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By Agbo Chima

Low-lying sections of open-pit mines accumulate water, especially during the rainy seasons, preventing access to resource-bearing areas. To sustain mining operations, the water must be lifted out of the flooded pits at a high flow rate using pumps. These pumps need to be mobile so that they can be removed during drill-and-blast operations. Most mobile pumps rely on diesel engines with high maintenance requirements. A special pump design was developed to address the unique needs of open-pit mining while making the dewatering process more sustainable. Using the target flow rate and head data, an efficient pump was designed, encased, and deployed in the open pit. A variable speed drive (VSD) was installed in a protective skid so that the pump could be tuned to match the preferred flow rate at any point during its operation. This system was tied to the national electrical grid instead of being powered by diesel pumps, which reduced the carbon intensity per kilowatt-hour. The high availability, low maintenance requirement, and greater reliability reduced the use of spare parts, the fuel consumption, and the logistics associated with operating the pump. This further reduced the carbon footprint of the dewatering process. This paper provides some of the two-year performance metrics for a deployment in West Africa. With a focus on availability, maintenance costs, average cost per volume lifted, and carbon footprint, this encased pump system is compared to the diesel-driven pumps that it aims to replace.

Jan 1, 2023

By Gary M. Bone

The autonomous control of vehicles interacting forcibly with their environment, such as dozers and tractors, is an unsolved and challenging problem. Forces and motions are inherently coupled between the tool and the means of vehicle propulsion. Furthermore, they are often operated within uncertain and unstructured environments, such as those encountered in underground mining. There is a growing industrial interest in the development of robotic vehicles to improve productivity, efficiency and safety in mining and construction. This paper focuses on the modeling and control of autonomous robotic dozing for a material removal operation. A dozing process model has been developed based on observations of both a fullscale dozer and a scaled-down version. The model characterizes the dynamic interactions between the blade position, material accumulation on the blade, material distribution in the environment, and the motions of the dozer. The dozing control objective is to remove the loose material as rapidly as possible by driving forwards at full power while automatically raising/lowering the blade in response to sensor measurements. Two different controllers were developed to meet this objective. The first controller is based on a set of heuristic rules, and the second is an optimal controller based on the dynamic model. An instrumented scaled-down robotic dozer and dozing environment, designed to emulate the full-scale operation, are used to implement the controllers and compare their performances over multiple dozing passes. Experimental results are presented showing that the model-based controller increased the material removal rate by 33% compared to the rule-based controller. Lastly, technologies for full-scale implementation are discussed, followed by proposed future work and conclusions.

Aug 1, 2013

By M. Bertrand

Oxalic precipitation is usually applied to process radioactive wastes or to recover actinides from a multicomponent solution. Precipitation reactions being highly sensitive to many operation parameters, the computer simulation appears to be a very effective tool to forecast the evolutions of the system subjected to various operating conditions. This study focuses on the tetravalent uranium oxalate precipitation modelling which combines population balance and hydrodynamics. Both experimental and numerical studies are carried out in order to analyse the reactor design influence on the precipitate characteristics. The simulations taking into account primary nucleation and crystal growth are in agreement with experiments.

Aug 1, 2010

By M. L. Jeremic

"The syngenetic and epigenetic mechanics of sedimentation and deformation of coal seams resulted in various types of internal structure, as listed below:TYPE I-massive structure with evenly distributed coal constituencies of integrated mechanical properties.TYPE II-broad-banded structure, with bright and dull coal bands of differential mechanical properties.TYPE III-heterogeneous structure, with sheared coal bands and partings of sectional mechanical properties.TYPE IV-contortional structure, with refolded coal layers and deteriorated mechanical properties.TYPE V-porous structure of orogenically crushed and pulverized coal, with disintegrated mechanical properties.The study suggests criteria for the estimation of coal seam internal structure (gamma-gamma density log and cracks density log), which might be related to the evaluation of strata stability and coal mineability.IntroductionIt is common knowledge that coal seams have various internal structures due to different syngenetic and epigenetic events. Investigations of the internal structure of coal seams have been carried out in the coal fields of Western Canada, as follows: geological field studies of coal-bearing strata;?,geophysical borehole surveying studies;?,geological borehole logging and crack density;?,underground phenomenological studies of mine structure;?,chemical coal analysis; and?,mechanical testing of coal samples.These investigations eliminated a large number of criteria previously established for the estimation of coal seam internal structure and indicated that, from an engineering point of view, only two of them are sufficient:(I) density of seam profile (inferred from gamma-gamma log);(2) density of crack s (inferred from geological log).On the basis of these criteria, five main structural types of coal seams have been classified, which might be related to mechanics of deformation and ' failure of mine structures."

