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By D. N. Tallman

The electrokinetic properties of MgO have been utilized to simultaneously filter suspended solids and remove trace amounts of dissolved heavy metals from synthetic mine water. Greater than 95 pct removal of metals from influent at neutral pH containing 1 to 6 mg/L of dissolved Cd, Cu, Mn, Ni, and Zn can be routinely achieved by filtering through a granular bed of MgO at flow rates typical of rapid sand filtration (0.3 cm/s). Filtrate concentrations of most metals can be maintained below 0.1 mg/L for 160 bed volumes or more loading. The more mobile metals (those with larger solubility products) are more difficult to remove, and are strongly bonded to the MgO granules so that chemical stripping with chelating agent is required to clean the bed. Less mobile ions are easily removed by the filter and are effectively stripped by conventional filter backwashing. The fraction of metals recovered by chemically stripping the loaded MgO filters correlates to the zero points of charge of the metals. This process may be applicable to removal and recovery of trace amounts of heavy metals in mine drainage that is partly neutralized by liming. Also, since many of these metals are critical and strategic, the technique can be adapted not only to recycle process water from mineral and milling waste streams, but also to reclaim their metal values.

Jan 1, 1986

By E. R. Cole

Laboratory heats of an 80 percent copper high-leaded tin-bronze alloy, similar to Brass and Bronze Ingot Institute (BBII) alloy 3A, were made with reduced tin content to determine whether an alloy comparable to BBII alloy 3A could be produced using less tin to aid in conserving this strategic metal. The tin content was lowered from 10 percent to 8 percent and 5 percent (nominal values), respectively, and the reduction in tin was offset by either increasing the lead content or adding zinc. Mechanical properties, machinability, and corrosion characteristics of the resultant alloys were investigated, and the mechanical properties were compared with BBII typical values and American Society for Testing Materials (ASTM) minimums for high-leaded tin-bronze alloy. Results indicate that the tin content of this alloy could be reduced approximately 1 percent (difference between the 8.4 percent actual tin composition obtained and the 9.3 percent BBII minimum) without seriously affecting the desired properties. Results also show the tin content could be reduced without significantly increasing the chances of rejects for mechanical property failures, which might result from normal variations in the casting process.

Jan 1, 1972

By Gary A. Kingston

Rolled steel, steel forgings, and steel castings in the Pacific Northwest (Washington and Oregon) are produced principally in the Seattle, Wash., and Portland, Oreg., metropolitan areas. Steel-mill products are rolled from carbon and some alloy &eels by three companies into shapes such as reinforcing bar, rods, rounds, squares, flats, and hot-rolled strips; structural shapes, - such as angles, channels, and I-beams, also are rolled. Carbon and alloy steel ingots are poured and forged at a Seattle plant into ship shafting, drive shafts, billets, slabs, bars, rings, hooks, and other items. Static, shell, investment, and centrifugal castings are produced at 19 steel foundries in a wide range of steel specifications. All Pacific Northwest steel output is based on remelting steel scrap. Local iron ore might be used in the future to supplement steel scrap as a metal source. Ore reduction would probably be achieved by methods other than the blast furnace. Current melt-shop practice and problems are basically the same in Pacific Northwest steel plants as in cold-melt shops in other parts of the country. Quality steel production is receiving more emphasis in this region with the installation of modern analytical equipment and vacuum pouring and melting facilities.

Jan 1, 1962

By Christopher Mark

This proceedings volume contains papers presented at technology transfer seminars sponsored by the National Institute for Occupational Safety and Health (NIOSH) on New Technology for Ground Control in Retreat Mining. The seminars were conducted at five locations: Uniontown, PA (March 26, 1997), Norton, VA (April 8, 1997), Pikeville, KY (April 10, 1997), Charleston, WV (April 17, 1997), and Evansville, IN (April 22, 1997). The papers presented here describe several new, highly practical technologies developed by the NIOSH Pittsburgh and Spokane Research Centers3 to improve safety during pillar retreat operations. Two central issues are addressed: pillar design and mobile roof supports (MRS's). Proper pillar sizing is essential for safe pillar extraction. The Analysis of Retreat Mining Pillar Stability (ARMPS) program and its large data base of actual mining case histories are presented. LAMODEL, a second computer program, can be used for analysis of multiple-seam and other complex mining situations. Other papers address pillar design to avoid massive pillar collapses and the proper role of coal strength testing. MRS's have greatly improved safety where they are used for pillar line support. We studied the application of MRS's at 20 mines throughout the Eastern United States. Conclusions regarding the most effective section layouts, cut sequences, and support placements are reported. Field and laboratory tests of MRS's are also described.

