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By G. V. Sullivan

This report describes an investigation by the Bureau of Mines of flotation techniques for the recovery of chromite from fine-grained disseminated ores. Reported work on the concentration of chromiferous materials shows that flotation has been applied almost exclusively to slime-free pulps. Therefore, chromium recoveries that could be obtained by flotation were related to the amount of slime rejected. However, results of recent studies by the Bureau of Mines showed that des liming is not a requisite to selective concentration of chromite. Laboratory-scale tests on seven ore types from the more important chromium-bearing areas of the Pacific Northwest showed flotation to be technically feasible for treatment of all but one of the samples. Concentrate grades were affected more by the composition of the chromite mineral than by the grade or character of the ore. Test results from three of the samples showed that, without prior desliming of the pulp, 78 to 91 percent of the chromium could be recovered in concentrates of 90 percent or more chromite; two samples responded to similar treatment, resulting in concentrates of more than 80 percent chromite with recoveries of 85 and 89 percent chromium. One sample of mill products, subjected to severe weathering, required removal of the primary slime to obtain a concentrate of 65 percent chromite with only 75 percent chromium recovery.

Jan 1, 1960

By E. A. Barrett, L. L. Rethi, B. Fotta

Employment and accident trends of independent contractors working at coal and noncoal mines in the United States are reported. Data include employee hours and accidents, both fatal and nonfatal, from 1985 through 1994. Also noted are increases or decreases in certain accident classifications and accident rates, particularly those which have shown significant change during the ten-year period.

By J. T. McCartney

Thin sections of coal have been prepared for many years either by cutting on a microtome (1,2)5 or by grinding and polishing (2,1). Specimens of most coals had to be demineralized in hydrofluoric acid and softened in caustic solutions before they could be successfully cut with a conventional microtome. Some lignites could be cut without pretreatment. Jeffrey (1) obtained sections from coals of all ranks, although long and tedious pretreatment was required for anthracite. His sections were less than 1 cm.2 in area (probably much less for high rank coals) and about 5 microns thick. Thiessen (2) also cut sections of softened coals, mostly of low rank. His sections were a few square millimeters in area and about 3 microns thick. However, Thiessen preferred ground and polished sections for detailed studies because they were larger and had not been chemically attacked by softening media. He prepared ground sections as large as 4 cm.2 in area and usually 5 to 10 microns thick. Thousands of such sections, covering complete column samples of many coal beds, were studied for a number of years (4). With the development of the electron microscope and increased interest in quantitative optical studies of coals, a need for much thinner sections arose. However, no suitable technique for preparing such sections was known until Fernández-Morán developed a diamond knife for cutting ultrathin sections of hard materials (5). Workers at the Centre d'Etudes et Recherches de Charbonnages de France applied this new tool to the cutting of coal sections and have recently described their technique to the Burg, of Mines. Using their methods, with some modifications, researchers of the Bureau of Mines have succeeded in cutting ultrathin sections of coals ranging in rank from lignite to

Jan 1, 1961

By J. M. Stuve

Provisional values for the heat of formation of europium trichloride and europium sesquioxide were determined by solution calorimetry utilizing europium metal of more than 99-percent purity. The resulting values for the heats of formation of Eu203 (cubic) and EuCls (hexagonal) were -386,970 ±l,200 cal/mole and -218,740 ±650 cal/mole, respectively, measured at 298.15° K.

