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By C. J. Thompson

In the course of the work currently conducted by the Bureau of Mines in cooperation with the American Petroleum Institute Research Project 48 on identifying sulfur compounds in petroleum, a micromethod was developed (12)5 for catalytically removing the sulfur atom from sulfur compounds. The product is the residual portion of the molecule; the structure otherwise was unaltered except for hydrogenation of any unsaturated bonds that were present in the original compound. Positive identification of sulfur compounds isolated from crude oils is a difficult problem. Direct comparison of properties of the unknown with those of reference compounds is often impossible because of the limited number of reference sulfur compounds available. However, a relatively large number of pure hydrocarbons is available, and the conversion of the sulfur compound to a hydrocarbon enhances the possibility of identification. The technique also can be used to prepare microquantities of scarce hydrocarbons by hydrogenating compounds that are readily available.

Jan 1, 1962

By L. D. Tracy

The first study of this subject hits been made in Illinois, but as opportunity affords, similar studies will be made in other States. It is hoped that the data obtained will assist the coal-mining industry to standardize the forms of leases, and so avoid some of the abstruse and ambiguous clauses which slay be found in many of them and the consequent liability of costly litigation. In some of the publications of the Illinois Mining; Investigations prepared under a cooperative agreement with the U. S. Bureau of Mines, the Illinois State Geological Survey and the Engineering Experiment Station of the University of Illinois, the coal areas of the 'State have been divided into eight geological districts, each district being treated separately. This report covers District No. VI of that classification, and it is hopped that studies of the other districts will be completed in the near future and similar results published.

Jan 1, 1926

By Sumner M. Anderson

ATHOUGH scattered signs of increased activity in the mining industry accompanied an incipient improvement in the overall economic situation during the latter months of 1963, production levels for the year as a whole responded to the general 1962-63 business recession with a 4.2 percent decline. The petroleum industry, active since 1907, did not become a dynamic force in the economy until exploration and drilling contracts were concluded with private companies in 1958 and 1959; on November 15, 1963, having virtually achieved self-sufficiency in petroleum in the preceding year, those contracts were unilaterally annulled. In the field of metallics, the only approach to internal sufficiency-aside from the iron and steel industry that has depended heavily on the importing of basic raw materials-has been in mining, smelting, and refining lead and zinc although iron ore, silver, beryllium, tantalite, and tungsten have been mine production items of economic significance. Reserves of lead, zinc, silver, bismuth, vanadium, and low-grade and metallurgically difficult iron ore-as well as those of beryllium, tantalite, and tungsten which are produced primarily for export-appear to be fairly abundant. The exploration of deposits of copper, cobalt, tin, lithium, gold, manganese and uranium has been undertaken on a relatively small scale, and little precise information is available on the extent of reserves. Argentina is dependent on foreign sources for part of its required iron and steel and, except for lead and zinc, most of its nonferrous metals. Nonmetallies and solid fuels present an exceptionally varied array of production items among which cement had the second largest 1963 output in South America. Borates, bentonite, common clay, diatomite, fluorite, granite, lime, limestone, obsidian, onyx, rhodochrosite, salt, and spodumene ordinarily are produced for export either exclusively or in excess of domestic consumption requirements. Barite, cement, chalk, gypsum, marble, and mica are both exported and imported. Argentina depends entirely or partly on imports for coal and coke, certain special types of clay, mineral abrasives, graphite, magnesite, mineral fertilizers, sulfur, talc, and minerals for construction, the last group being chiefly attributable to convenience of river transport from Uruguay.

Jan 1, 1964

By N. A. Gokcen

Equilibrium partial pressures of gaseous HCl and H2O over aqueous binary and ternary solutions of HCl and AICls were calculated or estimated in the range of 20° to 110° C, and up to saturation with AlC13?6H2O. The results were extended to solutions containing less than 10 wt-pct FeCl3 by assuming that FeCl3 and AIC13 are equivalent on the molar basis, since both salts have trivalent cations with a cammon anion. The ionic activity coefficient of HCl and the equilibrium constant for dissolution of gaseous HCl were also computed. This research is part of the effort by the Bureau of Mines, U.S. Department of the Interior, to provide thermodynamic data to expand the technology base relevant to the extraction of alumina from nonbauxitic domestic raw materials.

