Search Documents

By E. Mohammadi Zahrani

In this study, Mg-doped fluorapatite (Mg-FA) nanopowders were prepared through a sol-gel, technique and characterized. Designated degree of Mg2+ ions incorporation into the apatite structure was indicated by the x value in the general formula of (Ca10-xMgx (PO4)6F2), where x=0, 0.25, 0.5, 0.75, and 1. XRD, AAS, FTIR and TEM techniques were utilized to characterize the synthesized nanopowders. In vitro bioactivity of the powders was evaluated in simulated body fluid. Powders had a crystallite size less than 100 nm. It was concluded that Mg-substitution could alter bioactivity and dissolution behaviour of Mg-FA. These two parameters were proportional to magnesium content of the powders.

Jan 1, 2010

By H. Sahay

"DISCLAIMER NOTICEThe views and conclusions contained in this presentation are those of the author and should not be interpreted as necessarily representing the official policies or recommendations of the Department of Mines and Energy, Government of Newfoundland and Labrador. ABSTRACTThis paper describes the main testing procedures that should be carried out to evaluate the capacity and capability of the service brakes on the large-size diesel-electric trucks now in common use at open-pit mining operations. Brake testing programs in general are described, and then consideration is given to different techniques of service brake testing, brake performance evaluation, braking energy and typical performance characteristics.IntroductionThe first diesel-electric truck with a capacity of about 85 tons was introduced in 1963 by Unit Rig and Equipment Company of Tulsa in cooperation with General Electric Company, who successfully developed and supplied the most important component- motorized wheels. Since then, its popularity and numbers have continued to grow, and now more than 3700 such units are in operation in mines around the world. In Canada alone, their number is more than 700, including about 150 in the Province of Newfoundland and Labrador. Similarly, their size has also grown from that initial capacity of 85 tons to 350 tons.Although the introduction of the electric trucks proved to be invariably economical, their indiscriminate use was not without severe consequences. Many runaways and even fatalities occurred when the dynamic retarder failed while the truck was travelling loaded down severe grades. The service brakes in such cases proved incapable of stopping runaway trucks, mainly due to their limited capability and the fading caused by excessive heat produced during the act of braking itself. This eventually led the various governments, the open-pit operators and the manufacturers to seriously question the braking capability as well as function of both service brakes and dynamic retarders. Extensive testing"

Jan 1, 1980

By H. Warren Newcomen, Dennis C. Martin

"This paper describes the investigation of a large, progressive slope failure on the southeast wall of the east pit at Highmont Mine, British Columbia Geotechnical investigation s consisted of geological and structural mapping, assessment of blasthole drilling records, review of rock core information, slope movement monitoring and back analysis of various possible failure modes. Climate records and mining history were also assessed to determine their relationship to slope movement .Analysis of movement monitoring records and geotechnical information indicates that the failure is deep seated. The upper portion of the failure surf ace occurs along clay filled discontinuities. The lower portion of the failure surf ace appears to occur through the highly altered rock mass. High groundwater pressures and mining at the toe of the slope are documented to have had a major influence on stability at various times during the failure. Stability analyses results are presented and possible remedial measures are discussed.IntroductionHighmont Mine is located near Logan Lake in the Highland Valley approximately 50 km southwest of Karnloops, British Columbia (Fig. I). Mining of the porphyry copper and molydenum ore bodies began in 1980. In May, 1983, when mining in the east pit had progressed to a depth of about 60 m (200 feet) , a failure (designated the Southeast Failure) began to develop in the southeast corner of the east pit. Subsequent mining to a depth of 110m (360 feet) was accompanied by frequent and substantial slope movements involving between 500000 and I 000 000 m3 of rock . The slope was monitored extensively to assess short-term movement trends for operational safety. Geological mapping, core logging and rock mechanics testing were used in conjunction with the long-term monitoring information to determine the failure mechanism, conduct stability analyses, assess the effects of instability on pit design and enable design and installation of remedial measures."

Jan 1, 1988

Safety Leadership The management and leadership of a mining operation is a challenge at all times. The pressure to make production, safety, and environmental goals is intense. At some point mining cycles will put every operator into periods of time where economic issues seem to over-ride all other concerns. This is when leadership is most needed.

May 1, 2009

By E. Lovera

ABSTRACT: The current study analyzes the feasibility of an odd operation: to obtain, using a properly tailored drilling and blasting scheme, blocks suitable for the production of dimension stone from tunnel driving. Clearly, a compromise must be found between the rate of progression and the achievement of workable blocks. As a case study, a civil work under consideration in northern Italy was examined. The work was planned to cross a conglomerate that has traditionally been locally exploited for the production of highly prized paving and lining stones with excellent strength and aesthetic features. Natural exposures and mined-out quarries were available for tests. The relevant rock data are given, blast designs are shown (within the limitations of contour accuracy), and the test program is described.

