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By Jeffrey W. Lin, Jonathan D. Abbott, Patrick R. Bowden, Tyson J. Plitt

Pentolite is a class of high explosives containing trinitrotoluene (TNT) and pentaerythritol tetranitrate (PETN) with PETN content typically ranging from 40 to 60 wt%. Manufacture involves melting TNT, 80 °C, followed by addition of PETN and trace ingredients to form a homogeneous mixture. Once a mix is ready to be poured, several factors can influence the behavior of the finished product including how long the mix has been at temperature and cooling rate. After the manufacturing process has been completed, storage conditions combined with manufacturing conditions may cause physical changes. Two such changes explored were exudation, liquid exuding from solid boosters, and ratchet growth, irreversible volumetric expansion. Exudation is principally caused by excess water in the process. Ratchet growth is a common phenomenon of nitroaromatic compounds such as TNT where time and temperature fluctuations can cause materials to increase volume, simultaneously decreasing density. Although neither phenomenon affects common attributes such as sensitivity, performance, and shelf-life, both can cause issues in storage and handling. In this study pentolite was cast into various forms under different manufacturing conditions and evaluated over several months of controlled storage conditions including ambient, temperature cycling and elevated isothermal. Subjective and objective measurements were made throughout the evaluation period with the aim to determine the preferred storage methodology.

Jan 21, 2025

By Rolf Schillinger

Transport of Small Quantities of Explosives Material on Public Roads The transport of dangerous goods on public roads is extensively regulated by EU and national law. The transport of explosive material is not only done by forwarders but also by small companies and private persons with the goal of their own use. The following article tries to explain what is allowed and what is not.

Jan 1, 2010

By John Manka

Emulsion explosives consist of an aqueous oxidizer phase, a fuel phase, and an emulsifier. The ability to use lower-cost sources for any of these raw materials presents an obvious economic advantage to emulsion manufacturers. This paper focuses on using low cost waste drain oils as the fuel phase in emulsion explosive applications. Laboratory studies showed that emulsions made from waste drain oils and agricultural ammonium nitrate prills were usable for emulsion explosives though their shear stability was weak. Customer field results proved that waste crankcase drain oil could replace half of the virgin diesel fuel in emulsion explosives to make an effective emulsion explosive product with a very low cost.

Jan 1, 2003

By Luis Huaroc, Augusto Sotomayor, Erick Rodriguez, Paulo Fernández, José Ricaldi, Luis Alejandro

The application of the Kuz-Ram model for the prediction of fragmentation is used worldwide, in Coimolache Mine it was used to determine blast domains and optimize the process by obtaining drilling patterns that meet a required X80 and reducing the uncertainty of drilling.

Feb 1, 2020

By Fumihiko Sumiya, Yukio Kato, Yoshikazu Hirosaki

Secluential blasting is one of the most popular methods in blasting. tiowever, it is well known that an emulsion explosive can be dead-pressed by dynamic pressure generated by the previous detonation. It is difficult to gain the expected blasting performance due to tb.e malfunction of explosive caused by deadpressing and shock desensitization. Such malfunction of an explosive is undesirable for safety blasting operation. Voids in the emulsion explosives will considerably affect the performance of explosives such as sensitivity, detonation velocity (DV), pressure-resistance and so on. To clarify the detonability and the performance of precompressed emulsion explosives, the DV was measured. Three types of microballoon or micro bubble ; two types of glass microballoon(GMB), resin microballoon@MB) and chemical gas bubble ; were used as sensitizers for the sample emulsion expiosives. The underwater explosion test was carried out to load dynamic pressure into the sample explosives. The dynamic pressure was generated by the detonation of a donor explosive, and the DV of the sample explosives as acceptor was measured by ionized gap terminals. The dynamic pressure level and initiation interval for the donor and the acceptor were chosen as experimental factors. The detonability was carefully investigated at short initiation intervals taking into consideration the interaction between same delays caused by the deviation of the ignition time of the electric detonators. From these experiments, the following results were obtained ; A) The DV of precompressed emulsion explosives was low compared with that of uncompressed emulsion explosives in all pressure conditions. B) The decrease of DV in the sample explosives sensitized by GMB s was larger than that of DV in the sample explosives sensitized by RMBs or chemical gas bubbles. C) The recovery of the detonability occurred rapidly in the sample explosives sensitized by RMBs and chemical gas bubbles. However, a long period was needed for the recovery of detonability in the sample explosives sensitized by GME! s. It was concluded that the type of microballoon and micro bubble significantly influenced the detonability of precompressed emulsion explosives.

