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By David E. Fogelson

The breakage of rock by explosives depends largely on the ability of an explosive to transfer its stored potential energy to the rock as strain energy. Therefore, the relative rock-breaking abilities of explosives can be determined indirectly by determining the relative amounts of strain energy transferred to the rock at the time of detonation. This report presents experimental data on the strain energy contained in explosion-generated strain pulses in a granite gneiss. Six explosives were tested. The scaled total radial strain energy Es/W flowing outward through a spherical shell of scaled radius R/W1/3 surrounding the point of detonation was found to follow an exponential decay propagation law of the form [ ]

Jan 1, 1959

By John Nagy

Experience and research have shown that an effective way to reduce structural damage from explosions is to provide adequate pressure-relief vents in the walls of equipment and buildings within which explosions might occur. In general, free or unrestricted openings represent the most efficient type of vent. However, in many manufacturing operations it is impractical to use free vents, and it becomes necessary to cover the openings with diaphragms or blow-out disks, hinged panels, or other devices, in order to give protection against weather changes, to prevent the efflux of dusts or vapors from equipment during normal operations, or for other reasons. A few data on the pressure-relieving capacities of hinged panels and a paper diaphragm were published in Bureau of Mines Report of Investigations 3924, which covered the first phase of the dust-explosion venting study made by the Bureau. The present report describes recent experiments that were made to determine the relative effectiveness of an unrestricted vent and 22 types of closures, including various paper, cloth, and metal-foil diaphragms, hinged doors or panels, and several kinds of scored and unscored glass panes. The tests showed that many of the vent closures were effective in releasing the explosions rapidly during their incipient stage, so that the development of destructive pressures was prevented. Vents of this type should prove useful in safeguarding industrial equipment from severe explosion damage. The experiments disclosed that the venting capacities of the diaphragms are approximately inversely proportional to their static bursting strengths.

Jan 1, 1950

An independent contractor is defined by the Mine Safety and Health Administration (MSHA) as ?any person, partnership, corporation, subsidiary of a corporation, firm, association or other organization that contracts to perform services or construction at a mine.? Contractors that perform specific types of work are required to report the number of employees who work at coal mines and noncoal mines.

Aug 1, 2009

By Charles H. Atkinson

The Rio Blanco massive hydraulic fracturing demonstration has been undertaken by the Bureau of Mines, Atomic Energy Commission, and a group of 15 industry participants. CER Geonuclear Corp. has been retained as program manager to evaluate the stimulation effects of very long fractures, suitably propped open in thick sections containing multiple intervals of low-permeability gas-bearing sands. The zone of interest for this demonstration includes Fort Union and Mesaverde sands from about 5,800 to 8,.200 feet deep in Rio Blanco County, Colo., about 1 mile from the site of the May 1973 triple nuclear detonation aimed at stimulating production from the same reservoirs. Drilling the test well and evaluating the reservoir prior to fracturing was funded by Government participants; fracturing and production testing will be funded by industry. The test well has row been completed at a total depth of 8,170 feet, and data obtained from logs, cores, production and drill-stem tests indicate reservoir conditions to be less favorable for gas production than anticipated. Structural position is lower than expected, resulting in higher water saturation than was determined for the same sands at the nuclear fracturing location. The lower sands of the Fort Union sequence appear to have higher shale content than has been encountered in other wells in the area. Despite the likelihood that gas productivity will be undesirably low following stimulation, the industry participants decided to proceed with the stimulation program with the thought that the resulting data would be useful. The success of the stimulation test probably will have to be judged by production increase rather than by production volume.

Jan 1, 1975

By E. J. Harris

Data obtained from mine ventilation pressure and quantity surveys are required to accurately diagnose ventilation problems, project future air quantity needs, and to locate conditions adversely affecting the efficiency of a mine ventilation system. A method for making mine ventilation pressure surveys with aneroid altimeters was presented in Bureau of Mines Information Circular 7809, and a description of field calculation technique is presented. This report supplements Information Circular 7809 by developing the information obtained during a mine ventilation pressure survey into a single equation suitable, with appropriate modification, for use with desk-top calculators and digital computers. The equation can be used to calculate the ventilation pres sure from the base station to any underground station, or between any two underground stations, and can be programed for semiautomatic sequential calculation using a desk-top calculator. An example of application to a programed desk-top calculator is provided in the appendix.