Jan 1, 2011

By L. Voisin, G. Damm

"In order to develop a new pyrometallurgical process for eliminating detrimental arsenic and antimony from the impurity-rich matte produced from copper concentrate, and for treating the occasionally generated speiss in nonferrous smelting processes, the phase relations in the Fe-Cu-S-As-Sb system saturated with carbon at 1473 K were investigated. The distribution of elements between the condensed phases at the miscibility gap, where three equilibrated phases of iron-rich alloy, copper-rich alloy, and matte coexist, were also studied. The investigation was carried out by performing a series of laboratory scale experiments in an electrical furnace at 1473 K, followed by a quenching method on the final stage. The samples obtained from the experiments were analyzed by using Inductively Couple Plasma (ICP), Atomic Absorption Spectroscopy (AAS) and Carbon Infrared Spectrometry (CIS) techniques.The results were compared with previous investigations for the Fe-Cu-S-As-C and Fe-Cu-S-Sb-C systems and discussed on the basis of the molar fraction distribution for both arsenic and antimony in the matte phase at five different matte grades. It is expected that by using this phase separation technique it might be feasible both, the cleaning of a complex copper matte and the elimination of arsenic and iron together with an acceptable amount of antimony into the iron-rich alloy phase, which can be discarded as a harmless and smaller deposit."

Jan 1, 2014

By M. Fafard, D. Picard, J. -F. Bilodeau, G. Soucy

To simulate adequately the behaviour of a Hall-Heroult electrolysis cell, a finite element model must take into account the properties of each material. However, it has some lacking knowledge on the mechanical behaviour of materials, like the long-term visco-elastic (creep/relaxation) behaviour of cathode. A three-dimensional model is then proposed in this paper and will be ready to be implemented in the finite element code FESh++. The model was developed using the three-dimensional model based on thermodynamic of irreversible processes where the choice of the internal variables is based on a phenomenological approach. All parameters of the model are represented by constant constitutive tensors and the temperature and chemical dependencies are taking into account through scalar functions multiplying the constant constitutive tensor. The goal of the first part of this project was to determine the parameters of the threedimensional visco-elastic model at the reference state (virgin material at ambient temperature) of three different cathode materials. This paper presents the theoretical model and the results of creep tests at ambient temperature for the semi-graphitic carbon cathode.

Jan 1, 2006

By D. C. Fraser, W. J. Scott

"Airborne electromagnetic surveys were flown during 1965 in the Moose River area of Ontario. The systems used were INPUT Mark II and the Canadian Aero Otter. Anomalies indicated by both systems were located on the ground with vertical-loop EM. Two such anomalies were drilled, with no explanation being found in the bedrock geology. Subsequent seismic, resistivity and gravity surveys indicated that the sources of these anomalies lay in the overburden. Current work in the similar geological environment of the Winisk River area has shown that comparable AEM anomalies can still be misleading. The lesson to be, learned from these experiences is that additional geophysical work can help to resolve doubtful cases before drilling decisions are made."

Jan 1, 1973

By A. P. Williams

"This paper presents an overview of plant electrical systems in general, a discussion of the problems that may occur due to plant growth, the maintenance required to maintain the reliability and safety of the electrical system, and the selectivity of the relay protection system. It is divided into two main areas: short circuit levels within the plant electrical system; and relay protection systems.This information is directed at maintenance supervisors, mine managers and electrical superintendents who have been away from detailed short circuit and relay coordination calculations for some time. It points out the potential problem areas within an operating plant electrical system. Short Circuit LevelsTheoryThe electrical equipment in a plant such as breakers, switches and starters has two short circuit ratings, the momentary rating and the interrupting rating. These ratings may be given in MVA or current (amperes) depending on the equipment and manufacturer's preference. Since for a three-phase system MVA and amperes are related by the formula"

Jan 1, 1987

By J. Schmidt

Cold drawing of copper wire rod is usually combined with an in-line annealing process to adjust the ductile microstructure of the wire again. One important key factor for successful annealing is the quality of the copper itself. Rod producers can check the recrystallization behaviour of the rod by different methods: chemical analysis, Spiral Elongation Test (SEN) as well as the Rapid Elongation Test (AR) are some examples of common testing methods. The comparison of the results of these methods does not always show sufficient correlations. The paper introduces firstly the SEN and AR-Tests and their different approaches to the mentioned task. The second step is to compare some results of the SEN-Test with the results of the AR-Test and identify causes of deviations. Thirdly, the effect of pre-annealing is discussed, which is especially common for wire rod with diameters of more than 8 mm.

