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By Roy H. Grau, John C. LaScola

This Bureau of Mines report contains a tabulation of methane emissions during 1980 for all coal mines located in the United States with emissions greater than 0.1 MMcfd. Listed for each mine are methane emission quantity, location, and coalbed. The report also compares records of 1975 and 1980 and describes relationships between emissions in 1980 and the Bureau's coalbed gas content data on 11 mines.

Jan 1, 1984

By K. O. Bennington

Enthalpies of formation of three sodium titanates were determined by hydrofluoric acid solution calorimetry, The values obtained for formation from the elements at 298.15° K are -370.9±0.5 kcal/mole for Na2TiO3, -832.1±0.9 kcal/mole for Na2Ti307, and -1,510.9±1.7 kcal/mole for Na2Ti6013. Tables of enthalpies of formation and Gibbs energies of formation are given as a function of temperature both from the elements and from the component oxides for Na2Ti03 and Na2Ti307.

Jan 1, 1973

By Michael J. Brnich

Since 1991, Pittsburgh Research Center (PRC- formerly part of the Bureau of Mines) researchers have recorded extensive interviews with 30 individuals who are experts in the area of mine emergency response. These individuals, who have an average of 35 years of mining experience and 29 years of mine emergency response experience, related stories and observations from events that they experienced during their combined 850 plus years in mine emergency response. The purpose of this effort was to gather information that could be passed onto both today?s and tomorrow?s mine emergency responders to train and guide them in handling future events.

Jan 1, 1997

By John C. Edwards

The Bureau of Mines developed a mathematical model to calculate the aerodynamically induced lifting of coal and rock dust from a composite deposition on a mine entry floor and the subsequent transport of the dust ahead of the propagating combustion zone of a coal dust explosion. For a series of experimental explosibility tests approximated by combustion zones that expand at a constant flame velocity, the mass fraction of airborne rock dust ahead of the flame front, as well as the mass fraction overtaken by the combustion zone, was calculated. A statistical analysis of the theoretical results demonstrated with a high level of confidence that the propagating and nonpropagating test samples belonged to sepa-rate populations. This analysis was further supported by an independent model of the average temperature over the combustion zone.

Jan 1, 1988

By J. M. Stuve

Calorimetric determinations of the low-temperature heat capacities, standard enthalpy of formation, and high-temperature enthalpies were made of (Na20)4 ?Fe20,(c). The resulting values of entropy (S°), enthalpy of formation (?Hf°), and free energy of formation (?Gf°) at 298.15° K are 104.676 cal/deg mole, -656.2 ±.kcal/mole, and -603.4 A kcal/mole, respectively. Tabulations of Cp°, S°, - (G°-H°298)/T, H°-H°298, ?Hf°, ?Gf°, and log Kf are given to 1,200° K.

Jan 1, 1971

By J. A. Organiscak

Two types of airflow splitting methods for improving longwall dust control were investigated by NIOSH's Pittsburgh Research Laboratory. These methods included a translucent mesh barrier and a staged spray barrier system to confine the shearer-generated dust to the coal extraction side of the longwall face while maintaining a cleaner split of airflow on the opposing worker walkway side of the longwall face. The translucent mesh barrier was shown to provide notable dust control effectiveness up to 60 m downstream of the shearer in both the laboratory experiments and a longwall field evaluation, provided the mesh barrier remains relatively parallel to the airflow. The staged spray barrier system showed marginal dust control effectiveness in the laboratory and subsequently was not field tested.

Although early Spanish settlers used coal several centuries ago, significant commercial coal mining in New Mexico began in 1861, when the U.S. Army opened a mine to supply Fort Craig. Since then, coal from the state has been used to fuel railroads, lead and copper smelters, and other local industry. In recent years, lower-cost strip mining methods and an increased demand for coal by electric utilities in the Southwest have caused an increase in New Mexico coal production. The coal-bearing regions of New Mexico underlie about 25,000 square miles or20.6 percent of the total area of the state. However, the majority of coal-bearing regions lie under Indian lands that are regulated by the Office of Surface Mining (see Navajo and Hopi data on pages 72-75). Today, most of the coal produced in New Mexico comes from the San Juan Basin in the northwest part of the state and the Raton Area in the north central part. New Mexico's reserves are estimated to be 4.6 billion tons, about one percent of the national reserve. New Mexico's permanent regulatory program was conditionally approved December 3 1, 1980. Its Abandoned Mine Lands Program was approved July 17,198 1.

Jan 1, 1992

Eliminate the occurrence of false fire detection alarms caused by the operation of diesel-powered vehicles in underground coal mines. Approach Fire detection systems used in underground mines are based on measurements of airborne combustion products such as carbon monoxide or smoke particles. The effectiveness and credibility of these systems can be reduced by the occurrence of false alarms that result from the operation of diesel-powered equipment, which produces the same combustion products. False alarms end up being very costly to the mine operation in terms of downtime and labor needed for verification. To improve upon current fire detection systems used in the presence of internal combustion engine products, the U.S. Bureau of Mines developed a fire detector that can discriminate between the occurrence of real mine fires and the presence of engine smoke.