Jan 1, 1973

By F. S. Kendorski

This report covers the work on developing criteria for determining when a hazard exists when mining stratified mineral deposits beneath bodies of surface water. The nature of water bodies is considered, the disturbance to the strata induced by mining is described, inundation case histories reviewed, reasonable water inflows derived, and methods of mining to prevent or minimize the hazard are presented. Criteria are given whereby effected industries and agencies can recognize a potential hazard and plan a mine accordingly, releasing considerable mineral reserves otherwise considered unminable.

Jan 1, 1979

By G. B. Atkinson

To develop technology to help assure an ample domestic supply of zinc, the Bureau of Mines is investigating an aqueous chlorine-oxygen leaching process for treating complex sulfide concentrates. This report discusses the purification of aqueous C12-02 leaching solutions by utilizing zinc cementation to remove Cd, Co, Cu, Ni, and Pb. Additional processing of the purified solution is necessary to produce ZnC12 crystals suitable for molten-salt zinc electrowinning cells. The effects of solution temperature, reaction time, zinc dust concentration, ZnCl2 concentration, and degree of agitation on the removal of impurities were investigated for both simulated and actual leaching solutions. Zinc dust addition to a leaching solution at 30° C decreased the Cd, Cu, Ni, and Pb concentrations to acceptable levels of less than 3 mg/1 each. By increasing the solution temperature to 75° C, the cobalt content was decreased to less than 5 mg/l, an acceptable level for producing electrolytic cell-grade ZnC12. Impurity removal rates from ZnCl2 solutions are Pb>Cu=Cd>Ni>>Co. An increase in the solution temperature increases the rate of removal for these metal impurities.

Jan 1, 1982

By X. Shi, V. Vallyathan, N. S. Dalai

"Electron spin resonance (ESR) measurements show that grinding of quartz particles in air produces silicon-based (Si- and SiO-) radicals which decay with aging in air. ESR spin trapping measurements provide evidence for the generation of hydroxyl and possibly superoxide radicals from a suspension of fresh quartz particles. The hydroxyl radical generation potential of the fresh quartz particles decreases on storing in ambient air and on the addition of catalase, superoxide dismutase, desferoxamine, or DMSO. Silica-induced lipid peroxidation also decreases on storing the fresh particles in ambient air. These findings suggest that oxygenated radicals play a role in the biochemical mechanism of pneumoconiosis in general and acute silicosis in particular.INTRODUCTIONThis communication summarizes our electron spin resonance (ESR) investigation of the formation of oxygenated radicals by freshly crushed quartz particles in a cell-free aqueous medium, and its potential role in the biochemical mechanism of acute silicosis. This study was undertaken because the mechanisms by which the quartz particles exert their toxic action on cells and the process(es) by which these actions progress to fibrogenesis are still not well understood. 1-3 It is generally believed, however, that the action of quartz particles on the cell membrane is the starting point of the silicotic process. 1,4 Since the first step must involve surface reactions, characterization of the chemical structure of the surface of quartz particles has been the subject of several recent studies!-' For example, we reported that mechanical crushing of quartz under normal atmosphere generates silicon-based (Si• and SiO•) radicals which decay with time, and that these radicals are associated with a higher cytotoxicity of fresh quartz dust as compared to that of an aged dust from the same stock. 6,8 Independently Fubini and coworkers' have also reported on the formation of Si• and SiO• -type of radicals from quartz particles crushed under atmospheric conditions. Gulumian and van Wyk9 have reported that quartz particles react with hydrogen peroxide (H202) to generate hydroxyl (•OH) radicals. These authors9 suggested that this process might contribute to quartz's pathogenicity but the mechanism of the -OH radical formation was not clarified. Earlier, Gabor and Anca10 had suggested that the cytotoxicity of quartz particles might be associated with the generation of some factor or factors possessing the properties of a free radical and hence capable of promoting the peroxidative chain cleavage of polyunsaturated fatty acid moieties of the phospholipids in the cell membrane. More recently, Weitzman and Graceffa 11 reported that asbestos is able to catalyze the generation of -OH radicals from H2O2. Their later work12 indicated that lipid peroxidation might be one of the mechanisms of tissue injury by asbestos."

Jan 1, 1989

By R. L. Crosby

A part of the liquidus of the magnesium-zirconium system was determined by chemical analysis of suction samples taken from the melt in the approximate temperature range of 850° to 1,450° C. The melt was prepared in a furnace pressurized with an inert gas. The average zirconium value in weight-percent of the liquidus composition at each sampling temperature was 0.96 at 867° C, 1.40 at 1,062° C, 2.05 at 1,262° C, and 2.96 at 1,402° C. The equilibrium solid phase was zirconium.

