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By J. A. Dubinski

One of the greatest threats of mining in hard coal mines are underground fires, which in the past often resulted in the mining disasters. Implementation of scientific principles of fire fighting into practice contributed to a significant reduction of fire hazard in coal mines. However, despite numerous achievements of science in the fight against the underground fires, they still occur creating a potential hazard for the miners and contributing to generate significant costs of fire-fighting operations, the temporary suspension of production or loss of longwalls. This concerns both spontaneous fires and exogenous ones. A significant decrease in the number of spontaneous fires was the result of cooperation between Polish scientists with experts in the field of new methods of fire hazard prediction and selection of new fire prevention and fire hazard monitoring methods. A significant part played here researchers from the Central Mining Institute. The original method of endogenous fire risk assessment based on calorimetric tests of coal and developed mathematical model of the process of coal self-heating allow to predict the risk of spontaneous fires and select proper fire prevention measures adequate to the involved risk. The frequency of exogenous fires is in the last few years is low, but their share in the total number of fires is relatively high and constitutes about 30%. This results from the prevention activities, carried out regularly in mines which are aimed at reducing the fire hazard connected with the use of fire-resistant conveyor belts and other non-metallic materials. Further directions to reduce the hazards connected with underground fires should focus on improving the methods for monitoring hazards together with automation of fire fighting operations.

Aug 1, 2013

By Z. D. Hora

Brick shales and refractory clays are mined at Sumas Mountain near Abbotsford. Sholes and stoneware clays elsewhere in the province have not been developed. THE SUMAS MOUNTAIN deposit near Abbotsford, 80 km east of Vancouver, has been in continuous production since 1905. The deposit is exposed in a small outlier and comprises a sequence of alternating beds of clay and sand. Beds are of Eocene age. Within the 400 m thick ness of sediments are seven distinctive conglomerate members, some up to 20 m thick, interbedded with fine grained sediments including claystones and siltstone , or "shales". Shale is quarried to produce a variety of bricks, sewer pipes and similar products; it is also used for cement. Several different shale beds have been mined over the years and exhibit a variety of fired colours ranging from buff-pink grey to deep red; pyrometric cone equivalents (PCE) range from 3 to 20. A layer of fireclay 3 to 4 m thick that occurs at the base of the sequence has pinkish white to light buff fired colour and PCE of 30 to 33. It is used as a 266 primary component to produce refractory bricks. The shale is quarried and processed by Clayburn Industries Limited of Abbotsford. Another similar but smaller outlier of the same geological formation is known from Blue Mountain, about 20 km northwest of Mission. Other ceramic clays in British Columbia are reported from Quesnel (7 m bed of white stoneware clay, PCE 17 to 19), Giscome Rapids (25 km north of Prince George, 10 m bed of stoneware clay to PCE 31) and anaimo-Comox area (buff to red firing "shales", PCE 8 to 10-1 12) . From 1959 to 1974 Cretaceous shale from Saturna Island in the Strait of Georgia was used to produce lightweight aggregate. Similar deposits of expanding shale are known from the vicinity of Duncan on Vancouver Island.

Jan 1, 1984

By V. Polotski

This paper describes a platform for autonomous operations in open pit mining environments. A typical operation consists of: (1) Initial locomotion toward a remote worksite; (2) Pattern navigation within the worksite; (3) Worksite manipulations and (4) Return locomotion to the start location. The platform includes precise localization module based upon the fusion of odometry, inertial and GPS measurements. The guidance module starts from a set of way points specified on a GPSreferenced map and plans and executes the mission. A typical mission includes specified manipulative tasks along the navigation path. During motion execution the on-board system continuously verifies that the path is free of obstacles and that the hardware is not overloaded. Momentary losses of external positioning measurements does not adversely affect the performance, owing to the redundancy in position and heading estimation. A rehearsal phase follows planning and allows the supervisor to examine the kinematic behavior of the platform during motion, thus reducing the need for continuous monitoring during execution and providing protection against potential losses of communication.