Jan 1, 1997

By F. E. Block, Stephen D. Hill

The necessity for measuring radiation dose is encountered in studying both the beneficial and damaging effects of ionizing radiation on materials . It is also necessary to know the radiation dose absorbed by the reactants in order to evaluate the efficiency of reactions or processes that are promoted by radiation . Thus , a significant effort was made at the Albany cobalt 60 facility to investigate techniques by which the exposure radiation dose can be determined . Methods including ferrous sulfate , ceric sulfate , and methyl methacrylate chemical dosimeters , ion chamber dosimetry , and an absolute radiation calorimeter were investigated . Isodose curves were constructed for several standard source configurations using the dosimetry techniques which were investigated .

Jan 1, 1964

By J. P. Morris

A diphenyl ether calorimeter for measuring high-temperature heat contents of ferrous alloys and iron-and steelmaking slags was constructed and calibrated with specimens of molybdenum, alumina, and platinum that were heated to temperatures ranging from 1,720° to 1,875° K. The standard deviation of the calibration measurements was 0.37 percent. By measurements of the enthalpy of delta and liquid iron, the heat of fusion of iron was found to be 3,298 ±100 cal per mole.

Jan 1, 1966

By James S. Browning

The Bureau of Mines conducted laboratory batch and small-scale continuous selective flotation tests of barite-fluorspar ores from two deposits near Marion, Ky., to determine the technical feasibility of recovering commercial grade fluorspar and barite concentrates. The lignin sulfonate-sodium fluoride method of floating the fluorspar successfully produced acid-grade fluorspar concentrates. Flotation of the barite from the fluorspar tailing using petroleum sulfonate collector yielded concentrates suitable for use in compounding oil-well drilling mud. The fluorspar and barite recoveries were about 82 and 85 percent, respectively.

Jan 1, 1963

By Louis H. Berkelhamer

"INTRODUCTION ""Free silica"" includes all free forms of silicon dioxide, such as quartz, chalcedony, tridymite, cristbbalite, opal, diatomaceous earth, and lechatelierite. The term, has been used rather loosely however, as synonymous with quartz, as quartz is the most abundant form of free silica. ""Combined silica,"" on the other hand, has been reserved to denote silica combined with other elements as silicates.Improvements in methods for the determination of free silica, and quartz in particular, have been the subject of considerable interest during the past decade, owing mainly to the accented and increased knowledge concerning quartz as a causative factor in silicosis. Analysis for quartz, however, is of importance in many other fields, including the determination of quartz in ceramic raw materials, such as feldspar and clay; the evaluation of a beneficiation procedure by the ore dresser, such as in the concentration of iron ore; control studies of a manufactured product, such as silica brick; and routine analysis of rock, mineral, and ore samples by chemists and petrographers."

