Search Documents

By Van E. Shaw, D. J. Bauer

Conversion of euxenite concentrate to sulfates with sulfuric acid and solvent extraction of the yttrium- rare - earth mixture with EHPA were studied to determine extraction and separation characteristics . Digestion with 3.5 pounds of 96 percent sulfuric acid per pound of concentrate at 336 ° C for 4 hours resulted in an easily handled product with a yield in excess of 98 per- A thorium- free product was obtained by calcining the sulfated material for 3.5 hours at 650 ° C prior to leaching with water . Di ( 2 - ethylhexyl ) phosphoric acid solvent is an effective extractant with preference for cerium ( IV ) and heavy - group rare - earth elements including yttrium . Separation of complex rare - earth mixtures into light- and heavy - group fractions is feasible , and these fractions can be further processed to isolate ytterbium , neodymium , and dysprosium by changing processing conditions to obtain separation factors greater than two between these and adjacent elements .

Jan 1, 1965

By Dhanesh Chandra

[The U.S. Ucparunent of tlIe III LeriOr, Bureau of 1?Ilnes, lnta dcvcltil- (I a m.?tl,nd to extract nickel, i:ob.tll and IlIIicr Valuc:l,1, mrl?tl., lrom I.ow grad:, dumusI it Inlet itc.: :isin;; a rarb-i mnnnxid:: reducl.iun and ,innnonln/mumonlum sull,h.Ito Icitcll Col lowed by solved. evil let foil and clot tr:,winnfu,;. 'I 'o rain bcLtur undcI'sLandin;; uI the producLs reduced rind leached with the s;:Item, the liureau of t?Ilite; was enf,ngod In a 1 uinL sl.utly IIt1I the Uuttvcr ltc~:c:n-ch LnstiI-IL-. 'I'hr'ut;;h C(Im:drlod ahplit I¬L ion:; of a rotnbIW)L11nl ill eleu Lyon :utJ uplical inicrnscopy, cle trun beau micru,inal?;st?s and X-r.iv tcchnitlaes, Lhc factors jilt] ucncing low nickul e::lracl.on yLrids Iron, ccrlnin l;tteritos wul the hcuefhe al yCferL front addil.I:un u1. r:u)plowt' ruug,ounus and halides have bucn rrvealod. IL leas ht'en shown their nt nliJcrate Lion terlperuLuri's (5S0°C - 6501C) Lhe 111LACl extraction ylolds were low hccausc of the futmetlt-m of rufrill t,urv sillc:Ite compicxcs during ciii lit Hi [hut COOL.tlu sig nlficnnt anutunls of nickel .Lrui LhaL arc resistant Lu discolullull it, a su6r.C?quent ammnnlIca1 Jcaeh. 'This formation ill rulracLorv rnngtieves is altrlbuU?d Lo the prc.srnCV of aluauinum combined with c.ilicun jn addlt.lon In tnnl;neni~im in I.lic Lalerites, Iligb exII.Ictlon yields were oblalneJ when none or only a few I ,fraCLot' e, were InrmeJ. Hit s;intc rcfrarlnry cowl, Icxc5 also lend Lo surround Ow IaaIIiable meI.allle iron-IIIcI:el :iILoy CIUSisling ill the mau'ix, tIll: rrhv nreveu)Ling cuntacr ,Itlt LI5U Jeacl: solution; this, huwrvcr, ran ho ovu:rcoml by At ti itlon .111.11 retieCtiun. 'I'hc eIIcc l of prr.reJIctlun .,Ill itivi's vucli i's lye iii', ',udlum "Ill orIde, hv,Irogrn CIIInrILIC, etc., and Lht? 1111,Lre:InrLlI'll he'e:tleg un Lbe cxLt,icLitin are also iilsr.ussod 111 Lhe rcl,olt.]