Jan 1, 2007

By J. B. Hinzer, J. D. Harvey

"Noranda's Lyon Lake property in the Sturgeon Lake area of Northwestern Ontario was staked by Mattagami Lake Mines Limited in May 1969 to cover airborne Input anomalies. Subsequent ground geophysical and diamond drilling programs resulted in the disco very of the Boundary Extension, Lake and Creek ore zones. As of December 31, 1978, ore reserves were estimated at 3,945,000 tons assaying 6.53 per cent Zn, 1.24 per cent Cu, 0.63 per cent Pb, 3.42 oz/ton Ag and 0.010 oz/ton Au.These deposits are hosted within the South Sturgeon Lake volcanic pile of Archean age, which consists of several cycles of basic intermediate and felsic volcanic materials overlain by a sedimentary iron formation and built upon a plutonic base (Franklin , ' 1975). The top 50 m of the second felsic cycle, according to mine terminolo gy, contains the mineralization within Quartzphenocryst- bearing felsic lapilli tuff and underlying thin discontinuous graphitic sediments and altered coarse pyroclastics. The basal andesitic member of the overlying cycle forms the hanging wall to the ore deposits.Although there is no alteration pipe below the deposits, the coarse footwall rocks are permeated by chlorite, garnet, carbonate, iron sulphide and magnetitie-bearing veins intensifying from west to east.Immediate host rocks are alkali depleted and MnO, FeO, Zn and Cu enriched compared to Goodwin's (1972) average Archean rhyolites. Bedded pyrite-pyrrhotite-chalcopyrite lenses with sphalerite-rich tops are underlain by weakly developed stringer mineralization.Traversing eastward from the Lake Zone to the Creek Zone and toward the Sturgeon Lake Mine deposit, more rapid facies changes, more pronounced chloritic and carbonate alteration, the presence ofgarnets, greater MnO, FeO, CaO and Ag abundances, and increasing Zn/Cu and MnO/FeO ratios are apparent."

Jan 1, 1981

By J. E. Dutrizac, J. B. Sunstrum

"Lead was among the first metals known to man, and there are indications that lead was produced by the reductive smelting of galena in the mountains surrounding the Black Sea as early as 3000 B. C .(1). The early metallurgists soon discovered that silver could be recovered from lead bullion by cupellation techniques, and that the litharge product of the cupellation process could be reduced to give silver-free lead metal. By the Graeco-Roman era, lead-silver ores were being extensively exploited for both their silver and lead contents. Although silver was always of prime concern, a number of industrial uses existed for lead that included piping and sheeting. Subsequently, lead metallurgical practice developed steadily in different parts of the world, and was a relatively mature technology by the time of the European colonization of North America. In the United States, lead was produced on a small scale as early as 1720, and by 1800, the extensive Pb-Zn deposits of Missouri-Kansas and the upper Mississippi Valley were being developed(2). Many of the early American lead ores were low in silver, and seemed to have been worked primarily for their lead contents. Major uses of lead at the time included bullets, pipe and sheeting. During the period 1860-1890, the silver-rich galena ores of the western United States were exploited, and a number of lead smelters were operated. Although all the smelters produced lead metal, the recuperation of the associated silver and gold values was generally of prime concern. In Canada, lead deposits are abundant, and galenarich outcrops frequently attracted the attention of the early explorers and prospectors. In fact, the first record of a Canadian ore deposit seems to have been the observation of an argentiferous galena vein near Lake Temiscamingue in 17 41(3). The presence of silver-bearing lead deposits naturally attracted the attention of the mining community, and many outcrops were worked throughout the country. Because of the problems associated with transporting lead concentrates to existing American or overseas smelters, attention soon shifted to the establishment of local lead smelting facilities. The purpose of this article is to examine those early smelting efforts and to try to identify the first ""successful"" Canadian lead smelter."

