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By T. Ko, K. N. Han, C. S. Park, N. S. Kim, C. Yoon, H. Yoon

Quantitative analysis of Platinum Group Metals from ore samples and industrial materials using Inductively Coupled Plasma-Mass Spectrometer (ICP-MS), Inductively Coupled Plasma-Atomic Emission Spectrometer (ICP-AES), Atomic Absorption Spectrometer(AAS), and X-ray Fluorescence (XRF) techniques was conducted and the performance of various techniques was compared. The effects of different matrices in the sample materials were compared and discussed for each analytical technique. The ICP-AES technique exhibited better accuracy than AAS but showed limitations in its application due to strong spectral interference in the presence of common matrix elements such as iron. The ICP-MS showed the lowest detection limit and less spectral interferences than the previous two techniques. The XRF technique was also applied to examine the total amount of PGM from industrial materials. Results from each analytical method on various sources were presented and discussed.

Jan 1, 2003

By Erik A. Munroe, Nelia W. Dunbar, Virginia T. McLemore

In New Mexico, there are at least 100,000 abandoned mine waste rock piles with widely ranging geochemical and mineralogical compositions. A geochemical and mineralogical study was implemented for five waste rock piles, some which contained sulfides, in the Hillsborn Mining District. Chemical and physical characteristics of mineral grains and their secondary mineral oxidation rinds were examined with the electron microprobe. Pyrite and chalcopyrite appear to be the most reactive to oxidizing conditions. Clays, iron oxide, iron hydroxide, iron sulfate, and primary texture rinds exist in the waste rock piles analyzed.

Jan 1, 2000

By J. T. Crawford

A comprehensive strategic-planning model was developed for the phosphate strip-mining and chemical operations at White Springs, FL. The computerized model covers orebody modeling, production simulation and financial analysis. The model has several innovative features, including the use of NPV techniques in orebody block economics, the adaptation of the floating-cone method to a floating template for generating dragline mining units automatically, the use of interactive graphics for designing mining units, and the use of a dragline move economics algorithm for the automatic scheduling of mining-unit assignments and moves. The simulation of chemical-plant production uses linear programming and concentrate inventory levels to control mine-operating schedules.

Jan 1, 1999

By Marcel Michaud

Over the past five years, the two-fold growth in Canada's coal industry "Figure, 1" results primarily from the coking coal market to Japan and, to a lesser degree, by the increasing use of sub-bituminous and lignite coal for power generation in the Prairie Provinces. This expansion will continue, but production of coal for domestic thermal generation of electricity will grow at a faster rate than coking coal exports "Figure, 2". Half of the 20 million tons of thermal coal used for electrical power generation in Canada during 1974 were imported by Ontario Hydro from U.S. coal companies in West Virginia and Pennsylvania. Ontario Hydro's Nanticoke station on Lake Erie which will consume 7.5 million tons of coal in 1977 when fully operative, as well as other future planned projects, could cause Ontario Hydro's coal consumption to rise from 10 million tons today to 20 to 25 million tons by 1985

Jan 1, 1975

By G. D. Criswell, F. Palkovits, J. M. Johnson

A paste technology investigation was completed for non-pozzolanic fly ash from Units 3 & 4 of PPL Montana’s Colstrip Steam Electric Station. The purpose was to assess the feasibility of converting from dilute slurry deposition of ash products to a system using thickened or paste ash to reduce excess water storage in the impoundment, reduce seepage losses, and increase storage efficiency. The investigation included laboratory and field testing to characterize the rheological, geotechnical and dewatering properties of the ash products, an assessment of potential seepage reductions and an evaluation of potential for increased ash storage capacity by modifying impoundment operating procedures. The studies concluded that the conversion project was feasible, cost effective, and permittable. Critical facilities for the conversion project are currently under construction.

Jan 1, 2004

By F. M. Doyle, S. M. El-Raghy, M. F. El-Demerdash, E. Peters

The Activity Distribution Diagrams (ADD) developed by the authors are computed for Cu-S-H2O and Mo-S-H2O systems. The distributions of metal and sulfur between all species are estimated against pH at different potential levels. Both M-H2O and S-H2O distributions are compared to the M-S-H2O distributions to estimate the changes occurring due to the presence of sulfur. The method of computation follows the Activity Term Criterion, taking into consideration the multi-equilibrium interrelations and conservation of mass. Results are analyzed in terms of dividing a distribution curve into three basic segments. These segments are formation, stability, and dissolution.