Jan 1, 1979

By R. H. Schutz

TO ASSIST users in the selection of reliable and satisfactory respiratory protective devices, the Bureau of Mines bas established five schedules of minimum performance requirements for the approval of respirators. The current revisions of these schedules3 include 13D for self-contained breathing apparatus, 141F for gas masks, 19B and the amendments to 19B for supplied- air respirators, 21B for dust, fume, and mist respirators, and 23B for chemical cartridge respirators. Copies of these schedules may be obtained from the Bureau of Mines, Publications Distribution Section, 4800 Forbes Avenue, Pittsburgh, Pa., 15213. Approval tests on respirators are performed only at the request of the manufacturer4 of the respirator and at his expense. If the device meets the approval requirements, a certificate of approval is granted on the complete respirator. This certificate states that as long as the respirator is manufactured as originally approved, or in accordance with any changes covered by an extension of the original approval, the manufacturer may advertise and sell his respirator as being approved by the Bureau of Mines. Many industries and regulatory agencies require that respirators approved by the Bureau of Mines he used where respiratory protection is needed. The Bureau of Mines, however, has no regulatory power over the use of the respirators that it approves. It acts as an impartial testing agency to insure the availability of suitable and safe respirators.

Jan 1, 1966

By A. Gene Collins

The Bureau of Mines undertook research to determine the bromide and iodide content of Mississippi and Alabama oilfield waters of the Tertiary and Cretaceous Period to determine genetic relationships of the ions, to determine their origin, and to determine their genetic relation to petroleum. The 280 samples were analyzed after a pretreatment to remove interferences. The iodide was oxidized to iodate and was titrated with thiosulfate. The bromide was oxidized to bromate and was determined iodometrically. A computer was used to calculate the correlation coefficients of iodide to bromide and to other ions. The other ions are sodium plus potassium, calcium, magnesium, chloride, bicarbonate, and sulfate. The mineral content of the samples ranged from 52 to 1,760 mg/l for bromide and from 2 to 65 mg/l for iodide. The mean bromide-to-chloride and iodide-to-chloride ratios were 0.0065 and 0.0002. The correlation coefficient matrix and linear plots indicated a definite bromide-to-calcium relationship for the brines investigated.

Jan 1, 1967

By R. H. Schutz

TO ASSIST users in the selection of reliable and satisfactory respiratory protective devices, the Bureau of Mines bas established five schedules of minimum performance requirements for the approval of respirators. The current revisions of these schedules include 130 for self-contained breathing apparatus, 141F for gas masks, 19B and the amendments to 19B for supplied- air respirators, 21B for dust, fume, and .mist respirators, and 23B for chemical cartridge respirators. Copies of these schedules may be obtained from the Bureau of Mines, Publications Distribution Section, 4800 Forbes Avenue, Pitts- burgh, Pa., 15213. Approval tests on respirators are performed only at the request of the manufacturer of the respirator and at his expense. If the deice meets the approval requirements, a certificate of approval is granted on the complete respirator. This certificate states that as long as the respirator is manufactured as originally approved, or in accordance with any changes covered by an extension of the original approval, the manufacturer may advertise and sell his respirator as being approved by the Bureau of Mines. Many industries and regulatory agencies require that respirators approved by the Bureau of Mines he used where respiratory protection is needed. The Bureau of Mines, however, has no regulatory power over the use of the respirators that it approves. It acts as an impartial testing agency to insure the availability of suitable and safe respirators.