Jan 1, 1980

By Thomas H. Dubaniewicz

The National Institute for Occupational Safety and Health, Pittsburgh Research Laboratory conducted a study of laser safety in potentially flammable environments. Researchers measured threshold igniting powers as a function of beam diameter for butane and propane-air mixtures by laser-heating targets placed on optical fiber tips using a 1064 nm laser. The minimum igniting powers for propane-air and butane-air were about 250 and 300 mW, respectively. Threshold igniting powers for propane-air were approximately proportional to beam diameter for beam diameters from 0.1 to 2.0 mm. Results suggest that relatively powerful beams may be used in these atmospheres without causing ignition, provided the beam diameter is controlled. Threshold ignition delay times using 91125 and 62.51 125 pm fibers were approximately proportional to the inverse square of the laser power. Ignition delays were about 45 ms or longer for laser powers up to 800 mW. Preproduction samples of a commercial optical fuse prevented ignitions under selected test conditions. A self-healing effect was observed for one sample. Comparisons are made with the results of other researchers. O 2006 Laser Institute of America. Key words: propane ignition, butane ignition, laser ignition, nonbeam hazards, fiber optic fuse

May 3, 2006

By W. D. Ryan

The American public has at all times been prone to discuss important questions that call for consideration and adjustment. Debatable subjects upon which sides may be taken always receive unusual prominence, but other questions equally important may be neglected. The real "paramount issue," calling for remedial action, is the ever-increasing number of deaths caused by preventable accidents. This matter demands the attention of the entire American people; the importance of accident prevention can not be overemphasized, and in many phases of American life, especially among the mining and allied industries, far too little real attention has been given the importance of conserving life and limb by accident prevention. ACCIDENTS COMPARED TO WAR AS A CAUSE OF DEATH Harry T. Hoffman, Wyoming labor commissioner, writes the following: It is one of the peculiar complexes of this rapidly moving age that we all stand aghast at the horrors of war and view with appar- ent indifference the greater havoc of industrial peace. Did you ever stop to think that approximately twice as many people were killed by accidents in the United States in 1929, as there were American soldiers killed in the entire period of the World War? Every employer and every worker should be thoroughly aroused over the tremendous toll levied against industrial forces by accidents which are largely preventable and develop a faith in safety efforts that will fire them with a zeal as pronounced as that of their religion or their patriotism. Let us remember safety-first to the end that the workman shall live to enjoy the fruits of his labor; that his mother shall have the comfort of his arm in her age; that his wife shall not be untimely a widow; that his children shall have a father; that crip- ples and helpless wrecks who were strong men shall no longer be a by-product of industry.

Apr 1, 1931

To improve the efficiency and speed of under-ground post-disaster rescue operations. The Approach: Develop a battery-powered mine-rescue vehicle designed to carry rescue crews, rescued miners, and their support equipment. How It Works: The experimental vehicle, shown below, was designed and constructed by the Mine Safety Appliances Company under contract to the Bureau of Mines. ATV Manufacturing Company and Delco Electronics were subcontractors. A rechargeable, silver-zinc battery provides power to a 3-horsepower permissible motor, the speed of which is regulated by a solid-state controller. Three wheels on each side are independently driven by a chain and mechanical trans-mission.

Jan 1, 1974

By Joan T. May

Anhydrous methods were tested for the extraction of beryllium from low-grade source materials. The purpose of the investigations was to find new extraction processes that are applicable to domestic ores. Beryl, helvite, and phenacite materials containing from 0.1 to 2.8 percent BeO were used as starting materials for direct halogenation tests and pretreatment followed by halogenation. The results of the investigations showed that direct fluorination and carbide-chlorination are two practicable methods that can be applied to low-grade concentrates. Treatment of concentrate-carbon mixtures with anhydrous hydrogen fluoride extracted 99 percent of the beryllium in the concentrate; the soluble fluoride product, converted to an oxide, contained 70 percent BeO. Chlorination of beryllium-silicon carbide, prepared from low-grade concentrates, extracted beryllium into the volatile chloride product.

Jan 1, 1962

By Warren E. Morrison

The continuing high-level performance of the domestic mineral and mineral fuels industries during 1966 was sustained by the longest business upturn in the Nation's history. Spurred by consumer demand at home and the defense production requirements of the Viet-Nam war, the rising trend of economic activity during the year was reflected in the upward movements of the major economic indicators. At yearend the gross national product (GNP), representing the value of all goods and services produced, stood at $740 billion, $58 billion greater than in 1965. Corrected for price changes, the real value of GNP in terms of 1958 dollars was $648 billion and represented an annual increase in economic activity of 5.4 percent. Some 74 million persons were employed during the year out of a total population of 196.8 million, while unemployment fell below 4 percent. The Federal Reserve Index of Industrial Production averaged 156 for 1966, up 13 points from the previous year. However a jarring note in the 1966 expansion, and one which affected the mineral industries in particular, was the increasing pressure on prices and the threat of inflation. From 1961-65 economic growth was facilitated by relatively stable wages and prices and only mild inflation. During the period average wholesale prices hardly moved while average consumer prices rose only about I percent per year. But this long run of relative price stability ended during 1966 when consumer prices rose 2.9 percent and wholesale prices were up 3.2 percent from the previous year.