Jan 1, 1982

By T. H. Patching, M. W. Mikhail

"The gas sorption and emission characteristic of coals are important to the planning and conduct of mining operations. Methane drainage from coal strata can also provide a supply of fuel in certain circumstances. Gas emissions have also created hazards during the handling and transport of coals and the release of gas also appears to be related to the yield of fine sizes during mining and processing operations.This paper summarizes studies at the University of Alberta on the permeability and gas emission of certain bituminous coals. Permeability of 'solid' samples was found to be drastically reduced by confining pressure. An emission index, .P, which has been related to outbursting behaviour of coals, has also been related to the proportion of fine s in cleaning plants. Gas sorption isotherms are dependent on temperature, moisture content, the gas involved and the type of coal and can be approximately expressed by the Langmuir or the Freundlich equations. Sorption values in sections taken across a given seam were similar but considerable differences were found in . P indices in the different coal layers of a seam.IntroductionThe emission of gases, especially of methane, from coal has been a subject of great interest (and sometimes a matter of life and death), to those who dig and handle coal since it was first mined from underground pit s. Many studies and investigations have been carried out on gas occurrences and emissions but our knowledge of the precise mechanisms of gas sorption, desorption and flow from coal is still incomplete. It is the purpose of this paper to review the principal factors involved in these processes and to briefly rep ort some of the results that have been obtained by studies in the laboratories of the Department of Mineral Engineering, University of Alberta, and Coal Research Laboratory, Edmonton, CANMET"

Jan 1, 1986

By N. Dahata

B206 aluminum?copper alloy has a potential for wider use in the automotive industry due to its light weight and relatively superior mechanical properties as compared to aluminum-silicon alloys. The possibility of casting this alloy via Lost Foam Casting (LFC) has not been investigated in detail. Therefore, the effects of foam types (T170B standard untreated EPS and T175-brominated EPS), coating types (Styro Shield 5553 and Styro Shield 5554), copper level (4.5 wt % and 5.0 wt %) and titanium levels (0.5 wt % and 0.25 wt %) were related to fillability, microstructure and microporosity. The metal velocity in T175 EPS pattern was higher than that in T170B EPS pattern. For T175 EPS pattern, the total solidification time was 3% higher and the loss of temperature for decomposition of EPS was lower than those in the case of T170B EPS pattern. The grain size, porosity level and maximum pore size were quantified using Light Optical Microscopy (LOM) and image analysis. The casting with T175 EPS pattern showed larger grain size relative to that with T170B EPS pattern. The porosity level and the maximum pore size decreased significantly when the titanium level was increased from 0.05 wt % to 0.25 wt %.