Jan 1, 1989

By R. Blickensderfer

Test equipment that simulated frictional impacts between coal-cutter bits and mineral inclusions at a coal face during operation of a continuous coal mining machine was used by the Bureau of Mines in the laboratory to study the incendivity of impacts between various rocks, metals, and hard-metal alloys in an explosive mixture of air-7 pct natural gas. Quartzitic sandstone was found to be the most incendive of several rocks tested. Limestone concretions from a coal seam, known locally as "sulfur balls," sparked furiously but were not incendive. Among the metals tested, the type of steel used in commercial coal-cutter tools was the most incendive material tested. A l7-4PH stainless steel was less incendive and appears to be the most promising high-strength steel alloy, reasonably economical, for use in coal-cutter bits. Some hard-metal alloys, primarily titanium and zirconium diboride composites, were also evaluated as possible replacements for the conventional cobalt-bonded tungsten carbide used in the tip of coal-cutter bits. The metal-bonded diborides were generally less inc endive but more brittle than the conventional tungsten carbide. Carbonitride coatings on tool bits were also tested but found to have no advantage. The source of ignition during frictional impact between metal and rock was studied. Immediately after impact, a yellow flash was observed and a smear of metal near its melting point occurred on the rock. This hotspot on the rock, rather than the yellow flash or sparks or metal fragments, was observed to be the cause of the ignition.

Jan 1, 1974

Provide the National Park Service (NPS) with guidelines for closing abandoned mine openings such as shafts and adits. Approach The NPS needed alternative methods of closing a variety of abandoned mine openings on National Park lands. Because the U.S. Bureau of Mines (USBM) has a long history of mining-related experience, the NPS requested that the Bureau provide them with technical mine closure information. USBM engineers compiled information on various types of mine closures and prepared technical illustrations of those closure techniques. Multiple closure options, by type of opening, were prepared as one-page field guides to assist NPS field personnel in determining the most appropriate closure method for a given situation and detailing the construction of the closure method. Results Guidelines provided to the NPS included a description of the method, use applications, construction techniques, technical illustrations, and technical support information. The following provides a brief description of 11 mine closure techniques identified for use by NPS personnel. Most of the closure methods, except the backfill methods, allow for construction that can provide access to the mine. However, providing access makes the closure susceptible to vandalism. Most closure methods require periodic monitoring for subsidence and corrosion or deterioration of construction materials.

Jan 1, 1994

Detemine the elastic properties and structural integrity of a rock mass in situ. Approach An acoustic device that transmits and receives high-frequency seismic waves between boreholes was designed, built, and field tested. How It Works The acoustic cross-borehole apparatus operates by sending a seismic wave from a transmitter in one borehole to a receiver in a second bore? hole which may be located as far as fifty feet away, depending on the wave transmission quality of the rock. By measuring the wave's travel time and the distance between boreholes, the acoustic velocity of the rock mass can be determined. Characteristics of the seismic wave arriving at the receiver (such as the wave velocity, amplitude, and frequency content) are related to the physical properties of the geologic media, as calcu-

Jan 1, 1982

By Michael S. Wieland

The work-principle from thermodynamics was used to formulate a model for predicting toxic fumes from mining explosives in underground chamber tests, where rapid turbulent combustion within the surrounding air noticeably changes the resulting concentrations. Two model constants were required to help characterize the reaction zone undergoing rapid chemical transformations in conjunction with heat transfer and work output: a stoichiometry mixing fraction and a reaction-quenching temperature. Rudimentary theory with an unsteady uniform concentration gradient was taken to characterize the combustion zone, yielding 75% for the mixing fraction. Four quenching temperature trends were resolved and compared to test results of ammonium nitrate compositions with different fuel-oil percentages (ANFO). The quenching temperature 2345 K was the optimum choice for fitting the two major components of fume toxicity: carbon monoxide (CO) and total nitrogen oxides (NOx). The resulting two-constant model was used to generate comparisons for test results of ANFO compositions with additives. Though respectable fits were usually found, charge formulations which reacted weakly could not be resolved numerically. The work-principle model yields toxic concentrations for a range of charge formulations, making it a useful tool for investigating the potential hazard of released fumes and reducing the risk of unwanted incidents. Keywords: Toxicity; Fumes; Explosives

By B. E. Davis

As part of its program to increase the domestic availability of critical minerals, the Bureau of Mines conducted characterization and beneficiation studies on a St. Johns County, Fla., phosphate ore that was mined by borehole mining. Results revealed that the ore from this test mine was mostly sand-size carbonate-fluorapatite and quartz and contained 24.6 percent P205. Concentration by various flotation techniques produced phosphate concentrates that ranged, in percent, from 30.0 to 31.4 P205, 0.73 to 0.80 MgO, and 2.8 to 7.2 acid insoluble. Recovery of the phosphate from the ore ranged from 89.4 to 96.3 percent.