May 1, 2003

By D. R. Griffiths

"Oxidation of pyrrhotite prcxiuces sulphuric acid which in turn leaches out heavy metals, resulting in acidic contaminated seepages. The establishment of a marsh on top of the pyrrhotite would result in an anaerobic sediment, which should prevent further oxidation of the pyrrhotite. Initial data indicates that concentrations of sulphates and heavy metals in the seepage water are greatly reduced. Further hydrogeological studies are required however, to determine if metal and acidic loadings to the environment have increased.L'oxidation du sulfure de fer produit de l'acide sulfurique qui a son tour attaque les métaux ayant pour resultat une contamination d'acide et de métal des eaux d'infiltration. L'etablissement d'une couverture faite de boue et de vase au-dessus du depot du sulfure de fer réduit les effets de l'oxidation.Les données initiales indiquent que les concentrations de souffre et de métaux dans les eaux d'infiltration sent grandernent réduites.Des études plus poussées sent nécessaires pour déterminer si les quantités de souffre et de métaux dans les eaux d'infiltration ont augmentées.INTRODUCITONPyrrhotite tailings are readily oxidized through a combination of precipitation and atmospheric oxygen causing acidification of the unsaturated zone above the water table. This reaction is usually catalyzed by the bacteria, Thiobacillus ferooxidans. As the pH decreases, heavy metals become more soluble resulting in contaminated seepages to ground and surface waters.By creating a marshland on top of the pyrrhotite, an anaerobic intermediate layer should form between the organic covering and the tailings, preventing the oxidation process from progressing.In September 1986, Falconbridge Limited implemented a tailing reclamation project that involved creating a marshland on top of pyrrhotite tailings. The following paper will discuss and illustrate the preliminary results obtained during the sampling period of May to September 1987."

Jan 1, 1988

By Somchet Vongpaisal

This paper presents the R&D results on the development of a new knowledge-based system for predicting stope instability and associated unplanned dilution in deep underground mining operations. A new prototype was developed based on databases generated from 3D non-linear elasto-plastic finite element stress analysis, heuristic rules, and case histories. This prototype aims to assist mine operators to make decisions on strategic mine planning and feasibility in a quick and efficient manner thereby minimizing risk on ground failure and optimizing mining costs.

Jun 1, 2012

By X. Cao, X. -G. Chen, K. Liu

Due to the detrimental effect of platelet iron-rich intermetallics on mechanical properties (particularly ductility) in cast alloys, it has been essential to transform these phases into Chinese script morphology. In the present work, the effects of Mn and/or Si addition and cooling rate on the phase transformation of the iron-rich intermetallics in 206 cast alloys with different Fe contents ranging from 0.15 % to 0.5 % were systematically investigated. The results obtained showed that platelet ß-Fe and Al3(FeMn), Chinese script a-Fe, Alm(FeMn) and Al6(FeMn) can be observed in the 206 cast alloys, depending on the Fe, Mn and Si contents as well as the cooling rate. It was found that the addition of either Mn or Si favors the formation of Chinese script iron-rich intermetallics but inhibits the precipitation of the platelet phases. In addition, the combined addition of both Mn and Si has a synergistic effect on the phase transformation. Furthermore, there exists a critical cooling rate to effectively suppress the formation of platelet iron-rich intermetallics for a given alloy. The threshold cooling rate decreases with increasing Fe, Mn and Si contents. Casting process maps are established to correlate the intermetallics precipitated with alloy chemistry and cooling rate for 206 cast alloys containing various Fe levels.

Jan 1, 2014

By Shinji Shirakawa

The gold wire bonding technology is widely used for electrically connecting aluminum pads on IC devices to external terminal of semiconductor. In 1960?s, the tensile strength of gold bonding wire was about 100 MPa only. However, recently the wire with 300 MPa in strength has been developed. Since the gold bonding wire was started to use for IC package in early 1960?, the many types of gold bonding wire has been developing continuously in order to meet market?s needs, such as high density, small size and thin type of IC packages. Moreover, electronic equipments were used in automobile applications and also demanded good reliability under severe temperature environment. Thus Au-Pd alloy wire has been introduced instead of the wire with 4N(99.99wt%) purity gold to provide excellent reliability in Au-Al bond interface. The phenomena at Au-Al interface in the high temperature storage have been already explained by several studies as follows. There are five phases of inter metallic compound (IMC) between gold and aluminum. Just after bond gold ball on aluminum pad, Au5Al2 phase was formed and occupied almost all of IMC area. During high temperature storage test, Au5Al2 phase transformed to Au4Al phase, then this phase was corroded by Bromide (Br) ion that was isolated from molding resin. Thus the reliability between Au and Al degraded. In case of Au-Pd alloy wire, the concentrated palladium phase (Au-Pd-Al) was formed at the interface between Au alloy ball and Al pad. The Au-Pd-Al phase prevented from transforming between Au and Al, therefore Au5Al2 phase was hard to transform to Au4Al phase. Consequently the reliability at the interface between Au alloy ball and Al pad was less degradation. However, in recent study using several advanced analysis technique, Au4Al phase was found at the interface between Au alloy ball and Al pad same as the case of conventional gold wire (4N purity gold bonding wire). It was suggested that the formation of concentrated palladium phase (Au-Pd-Al) related the excellent reliability at ball bonding process.