Jan 1, 2002

By John C. Brulia

Blasting is both an art and a science with the primary objectives being safety and performance. Safety, the paramount objective, is a process that has limitless opportunities for improvement. Quality, a concept espoused by world-class corporations to competitively meet the needs of customers for goods and services, can be adapted to the explosives industry to improve blasting safety.

Jan 1, 1993

By Lina Lopez, Jose Sanchidrian, Jean Du Mouza, Essaieb Hamdi

This paper evaluates the actual energy delivered by the explosives used in the fragmentation of rock during blasting vs. the available theoretical explosive energy. The evaluation of the fragmentation energy of the blast is first done. Fragmentation by blasting can be seen as a process in which creation of new surfaces within the rock mass is made by generation of new cracks or extension of pre-existing ones. From this idea, the fragmentation blast efficiency can be assessed as the fraction of the available explosive energy used for creation of new surfaces. The evaluation of new cracks area created by the blast is based on the SIMBLOC methodology and the corresponding fragmentation energy is then obtained by the Griffith theory. Secondly, the amount of energy delivered down to a certain pressure or volume along the detonation product expansion process, given by the useful work, is calculated. This is done by first determining the CJ state of the reacted explosive and subsequently performing an adiabatic expansion calculation of the detonation products from that state. W-Detcom code has been used for the calculations using the BKW equation of state with the Sandia parameter set. The fragmentation energy and the useful work are calculated for blasts performed in two mines in Spain. Multiple regression is applied to the results in order to give an assessment of the better description of the explosive energy .

Jan 1, 2002

By Magnus Gynnemo

The primary purposes of drilling and blasting in hard rocks is to fracture solid rock and prepare it for excavation and subsequent transport to the crushing plant. Using explosives in excavation operations without counting for the geology gives no consideration to the quality of the macadam product or the excess production of waste material (fines).

Jan 1, 1997

By Diane F. Baker, Cathy Aimone-Martin

A series of small-scale explosive experiments were conducted in a perlite mine near Socorro, New Mexico. These experiments were a joint effort between Los Alamos National Laboratory, New Mexico Institute Of Mining and Technology, Southern Methodist University, and Defense Nuclear Agency. The purpose of these tests was to measure the changes in the shock wave and seismic coupling as a function of depth of burial and structural setting. The size of the explosive charges ranged from 1 to 68 kg. Over 1150 measurements of velocity and acceleration were made on thirteen experiments using three component sensors. The sensors were placed to maximize the azimuthal coverage as well as to provide data at a variety of ranges from ~1 to 130 m A few far field measurements were made at ranges of ~2Êkm. While the bulk of the measurements were made on the surface, high g accelerometers were placed in one instrumentation borehole to provide some free-field measurements. Preliminary results indicate that significant differences in the amplitudes of signals can occur when the location of the explosive charges are changed by only meters. Part of the observed difference is attributed to variations in the rock immediately adjacent to the charge affecting the shock coupling; and part to the effects of the site characteristics.

Jan 1, 1994

By Javier Castaneda, Luis Zozaya, Noel Huarachi, María Rocha

The objective of the project was to implement and calibrate drill and blast models supported by Geotechnical and Geological models as well as the mine and operation characteristics. The models would then be migrated to HxGN Blast to ensure a productive process that is simplified, digitized and optimized.

Feb 1, 2020

By Steven Richardson, E A. Cameron, Reza "Ray" Jambakhsh

This paper outlines the design and implementation of a method to use Long hole Carbide drilling to blast an "Upper Blind Slot Raise" in the range of 12m (40 ft).

Jan 1, 1992

By Peter G. Bellairs

The traditional concept of Optimum Drill and Blast is that it is achieved when ore is produced at the lowest unit cost and due to the complexities of most mining operations represents a band which extends either side of an overall cost minima. The above definition implies that Optimum Drill and Blast is static and once blasting is within the band around the cost minima then the process is optimised. However mining operations are not static with many events both long and short term impinging on the cost structure and productivity.

Jan 1, 1995

By P A. Gibson, J R. Brinkmann

The South African gold mining industry fires approximately 800 000 sloping blastholes daily. A programme aimed at characterizing the stope blasting process is underway in order to identify areas for improvement and to provide blasting related information for the design of mechanized sloping systems.