Jul 1, 1944

By A. B. Pederson, G. E. Bartlett

As a part of our study of how coal mine dusts injure the lung we have studied the effects of dusts and dust-exposed pulmonary alveolar macrophages (PAMs) on the growth of lung fibroblasts (LF). Fibroblasts were cultured near confluence in low-serum medium, either alone or in the presence of dusts, dusts plus PAMs, dust leachates or superriatants of dust-exposed PAM cultures. We report here provisional conclusions, based on initial observations. Rat LF were relatively unresponsive to direct effects of dusts, showing weak stimulation in only a few cultures, and there was no evidence that dust-exposed rat PAMs had released any growth-regulatory products. In contrast, guinea pig cells were more responsive to the dusts. The pattern of responses was quite complex. Three of the dusts stimulated LF directly (with no mediation by PAMs). Two dusts were essentially inert when added directly to fibroblast cultures, either with or without PAMs, but their leachates were active: 867 leachate was inhibitory and RF leachate was stimulatory. Dust 1361, either directly in the cultures or as an aqueous leachate, was stimulatory, and it activated cocultured PAMs to stimulate LF growth; however, supernatant products of 1361-stimulated PAMs were inhibitory. Direct exposure to 1192 stimulated LF, but its leachate was inert; cocultured PAMs exposed to 1192 had weak stimulatory effects, but supernatants of 1192-exposed PAMs were mildly inhibitory. MP3-3 had effects similar to 1192, except that the cocultured, dust-exposed PAMs had no effect on growth. We conclude 1) that guinea pig lung cells are more responsive to dusts than are rat lung cells, 2) that dusts can influence growth of LF by four kinds of interaction (by direct dust-cell interaction, by release of soluble dust components into the culture medium, by activating P AMs to exert direct cell-cell interactions, and by activating P AMs to release growth regulatory products into the culture medium), 3) that each kind of interaction may be neutral, inhibitory or stimulatory, depending on the dust tested, 4) that four of the dusts tested were neutral, inhibitory or stimulatory, depending on the assay (the fifth <lust was either neutral or stimulatory), and 5) that the effects of soluble mediators (leachates or products of activated PAMs) frequently did not correspond with the direct dust-cell or PAM-fibroblast effects. These results suggest that the nature of the dust-lung interaction at the level of cells and molecules is exceedingly complex. These observations need to be confirmed and extended to determine what characteristics of the dusts determine the nature of the cellular responses, and to determine which patterns of responses are detrimental and which are beneficial in the overall health of the dust-exposed lung.

Mar 1, 1989

By R. L. Blake

The crystal structure of hematite, a-Fe203, has been refined as part of a continuing study of the behavior of phases in the Fe-O system during reduction and oxidation. Three-dimensional diffraction intensities were collected on two spherical single crystals of hematite with a semiautomated Buerger single-crystal diffractometer. The first crystal refined was a natural Elba hematite with minor impurities. The other, a synthetic crystal, was refined at the request of Mossbauer spectroscopy investigators concerned with impurities in the natural crystal. The structure has been refined with a least-squares program and the final structure for the natural crystal irradiated with CuKa-radiation gave a discrepancy factor (R) of 3.65 percent using 49 unrejected reflections of the 51 measured. For the synthetic crystal, using MoKa-radiation, the discrepancy factor converged to 2.8 percent using 95 unrejected reflections and was 3.3 percent for all 109 reflections. The structure model of Pauling and Hendricks has been confirmed with essentially no change in the iron coordinates and approximately a 5-percent change in the oxygen coordinates. Selected interatomic distances and angles were calculated as were anisotropic temperature factors.

Jan 1, 1970

By Charlie Wyche

The British Solomon Islands Protectorate continued developmental work on bauxite deposits on the Islands of Rennell and Vaghena. A feasibility study was completed by Mitsui Mining & Smelting Co., Ltd., and Pacific Aluminum Ltd. (a subsidiary of Conzinc Riotinto of Australia Ltd,), and negotiations with the Government were in progress. The Government will receive a 25% share if the project is realized. It was estimated that the Islands contain 60 million tons of bauxite with an alumina content of 45% to 50%.

Jan 1, 1980

By Pramod C. Thakur

In This Chapter [Origins of coalbed methane Reservoir properties of coal seams Thresholds for coal seam degasification Methane emissions in mines Methane drainage techniques How to transport gas safely in mine pipelines and Economics of coal seam degasification Recommended publications on coal seam degasification are Gas Control in Underground Coal Mining [Creedy et al. 1997], Coalbed Methane Extraction [Davidson et al. 1995], and Methane Control for Underground Coal Mines [Diamond 1994].] ORIGINS OF COALBED METHANE AND RESERVOIR PROPERTIES OF COAL SEAMS Origins of coalbed methane. Coal seams form over millions of years by the biochemical decay and metamorphic transformation of plant materials. This coalification process produces large quantities of byproduct gases, such as methane and carbon dioxide. The amount of these byproducts increases with the rank of coal. It is the highest for anthracite, where for every ton of coal nearly 1,900 lb of water, 2,420 lb (20,000 ft3) of carbon dioxide, and 1,186 lb (27,000 ft3) of methane are produced [Hargraves 1973]. Most of these gases escape to the atmosphere during the coalification process, but a small fraction is retained in the coal. The amount of gas retained in the coal depends on a number of factors, such as the rank of coal, the depth of burial, the type of rock in the immediate roof and floor, local geologic anomalies, and the tectonic pressures and temperatures prevalent at that time. The gases are contained under pressure and mainly adsorbed on the surface of the coal matrix, but a small fraction of gases is also present in the fracture net-work of the coal. Methane is the major component of gases in coal, comprising 80%–90% or more of the total gas volume. The balance is made up of ethane, propane, butane, carbon dioxide, hydrogen, oxygen, and argon.