Oct 1, 2003

"In the past year, mining at the Doyon Mine has shifted entirely from open pit to underground. The mine produced 234 692 ounces of gold in 1989 and is expected to produce 225000 ounces in 1990. The Doyon Mill has been running slightly above design capacity, and recovery has increased 3%.IntroductionThe Doyon Mine is located 25 miles east of Rouyn-Noranda, Quebec (Figure I).It is a joint venture owned by Lac Minerals and Cambior, with each holding a 50% interest. Lac Minerals operates the mine under the direction of a management committee.Production at the Doyon Mine began in 1980 with the start up of the Main Zone pit. Shortly thereafter the Doyon Mine became the largest open pit gold producer in Canada.In 1983, a ramp leading to the fourth level and exploration drifts were driven. Results were very encouraging, therefore the decision was made to sink a 2150-foot deep shaft, which was completed in 1986.In mid-1986, production began in the West pit, while underground mining of the West Zone started shortly thereafter, at the end of the same year.In 1987 the mill capacity was increased to 3300 tons per day and the Main Zone underground operations commenced."

Jan 1, 1990

By Chas. L. Emery

"The laws of rock mechanics apply equally well to all rock structures, and open pits are not exceptions. The concepts and some arguments about the emphasis to be placed on various aspects of open-pit design are discussed in this article.RocksROCK can be described as a granular material consisting of grains and glue. The grains may be fragments of other rocks or polycrystalline aggregates. The glue may be ferruginous, calcareous, argillaceous, siliceous or other material connecting the grains. In a crystal intergrowth, the outer layers of the crystals in contact with each other may be considered to act as a glue. Water may be a glue in clay or a grain in a crystal structure. Air and other fluids or gases are grains if they occupy spaces in a granular mass. Such grains are functional either chemically or mechanically or both."

Jan 1, 1966

By Arnold Blaisonneau, Théophile Guillon, Xavier Rachez, Sylvie Gentier

"L’étude présentée ici vise à étudier l’influence, lors de stimulation hydraulique de puits dans les réservoirs géothermiques de type Enhanced Geothermal System (EGS), du comportement mécanique des zones de failles recoupant le puits sur la réponse hydraulique du réseau de fractures 3D. Dans ce but, un modèle 3D, basé sur la méthode des éléments distincts et dans lequel les zones de failles recoupant le puits sont modélisées par des fractures numériques 2D, est mis en oeuvre. Les modélisations présentées ici visent à caractériser l’influence du comportement mécanique (type de comportement, hétérogénéité) sur la cinétique de la stimulation hydraulique, ainsi que sur son effet spatial autour du puits. INTRODUCTIONPour le développement de l’exploitation géothermique de type Enhanced Geothermal System (EGS), la phase de stimulation conditionne grandement le succés du projet ; en effet, elle a pour objectif d’augmenter l’injectivité et la productivité des puits et doit permettre d’assurer la connexion entre les puits d’injection et de production garantissant ainsi la viabilité technique et économique de l’échangeur. Pour le site EGS de Soultz-sous-Forêts (France), parmi différentes techniques de stimulation, la stimulation hydraulique a été utilisée à cette fin en provoquant une augmentation irréversible de la perméabilité autour des puits. Dans ce type de réservoirs fracturés, le but des stimulations hydrauliques est de réactiver, plus spécifiquement en cisaillement, des structures hydrauliques pré-existantes (fractures, zones de failles etc.) dans le socle cristallin. La compréhension des phénomènes physiques durant la stimulation hydraulique est cruciale pour optimiser cette technologie et pour contrôler/limiter les risques associés (viabilité technique et économique des puits, sismicité induite etc.). C’est notamment le cas pour la relation entre le comportement mécanique des structures stimulées et les conséquences sur le comportement hydraulique dans un contexte tectonique spécifique."