Jan 1, 1967

By Sidney Katell

Continuing the series of cost bibliographies which was initiated with the publication of Information Circular 7516 in October 1949, the present report covers the period from January 1959 through December 1959. The abstracted articles, concerned with all facets of cost engineering in the field of petroleum and chemical plants and related facilities, were obtained from the following sources: 1. Bureau of Mines Information Circulars. 2. Bureau of Mines Report of Investigations. 3. Chemical Engineering. 4. Chemical Engineering Progress. 5. Chemical Week. 6. Coal Age. 7. Coal Utilization. 8. Cost Engineering. 9. Industrial and Engineering Chemistry. 10. Nucleonics. 11. Oil and Gas Journal. 12. Petroleum Engineering. 13. Petroleum Refiner. 14. World Oil. On Oct. 16, 1959 a cooperative agreement between the Bureau of Mines and the American Association of Cost Engineers became effective. This agreement provides for the publication of the annual bibliography under the sponsorship of both groups with the work load involved in the preparation divided equally between the two. As a result, the present report partially reflects the efforts of the members of the Association.

Jan 1, 1960

By J. E. Dooley

An analytical procedure developed by the Bureau of Mines was applied to the separation and characterization of a 370° to 535° C distillate from Swan Hills (south field), Alberta, Canada, crude oil. Investigators determined the general characteristics of the crude oil by the Bureau's routine method for crude oil analysis. Suitable fractions were prepared for instrumental analyses by utilizing such techniques as isothermal and molecular distillations, chemical treatment, silica-alumina gel chromatography, and gel permeation chromatography (GK). A detailed characterization of the 370° to 535° C distillate was possible by the application of GPC-mass spectrometry correlations and nuclear magnetic resonance spectrometry. Semiquantitative data based on mass Z series distributions were determined and are shown. The data will be valuable in developing future processing techniques and in calculating yields for converting high-boiling distillates into more useful energy forms.

Jan 1, 1973

By W. W. Weller

Heat-capacity measurements of sodium dimolybdate (Na2Mo207) and sodium ditungstate (Na2W207) were conducted over the temperature range from 51° to 298° K. The entropies of the two compounds at 298.15° K were calculated from the heat-capacity values and were used, in conjunction with other entropy data, to evaluate the entropies of formation of the compounds from their constituent elements and oxides.

Jan 1, 1963

By V. E. Erwin, W. W. Adams

"INTRODUCTION This report presents statistics of accidents at coke ovens in the United States during the calendar years as 1933, the twenty-first year for which data of this kind are available, 1913 being the first year for which accident reports were collected from the operating companies by the Bureau of Mines. The present report is presented in mimeograph form because insufficient funds are available for printing it. The first report of the Bureau of Mines that contained statistics of accidents for the coke-mining industry in the United States covered the two calendar years, 1913 and 1914. While the figures presented therein related both to beehive and by-product ovens, the original returns from the operating companies were not classified so as to permit the presentation of accident statistics for each class of ovens separately. Beginning with 1915, the accident reports from the operating companies have shown the general type of ovens to which the reports related; therefore, since that year, separate statistics for each of the two classes of ovens have been given in the Bureau's yearly reports of accidents at coke ovens.The coke-making industry in the United States established a safety record in 1933 almost equal in merit to that which it achieved in 1932, when the accident-frequency rate was the lowest and therefore the most favorable that the industry has known. Credit for the achievement is due almost entirely to companies operating byproduct ovens. (See table 8.)"

Mar 1, 1935

By J. G. Schoning

The Holmes Safety Association is an offspring of the Joseph A. Holmes Safety Association which was organized in Washington, D. C., in 1916 at a meeting of representatives of twenty-four leading mining associations connected with every branch of the United States mineral industries. The purpose of the meeting was to do honor to the memory of Joseph A. Holmes, one of the founders of the United States Bureau of Mines and its first director, whose death had occurred the year before on July 12, 1915. In deference to what was believed would have been the expressed wish of this great humanitarian and benefactor of the mineral industries, it was decided to establish a national safety organization to cover the mineral indus¬tries exclusively; out of respect for his memory and service, the organization was named the Joseph A. Holmes Safety Association. On receiving requests from several mining districts, in 1922 a number of chapters ware established in several mining States.

Jan 1, 1929

By S. A. Gustavson, H. E. Olund

This report has been prepared to review the history of the Premium Price Plan for copper, lead, and zinc, which was in operation from February 1, 1942, to June 30, 1947. It includes various charts and tables comparing costs and production data, and data on exploration premiums that were included in the Plan during the last year of its operation.