Jan 1, 1965

By H. Foster Bain

Ten years ago there was no general , country-wide service for the systematic training of miners in matters relating to safety . A beginning only had been made at a few scattered points . Under the old conditions each man was left largely to look out for himself in meeting the hazards of his day's work, and the foreman , shift bosses , and superintendents chiefly relied upon improvision when major accidents occurred . So long as the mines were small and the workers highly intelligent and well trained in routine mining methods , and when too , the pressure for output had not yet speeded up industry to the extent it has since those days , there was something to be said for this lais- sez faire attitude . When , however , the rapid expansion of industry lead to the introduction of new and little trained labor and to units of production of greatly increased size , the natural dangers of mining were greatly intensified . An accident in a small mine affects only a few; the same accident in a large mine , unless proper precautions have been taken , may cost the lives of many . The public does not generally recognize that the greatly increased outputs of the mines , of coal mines in particular , have been in recent years , obtained from substantially the same number of miners as ten years ago but with a personnel not nearly so well trained in mining . It is inevitable under : such conditions that more care must be devoted to avoiding accidents and much more elaborate preparations made for meeting them . In the years immediately preceding the establishment of the Bureau of Mines this speeding up of industry , change in the character of mine labor , and increasing hazard had all begun to be felt . Immediately prior to the organization of the Bureau of Mines , public attention had been drawn to a series of disastrous coal-mine explosions , to the increasing frequency of these disasters , and to the terrible loss of human life . resulting therefrom. One of the first problems , therefore ; confronting the Bureau was clearly that of finding methods of reducing the number of such disasters and lessening the severity of those that continued to occur . Toward this object were immediately directed the energies not only of the Bureau of Mines but also those of State mine inspectors , mine operators and various other agencies , all of whom were urged to cooperate in this great humanitarian work. The results of this work naturally cannot be measured by figures only . Work for increasing the health , safety , comfort , and happiness of human beings may not be gaged with mathematical precision . But certain features of this work as revealed by the record from year to year are of much interest . ”

Apr 1, 1921

By D. H. Baker

This report, one of a series prepared by the Federal Bureau of Mines on the technology of titanium, describes the development of an electrorefining cell from which cathode deposits up to 30 inches long can be produced. Data show individual deposits to be homogeneous, comparable from top to bottom, and not varied in quantity or quality of metal over the entire length of the deposit. Investigations concerned with various diameter cathodes showed that cathode current efficiencies were materially reduced with cathodes less than 2 inches in diameter. Deposits produced on 1/2-inch-diameter cathodes showed cathode current efficiencies of 19 percent and on 1-inch cathodes, just over 22 percent, whereas deposits produced on 2- and 4-inch-diameter cathodes showed about 70-percent current efficiencies. A series of 20 deposits on 4-inch-diameter cathodes was produced under simulated production operation. The average current efficiency, based upon a divalent ion, was 72 percent with 11 1/2 pounds of metal produced per cycle of operation - 98.8 percent of which had a Brinell hardness number (B.h.n.) of 80 or less.

Jan 1, 1959

By Bill M. Stewart

The Bureau of Mines conducted laboratory tests to determine the effects on the physical properties of coarse coal waste of adding large amounts of fine coal waste. Maximum laboratory dry density, optimum moisture content, shear strength, and permeability tests were conducted on samples that contained 18 to 60 pct minus No.4 (U.S. Standard sieve size) coal waste. For the nonslaky materials, maximum laboratory densities were highest and permeabilities lowest when the samples contained between 30 and 40 pct minus No.4. Shear strength increased rapidly when the proportion of minus No. 4 was increased from 20 to 40 pct, but then increased only slightly or leveled off when the minus No. 4 was increased to 60 pct. Optimum moisture content and permeability were the physical properties most affected by the addition of fines. Optimum moisture content increased as much as 3 pct, and permeabilities decreased up to three orders of magnitude. Slaky coal waste material had physical property reactions to the addition of fines substantially different from those of nonslaky material.

Jan 1, 1981

By C. W. Dwiggins

The Bureau of Mines characterized the chemical and physical properties of metallo-organic materials in petroleum to determine their effect on petroleum production and refining. The structures and physical properties of porphyrins and materials that normally contain metalloporphyrins such as crude oils and asphaltenes were investigated using elemental analysis, NMR analysis, absorption spectrometry, and small-angle X-ray scattering. Petroleum fractions greatly enriched in metalloporphyrins were obtained using asphaltene precipitation, liquid extraction, and large-scale liquid-solid chromatography. Selected fractions containing porphyrins were further purified by chromatographic methods, crystallization, and demetalation followed by chromatography. Nonporphyrin metals could not be appreciably concentrated from the bulk of the asphaltene.

Jan 1, 1969

Objective: To improve the effectiveness of dust collector capture on surface mine drills.

Oct 1, 2005

By Curtis H. Elder

In studies conducted by the Bureau of Mines, two test areas were hydraulically stimulated and exposed by mining: One in the Pittsburgh coalbed at the Vesta No. 5 mine, Washington County, Pa.; and one in the Illinois No. 6 coalbed at the Inland mine, Jefferson County, Ill. Induced fractures were contained totally within the coalbed with no adverse effect on the stability of associated rock strata. Induced fractures were vertical and were propagated normal to the direction of least residual tectonic stress. Gas production was increased fivefold to twentyfold by hydraulic stimulation.