Jan 6, 2006

By J. R. Ross

A reconnaissance for sources of scandium and a metallurgical investigation of recovery methods for byproduct scandium from uranium mill solutions were conducted by the Bureau of Mines. The work on scandium was undertaken to obtain information on domestic resources and to explore and develop recovery procedures in consonance with the Bureau&apos;s long-range program for conservation and wise utilization of mineral resources. The element scandium is widely distributed in the earth&apos;s crust in trace amounts, but it seldom occurs as an important constituent in any mineral. An exception is thortveitite, (Sc,Y)2 Si207) a rare mineral that contains various amounts of scandium and yttrium and may contain up to 42 percent scandium oxide (SC203). Knowledge of the chemistry of scandium has expanded rapidly in recent years (1, 4, 9)4 but only fragmentary information is available about the metal because it is still largely a laboratory curiosity without established uses (2, 3). A recent study shows some of the physical proper-ties of the metal are (1) density of 3.05 grams per cubic centimeter) (2) melting point of 1,540° C, (3) hexagonal close-packed structure) (4) hardness of about 50 Brinell (500-kilogram load), and (5) an alloy behavior similar to yttrium and rare-earth metals (2). The price of $2,850 a pound for scandium oxide of 99.9 percent purity and $2,700 a pound for oxide of 99 percent purity reflects the scarcity and complex chemistry of the element.

Jan 1, 1962

By A. C. Smith

The U.S. Bureau of Mines constructed a large-scaJe facility to study the self-heating of a large coal mass under conditions that simulate a gob area of a mine. The insulated coal chamber can hold up to 13 short tons (st) of coal and is provided with a forced ventilation system and computer-controlled temperature and gas measurement systems to monitor the heat and mass transfer phenomena that occur in the coalbed. Three experiments were completed with high-volatile C bituminous coals that exhibited high spontaneous combustion potentials in laboratory-scale tests. In the first two tests, a sustained heating was not achieved. In the third test, temperatures throughout the coalbed increased steadily from the start, with thermal runaway occurring near the center of the coalbed after 23 days. The thermal reaction wne then moved toward the front of the coalbed. The results of these tests showed that the self-heating of a large coal mass depends not just on the reactivity of the coal, but also on the particle size of the coal, the freshness of the coal surfaces, the heat-of-wetting effect, and the availability of O2 at optimum ventilation rates.

Jan 1, 1991

By Allan E. Martin

As part of a comprehensive investigation of tie mechanism of desufurization of iron and steel by slags, the Blast Furnace Studies Section, Metallurgical Division, Bureau of Mines, in cooperation with the Institute of Technology-, University of Minnesota, has made a study of the forms in which sulfur occurs in blast-furnace slag. This report presents data on the three sulfides most important in iron smelting, namely, ferrous sulfide, manganous sulfide, and calcium sulfide. The tendency of these sulfides to form colloids in the molten slag was determined by an examination of quenched samples with an ultramicroscope. Vogt5/ conducted experiments on sulfide silicate melts and examined synthetic blast-furnace slags in a partly crystallized condition. His conclusions were that FeS, CaS, and bins, or isomorphous compounds, such as (FexCay)S and (MnxCy)S, were precipitated Prom the melt, depending on the composition of the slag. In all specimens sulfides were visible and were spherical.

Jan 1, 1941

By V. B. Dale

This report is one of a series covering the mineral resources of the Nation. It briefly describes most of the known tungsten deposits in Gila, Yavapai, and Mohave Counties, Ariz. Many of the descriptions are taken from the reports of previous examinations by Bureau of Mines engineers, and from Defense Minerals Exploration Administration files. Where a previous examination had been made, and an inquiry disclosed that little or no work had been done since that time, pertinent information from the report was used in this paper with acknowledgment of the source. However, the majority of the descriptions is from field examinations by the author. In the past 3 years (July 1956-May 1959) only necessary annual assessment work was conducted on nearly all the properties described in this paper. There was no active mining on any of the properties examined.