Jan 1, 1966

By Joseph M. Kurtak

The U.S Bureau of Mines conducted a five-year mineral resource assessment of the 16.6 million acre Colville Mining District in northern Alaska, which includes part of the National Petroleum Reserve in Alaska. The study was initiated at the request of the Bureau of Land Management, which administers the majority of the region. The study was done in cooperation with the Alaskan Division of Geological and Geophysical Surveys, the U. S. Geological Survey, and the University of Alaska. During fieldwork, 1593 rock, soil, and stream sediment samples were collected and four bulk samples taken for beneficiation studies. A total of 40 mineral occurrences were documented, including 27 which were previously undescribed. No mining has occurred within the district. Mississippian carbonaceous shale and siliceous mudstone contain stratiform exhalative lead-zinc-silver occurrences. Grades average 8.0% combined lead/zinc and 51 gm/mt silver. Upper Devonian to Lower Mississippian sandstones host breccia veins, containing up to 29% combined lead/zinc and 274 gm/mt silver. Mineralized quartzites of similar age have potential for disseminated-type lead-zinc deposits. Samples from Lower Cretaceous mudstone and shale beds up to 6.5 meters thick, contain as much up to 12% manganese. Upper Mississippian carbonaceous shale and limestone beds contain up to 23% phosphate. Stratiform barite deposits hosted by cherts, are up to 27 meters thick with an average specific gravity of 4.16. Vein-type fluorite occurrences are associated with Mississippian limestone. Moderate potential exists for development of zinc -lead-silver, barite, and phosphate deposits.

Jan 1, 2011

By C. Özgen Karacan

The methane emission rate into an underground mine environment from overburden strata during longwall mining is impacted by reservoir and geomechanical characteristics of the coal measure rocks in the overlying strata, as well as the presence of any coal seam. The reservoir characteristics and how they change during mining potentially affect the performance of gob gas ventholes, which consequently impacts the efficiency of methane control in the mining environment. This study presents reservoir and elastic properties of coal measure rocks in the Lower Monongahela Group in Greene County, southwestern Pennsylvania, of the Northern Appalachian Basin. Since the source of methane in this region from underground mining is located between the Sewickley coal and the Pittsburgh coal, a specific emphasis was given to this interval. Core analyses were performed in the laboratory to determine rock porosity and permeability. Geophysical logging data (gamma, density, sonic) obtained from two exploration boreholes were used for evaluating formation boundaries, shale contents, log porosities, and geomechanical properties of formations. Permeability was also calculated using density-log data and empirical equations and compared with laboratory measurements and slug tests performed in isolated intervals of boreholes. The results presented in this study can be used as data sources for reservoir studies related to the production and control of methane.

Jan 1, 2009

By M. R. Geer

The Bureau of Mines examined the washability data for 25 Appalachian coals requiring low-density washing to reduce sulfur content to 1 percent, using the distribution-curve method. The purpose was to estimate how closely theoretical sulfur values could be approached, what yields of washed coal could be expected, and the recovery efficiencies that might be achieved. Assuming that the run-of-mine coal would be crushed to 3/8 inch and cleaned in dense-medium cyclones, the calculations indicate that theoretical sulfur contents could be approached closely when cleaning at a specific gravity of separation as low as 1.30. With coals that have favorable specific gravity compositions the recovery efficiency anticipated for cleaning at 1.30 specific gravity is surprisingly high. Similar calculations for cleaning with concentrating tables at intermediate specific gravities indicated that theoretical sulfur contents at 1.50 specific gravity could be approached closely with some coals but not with others. The calculations suggest that operating a table at a specific gravity of separation much lower than about 1.50 probably would be unsatisfactory with most coals.

Jan 1, 1968

By Barry L. Warner

This program involves the evaluation of means for suppressing fires on underground coal mine conveyor belts. Full scale conveyor belt fire tests were conducted to determine the requirements of automatically actuated water sprinkler, high expansion foam, and multi-purpose dry powder extinguishing systems, and of various fire detection devices, necessary to adequately protect underground belt heads. The program included the development of a suitable MI scale conveyor belt test fire, conducting of fire tests in which extinguishing and detection systems and equipment were evaluated, and testing to evaluate the effects of the coal mine environment on detection equipment. Preliminary testing conducted to develop a suitable test fire revealed that fire can propagate on some conveyor belting classified as fire-resistant. New fire-resistant PVC and new non-fire resistant rubber belts were used in the full scale fire tests. These tests indicated that a single branch line sprinkler system with relatively low water pressure provides adequate belt head protection. High expansion foam and multi-"purpose dry powder extinguishing systems as presently specified by regulation were found to be suitable for belt head protection, although care is required with powder systems to assure adequate distribution. Thermal type detection devices were found to be most practical for conveyor belt protection, with combustion products and optical detection methods having serious disadvantages.