Jan 1, 1977

By D. R. Tesarik, M. K. Larson, J. P. Dunford, E. G. Zahl

Western coal mines are operating under increasingly challenging ground conditions. Researchers at the Spokane Research Laboratory of the National Institute for Occupational Safety and Health are cooperating with mines to evaluate how these conditions affect mine opening stability and related miner safety. A system was developed to monitor rock and coal stresses during mining of an entire longwall panel. The system was designed to generate data in near real time to evaluate rock behavior in roof strata and the onset of hazardous conditions as overburden stress was redistributed over working entries during gob formation. Computer simulations and in-mine evaluations were used to optimize instrument placement. A prototype packer assembly was designed and tested for installing sensitive instruments in a mine roof. This paper provides background information on the stress monitoring concept and focuses on the development of instrument placement techniques and the prototype packer assembly.

By Douglas Pollock, John Organiscak

Water spray characteristics, including droplet size and velocity, airborne dust capture potential, and induced airflow quantity for various spray nozzle designs were evaluated to provide basic information for improving spray applications. Water droplet size and velocity characteristics were initially measured by a Phase Doppler Particle Analyzer (PDPA) for hollow cone, full cone, flat fan, and air atomized spray nozzles at similar operating parameters. Airflow inducement and dust capture experiments were also conducted under the same operating parameters to examine any salient features of the spray nozzle type, droplet characteristics, induced airflow, and airborne dust capture. Test results indicate that there are trade offs between airflow inducement and dust capture efficiency. A spray nozzle with a wider discharge angle was observed to induce more airflow, but at reduced dust capture efficiencies. Increasing spray nozzle fluid pressure(s) generally reduced water droplet sizes with concurrent increases in droplet velocity, airflow inducement, and airborne dust capture. Placing a three-sided barrier around the spray nozzles normally reduced spray air induction and increased dust capture efficiency. A direct relationship between airborne dust capture efficiency and spray input power normalized per unit of airflow induced was ob- served. This information can be utilized to improve the performance of water sprays for reducing airborne dust levels.

By T. W. Goodman, J. Cervik

The Bureau of Mines conducted studies to compare the effectiveness of the cross-measure borehole system with that of surface gob holes on two successively mined retreating longwalls in the Lower Kittanning Coalbed. Only the cross-measure system was in operation on panel A; on panel B, both systems were in operation. In addition, the cross-measure bore-holes on panel B were drilled parallel to the face, whereas those on panel A were drilled at a 45O angle with respect to the longwall axis. The studies show that the cross-measure system captured 71 pct of the methane generated by longwall mining on panel A. On panel B, the sur- face gob hole dominated over the cross-measure system for about 700 ft (213 m) after it was intercepted. Beyond that point, the cross-measure system dominated. About 93 pct of the methane generated on panel B was captured by the two systems. Cross-measure boreholes that were drilled parallel to the face were as effective as boreholes oriented 45" with respect to the longwall axis. In addition, they are shorter and require less drilling time. Comparison between observed gas pressure differentials in boreholes and calculated values indicate that boreholes can be shortened further to 140 ft (43 m). Additional studies are needed to verify these calculations.

Jan 1, 1986

By H. C. Ko

As part of the Bureau of Mines effort to provide thermodynamic data for the advancement of mineral technology, the standard enthalpies of formation for ZnO?2ZnSO4 and COS04-6H20 were determined by HC1 acid solution calorimetry. The values are -550.31 ±0.28 and -641.33 ±0.15 kcal/mot, respectively.

Jan 1, 1982

Develop a new method for coal mint pillar stability evaluation and design based on pillar load measurements. Approach A novel approach to chain pillar stability evaluation and design for longwall coal mining panels has been developed by the Bureau of Mines. The evaluation approach uses an INTEGRITY FACTOR as the criterion for stability. Hydraulic borehole pressure cells developed by the Bureau are used to measure stresses in a pillar for stability evaluation. The results are used to improve the pillar design.