Jan 1, 1961

By J. A. Eisele

The Bureau of Mines conducted bench-scale cyclic tests to determine the composition of recycled leach liquor in the Bureau?s proposed clay/HCl leach/ HCl sparge process for producing Al203 from clay. The data developed from these tests make it possible to synthesize leach liquors for predetermined steady-state operating conditions when conducting large-scale crystallization tests. The results of two sparge tests were compared. One was a 20-cycle test with a 36-pct-HCl concentration in the mother liquor; the other was a 10-cycle test with a 26-pct-HCl concentration in the mother liquor. The effect of impurity concentrations in the leach liquor on the purity of aluminum chloride (AlCl30?6H20) crystals was determined, but there was poor correlation between this data and results that have been obtained from miniplant-scale work.

Jan 1, 1980

By Rethel L. Hubbard

Fourteen straight-run asphalts were prepared in the laboratory from bitumens obtained from three sources: (1) native bitumen from Rozel Point, Utah, (2). bitumen extracted from Athabaska bituminous sandstone at Canada, and (3) bitumen extracted from Edna bituminous sandstone outcropping in San Luis Obispo County, to seven asphalts with penetrations ranging from 19 to 287 at 77 F. were prepared from each of the bitumens. The yields of the prepared asphalts ranged from 74.5 percent for a 27-penetration asphalt from the Athabaska bitumen to 99.5 percent for a 271-penetration asphalt from the Rozel Point bitumen.

Jan 1, 1949

By Joseph D. Davis

Selection of a suitable coal or coals for the manufacture of coke of desired quality with due consideration of the purpose for which the coke is intended requires careful thought, and often it will pay to go to consider able expense in testing such coals as may be available. In general it will always be possible to obtain a satisfactory coal or blend of coals for the particular purpose in view, but in some places the cost of transportation would be prohibitive. It may then be necessary to consider a coal or coals inferior in grade, rank, or both. At times, in fact, only one inferior coal may be available, when the problem becomes mainly one of selecting equipment and operating conditions best adapted to that coal, keeping in mind that the end product of the plant must compete with the imported product in the market the plant will serve. This applies particularly to new projects for which it is necessary to build a plant and start with a clean slate, so to speak. However, it will pay every coke-plant manager to employ a force to continually test the coals used and the coke produced to make sure that the quality is not changing appreciably. Furthermore, if the supply of coals used becomes exhausted it will be necessary to use other coals. Continual testing is particularly necessary at plants using borderline coals or blends, where slight changes in the composition or in operation of the ovens may render them dangerously expanding. In this connection it should be stated that control in the newer coke plants is considerably easier than for those built a decade or so ago, consequently in the new ovens a given operating program can be maintained more precisely. This point is important, because one of the main requirements of the coke user is uniformity in both physical and chemical characteristics. For example, any appreciable changes in the quality of coke delivered to the blast?-furnace operator will involve changes in operation if the best results are to be obtained. Such changes are expensive usually they take considerable time and involve production of inferior iron.

Jan 1, 1942

By Irving Wender

This report describes Bureau of Mines experiments and reviews the work of others on the exposure of coal and coal-derived products to gamma rays and some other types of radiation. Results are presented on tests of three bituminous coals and a lignite that had been pulverized to minus 200-mesh particles and exposed to 1,000 megaroentgens of gamma irradiation from spent-fuel elements of a nuclear reactor. Of about 20 chemical and physical tests in Bureau work, only mass spectrometry of gases evolved during vacuum pyrolysis of the coals to 450° C gave results indicating differences in the irradiated and unirradiated samples. Mass-spectral distribution curves for CO and CO2 evolution showed fewer irregularities (reversals of curvature) for irradiated coals; thus, mass spectrometry appears to be the most sensitive method for determining radio-induced changes in coal. It is concluded that coal is not significantly altered by gamma irradiation owing to the resistivity of its highly condensed ring structure. High-level gamma irradiation, therefore, is unlikely to prove advantageous in coal processing and utilization. Specially treated coals, because of resistivity of coal to radiation damage, may be useful as an absorbent in processing radioactive wastes.

Jan 1, 1968