Jan 1, 1974

By R. T. Johansen

The adverse effects on waterflooding and well-completion methods of clay minerals indigenous to petroleum-production formations recently have received considerable attention. Knowledge of the types and amounts of clay minerals present would allow estimates of the response of such formations to injected or infiltrated water; however, the random distribution of clays in sedimentary formations makes direct evaluation of ?water sensitivity? desirable. A method for the direct evaluation of water sensitivity has been developed, based on measurement of water-vapor adsorption. Correlation of such data with the results of nitrogen-adsorption measurements provides valuable information on the content and properties of clay minerals in sedimentary rocks. The method is relatively simple and has the advantage that it may be used with small, irregularly shaped chips or shale-streaked samples, as well as with typical core samples. Methods previously employed required separating the clay from the rest of the reservoir-sample material and then performing a clay analysis either by X-ray diffraction, differential thermal analysis, liquid permeability, or a combination of these methods (2,3) .3/ This water-vapor-adsorption method requires measuring only a few points on the isotherm to tell whether or not the sample is water sensitive. The goal of these measurements is not to determine the type or amount of clay present, but what will be its sensitivity to flood water. This method gives a direct means of solving this problem.

Jan 1, 1958

By F. F. Aplan

Separation of the slightly soluble minerals (Ksp? 10-10), one from the other is one of the more difficult tasks confronting flotation engineers. This study has focused on means of separating such prominent members of this class as scheelite, fluorite and calcite from one another. Some experimental work has also been done on the minerals magnesite, dolomite and apatite. Carboxylic acid-type collectors are commonly used industrially to float all of these minerals. Thus, the problem at hand is to ascertain means of achieving selectivity between minerals known to respond rather similarly in flotation. Four techniques have been proposed for the separation of minerals of this class from each other: 1. Control of potential determining ions 2. Use of stereo-specific collectors 3. Use of flotation rate differences 4. Use of selective activating and depressing compounds. This study was directed toward a cursory evaluation of each of these techniques, and each was found to be a possible method of achieving selectivity. Stereo-specific collectors -- those whose parking area may closely match the available adsorption site on one mineral but not on another -- are a possible means of achieving selectivity between scheelite, fluorite and calcite. Stereo-hindered carboxylic acid salts and sulfonates all show selectivity between the three minerals tested. Separations also appear to be possible by the controlled use of the lattice ions (e.g., Ca and [W0=4] for scheelite, CaW04), H+, [OH-, C0-3 and HCO=3]; all of them ostensibly potential determining in the systems studied. Flotation rate differences of the minerals as a function of pH under conditions of starvation collector usage also showed promise. Scheelite and fluorite float most rapidly with sodium oleate in slightly acidic (pH 4-7) solutions whereas calcite floats most rapidly near pH 10. Use of Mn++, Pb++, or other heavy metal hydroxy complexes as activators was seen to effect each of the slightly soluble minerals differently. This is in sharp contrast to the oxygen containing, relatively insoluble minerals, where all minerals respond in a similar manner to such activation procedures. Results indicate that all four methods outlined above may potentially be used to achieve flotation separation of the slightly soluble minerals. More extensive research should be undertaken to detail the spcific applicability of each of the procedures and to make a more complete evaluation of the effect of collector type and concentration, mineral type, pH and size effects.