Jan 1, 2007

By P. R. G. Brandão, E. E. Ferreira

The presence of metallic cations in solution will affect the aggregation or dispersion of the fine hematite particles, depending on the type of cation adsorption: either specific or non specific adsorption. In this work, the zeta potential measurements were carried out on a sample of pure hematite as a function of pH and metallic cations concentration (Ca2, Mg2+, Mn2+, K+, Na+ and Al3+). The objective of these studies was to clarify the effect of these metallic cations on the surface chemical properties of pure hematite. The cations K+ and Na+ adsorbed as non-specific species and caused only the reduction on the values of zeta potential (in terms of absolute value) over the entire range of pH values tested. For the Al3+ cation, in the acidic pH range it adsorbed as a specific species and increased the zeta potential values. The cations Ca2+, Mg2+ and Mn2+, adsorbed as a non specific species at pH levels less than 6.0 and caused the reduction of zeta potential due to the compression of the electrical double layer. However, for pH values greater than 6.0, these cations adsorbed as a specific species causing the zeta potential to increase and became more positive as the pH value increased (alkaline). This effect could be due to the adsorption of some hidroxy complex species of these cations, which contributed to the positive charge. The effect of metallic cations (Ca2+, Mg2+ and Al3+ concentration, at pH 4.0, 7.0 and 10, showed the following results: a) at pH 4.0, increasing the concentrations of Ca2+ and Mg2+ resulted in on a small reduction in the value of the zeta potential. At this pH, increasing the concentration of A131 cations caused the zeta potential to increase due to specific adsorption of a negatively charged Al3+ hydroxy complex b) at pH 7 and 10, increasing the concentrations of Ca2+ and Mg2+ caused the zeta potential to change its charge from negative to positive.

Jan 1, 2004

By D. B. Haas

THE HYDRAULIC TRANSPORT of solids is becoming increasingly prevalent throughout the world. Major long-distance slurry pipelines currently in operation transport commodities such as coal and various ore concentrates distances of up to hundreds of miles. In the United States, a number of large-diameter, high-tonnage pipelines are under consideration for the transport of Western Plains coal to markets up to 1000 miles away. In these and other applications, the solids are generally quite fine, with 14 mesh being a typical limit of particle size for long-distance (over 100 miles) slurry transport. There are applications where it might be practical to transport solids consisting of larger particles distances of up t o 100 miles. Deposits of high-quality metallurgical coal are found in the inner foothills belt along the eastern edge of the Rocky Mountains on the Alberta-B. C. border. There are few existing railroad s and the possibilities of constructing extensions are limited because of environmental and economic factor s. In these circumstances, the most efficient transportation system might consist of a pipeline to transport the coal from the mine to beneficiation plants located near existing railroads 50 or 100 miles away. Such systems would minimize environmental effects, capital cost s and operating costs. To determine whether such a system would be technically feasible, experimental testing is needed to determine the energy requirements for transporting coarse coal in a pipe line. Currently, run-of-mine metallurgical coal is crushed to less than 1 1/2 inches before going to the beneficiation plant. In the proposed scheme, coal of this size would be transported through a pipeline to the beneficiation plant located at the railroad. The Transportation Development Agency and the Department of Supply and Services have awarded a contract to the Saskatchewan Research Council to study pipelining of coarse coal in pipelines ranging from 4 inches to 12 inches in diameter.

Jan 1, 1977

By H. Fujiwara, T. Ito, T. Mizuguchi, K. Kawasaki

"In this study, we characterize the high-temperature deformation of typical “Class I” solid solution Al-Mg alloys as a superplastic elongation attributable to the solute drag creep of dislocations. The second-phase particles formed by adding Fe or Si as impurity atoms to the Al-Mg alloys impeded the gliding motion of dislocations, thereby decreasing their hot ductility and resulting in cavity formation. High-temperature tensile tests were performed with initial strain rates in the range of 1×10–3 to 1×10–1 s–1 at air temperatures 673–723 K. The dominant high-temperature deformation mechanism in these alloys was the solute drag creep controlled by the interdiffusion of Mg in Al. In this study, the calculation of critical length, defined by the diffusion-based relaxation of the stress concentration region around second-phase particles, is reported using the Needleman–Rice parameter. An analysis of the impact of cavity formation based on a comparison of the Needleman–Rice parameter and second-phase particle size is also reported.INTRODUCTION Aluminum alloys with high specific strengths are utilized as structural materials for transportation machines to minimize their weight, which consequently maximizes fuel efficiency, environment preservation, and so on (Miller et al., 2000; Heinz et al., 2000; Starke & Staley, 1996; Polmear, 1996; Immarigeon et al., 1995; Burger, Gupta, Jeffrey, & Lloyd, 1995; Ye, 2003). Microstructure refinement by severe plastic deformation (SPD) has been performed on a laboratory scale to achieve a higher strength of crystalline materials (Valiev et al., 2006; Song, Ponge, Raabe, Speer, & Matlock, 2006; Beyerlein & Toth, 2009; Sabirov, Murashkin, & Valiev, 2013; Sauvage, Wilde, Divinski, Horita, & Valiev, 2012). At room temperature, grain refinement strengthens the material, as given by the Hall-Petch relationship (Hall, 1951; Petch, 1953); at higher temperatures, superplasticity can be expected (Sherby & Wadsworth, 1989; Edington, Melton, & Cutler, 1979; Furukawa, Horita, Nemoto, & Langdon, 2001; Langdon, 2006). However, the synthesis of large-size materials by SPD processes is not yet feasible."