Jan 1, 1965

By Christopher H. Roe

This Bureau of Mines report reviews the various methods of removing the liquid from tailings slurries that contain very fine grained solids. Gravitational settlement, centrifugation, filtration, and thermal drying methods are discussed in detail. Chemical additives, electrokinetic dewatering, and the rotary trommel screen are also mentioned. Lists of dewatering equipment and suppliers are given in the appendixes to assist the planner who must choose the most efficient, economic, and practical method of dewatering very fine grained mill tailings.

Jan 1, 1984

By K. K. Kelley, L. B. Pankratz, W. W. Weller

Mullite is a substance of prime importance in ceramic technology . Despite this fact , its thermodynamic properties have received little attention . A Bureau of Mines literature survey disclosed the absence of lowtemperature heat capacity data , the absence of an experimental entropy value for 298.15 ° K , and the lack of heat content data beyond the temperature range from 298° to 576 ° K. Data supplied in this Bureau report fill these gaps in the thermodynamic knowledge of mullite . According to equilibrium phase studies of Aramaki and Roy ,3 the mullite phase melts congruently at 2,123 ± 15 ° K , and the equilibrium crystallinephase composition extends from Al Si2013 to Al6.8 Si₂ Q4.2 . The results in this report are for the stoichiometric composition , Al Si¿Qз . • Heat capacity measurements were made over the temperature range from 50 ° to 298 ° K , and the entropy at 298.15 ° K was evaluated . Heat content measurements covered the temperature range from 298 ° to 1,800 ° K. Heat content

Jan 1, 1963

By B. W. Naugle

This report describes the carbonizing properties of coals from the principal beds in Cambria County, Pa. Samples of coals from Upper and Lower Freeport and Upper and Lower Kittanning beds having estimated minable reserves of 50-million tons or more were studied by the Bureau of Mines. Cambria County coals rank either as medium-or low-volatile bituminous. A preparation study indicated that all coals tested in this county, except one sample from the Lower Freeport bed, were responsive to cleaning and would yield a product with satisfactory chemical properties for metallurgical coal. All coals tested from Cambria County yielded strong coke; however, they expand excessively when carbonized singly, and should be used only as minor constituents in metallurgical coking blends when carbonized in slot-type ovens.

Jan 1, 1959

By Martin H. Stanczyk

Acid leaching of selected copper sulfide minerals, impure copper sulfide flotation concentrates, and a cement copper precipitate at elevated temperatures and pressures was investigated. Copper extractions of 97 to 99 pct were obtained by leaching chalcopyrite and the flotation concentrates with water under oxidizing conditions at 200° C for 30 to 60 min. In tests with bornite, chalcocite,and cement copper, addition of sulfuric acid or pyrite to the autoclave was required to obtain similar copper extractions. The chemistry of leaching copper minerals was studied. It was determined that different copper sulfides altered to covellite as one step in their dissolution.

Jan 1, 1963

By G. E. Bobeck

The first year's work of a proposed three-year study of the effects of the exposure of coal mine roof rocks to the mine atmosphere has been completed. The project has been terminated. The goal of the project was to determine if possible the mechanism or mechanisms by which coal mine roof rocks interact with the mine atmosphere and weaken, and coupled with mechanical stresses, ultimately fail. The scope of the study was limited to the effects of environmental factors on the deterioration of the rocks. While mechanical stresses may play an important role in the interaction of environmental factors, stress effects were excluded from the study. In order to study the effects of environment on coal mine roof rocks, samples were obtained from several coal mines in the western states. The rocks forming the roofs of most of the mines visited were shales of varying composition. These shales were subjected to numerous tests to determine how the rocks changed with time after exposure. In addition, the identity of the minerals present in the shales was determined by x-ray diffraction analysis and by thermal analysis as well as by optical microscopy

Jan 1, 1973

By Allen D. Look

Underground fires often prove difficult to control , and a small fire can quickly grow into a large one , endangering life and causing large property damage . Even a small underground fire may produce enough noxious gases to cause suffocation ; therefore , every precaution should be taken to prevent and control such fires . It is ironic that mine fires should be caused when utilizing materials that are in themselves fire - resistant ; yet , cutting and welding of iron and steel are proving to be common causes of underground fires in metal mines . This paper includes 19 examples of underground fires of this nature , and undoubtedly this is only a fraction of the number of similar fires that have occurred in the last few years . This paper will review some metal - mine fires caused by cutting or welding and point out precautions to be taken to prevent other fires from this cause .

Apr 1, 1948

By George R. McCormick

Because several new and unusual synthetic minerals were found in the system MgO-MgF₂ - SiO2 with Li * , or Nat a similar system with Geo₂ replacing Sio , plus Lit was investigated . In addition to the expected compounds of germanium , Ge - fluor - hectorite and a Ge - fluor- chrysotile were synthesized . Protoamphibole was not observed . Data are given for 69 compositions prepared in the system MgO- MgF₂ - Ge02 at 6.94 percent LiF .