Jan 1, 1983

By B. J. Scheiner

The Federal Bureau of Mines has successfully demonstrated an electrooxidation-solvent extraction-carbon adsorption process for recovering molybdenum and rhenium from offgrade concentrates. The flow sequence consists of dissolution of metal values by electrooxidation, liquid-solid separation by thickening, acidification and chlorate ion removal by sulfur dioxide treatment, solvent extraction to concentrate the molybdenum and rhenium, separation of molybdenum and rhenium by carbon adsorption, and metal recovery by crystallization. Molybdenum and rhenium were recovered as ammonium paramolybdate and ammonium perrhenate. Electrolysis of brine-concentrate pulps to generate a hypochlorite oxidizing agent in situ resulted in the dissolution of 98.9 and 99.1 pct of the molybdenum and rhenium, respectively, at an energy consumption of 13.7 kwhr/lb of molybdenum extracted.

Jan 1, 1976

By A. W. Deurbrouck

The separations achieved by eight conventional cyclone washers have been evaluated to determine their performance when processing intermediate size coal of 28 mesh bottom size. The dense-medium cyclones provided efficient, sharp separations in treating feeds of up to 44 percent of near-gravity material at separating specific gravities ranging from 1.42 to 1,55 (one separation of a secondary feed was made at 1.63). Complete washability analyses are shown by sizes of the composite feed to these cyclones. The magnetite losses per ton of coal processed ranged from 0.6 to 2.0 pounds; however, of the eight plants reporting losses, seven indicated magnetite losses were 1.1 pounds or less per ton of coal processed.

Jan 1, 1972

Objective To reduce dust generated from soiled floors within enclosed operator cabs. Background Enclosed operator cabs are widely used on mobile excavation equipment in the mining and construction industries. They protect the operator from bad weather, noise, and airborne dusts. The inside cab environment usually must be kept at very low dust concentrations because of quartz dust generated from the excavation of silica-bearing rock. For cabs to be effective in controlling airborne respirable dust, they must have an efficient air filtration system, while providing a positive pressurization of the cab interior. Ideally, the recirculated and exterior makeup air filtration should provide at least 99% capture efficiency for dust particles as small as 0.3-µmaerodynamic diameters. Many of these enclosed cabs use heating units mounted or directed along the floor (see figure 1), which can cause dust entrainment problems. Prior studies by the National Institute for Occupational Safety and Health (NIOSH) of enclosed cabs have shown that these floor heaters can generate notable amounts of dust within the cab enclosure (see Technology News 486). Multiple-shift dust levels measured inside a drill cab increased on average from0.04 mg/m3 during the summer months to 0.68 mg/m3 during the winter months. Additional dust level measurements, made with optical particle counters during a nondrilling time period, verified that dust levels inside the cab increased from 0.03 to 0.26 mg/m3when the floor heater/fan was turned on. Dust levels within the cab also became greater than the ambient air dust levels outside of the cab when the floor heater was turned on during the nondrilling time period. This shows that the floor heater was a notable dust source problem. Cab floors are commonly soiled from operators tracking dirt inside the cab upon entering from the mine or construction site. Interior cab dust levels can be increased by (1) airflow disturbance of the soiled floor or (2) operator disturbance of the soiled floor. Approach During prior NIOSH surveys of surface coal mine drills, several drills with very low cab dust levels (#0.1 mg/m3) were observed to have floor sweeping compound spread out over the cab floor during the working shift. This initial observation led to a more controlled A-B study of the effect of the sweeping compound on the interior cab dust levels. This study involved dust sampling with and without sweeping compound inside the cabs of a bulldozer and two drills. Sweeping compounds commonly use sawdust or cellulose as the main bulk material, with oil or wax added for dust adhesion purposes. Sand is sometimes added to increase bulk density. Sweeping compounds with sand are commonly used to sweep up concrete floors. Those without sand (usually referred to as "gritless") are used to sweep up smooth finished floors. Most of the oils and waxes used for the adhesive ingredient are petroleum-base and can have an irritating odor. People sensitized to petroleum distillates could have allergic reactions to these sweeping compounds. A few companies offer non petroleum-base sweeping compounds, using either a natural oil or chemical additive for dust adhesion. During this study, it was decided that only the gritless sweeping compound (without sand) would be used, eliminating the addition of another potential silica source inside the cab. Since the sweeping compound would be applied on the enclosed cab floor for the duration of the shift, it was decided to use a canola oil-base sweeping compound to eliminate irritating odor from the petroleum-base sweeping compounds. The natural canola oil-base sweeping compound had a slight woody scent. The three pieces of equipment used in this study had notably different cab layouts. The bulldozer had a small cab with vents discharging air-conditioned or heated air from adjustable louvers at operator waist level and floor level. The bulldozer also had a cloth fabric seat and a carpeted floor. Drill A had a large cab with the heat directed from adjustable louvers at operator knee level and the air-conditioned air directed from cabin ceiling louvers. This drill had a vinyl fabric seat and a steel plate floor. Drill B had a small cabin with the heat directed across the floor (see figure 1) and the air-conditioned air directed down from the ceiling. It had a vinyl fabric seat and a worn rubber mat on a steel floor.