Jan 1, 2018

By Rodney Allen

Background: Development of the Project ?European GEODE collaboration 1999: considers possible projects, including a VMS project, to continue after GEODE ?GEODE-CODES-Canada collaboration 1999: Questionaire, database ?Workshop at CODES 2000: project theme and strategy selected ?GEORANGE (Sweden-EU) 2001 supports development of Global VMS Project: interest from 12 nations ?Skellefte VMS Project set up as Sweden?s component of Global VMS, 2002; other projects in Spain, Canada collaborate ?Low metal prices ---> little funding from mining industry 2001-2003, change in strategy ?IGCP/UNESCO support 2004: enlargement to over 20 nations

Apr 1, 2005

By Kim H. Shikaze, John R. Hawley

"Even though acid mine drainage is an old problem, particularly in coal mining areas, its appearance in the form of a major environmental hazard in the hardrock mining districts of Ontario was unexpected. The yellow and amber coloured wastes that characterize an acid mine drainage situation were first noted by the Ontario Water Resources Commission in the uranium mining Elliot Lake district. Problems of a similar nature were also noted in the copper-lead-zinc camp at Manitouwadge, the nickel camp at Sudbury and at numerous isolated base metal properties, both in and out of the Province of Ontario.Without exception, when acid mine drainage type effluents were evident, the specific companies involved worked sulphide or sulphide-associated ores. Without exception, the ore bodies contained quantities of iron sulphide (in various mineralogical forms) and, without exception, the milling circuits serving these operations were such that the iron sulphides were rejected to the tailings areas as waste.Once in a tailings area and after a varying period of time, iron sulphides react to form water soluble salts which, when discharged in the effluents from the tailings area, can affect stream chemistry and stream ecology.It is not unusual that the minerals pyrite, marcasite and pyrrhotite (all iron sulphides) react to form a stable oxide under atmospheric conditions. The law of stability of rocks and minerals, for instance, states that rocks and minerals are stable only in the environment of their formation and, as the environment surrounding them changes, the rocks and minerals tend to change to other species which are relatively more nearly stable under the conditions of the new environment (a). Under atmospheric conditions, iron oxide exhibits a greater stability than iron sulphide."