Jan 1, 1993

By P. L. Webster, S. D. Thompson

The Coal Mine Belt Capacity Simulator (CMBCS) was originally developed to provide an improved belt capacity simulation through more detailed, flexible and realistic modeling of belt loading. While this model offered improved capacity design for conveyor belts and surge bins, it lacked the capability to simulate some key protection and segregation applications for bunkers. Recently, CMBCS was extended so that these latter bunker applications could be considered. In addition, a fear minor extensions were made to improve the model's flexibility and of efficiency. These various extensions and the steps taken to verify and validate them are described. The associated modifications in the model's input and output as well as the model's current requirements and availability are also discussed.

Jan 1, 1992

By S. Lin, Y. J. Wang

Through an example three fan ventilation network concepts of subsystem solution and characteristic curves of a multiple fan ventilation system are introduced. The major steps of defining a subsystem, working out the subsystem equations, constructing a solution curve and a characteristic curve, and determining the operating points of the reference fan and the ventilation system are systematically demonstrated through three and two-dimensional curves. Also briefly discussed are the main features of a subsystem characteristic curve.

Jan 1, 1993

By C. D. Ashley, X. P. Garzon-Villalba, R. M. Lopez, T. E. Bernard

Federal standards for refuge alternatives (RAs) mandate that they not exceed a Steadman apparent temperature (AT) of 95 °F (35 °C) at an assumed metabolic rate of 325 W, a limit that appears to be arbitrary. Occupants in an RA spend most of their time at rest (a metabolic rate less than 325 W), and thermal equilibrium can likely be maintained at an AT > 35 °C. The purpose of this study was to examine the upper limit of sustainable heat stress during 4- and 8-h exposures at rest. Five men underwent five 4-h trials (phase 1: AT range 39 to 49 °C, 90% rh) and five 8-h trials (phase 2: AT range 46 to 56 °C, 90% rh) in a semi-recumbent position. Descriptive statistics for gastrointestinal temperature (Tgi), heart rate (HR), systolic and diastolic blood pressure (SBP and DBP), sweat rate, fluid intake, urine color, urine specific gravity (USG), and changes in body mass are reported. Mean Tgi for all trials ranged from 36.9 to 37.3 °C, and mean HR for all trials ranged from 61 to 75 bpm. To determine the effects of increased heat exposure, differences in heat strain between 4- and 8-h trials were examined via repeated measures analysis of variance (ANOVA). As AT increased, there were no significant changes in ΔTgi and ΔHR from 1 to 4 h in the 4-h and 8-h trials. During the 8-h trials, as AT increased, there was a difference in ΔTgi between 4 and 8 h. In conclusion, there was support for sustainable exposures resulting in no significant increase in physiological strain at an AT greater than 35 °C AT, with a sustainable limit (no increases in Tgi due to increases in AT) below 46 °C AT. Although the participants were not representative of coal miners, the results provide support for sustainable exposures greater than 35 °C AT at an average metabolic rate of 155 W.

By G. E. Jones, G. K. Hoffman

Two Sun Juan Basin studies were completed through the USGS National Coal Availability program. The study areas are in the northwest Bisti field (Fruitland Formation) and in the eastern Standing Rock field (Menefee Formation). In the Bisti and Standing Rock areas, the original coal resource5 are estimated at 4.66 and 3.1 7 Gt (5.14 and 3.49 billion st), respectively. The Bisti coal resources are greatly reduced by the Bisti-De-Nu- Zin wilderness area, which contains an estimated 1.13 Gt (1.25 billion st) of coal. Technological restrictions remove 32.5% from Standing Rock's original resource. Available resources are 60%. 2.79 Gt (3.07 billion st), of the Bisti original resource and 65%, 2.07 Gt (2.28 billion st), of the original Standing Rock resource.