May 1, 2001

By J. H. Wiggins

"The tests described below were conducted by the Bureau of Mines at a lease in Oklahoma on installations designed to decrease evaporation losses of crude oil Pram storage tanks. Use of the lease was granted by the Oklahoma Producing and Refining Corporation of America. Tankage was obtained through the courtesy of the Parkensburg Pig and Reel Co. The purpose of the installations and tests was to demonstrate the value of making crude-oil storage tanks gas-tight, rather than to determine the amount of evaporation in any one type of tank. None of the tanks used were absolutely gas-tight, but one of them was very nearly so. They comprised a tank of the ordinary open type with an 18-inch manhole, a tank with a ""4-inch vent"", a tank with a ""smaller vent"", and a tank which had only ""pin holes"" through which air and vapor could pass freely. On the last two tanks any excess pressure was taken care of by an automatic differential pressure regulator.The results obtained in these tests indicate that tight tankage will soon pay for itself. They will not, however, serve as a basis on which a producer can compute the actual number of days necessary for tight tankage to pay out, because the oil used was exceptionally volatile. It is probable that the average evaporation loss in the Mid-Continent field is at least one-half as great as that shown by these tests, and if this is true, the saving that would be effected by providing tight tankage on the lease will undoubtedly justify the expense. The installation of evaporation-proof tanks on the lease has been delayed by the failure of production managers to realize, first, that their evaporation losses are enormous, and, second, that they can practically eliminate these losses by a simple and inexpensive installation."

Apr 1, 1921

By Paul M. Ambrose

ADVANCES in mining and processing technology made it possible to reopen the De Beers diamond mine in South Africa, originally located in 1871 by Cecil Rhodes and closed in 1908. Radioactive material was used to indicate the efficiency of hydro-cyclones used in diamond concentration. Added interest was shown in recovering diamond from the sea off the coast of South-West Africa. Production of crude artificial abrasives declined because demand was paritally met by withdrawals from stocks. The value of graded grain-coated abrasives and grinding wheels surpassed those of 1962.

Jan 1, 1964

By John Durkin

A computer model has been generated to evaluate speech intelligibility of individuals wearing conventional and electronic hearing protectors. For speakers talking at normal levels in noise levels of 65 db(Lp) or less, it was found that conventional hearing protectors significantly reduced speech intelligibility. Under the same conditions, electronic protectors provided scores equal to those for the unprotected individuals while providing protection from high noise levels. Therefore, electronic hearing protection is valuable in areas where high noise level is intermittent.