Jan 1, 1964

By G. L. Neumann

The Andover-Sulphur Hill iron mines in Sussex County, N. J., have a production record extending over 100 years. The last production recorded was about 1880. These mines produced high-grade ore of two types: Bed ore (hematite) and blue ore (magnetite. Some sulfides (lead, zinc, and copper) were found underlying the iron deposits. Data as to size and grade of these sulfide bodies are very sketchy, Toward. J. Hewitt of Elizabeth, N. J., lessee of the Sulphur Hill mines from 194045, prospected for lead, zinc, and copper. .His Only production was several hundred tons of low-grade iron ore, which was crushed and used as heavy aggregate to make concrete blocks for ship ballast. In October and November 1942 made a magnetic survey of this area and bored six-diamond-drill holes with the dual objective of prospecting for sulfides and testing for extensions of the iron-ore deposits indicated by the magnetic survey. In 1944, an iron-mining company examined this property and diamond-drilled seven holes Between December 1949 and March 1950, the Bureau Of Mines in search of sulfide deposits, bored three additional diamond-drill holes. Two of these were on the Sulphur Hill tract and one on the adjoining Tar Hill tract.

Jan 1, 1952

By J. J. Jakowsky

[The legislation in many States against the present method of producing carbon-black by the incomplete combustion of natural gas, and the continually increasing demand for gas for otter purposes, indicates that the supply of carbon-black may Gradually be decreased and that new methods for its production, utilizing a greater parentage of the carbon in the has should be developed. In the course of investigations of the effects on hydrocarbons of high voltage discharges, it was noted that under certain conditions natural gas could be decomposed and that carbon-black could be produced. The effects of several tyres of electrical discharges on natural gas have, accordingly, been studied' in order to find out the fundamental factors underlying the reactions and their possible influence in the recovery of a greater part of the carbon content of natural gas than is now possible. Present commercial plants using natural gas for the manufacture of carbon-black recover from 0.9 to 1.5 pounds of carbon-black per thousand cubic feet of gala consumed, or less than 5 per cent of the total Gabon in the gas: It should be noted, however, that the, present methods involve heating the gas to incandescense by burning it as a luminous flame, and a considerable part of the gas is thus consumed as a source of hest. If this heat can be supplied from some other source, or if a more efficient method of applying the energy con. tamed in part of the gas, to the decomposition of the rest of it, can be worked out, then a greater yield of carbon-black per thousand cubic feet of gas care be expected. The present abort paper contains a brief summary of tie investigations so far conducted upon natural gas.]

Jan 1, 1922

By K. K. Kelley, L. B. Pankratz

The heat contents of four silicate minerals -- akermanite , cordierite , gehlenite , and merwinite --were measured from 298 ° to around 1,700 ° K by the dropping method . The results were compiled into tabular and equation forms suitable for thermodynamic calculations . The heat contents of these compounds are nearly additive with respect to their constituent oxides .

Jan 1, 1964

By Ludwig Schmidt

The economic value of reducing the evaporation losses of crude oil and of gasoline is so well founded that the petroleum industry is constantly seeking new and improved storage tanks and methods of handling its products to further reduce these losses. A comparison of the methods and apparatus used in handling and storing crude oil and its products today with those in general use 10 years ago would show that an oil tank is no longer simply a container for holding liquid, but is now considered an important piece of equipment which if, subjected to constant inspection and care. In fact, the modern vapor-tight tank often requires as much care as a boiler or pump when one considers Its various component parts such as vapor-tight gage hatches and thief-hole covers, vacuum and pressure relief valves, swing line apparatus, vapor-recovery systems, insulation, cooling devices, and often automatic gaging devices. As an auxiliary to the physical equipment of the tank itself the subject of paints and paint colors is now given considerable attention. In addition to vapor-tight tanks and auxiliary equipment, other types of tanks for reducing, evaporation which are new to the industry have also been developed and placed on the market within the past few years. The development of the floating roof type was an innovation in tank construction, directed toward the reducing of evaporation losses. This type of roof rides on the surface of the oil and thus eliminates all vapor space. It is especially valuable for working tanks.3 A recent development in tank construction is a new type of tank roof known as the diaphragm or "breather roof," Which practically eliminates the movement of air-vapor mixture from a storage tank filled with oil. It is of especial value for use on tanks in which oil is stored over long periods.

Jan 1, 1930