Jan 1, 1971

By D. S. Harries, R. I. L. Guthrie

"The use and development of scientific disciplines involved in heat transfer technology, related in general to steel masses and in particular to batch annealing, is demonstrated.The measurable benefits of cooperation are tabled; on industry's side, this includes a 10 to 20 per cent decrease in annealing time, and a corresponding higher productivity potential. The returned benefits to the academic engineer include the development and refinement of new computer algorithms related to heat transfer mechanisms.IntroductionThe object of this discussion is not really to describe an improvement in the batch annealing operation, but to use the project as an example of joint work between industry and the academic field. Both parties have derived a number of substantial benefits. These benefits will be listed, of course, but the batch anneal project will be used just as a typical example of cooperation. Why it happened will be explained, what actually happened will be described and finally some thoughts about areas in the field of heat transfer, where cooperation will continue in the future, will be highlighted. The paper will close with a message.Industry OverviewAt the outset, perhaps it should be understood that, in general, the Research Department at Dofasco believes that the universities and their staff are not destined for the problem-solving role in industry. Its opinion is that the university staff is best suited to the gathering and dissemination of knowledge. There are other more professional problem solvers for industry, including the steel industries' own individual investigation groups. Dofasco, therefore, looks to its academics for consultation. It benefits by bouncing ideas off them, and through rubbing shoulders with them in such a way that their knowledge can be tapped, and thus establish more effective scientific routes. In addition, the younger and brighter engineer s can broaden their scope through the intellectual contact with experts. The university professors can, it is believed, benefit through closer contacts with result-orientated research. They can also develop an appreciation of the fiscal control necessary for industrial investigations, without government subsidies, grants, etc., and with massive overheads."

Jan 1, 1982

By D. R. Spink, G. L. Rempel, C. O. Gomez Bueno

"A morphological and chemical study of the Great Canadian Oil Sands Ltd. (GCOS) fly ash has been carried out. Extensive scanning electron microscopy, as well as light microscopy, showed that the GCOS fly ash consists of two fractions, one composed of unburnt or partially burnt irregular-shaped carbon particles and an ash fraction composed of transparent and opaque, often coloured, glassy spherical particles-some of them cenospheres (hollow spheres) and the others plerospheres (hollow spheres packed with smaller spheres). Microcrystals (0.1 to 0.3 um long) growing on the inner and outer surfaces of some of the spheres were also noted and found to contain more Fe, Ti, Ni and V than the spheres.The carbon-free GCOS fly ash particle size follows a lognormal distribution, with a geometric median particle size (by count) of3.8um and a geometric standard deviation of 1.84. IntroductionCanada's current energy situation strongly suggests that oil from the Alberta tar sands deposits will probably be recovered more extensively in the future. Today's commercially proven technology to recover oil from the Athabasca tar sands, as practised by Great Canadian Oil Sands Ltd. (GCOS), involves two major operations, namely: separation of the bitumen from the sand and upgrading of the bitumen to refinery oil; the production of significant amounts of petroleum coke and sulphur during the bitumen upgrading process. The bulk of the petroleum coke is burnt in boilers to fulfill the energy requirements of the entire operation. The boiler ash, which contains appreciable amounts of metals, such as vanadium, nickel, titanium, iron, aluminum and other elements, is collected in the boiler hoppers and cyclones of the petroleum coke-fired steam generation plants. Thus, as well as representing a petroleum resource, the tar sands represent a resource for vanadium and possibly other metals providing that metal recovery processes can be developed."

Jan 1, 1980

The mechanism of thiosulfate decomposition and the products formed were investigated in the presence of pyrite or pyrrhotite in copper-ammonia solutions used for leaching gold. The presence of the sulfides significantly increased the decomposition of thiosulfate. The sulfide-surface-catalyzed oxidation of thiosulfate to tetrathionate by dissolved oxygen or the cupric tetra-ammine complex was proposed to be the dominant thiosulfate decomposition mechanism. The catalysis of the sulfides in this reaction could originate from their strong affinity for aqueous sulfur species and their semiconducting properties. Oxygen was found to be the initial driving force for thiosulfate decomposition in the absence of cupric ions and the driving force for the continuous decomposition of thiosulfate in the presence of cupric ions. Under an oxygen free atmosphere, the decomposition of thiosulfate was limited to reduce the cupric ions and the catalytic effect of the sulfides was also marginal. The dominant oxidative product of thiosulfate was trithionate in alkaline solutions especially in an oxygen rich or cupric ion rich environment. Tetrathionate was found in relatively smaller amounts in an oxygen and cupric ion deficient environment. Tetrathionate was not stable and would further decompose after extended periods. Trithionate concentrations increased almost linearly with time.

