential for several reasons, but particularly: (1) to obtain reliable estimators of the population parameters -for example, mean and variance; and (2) to use these estimators in hypothesis-testing concerning future experiments -sample points and sample intervals."

Jan 1, 1968

By Nural Kuyucak, Bohumil Volesky

"Extensive screening revealed a seaweed (alga) biomass type which in its non-living state possesses a very high cobalt sequestering capacity comparable to that of activated carbon and the ion-exchange resin currently used in the cobalt production process. Performance of the new bio-sorbent material was studied by examining its equilibrium metal uptake isotherms generated under different solution conditions such as initial cobalt concentration pH, temperature, and the presence of selected cations and anions. The rate of cobalt uptake was determined, which is a crucial parameter for recovery process design. Almost all cobalt sorbed can also be desorbed with a solution of CaCI2. The bio-sorbent material can be used repeatedly in the sorption-desorption cobalt concentration process. IntroductionIt has been well documented that certain types of microbial biomass, living or non-living, possess a high potential to sequester and accumulate inorganic ions present in aqueous solutions. Metal concentration by microbial biomass from a solution is termed bio-sorption. This phenomenon is quite complex and includes adsorption of metals onto the surface of a microorganism and/or into the cellular structure in combination with ion-exchange, complexation, and/or micro-precipitation. Bio-sorption is generally considered to be a rapid physical/chemical process. The cell wall structure is porous and allows metal ions, as well as large organic nutrient molecules, to pass freely through. Polysaccharides of the cell wall could provide binding amino, carboxyl, phosphate and sulphate groups. In addition to these functional binding groups, polysaccharides often have ion-exchange properties. Sometimes, bivalent cations, such as Ca2+ or Mg2+, help the formation of ionic bond bridges between the negatively charged cell surfaces and positively charged cations in the solution, Proteins in the cell wall could offer functional groups and also offer peptide bonds to bind ions. Interactions between metal and the cell wall components are responsible for the sequestering of metals by way of bio-sorption. Many metals feature a complex solution chemistry and it is not always possible to determine what ionic species are actually present in the solution. The equilibria involved are dependent on pH, concentration, the anions present and other factors. The transport system for the ions are sometimes dependent on both temperature and energy. Biosorbent material could also be regenerated for multiple reuse."

Jan 1, 1988