Jan 1, 1999

By R. J. Mitchell

"The use of hydraulically delivered classified tailings sands to provide ground support in large mining operations is still widespread despite recent developments of alternate backfilling methods and materials. The major disadvantages of the use of hydraulic fill are the costs and risks associated with slurry delivery. The main risk is that of bulkhead failure resulting from sand liquefaction due to insufficient operational control or due to dynamic loading from earthquake or rockburst. That risk may be eliminated by the pouring of a stiff cemented sand plug in the base of each stope prior to continuous fill pouring in that stope. An additional advantage of cemented plugs is that massive bulkheads are not needed. Instead, a temporary (removable and reusable) bulkhead can be used for plug forming.Physical model studies of fill pressures on a temporary bulkhead were carried out in a 3 m radius centrifuge facility. Fill pouring in-flight was carried out in order to model prototype stress paths. The results indicate that the average bulkhead pressure is likely to be less than 10 kPa under normal operating conditions and less than 20 kPa under the poorest anticipated operating conditions which include smooth walls, high slimes content and high water-content slurries. A portable bulkhead consisting of a central core and a surrounding sealing bladder was modelled and found to be effective. The use of different sizes of cores allowed the stress distribution adjacent to these bulkheads to be evaluated."

Jan 1, 1992

By Cesar A. Urbano Jr., Gretchen T. Lapidus

A series of experiments examined silver extraction from a high-grade sulfide concentrate employing thiourea solution. Thiourea was initially oxidized with hydrogen peroxide (H2O2) to form formamidine disulfide (FADS) and used to extract silver from the as-received concentrate and after various pretreatments. Very low recoveries (~30%) were obtained with the as-received concentrate due to competitive cementation reactions by metallic iron and easily oxidizable copper phases. Over 80% Ag recovery was obtained when the concentrate was pretreated to remove this iron and copper. The results suggest that an oxidative acid pretreatment of this concentrates significantly improves silver recovery upon leaching with thiourea.

Jan 1, 2014

By B. M. Das, F. Claridge, V. K. Garga

Coal, as well as a large part of other minerals in Canada, is produced by surface mining methods. This has resulted in short and long-term accumulation of waste rock in dumps. Two main problems arise from the flow of water through these dumps: stability of dumps and the impact on stream flows. In recent years, a number of mines have started placing waste rock in valleys for general disposal or far constructing mine access road ways. All these have created challenges in the following areas: effective design of dumps and flow-through dams; stability monitoring of the structures; environmental impacts downstream by way of increased amount of fines in suspension, sedimentation, and toxic substances; and long-term status of flow and flood. Similar situations also exist in many civil engineering structures. This paper discusses the status of rock drains and the immediate and future research needs.

Jan 1, 1990

By Brian Putland, Fred Kock, Leigh Siddall

Single stage semi-autogenous / autogenous (S/AG) milling has become a common design for a variety of ore types with the advantages of being comparatively low capital cost and flexible for future expansion. The single stage SAG/AG milling option is ideal for starter projects with significant exploration and expansion potential. Currently a number of the largest SAG mills designed are installed in single stage configuration. This paper discusses the challenges associated with the process design of single stage SAG/AG milling circuits, the design flexibility required to ensure a robust circuit and the operating techniques adopted at successful installations.

Jan 1, 2012

By J. Borlee, F. Sorrentino, A. Fleischanderl, M. Gimenez, W. Gebert, U. Gennari

Large quantities of solid by-products are generated by the steel industry and other important activity sectors in Europe (power plants, car dismantling companies, urban incinerators) with no or very limited potential for direct recovery. In the frame of a multi¬national project supported by the European Union, a consortium has been created to develop a treatment process able to turn these by-products into valuable metallic and mineral products. VAI has been responsible for the design, erection and start-up of the pilot plant for the new metallurgical process and for the execution of the test campaigns, with the targets defined together with the partners. Up to now, 9 campaigns comprising 60 heats have been performed successfully. By-products from C-Steel and stainless steel plants, as well as fly ash and auto shredder residues, have been used and defined products such as hydraulic binders for cement, metallurgical powders for De-S practice and recycled metal phase have been produced. The mineral products were positively assessed under industrial conditions. Results from cement tests and secondary metallurgy are reported, as well as a detailed characterization. The economic value of the products, credits from avoiding dumping and significant savings on CO2 emissions make the new process economically very attractive.