Jan 1, 1950

By Richard E. Dawes

Physical variables, a principal factor in the economies of mineral production, affect both capital and direct operating costs. By using a revenue-cost system for the framework, the analyses of revenue and cost categories demonstrate the relative importance of groups of physical variables, whether explicitly defined or not, to a lead-zinc mining operation. Physical variables affecting the producer represent about 60 percent of the total system influence as expressed by cost ranking. Other physical variables affect the remaining costs as controlled by the smelter, the transporter, and the landowner. Such resource conservation aspects as mineral losses due to mining method and mineral processing constitute a portion of the total revenue effects of physical variables. The physical variable revenue-cost system presented in this report offers a framework for cost-benefit analysis of mineral related research.

Jan 1, 1969

By C. W. Lee

"Introduction of diesel engines in underground mines may generate severe health hazards associated with exhaust contaminants. One of the most important parameter in determining the optimal air quantity for hazard reduction is the exhaust dispersion. Through analyzing the exact solution of the diffusion equation and its approximation by finite difference method(FDM) , this paper aims at doing a fundamental research to find an efficient dispersion model suitable to the domestic mines. Diffusion coefficients are likely to be small in the underground airways with high ventilation resistance. This makes concentration profiles similar to the convection-based step functions. It is the case for fixed as well as moving engines. Concentration estimation by exact solution is almost impossible in the case of either a single engine moving at a variable speed or the existence of multiple engines. Application of FDM to the diffusion equation including turbulent dispersion results in the various problems; unstable concentration profiles depending on the engine location, nuctuating concentrations near the engine, and overestimation of the dispersion region of which error grows with waning diffusion coefficient.Convection-based dispersion model is found to fit well for dynamic simulation of exhaust dispersion from multiple diesel engines in the airways showing low diffusion coefficients. Its suitability is more likely in the regions with frequent equipment passage. Published"

Nov 1, 1995

By C. J. Chindgren

The Bureau of Mines investigated the technical problems involved in recovering commercial-grade vanadium products from alkaline solutions of low vanadium content. Conditions were defined for precipitating calcium vanadates from sodium vanadate solutions with calcium chloride and calcium hydroxide and for dissolving the precipitates with acid, sodium carbonate, and sodium bicarbonate to obtain vanadium-enriched solutions from which either red cake or ammonium metavanadate was recovered. Calcium vanadates with CaO:V205 mole ratios of 2, 3, and 4 were produced with recoveries of 93 to 100 percent. Optimum recovery of the low-lime variety of calcium vanadate was obtained by employing excess calcium chloride and adjusting the pH to a range of 8.0 to 8.5. High vanadium extractions were obtained in concentrated solutions by dissolving the calcium vanadate precipitates with any of the reagents tested. The resulting extracts contained 25 to 125 grams V205 per liter. Conventional procedures used to precipitate either red cake or ammonium metavanadate from the enriched solutions gave excellent vanadium recoveries.

Jan 1, 1967

By W. W. Adams, V. E. Wrenn

"Production of explosives in the United States during the calendar year 1936, as represented by reports of sales by manufacturing companies, totaled 391,604,500 pounds, an increase of 27 percent over the amount produced during 1935. This quantity included 81,698,375 pounds of black blasting powder (granular and pellet), 262,047,106 pounds of high explosives other than permissibles, and 47,859,019 pounds of permissible 5/ explosives.The manufacturers' reports to the Bureau of Mines classify the sales of explosives according to five main classes of work in connection with which the explosives were used.Coal mines used 87 percent of the total amount of black blasting powder sold, bituminous-coal mines 79 percent, and anthracite mines 8 percent; coal mines also consumed 98 percent of all permissible explosives and 9 percent of the high explosives other than permissibles. The coal-mining industry consumed 16 percent more explosives in 1936 than in the preceding year, the increase at bituminous mines being 21 percent and that at anthracite mines 4 percent.Metal mines used 29 percent of the high explosives other than permissibles and less than 1 percent of the black blasting powder and permissible explosives. The total quantity of the three classes of explosives used in metal mining in 1936 was 36 percent more than the quantity so used in 1935."

Jul 1, 1937

By F. W. Lane

[The rapid expansion of the petroleum industry, the steadily growing use of oil fuel or steamships, the increasing transportation of oil in tankers and the extensive use of petroleum oils for many land industries, has resulted in pollution of our coastal eaters by these oils. On account of the great importance of this problem to the petroleum and shipping industries its, the Bureau of Mines, in cooperation with the American Petroleum Institute and -he American Steamship Owners Association has undertaken to ascertain the extend of petroleum oil pollution along the coasts of the United States and to indicated the principal so arcs of such pollution. Certain typical methods and devices in use and proposed for the separation of oil from water, and for the disposal of oily castes from ships and industrial plants have been studied. An attempt has also been made to point out the nature of the fire hazard resulting from oil pollution and to indicate the effect of such pollution on bathing beaches.]

Jan 1, 1924