Jan 1, 2005

By D. H. Schwarz

The performance of proton exchange membrane (PEM) fuel cells depends on catalyst layer composition and structure. Experimental observations reveal that state-of-the-art catalyst layers consist of microporous agglomerates of carbon-supported catalyst sites bound together by polymer electrolyte. In between the agglomerates are macropores which provide pathways for the transport of gaseous reactants. In this work, three-dimensional, multicomponent and multiphase transport computations are performed using a computational fluid dynamics (CFD) code (FLUENTTM) with a new PEM fuel cell module, which has been further improved by taking into account the detailed composition and structure of the catalyst layers using a multiple thin-film agglomerate model. In this model, it is assumed that thin films of polymer electrolyte and liquid water surround the catalyst sites. The results of CFD computations show that transport limitations associated with the thin film of polymer electrolyte and the presence of liquid water in the catalyst and gas diffusion layers have substantial negative effects on PEM fuel cell performance. Also, the results of computations with variable distributions for a given precious metal loading show that, in general, uniform catalyst loading provides the best fuel cell performance.

Jan 1, 2005

By T. B. Armstrong

"The energy situation is extremely fragile and there is a critical need for energy conservation in the short term and development of new technology in the long term. To keep tabs on energy flow, separate electrical metering is being installed in major industries: The first step reduces demand through peak load control; the second reduces the waste of energy by monitoring energy used per unit of production. IntroductionThe current energy situation is best described as being extremely fragile. The supply of hydrocarbons is being exhausted, while energy needs remain the same in the industrialized nations and are increasing in the Third World.The petroleum era is expected to come to an end in this century, as there will no longer be enough. Gas, coal and electricity will replace some oil as it becomes scarcer during the transitional period before new sources are gradually developed.There is a critical need for energy conservation in the short term. Conservation will, to a great extent be justified by savings, as it will be less expensive to recover energy that is being wasted than to acquire additional energy.The gradual development of new technology is expected to increase energy self-sufficiency in the long term. New energy sources are attracting a growing interest and are becoming more economically feasible and marketable. These rediscovered energy sources include peat, wood, solar, domestic waste and windmills.The sudden increase in energy prices has forced users to look at the way energy is used and find ways to save it. Major industries have found that using separate meters for each department spurs energy responsibility. Energy trim programs now rank in importance with profitability, productivity and with quality.Energy has become such a crucial cost element that better data are essential for planning. Data acquisition varies with plant size and number of utilities. Meters can be read manually or monitored by computerized energy management systems.The relationship of electrical energy input and production levels for a typical uranium mine will be used to demonstrate two steps to energy management. The first step reduces demand through peak load control; the second reduces the waste of energy by monitoring energy used per unit of production.The direct benefit of saving energy is the money saved."

Jan 1, 1980

By C. Díaz, A. D. Dalvi, C. E. O'Neill

Roast-reduction smelting (RRS) of nickel concentrate, combined with flash smelting of copper concentrate, was one of the process options that Inco considered as a means of meeting its 1994 sulphur dioxide abatement target at its Copper Cliff operations. RRS involves deep roasting the nickel concentrate in fluid bed roasters. The roaster off-gas is treated in a sulphuric acid plant, and the low sulphur calcine is reduction smelted with coke in an electric furnace to yield a sulphur- deficient matte. The latter material is converted to Bessemer matte in Peirce-Smith converters, with minimal evolution of sulphur dioxide, and the converter slag is reverted to the electric furnace. Excellent nickel and cobalt recoveries (Ire obtained. This paper discusses the development of RRS, including extensive commercial scale testing at Inco's Thompson Smelter, and its key operating parameters.