Jan 1, 1979

By J. T. McCartney

The Bureau of Mines has developed an automated reflectance scanning microscope system, primarily for determination of volume proportions, size distribution, and mode of association of the physical (petrographic) components of coals. The process, which is potentially more rapid and objective and less tedious than a visual microscopic procedure, involves magnetic tape recording of several millions of reflectance readings on micro-meter sized areas of polished coal surface and computer analysis and interpretation of some characteristics of the coal components. The system was tested in a study of pyrite distribution in steam coals. The application was essentially successful, but defects in polished pyrite surface characteristics and problems in adequate sampling prevented completely satisfactory results. Pyrite con-tent and coal-pyrite particle association could be determined nearly as well as by visual microscopy, but size distribution data were less acceptable.

Jan 1, 1969

By Roy C. Bartholomae, Jeffrey Shawn Peterson

1. INTRODUCTION In the early 1980s, the U.S. Department of the Interior’s Bureau of Mines Pittsburgh Research Center required that a large reverberation acoustic facility be constructed. This facility was designed to determine the sound power level emissions of mining equipment, especially continuous miners and jumbo drills. A contract for a conceptual design of a reverberation chamber was awarded to Wyle Laboratories of Huntsville, AL, which had extensive experience in the design, construction, and accreditation of acoustical reverberation chambers. The following standards were referenced as guidelines for the design of the chamber: ANSI S1.31-1980, “Precision Methods for the Determination of Sound Power Levels of Broadband Noise Sources in Reverberation Rooms” and ANSI S1.32-1980: “Precision Methods for the Determination of Sound Power Levels of Discrete-Frequency and Narrowband Noise Sources in Reverberation Rooms.” Specific requested criteria included that the room be large enough to accommodate typically large mining equipment and that there be adequate acoustical modal density in the frequency range of interest. It was also required that the room dimensions would support broadband acoustical measurements down to the 100 Hz third octave band. With the closing of the Bureau of Mines in 1996, this reverberation chamber lay dormant for a number of years. However, this facility is now part of the National Institute for Occupational Safety and Health’s (NIOSH’s) Pittsburgh Research Laboratory (PRL). One of NIOSH’s missions is to decrease noise induced hearing loss among the nation’s mineworkers. To this end, PRL researchers are refurbishing and instrumenting this reverberation chamber to facilitate assessment of the various engineering controls being developed to decrease the sound power level emissions of mining equipment. Early on, this work has sought to bring the chamber up to the level of ISO 3743-21 standard for engineering grade measurements for broad-band noise, with a longer range goal of improving the lab to meet the requirements of ISO 37412standard for broadband precision grade measurements. 2. DESIGN OF THE REVERBERATION CHAMBER The nominal room dimensions are 18.3 meters long by 10.3 meters wide with a height of 6.7 meters. The chamber volume is 1,286 cubic meters. These dimensions are important, as few reverberation facilities are large enough to test typically huge mining equipment. The floor is poured concrete with a sealer to make it acoustically reflective. The walls are built of hollow concrete block, 16 inches long x 8 inches high by 12inches thick. Each block has two hollow cores. The hollow block cores were completely filled with concrete with horizontal and vertical steel reinforcing bars 16 inches on center. This was done to supply a

By J. B. Zink

The Bureau of Mines developed a spectrochemical method to determine six constituents in coal ash in the following concentration ranges: silica 9 to 63 percent, alumina 7.5 to 35 percent, ferric oxide 2 to 30 percent, calcium oxide 1 to 29 percent, magnesium oxide 0.5 to 6 percent, and titanium oxide 0.5 to 4 percent. Samples of coal ash are fused with a mixture of lithium tetraborate and vanadium pentoxide. The resulting beads are crushed, mixed with powdered graphite, and briquetted. The pellets are analyzed spectrographically, using controlled high-voltage spark excitation. Vanadium serves as the internal standard. Effects due to matrix variations are minimized by fusion with lithium tetraborate. Intensity ratios of selected analytical lines are determined photometrically, Concentrations are read from analytical curves, prepared from synthetic standards, relating log intensity ratios to log concentration. A combustion procedure is used to determine sulfur tri-oxide. The method is most useful when large numbers of coal ashes must be analyzed but a high degree of accuracy is not essential.

Jan 1, 1967