Jan 1, 2002

By Tim Wolf

The author has seen an increased use of shaft-mounted, right angle drive assemblies. These designs use the pulley shaft as its 'foundation" and can create significant overhung loads. To reliably perform, the pulley and shaft must be designed for these special requirements. This paper will focus on the development of overhung loads and their design effects. Special considerations to maximize performance will be presented and comparisons with other drive options will be made. Experience in heavy mining applications will be used throughout.

Jan 1, 2000

By Lijun Xu, Jan M. Mutmansky

The purpose of this research was to investigate airborne coal mine dust characteristics in order to assess the possibility of contribution of these characteristics to the incidence of coal workers' pneumoconiosis (CWP). The characteristics studied included physical (mass concentration and size distribution), chemical (elemental composition), and mineralogical (quartz and kaolinite content) variables of the dust. The results are based primarily upon analysis of the characteristics of 99 impactor samples from 18 mines in seven states. Because the eight stages of the impactor span the range of dust sizes up to 20 microns, the characteristics analyzed should represent respirable dust characteristics well and also provide size-dependent representations of the characteristics. In general, the patterns of mass concentration and size distribution in the various mines studied were similar with mass concentrations being high downwind of the continuous miner. The concentrations and size distributions were more variable upwind of the continuous miner, apparently as a result of the variations in the dust conditions in the working section. Significant size effects on the elemental and mineralogical content are shown in the data. Concentrations of most of the elements decrease as size decreases. However, minerals content increases as the dust size decreases. Regional variations of elemental and mineralogical content are also significant. Quartz and kaolinite contents are small in regions with low incidences of CWP. However, the elements of Cu and Zn are high by comparison to their content in high-incidence coal fields and may have the effect of protecting against the disease.

Jan 1, 1991

By L. Xiao, P. Somasundaran

Using potassium oleate as a collector and alizarin red S as a modifying agent, selective depression of dolomite from francolite was achieved in an alkaline medium (pH > 9.0). Adsorption of alizarin reds alone on dolomite was found to be higher than that on francolite. Complimentary adsorption experiments of alizarin red S and oleate showed that oleate adsorprion was increased in the presence of alizaring red S. The results are explained in terms of comparative adsorption for the active sites on francolite and dolomite by oleate and alizarin red S and their interactions with dissolved mineral species in solution.

Jan 1, 1990

By G. G. O. O. Uwadiale, M. A. Kollere, M. A. U. Nwoke

Birnin Gwari and Alawa graphite deposits were upgraded by flotation. Using 0.5 kg/t kerosene and 0.25 kg/t sodium silicate, flotation concentrates grading 90.7% and 88% Cg with recoveries of 86.2% and 84% were produced from Birnin Gwari and Alawa graphite samples, respectively. The combination of 0.5 kg/t kerosene, 0.2 kg/t pine oil and 0.25 kg/t sodium silicate yielded high-grade graphite (92.3% Cg) with a recovery of 83.9%. Flotation with refined rubber nut oil and kerosene, at a 1:1 ratio, produced a concentrate grade of 86.3% Cg with a recovery of 90.4%. With acid leaching of the flotation concentrate, a high-grade graphite concentrate containing 98% Cg was produced.

Jan 1, 1998

By M. W. Rutland, E. Manev, R. J. Pugh

Data collected from several different fundamental surface chemical techniques were compared to study the interfacial interactions in the dodecylaminelmica flotation system. In the present study, the method used was the microinterferometric free foam film technique of Scheludko (1967) in which the stability, thickness and interfacial potentials at the air/dodecylamine solution interface were determined. These results were compared to previously published data, obtained from surface force measurements (Rutland et al. 1992), in which the interaction and hydrophobic adhesion (pull-off force) between molecularly smooth mica sheets in the amine solution had been reported. Also equilibrium contact angle measurements were used for comparison. The data was collected over a range of pH values and related to the batch flotation response of mica in dodecylamine solution. It was found that maximum flotation occurred at pH 8, but this did not correlate with the minimum in double layer interaction potential. However, it appeared to correspond with a tightly packed collector monolayer giving maximum hydrophobicity to the mica surface. Finally, from the extended DLVO theory, it was shown that heterocoagulation between the bubble and the mica could only occur, providing there was a very long range hydrophobic interaction force to counterbalance the repulsive van der Waals and electrostatic forces.