Jan 1, 1982

By Edward D. Thimons, Jay F. Colinet

NIOSH conducted a strategic planning effort to identify those areas in mining with the greatest research needs. Data analysis and stakeholder input identified the need to reduce worker exposure to respirable crystalline silica dust as a high priority area. MSHA dust sampling data were analyzed to target the mining commodities and occupations with the greatest percentage of samples containing silica above compliance levels. In response, the Pittsburgh Research Laboratory (PRL) has implemented a multi-faceted research program to improve silica dust control for these problematic commodities and occupations. A review of silica compliance trends, PRL silica research programs, and recent control technology developments are provided here.

By J. M. Singer

Approximate equations were used to compute the radiant heating of float coal dust by approaching flames for various combinations of particle size, dust path length (flame travel distance), flame temperature, dust concentration, flame speed, and flame length. The computed values of degree of radiant heating and flame travel distance for preheating the coal dust should be useful for estimating the increased fire hazard of different coal dust-flame parameters. Some findings relating to coal mine disaster control are-- 1. Coal dust clouds cannot be preheated to ignition temperatures by flame radiation alone when deflagration speeds are greater than about 10 m/sec. Thus it appears unlikely that radiation alone will cause flames propagating in dust clouds to accelerate to detonation velocities. 2. Small particles in the radiation flame zone caused by burnout and soot formation increase the degree of preheat significantly. 3. The concentration of float coal dust (radii = 3 to 40 microns) for maximum radiant heating usually peaks in the range 50 to 200 mg/liter of air.

Jan 1, 1970

By W. L. Hunter

Eleven steelmaking heats are described in this Bureau of Mines report in which acid practice was used to produce carbon steel from pre reduced iron ore pellets. Furnace slags obtained with no flux addition to the charge became quite viscous as they cooled, which precluded pressure casting from a ladle. Lime was added to the furnace charge at two levels to eight of the heats to modify slag characteristics in the furnace, and to the ladle in two heats to further modify the ladle slag cover. Selected ingots from nine heats were successfully rolled on a commercial mill to produce No. 10 reinforcing bar.

Jan 1, 1974

By C. M. Frost

Crude shale oil prepared by gas-combustion retorting of Colorado oil shale was hydrogenated over a cobalt molybdate catalyst at an operating pressure of 1,000 psig, temperatures of 781° and 761° F, and liquid hourly space velocities of 0.10 and 0.05 Vo/Vo/hr, respectively. The yields of total liquid products and the amounts of nitrogen and sulfur removed were comparable with those obtained at an operating pressure of 3,000 psig and a liquid hourly space velocity of 1.0 Vo/Vo/hr. Approximately 1.5 times as much gasoline was produced at the lower pressure and space velocities.

Jan 1, 1973

By G. S. Morrow, C. D. Litton

This report presents the results of a U.S. Bureau of Mines evaluation of smoke detectors placed in conveyor belt entries of underground coal mines. The selected mines are located in six different Mine Safety and Health Administration (MSHA) districts, are operated by seven different companies, and use atmospheric monitoring systems from seven different manufacturers. Principal concerns are early detection and warning of fires, reliability of operation, frequency of maintenance, and adaptability of detectors to monitoring systems and the mining environment. The data contained in this report provide for some comparisons between smoke detectors and CO sensors, specifically in the areas of early detection of fires and susceptibility to nuisance alarms due to diesel exhaust contaminants. Finally, recommendations for performance standards, sensitivity tests, detector classification, and maintenance are presented.

Jan 1, 1992

In the past, mine management has been concerned with removing water from active mining sections primarily because it hampered the movement of mining equipment and aggravated the working condition of the miners. Pumping water to sumps and gravity drainage by ditching have proven successful in mines for minimizing section down time due to water influx. However, with the advent of more strict pollution laws the mining engineer must now be concerned with keeping water out of the section and also with preventing it from causing pollution. A review of the handbooks and textbooks used in the mining engineering curricula reveals that little has been written concerning acid mine water prevention or control in underground coal mines. Additionally, the review of the curricula of mining schools indicates they are not teaching the engineering students the necessary techniques of mine water management as they relate to the abatement of mine water pollution.

Jan 1, 1970

By R. W. Nash

This report describes the design and operation of a digital instrumentation package for the Bureau of Mines improved torsion pendulum, a scientific instrument that measures the vibration damping of metallic materials. The new design eliminates manual analog-to-digital conversion, reduces the data acquisition time, and increases the precision of the measurements. The digital output can be coupled directly to a micro-processor or computer to produce the final data in real time.

Jan 1, 1983