Jan 1, 1985

Computational techniques in determining particle size distributions after blasting is getting wide acceptance. A well known approach to extract this kind of information from digital images is edge detection. The number of edge points on a given image increase proportional to the increase of the particles on the image. By selecting a conveniently smooth threshold, counting the signed edge pixels may be a suitable metric further used to quantify the number of particles in the image. Here we propose an image processing algorithm together with Adaptive Neuro Fuzzy Inference System (ANFIS) to efficiently count the rock particles with various sizes on a given surface. To determine a suitable approximation for a mapping between the number of edge pixels and the number of particles, ANFIS is a suitable tool. As a trainable classifier ANFIS proved itself as being better efficient approach than other well known multilayer perceptron classifiers. ANFIS is trained by using convenient training data pairs previously experienced from empirically counted sample images. When given a new image containing the particle information of selected surface, the hybrid neuro fuzzy image processing approach provides satisfying performance on counting the correct number of particles up to the given scale of sizes. In this paper an experimantal study for assessment of particle size using ANFIS is presented.

Jan 1, 2004

By Joe Sr Strobbe

In 1933 the Cobre Mining Company re-opened the 32-year-old UV Industry Mine, which is located in a scenic canyon near Silver City, New Mexico. The site location is shown in Figure 1. Current mineral extractions are copper and magnetite; both extractions similar to those mined many years ago. Copper is extracted from chalcopyrite imbedded in the host rock of massive limestone deposits and magnetite, an iron ore, is a by-product of the same extraction process.

Jan 1, 1998

By Li Jianjun, Zhang Xiaozhi, Guan Li, Jin Jinzhe

People used to regard emulsion explosives as the safest industrial explosives. But in the process of manufacturing emulsion explosives spontaneous ignitions of the remnant emulsion matrix have happened under the conditions of constant or low temperature. These fatal accidents show both emulsion explosives and emulsion matrix may involve hidden danger. Since the temperature in its production emulsion matrix is high, emulsion matrix is sensitive to mechanic action.

Jan 1, 1998

By Mark R. Fritzen, Ted A. Fritzen

Anytime that blasting operations will be conducted near existing inhabited structures, vibration damage claims are a major concern of the blasting contractor. It has been our experience that even when vibration and airblast levels generated from a blast are well below accepted damage thresholds, damage claims can still arise. The single greatest source of damage claims is the element of surprise associated with not knowing that blasting operations are being conducted nearby. The second greatest source of damage claims arise from the inability to produce accurate and detailed records of all blasting activity which provides evidence that vibration and air blast levels from each blast had been taken by seismic recording equipment.

Jan 1, 1994

By R. Sibley, K. Perry, E. McCorkle, M. Coy

Black powder has been used in fireworks since the 10 th century in China. To this day, black powder still has a variety of uses, including fireworks, and remains relatively unchanged. Black powder is used in the firework shell to help produce the effect and in the lift charge to propel the shell skyward. The performance of fireworks shells used in displays varies greatly. In fireworks shells, there are two different black powder charges that differ in construction based on the desired performance of the shell. The two charges consist of the lift charge and the break charge. The lift charge is the first to fire and propels the shell out of the mortar. The break charge is the second to fire and is initiated after a delay from the lift charge; its purpose is to burst the shells effect over the desired area of the sky. The lift charge provides the shell with its initial velocity by pressurizing the mortar below the shell body. The pressurization process is violent and occurs in fractions of a second. The purpose of these experiments are to better understand the pressures sustained in fireworks mortars during the firing process. Mortars and shells vary by size and weight. Pressures in each mortar were monitored at various heights along the mortar to provide a pressure profile during shell lift. A high-speed camera was used to measure shell exit velocity near the mortar’s muzzle. This information was correlated with the size and weight of shells and their respective lift charges

Jan 1, 2024

By Kirstin Girdner, Vicki Seppala, Tom BoBo, John Kemeny, Mike Higgins

Optimal blast fragmentation is fundamental to all phases of comminution. Changes in blast design may affect efficiency and productivity of downstream processes such as crushing, milling and leaching, resulting in cost savings or losses.

Jan 1, 1999

By George D. Raitt, Rudy Lyon

Until fairly recently, Down-The-Hole (DTH or DHD) hammer drilling was never really a factor in large scale open pit surface mining. It was a method confined to water well drillers, aggregate quarries and limestone mines where the hole size rarely exceeded 6-1/2" (165 mm). Also it was somewhat limited to the harder rock areas such as the North East and South East United States. The trend in the big mining pits for coal, copper, gold and iron, was for the big rotary drill rigs with lots of muscle in pulldown, bitload and rotary torque.

Jan 1, 1998