Jan 1, 1989

By D. R. Tesarik, R. W. McKibbin, J. B. Seymour

Displacement and stress changes in cemented backfill and ore pillars at the Buick Mine, near Boss, MO, were monitored by engineers from the U.S. Bureau of Mines and The Doe Run Co., St Louis, MO. A test area in this room-and-pillar mine was backfilled to provide support when remnant ore pillars were mined. Objectives of this research were to evaluate the effect of backfill on mine stability, observe backfill conditions during pillar removal, and calibrate a numeric model to be used to design other areas of the mine. Relative vertical displacements in the backfill were measured with embedment strain gauges and vertical extensometers. Other types of instruments used were earth pressure cells (to identify loading trends in the backfill), borehole extensometers (to measure relative displacement changes in the mine roof and support pillars),and biaxial stress meters (to measure stress changes in several support pillars and abutments). Two- and three-dimensional numeric codes were used to model the study area. With information from these codes and the installed instruments, two failed pillars were identified and rock mass properties were estimated.

Jan 1, 1995

By Oleg Terichow

Electrophoretic mobility measurements were made on samples of Florida phosphate slimes to determine the optimum conditions of coagulation and precipitation in aluminum sulfate solutions. The addition of silica sand and other selected materials as mutual coagulants has demonstrated the practicability of coagulating two dissimilar particle systems by elimination of the repulsive double layers. By proper selection of the solution and its concentration, the reduction of the double layer to a zero point of charge causes coagulation and rapid precipitation of both particle systems. Confirmation was found in filtration tests and sedimentation tests.

Jan 1, 1973

By J. P. Morris

This paper describes a gas-transport method for measuring vapor pressures of liquid metals. Vapor pressures of iron and nickel were determined at temperatures between 1,540° and 1,620° C. The results can be represented by the following equations: log Pmm (iron) -19,460/T + 9.147, log Pmm (nickel) -2l,030/T + 9.689. The study was undertaken as part of a program to determine thermodynamic activities in liquid iron alloys.

Jan 1, 1957

By J. C. Edwards

Fire experiments were conducted in the Safety Research Coal Mine (SRCM) at the National Institute for Occupational Safety and Health, Pittsburgh Research Laboratory, with coal, diesel-fuel, electrical-cable, conveyor-belt, and metal-cutting fire sources to determine the response of fire sensors to products-of-combustion (POC). Metal oxide semiconductor (MOS) and smoke fire sensors demonstrated an earlier fire detection capability than a CO sensor. This capability was of particular significance for a conveyor-belt fire in which the optical visibility was reduced to 1.52 m with an increase in CO of less than 2 ppm at a distance of 148 m from the fire. Application of a neural-network program to the sensor responses from each type of fire source resulted in correct classifications of coal, diesel-fuel, cable, belt, and metal-cutting combustion with a mean of 96% of the test data correctly classified.

Jan 1, 2000

By G. L. Barlett, J .. D. Barry

Supernatant media of dust-exposed pulmonary alveolar macrophages (PAMs) were inactive in assays for both Interleukin-1 and fibroblast growth factors (FGF). We have begun to evaluate several factors that may interfere with dust-PAM interactions. To determine the effect of sterilization on the activity of dusts, PAMs were exposed to autoclaved dust, heat-sterilized dust or to dust that had not been heated. Supernatants from the first two groups were inactive in the FGF assay, but supernatant from PAMs exposed to unheated dusts stimulated growth of lung fibroblasts. Recent data have revealed that freshly crushed mineral dusts possess labile free radicals that are absent in dust that has been stored for more than a few days. Suspensions .were prepared of a "stale" sample of anthracite dust 867 and of a freshly ground sample of the same dust. These suspensions were instilled intratracheally into guinea pigs under general anesthesia. Two, five or eight days later, PAMs were collected from the lungs by bronchoalveolar lavage, and the cells were counted. At two and five days after instillation, all lavage suspensions contained 70 to 85% PAMs, of which 5 to 18% contained phagocytized dust particles. On day eight there were again 80-84% PAMs in all suspensions, but in the presence of "fresh'" dust, 48% of PAMs. had phagocytized particles in comparison to 16% in the presence of '"stale'" dust. A similar experiment was performed in short-term cell culture. During 24 hours, >95%. of PAMs phagocytized dust particles, whether or not the dust was "stale" or '"fresh". Our studies are being extended to determine the effect of (1) removing surface oil contaminants by organic extraction and (2) suspending dusts without surfactant.

Jan 1, 1988