Jan 1, 2004

By P. J. Mackey

"The metal producing industries in Canada and in the U.S. in many ways owe their technical beginnings to Welsh technology. The first copper smelter in Canada started in 1849-50 with a Welsh reverberatory furnace and skilled furnacemen brought across from Swansea to operate the equipment1- The Rocky Mountain smelting industry began with the installation of furnaces resembling the Swansea smelters(2). It was only later that the North American industry developed newer and improved methods. This article briefly describes the metallurgical history of the Lower Swansea Valley, being that section of land stretching northward from Swansea along the banks of the River Tawe, and bordered by hillsides east and west of the river. The Valley has had a classic cycle of development and decline common to industrial areas of Britain which grew in the Industrial Revolution. Perhaps more than any other area today, the Swansea Valley represents a complete cycle of use from agricultural to the peak of industrial development through to decline and dereliction. The conditions which made the Tawe Valley attractive to certain industries were laid down nearly 300 million years ago with the Carboniferous swamps and forests which covered the area, later forming the south Wales coalfield. As a result of glacial action and the deposit of glacial outwater and alluvial gravels, the valley adopted the traditional configuration, with its rocky sides occasionally remaining exposed. Up to probably about the 16th century, the Lower Swansea Valley was similar in use and appearance to many other valleys in the region. From the 14th century, the natural oak woodland had provided a continuous source of timber to produce charcoal for iron making as well as for structural purposes. Agriculture was the main activity in the valley in this period, but it was likely that the farmers also mined small amounts of coal by way of ""bell pits"", and adits into the coal seams."

Jan 1, 1999

By C. S. Touchard, F. Bourgeois, L. Cassayre, Julcour-Lebigue C.

Developing a hydrometallurgical process that can overcome the refractory nature of chalcopyrite (CuFeS2) to leaching still eludes the minerals industry, despite major research efforts spanning decades. The several leaching experiments of this ore in sulfuric acid tend toward the same conclusion that the precipitation of elemental sulfur or iron containing species are the main dissolution inhibitors. Describing both the electrolyte composition and the various solid phases in equilibrium for the Fe-H2SO4-H2O system is essential to overcome this issue and to find an operating window. According to the thermodynamic models and to the thermodynamic data, we demonstrate, in this study, the need to use the Specific ion Interactive Theory (SIT) model to describe complex electrolytic systems through a limited number of parameters. Hence, the binary interactions for our case study have to be defined and estimated. This work develops a methodology to determine these parameters of the SIT model up to 90°C and an acid concentration of 1 mol/kg from published data for H2SO4-H2O and Fe(II)-H2SO4-H2O sub-systems or from new experimental data for the Fe(III)-H2SO4-H2O one. This method will eventually be applied to copper systems to lead to a thermodynamic description of the complete CuFeS2-H2SO4-H2O system. INTRODUCTION A leaching process consists in the dissolution of a solid phase into an aqueous medium in order to extract compounds of interest. It is a key step in the hydrometallurgical processes used in the primary production and recycling of metal components. One of the main leaching issues is the formation of passivating layers on the surface of solid particles, whose consequence is a partial or total hindrance of the dissolution. The leaching of chalcopyrite (CuFeS2) in sulfuric acid is a prime example. No industrial solution for the atmospheric pressure leaching of this ore has been developed to date because of passivation phenomena caused by the formation of elemental sulfur or iron-containing precipitates on the surface of the particles (Li, Kawashima, Li, Chandra, & Gerson, 2013). In the 1970s, the Pourbaix diagrams established for the Cu-Fe-S-H2O system at 25°C for low concentrated solutions (Garrels & Christ, 1965; Peters, 1976) agreed that copper and iron are fully dissolved at high potential and in acidic medium (pH < 4). However, they neglected the many stable solid phases that can form in these conditions. In addition, the Pourbaix diagrams of chalcopyrite in water, calculated with two recent databases (FactPS and Thermoddem 2017) associated to FactSage and PhreeqC softwares respectively, show large discrepancies at 75°C (Figure 1). Indeed, at high potential, FactSage predicts the formation of goethite FeOOH at a pH value of 1, while PhreeqC predicts the formation of jarosite (H3O)[Fe3(SO4)2(OH)6] for pH greater than 2.5.

Jan 1, 2019

By Sandra L. Mesa-Espitia, Gretchen T. Lapidus

Gold present in arsenopyrite matrices is refractory and requires highly oxidative pretreatments in order to obtain acceptable degrees of extraction. However, these release many byproducts that are harmful to the environment. In the present work, a high-grade arsenopyritic ore was pretreated with different solutions, containing hydroxide ion, EDTA, oxalic, tartaric, or citric acids, to improve gold extractions in a posterior leaching step. The pretreatments were carried out at room temperature for 24 hours with a respective ligand concentration of 0.25 M. Once completed, the residue was leached in a thiosulfate solution to quantify the effect of the pretreatment on gold extraction. Only 29% of the gold content was leached, with very slow kinetics, in the untreated mineral. However, after pretreatment with tartaric or citric acid, the kinetics improved, although the percentage of gold extraction only reached 42-45%. The highest gold recovery, with very rapid kinetics, was found with the oxalic acid or the hydroxyl ion pretreatment (70 and 62%), respectively, but also corresponded to the most arsenic co-dissolution.

Jan 1, 2014