Jan 1, 2015

By P. G. Keohane, J. S. Drake

"Cominco's Polaris Mine is a lead-zinc underground operation that began commercial production in early 1982. The mine site is located on Little Cornwallis Island in the Canadian Arctic at a latitude of 75°23'N and at a longitude of 96°55'W. The nearest settlement, Resolute Bay, some 100 kilometres southeasterly from the mine, is accessed from the mine by light aircraft. The mine site can be accessed by sea during the six-week ice-free period each year. During this time all major operating supplies are brought to the mine and the lead and zinc concentrate products are shipped out to market.GeologyThe Polaris orebody lies near the top of the Thumb Mountain Formation of Ordovician age. This formation is a relatively homogeneous section of thin to medium bedded limestones which are brecciated and dolomitized in the area around the orebody. The deposit is described as a Mississippi Valley-type orebody. Ore minerals are sphalerite and galena with the waste being predominantly dolomite with calcite and marcasite. The ore is quite porous with voids being generally filled with ice as the mineralized zone lies entirely within permafrost. Reserves consist of about twenty million tonnes of ore grading 3.8% Pb and 14.3% Zn with a further three million tonnes of inferred ore at a slightly lower grade.The orebody strikes in a north-south direction with the hangingwall dipping at about twenty degrees to the east. It is generally conformable with the stratigraphy. The footwall in the western portion of the orebody, the Panhandle, lies about 10 to 30 metres below the hangingwall. To the east the footwall drops sharply, creating an orebody height of up to 110 metres in what is referred to as the Keel Zone. The Panhandle Zone has typically 80 - 110 metres of cover above the hangingwall , About 25% of the reserves are in the Panhandle Zone, the remainder being in the Keel Zone. Figure I illustrates a plan view of the orebody relative to other surface facilities on the property and Figure 2 illustrates a simplified section through the Panhandle and Keel Zones."

Jan 1, 1985

By Raynald Vézina, Richard Leclerc, Jean Boissonnault, Louis P. Gignac, Gérald Veillette

Since mid-1989, Cambior has increased its producing gold mines from four to six, having acquired the Chima Mine and brought the Silidor Mine onstream. In June 1990, the company announced that the Mouska project would also be put into production. Gold production reached almost 190 000 ounces in 1989 and is expected to exceed 220 000 ounces this year. Cambior has also a non-gold operation with an interest of 50% in the Niobec Mine and has recently signed an option agreement in the development of the Lac Knife graphite deposit in northeastern Quebec. During the past year, the company has extended its exploration activities to the United States and Indonesia, and now has interests in nearly 80 properties. Last May, Cambior signed an option agreement with Golden Star for a gold deposit in Guyana, the OMAI Project, containing at least 2 000 000 ounces of gold in situ.

Jan 1, 1990

By H. W. Hughes

"The Wasamac Gold Mines mill, situated 10 miles from Rouyn-Noranda on highway 59, commenced milling April 1st 1965 at a rate of 700 tons per day. This has gradually increased to over 1200 tons per day in December. The mill has done up to 1400 tons on occasion.The ore was formed in the Wasa shear zone by means of replacement. The minerals which replaced the original rocks were carbonates, quartz, pyrite, chlorite, gold and silver. Work index varies from 9. 6 on the chlorite to 11. 6 on the quartz. The gold is very finely disseminated throughout the gangue and while associated with the pyrite is not included in the pyrite. Very seldom is gold found or seen in the free state.Test work showed a medium fine grind of 85 to 90 per cent was necessary to achieve a 95.00 per cent extraction. Straight cyanidation time of 30 to 36 hours was indicated. This has been borne out by subsequent mill performance with a grind around 87 per cent minus 200 mesh and extraction ranging from 95 to 96 per cent.When it was decided to bring the Wasamac property into production, the Bicroft Uranium Mines Ltd. crushing and grinding units together with one pebble mill and the pachuca tanks from Dyno Uranium Mines Ltd. were purchased.Wasamac crusher house and mill buildings are of laminated wood construction, covered with 5/ 8th inch plywood and corrugated iron sheeting."

Jan 1, 1966

By T. T. Perles

This paper will review the state of the global vanadium industry and outline the implications for the market in the coming years. Global vanadium resources and reserves will be defined. Current production of vanadium will be quantified and examined in terms of production by country, sources of raw materials for production and cost implications of the production processes. Current consumption of vanadium by country and by application will be reviewed. Vanadium supply/demand balance in recent years and the resulting impact on global inventory levels will be discussed. Projections for changes in global production, consumption and resulting inventory changes for the vanadium market in the coming years will be made.