Jan 1, 1994

By W. Wallace

The aerospace industry celebrated 100 years of powered flight in 2003, and the remarkable achievements that have occurred during the past 100 years are in no small way due to major developments in materials. Modern alloys for airframes, engines and other major sub-systems have evolved through the intelligent application of new processing concepts involving melting, casting, hot and cold working, heat treatment and more recently vapour phase processing. Alloy design has evolved in parallel to allow maximum benefits to be achieved from these processing advances. However, the pace of development seems to be slowing and future gains are likely to be made by learning how to extract major value from aerospace assets. Understanding the modes of deterioration and establishing cost effective lifetimes by holistic life cycle management seem to be the way of the future. Extending component lifetimes by repair, rejuvenation and refurbishment are all viable possibilities and they offer great opportunities for Canada, which, traditionally, has been a major user of modern aerospace materials rather than a supplier. The challenges for metallurgist, physicists and engineers will be no less than in the past and should create new business opportunities for Canada. The scenario described above will be developed by calling upon examples drawn from the author's experience.

Jan 1, 2004

By David E. Pearson

"Western Canadian coking coals are located in the Rocky Mountains arid foothills of British Columbia and Alberta. They are typical of non-marine coals, characterized by total sulphur contents of less than one per cent and with ash contents of 10-30 weight per cent. This mineral matter is composed principally of kaolinite and quartz.The petrographic compositions of most of the coking coals which constitute the 2.065 billion tonnes of British Columbia's measured reserves, and the compositions of the metallurgical coal currently exported from Alberta, show them to be rich in the inertinite macerals, macrinite, fusinite and semifusinite. When the mean maximum reflectance of vitrinite in oil/Romax) is used as the coal rank parameter, this high inertinite content is reflected in the lower volatile-matter yields, but the relatively inert character is also displayed by lower free swelling indices (PSI), lower maximum dilatations, lower maximum fluidities and lower coke strengths than other coals of the same rank, but richer in the reactive macerals, vitrinite, exinite and semifusinite. Despite these reduced values in the so-called caking tests, inertinite-rich coals produce strong coke.A system of classification of coking coals is introduced which is based on rank, as indicated by Ro max, and either petrographic composition, maximum dilatation, maximum fluidity or, to a lesser extent, PSI and volatile-matter yield. Six principal coal groups can be distinguished among coking coals using this versatile classification. Inertinite-rich coals are assigned to the Keystone Group (GI), Balmer Group (G3) or Moura Group (G4), each group being named for a coal typical of that population ofcoals. Reactive-rich coals are assigned to the Pittston Group (G2), Kellerman Group (G5) or Big Ben Group (G6). A multiple-regression analysis of coal quality versus price shows how the value of coking coal in the Japanese market appears to be related to reflectance and the free swelling index, and confirms the economic viability of the classification.British Columbia's measured reserves of coking coal contain representatives of four of these groups; Balmer Group (73%), Moura Group (/6%), Pittston Group (3.4%) and Kellerman Group (7.6%).This analysis of the quality of Western Canadian coking coal indicates that despite the need for large proportions of inertinite-rich coking coal in blends produced in the Japanese steel industry, there is nevertheless a demonstrated overabundance of Balmer Group and Moura Group coals available to the international coking coal market."

Jan 1, 1980

By R. Baker

A novel electrochemical half-cell and corresponding working electrode were designed to evaluate the electro-catalytic activities of catalysts in an environment close to that of an operating proton exchange or polymer electrolyte fuel cell (PEMFC). Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) techniques were employed using the novel cell to characterize various methanol electro-oxidation parameters that contribute to the overall reaction on a fuel cell anode. The effect of temperature on methanol oxidation kinetics was examined in the potential range of 0.31 to 0.65V (vs. NHE). The data was collected in the temperature range of 20 to 80°C. Based on the experimental analysis and literature data, an equivalent circuit model (ECM) for methanol oxidation was proposed and was used to fit the EIS experimental data. The experimental data and ECM electrochemical data was used to extract electrochemical kinetic parameters for methanol oxidation such as the exchange current density, Tafel slope, and energy of activation for the reaction. Kinetic data, especially at different temperatures, is very limited in the literature.

Jan 1, 2005