Jan 1, 1995

By E. Topuz, M. J. McPherson, I. M. Konduri

This paper describes experiments conducted to evaluate the effectiveness of jet fans for ventilating blind headings in under- ground mines. A laboratory model of a mine heading was built by using dynamic similarity criteria, and water as the fluid medium. In order to verify laboratory test results, field experiments were designed and carried out in a full scale mine model and in a coal mine in West Virginia. Using CO, as the tracer gas and in combination with a computerized gas monitoring system, tests were conducted to evaluate jet fan performance. The results highlight the flexibility and versatility of jet fans for ventilating blind headings. Numerical modeling of a jet fan in a typical coal mine heading was carried out to evaluate the potential of computational fluid dynamics.

Jan 1, 1997

By F. M. Doyle, Jun Li, Milton E. Wadsworth, E. Peters

The Raman spectroscopic technique was used to study electrochernically oxidized pyrite in-situ. It was found that Raman-active sulfur oxidation products could be detected after a proper potential was applied to the pyrite electrode for a threshold period of time. There existed a minimum potential below which sulfur could not be observed. However, when the applied potential exceeded a certain limit, the intensity of the sulfur spectra decreased. The minimum potential at which sulfur could be observed changed with solution pH. For both acid (pH 2.7) and weak alkaline (pH 9.2) solutions, the minimum potential was 0.8 V/SCE, whereas for neutral (pH 6.5) solutions the value was 0.4 V/SCE. In strong alkaline solutions (pH 12.5) surface sulfur oxidation products could not be detected at any potential.

Jan 1, 1993

By Robert A. Jankowski, John J. McClelland, Charles Babbitt

The purpose of this study was to develop guidelines to enable mine operators to maximize longwall dust reductions, while optimizing the use of ventilating air and shearer water consumption. A recent investigation by Foster-Miller Incorporated, under a Bureau of Mines contract, quantified the effect of increased face airflow and shearer water supply on face dust concentrations. A 70 pct reduction in respirable dust levels was achieved at the shearer operator's position during tail-to-head cutting by an incremental increase in average face air velocity from 83.8 m/min (275 fpm) to 123.4 m/min (405 fpm), while holding shearer water consumption constant. A 60 pct reduction was achieved through an increase in shearer water pressure and flow from 9.1 kg/cm2 (130 psi) at 0.19 m3/min (50 gpm) to 19.7 kg/cm2 (280 psi) at 0.28 m3/min (75 gpm), holding airflow constant. The combined effects of increasing both parameters produced an 85 pct reduction. Optimal usage of ventilating air and shearer water consumption can be achieved by defining a "point of diminishing returns" above which further increases no longer reduce dust concentrations, proportionately .

Jan 1, 1987

By V. L. Magnus

The text of this chapter was not received in time for printing.

Jan 1, 1979

By Robert A. Haney, Scott G. Vail, Kenneth G. Fields

The Mine Safety and Health Administration, in cooperation with IMC Global Operations, Inc., conducted a joint study to determine the effectiveness of the technology currently in use at the mine to control diesel particulate exposures. IMC Global operates an underground potash mine using diesel-powered equipment to extract minerals. IMC uses a variety of technologies to control worker exposures to diesel particulate. These technologies include: ventilation, low sulfur fuel, oxidation catalytic converters (OCC), maintenance and work practices. The study was conducted over a two-week period, two shifts per day. During the first week (six shifts), baseline data on exposures and diesel particulate emissions were obtained. New OCC's were installed over the weekend on all equipment on the test section. During the second week (six shifts), data were collected to assess the effectiveness of the new OCC devices. In addition to exposure and diesel particulate emissions data, mine ventilation, engine exhaust temperatures and mine operational data were obtained. The primary means of determining diesel particulate concentrations was the respirable combustible dust (RCD) method. Gas concentrations carbon monoxide (CO), carbon dioxide (CO,), and nitrogen dioxide (NO,) were measured using passive dosimeter badges and gas bottles. Results of measurements of diesel particulate, gases, and air- flows were analyzed to determine the effectiveness of airflow and oxidation catalytic converters for controlling diesel particulate exposures. The use of oxidation catalytic converters resulted in reductions of both workers' exposures and diesel emissions.

Jan 1, 1997