Jan 1, 2014

By Ken G. Stowe, Stephen L. Chryssoulis, Christian Bendel, Joe Y. Kim, Ewald Niehuis

"TOF-SIMS (Time-of-flight secondary ion mass spectrometry) was used to detect collectors sorbed onto the surface of mineral particles in concentrate and tailings samples from the Brunswick, Matagami and Kidd Creek concentrators. This technique uses ion beams from either Cs or Ga sources to sputter the particle surface, a method which reduces fractionation of the collector molecule during sampling.In the Brunswick Zn circuit, sphalerite particles lost to the scavenger tails had less amyl xanthate and isobutyl xanthate compared to sphalerite recovered to the Zn final concentrate. Xanthates were detected on the surface of sphalerite particles floating to the CuPb final concentrate.At Matagami, significantly more isopropyl xanthate and isobutyl dithiophosphate were detected on sphalerite recovered to the Zn final concentrate, compared to sphalerite lost in the Zn rougher tails.In the Zn circuit of Kidd Creek, sphalerite lost to the tails had on average ten times less xanthate compared to sphalerite recovered into the Zn final concentrate. Xanthate was also detected on the floated pyrite particles. In addition to isobutyl xanthate, amyl xanthate was also detected on the floated sphalerite and pyrite particles.This preliminary investigation has (a) demonstrated the ability of TOF-SIMS to detect individual collectors on particle surfaces from plant samples and (b) shown that TOF- SIMS is an excellent tool, complimentary to TOF-LIMS, in establishing the surface chemistry of minerals as related to mineral processing."

Jan 1, 1995

By R. Hagiwara, S. Kobayashi, K. Yasuda, T. Nohira, K. Kondo

To establish a process for the electrochemical recovery of rare earth elements from used magnet scraps, the electrochemical formation of RE-Ni alloys in molten NaCl-KCl-RECl3 salt at 973 K was investigated. Cyclic voltammetry and open-circuit potentiometry indicated the formation of several phases of RE-Ni alloys. The formation potential for each RE-Ni alloy phase was determined from the results of scanning electron microscopy and X-ray diffraction of alloy samples prepared by potentiostatic electrolysis of a Ni plate electrode at various potentials. The optimum electrolysis conditions for the separation of Nd, Dy, and Pr are discussed.

Jan 1, 2014

By J. Someehneshin

Nowadays along with population growth, industry development, consumption of mineral resources and the fact that the reserves on hand are running out, the depth of surface and underground mines for further exploitation are increasing. During recent years, in underground mining, the block caving method for low-grade and large-scale deposits has shown a growing rate of application. This method is very cost effective and economically affordable. The dimensions of blocks are one of the most important parameters which should be taken into account since it has been proved to have a great deal of effect on technical issues such as commencement of caving and mine design. Proper calculation of the length and width for a block in this method leads to proper caving and discharging which are the most important stages. Therefore, in this method, the calculation of the optimized dimensions (length and width) of blocks is not only important but also directly helps the productivity of extraction. In this study, firstly for the purpose of facilitation, some assumptions were considered and having used these assumptions for estimation of optimized length and width of block, a relationship based on rock mechanics and physics was explored. Furthermore, some necessary details were added to the said relationship and finally, it was transformed into an inequality. Solving this inequality provides us with the optimized length and width of the block. The explored relationship was analyzed with MATLAB software and the graphs thereof were drawn. In these graphs, each time one of the input parameters has been drawn up in a logical range so that it could be compared with previous states.

Aug 1, 2013

By S. Kodama, G. Sasaki, K. Matsugi, K. Sugio, Y. B. Choi

"Pure aluminum (Al) matrix composites with changing the volume fraction of TiB2 particle content from 10 to 30% was fabricated by spark plasma sintering (SPS) process. Then the microstructure, density, dispersibility and thermal conductivity of the composites was estimated. As increasing TiB2 content, the dispersibility of particles and the density of the composites degraded slightly. And, the effect of the dispersibility of TiB2 particles on the thermal conductivity was quite little. The thermal conductivity of the composites was less than the theoretical value calculated by Maxwell-Eucken equation considering the effect of the density. It is due the influence of the interface heat transfer rate, because these composites have many small sized particles and have high interface density.INTRODUCTION Recently, metal matrix composites (MMCs) have been used widely in electric / electronic components, architectural materials, transportation equipment, aerospace and a precision instruments, because it’s superior properties have been greatly watched. Demand of MMC for industrial use has been increasing gradually. Furthermore, multifunction properties are required for the composites strongly. By integrating the dissimilar materials, the composites have various properties that we cannot get from monolithic materials. On the other hand, the response to the thermal management is required for materials, recently, and the need for the structural material controlling the thermal conductivity has been increasing. Especially, superior thermal conductivity and good mechanical properties from room temperature to high temperature are required for heat sink and heat exchanger at the same time. In late years, a study on the composites combining carbon materials and aluminum and copper has been developing, and actually the composites with high thermal conductivity which is not provided in the conventional materials is developed. On the other hand, non-oxide ceramics particles such as SiC and AlN, TiB2 have good thermal conductivity. Particularly, as TiB2 has good electrical conductivity, TiB2 containing MMCs is expected as innovative materials used as electric/ electronic components. Furthermore, as TiB2 has low density, high melting point, low thermal expansion and good deformation resistance, the development of high performance composites with multi-functional properties is expected. As thermal conductivity of pure Al and TiB2 are 225 and 66.4 W/mK, respectively, it is expected that the degradation of thermal conductivity by adding dispersant in Al matrix is suppressed. The authors have carried out a thermal conductivity, electrical conductivity, mechanical properties of 20 vol.% TiB2 dispersed Al composites (Sugio, 2016, Sasaki, 2016). In this study, the influence of quantity of addition of TiB2 on microstructure, thermal conductivity was studied minutely."

Jan 1, 2018

By Leopoldo Gutierrez, Sergio Castro, Lina M. Uribe, Janusz S. Laskowski

"The effect of sulfite and metabisulfite ions on the amyl xanthate flotation of copper-activated pyrite, in distilled water and seawater, has been studied by micro-flotation tests and redox potential measurements. The activation of pyrite was carried out varying copper ions concentration. It was found that in the presence of copper ions in solution, sulfite and metabisulfite are able to depress copper-activated pyrite at neutral or slightly acid pH. After the addition of sulfite or metabisulfite ions the resulting pH is more acidic with metabisulfite ions. A significant increase of the redox potential of the solution was observed as copper ions concentration increased. Then, the initial reducing conditions brought about by sulfite and metabisulfite ions, change abruptly to oxidizing conditions in the presence of copper ions. Under these oxidizing conditions, the metabisulfite showed to be an effective depressant for pyrite mainly in seawater. However, sulfite was a pyrite depressant in both distilled water and seawater. Based on these results, the pyrite depression by sulfoxy-depressants during the flotation of Cu/Mo ores in distilled water and seawater is discussed.INTRODUCTIONDepression of pyrite by sulfoxy-depressants (sulfite and metabisulfite) in the presence of copper ions is an important issue. This is particularly true when pyrite depression in the flotation of Cu/Mo sulfide ores is carried out in seawater. The use of lime in seawater must be avoided because the formation of magnesium hydroxy-complexes and precipitating magnesium hydroxide strongly depresses molybdenite flotation (Castro et al., 2014). In order to solve this problem, one large plant in Chile uses sodium metabisulfite (MBS) instead of lime to depress pyrite in seawater. In plant practice, this also improves molybdenite flotation since with the use of MBS the pyrite depression is carried out at pH 6-7, instead the pH 11-12 usually employed with lime.From a general point of view, pyrite exhibits some natural floatability over acidic pH ranges and may be partially floated without thiol collectors (a coating of sulfur/polysulfides has been claimed). Therefore, pyrite flotation with xanthates is usually high in the acidic pH region, but decreases greatly at alkaline pH (Leppinen, 1990; Fornasiero and Ralston, 1992; Zhang et al., 1997)."

Jan 1, 2016

By F. Cheuk, E. Krause, V. G. Papangelakis, G. A. Moldoveanu, S. Abendschein

Systematic studies have been conducted at the University of Toronto in order to evaluate lanthanide extraction from clay minerals from different geographical regions. It was found that rare earth elements (REE) are easily recovered into an aqueous solution via an ion exchange mechanism by leaching with electrolyte solutions containing monovalent cations under ambient conditions. In this study we assessed extraction levels of individual REEs as a function of initial clay composition and leaching conditions. It was found that, in spite of variations in clay origin, all clays consistently reached peak REE extraction levels with fast kinetics. However, terminal extractions were clay-specific. The feasibility of using seawater as a leaching solution and potential synergies with ammonium sulphate as a lixiviant was also investigated. Seawater was found to be inferior to using ammonium sulphate, and provided no observable synergy in leaching performance when used together. The aqueous phase trapped in leached clays was shown to contain significant amounts of REE, as demonstrated in clay washing tests. Techniques to improve the REE concentration in leachate through process variations were investigated. However, it was found that most techniques capable of increasing REE concentrations in the resultant leachate also resulted in reduced REE extraction.

Jan 1, 2014