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By Y. C. Lo

This paper presents the development of ultrasonic grinding technology for material and mineral processing. The principles underlying this new technology, as well as their implementation in two laboratory scale devices are described in detail. Ultrasonic grinding experiment results are discussed with respect to operating variables and the achieved product sizes. Special attention has been given to the electrical energy consumption of the grinder, and an attempt to compare its efficiency with tumbling mills has been made. A mechanical system capable of measuring the specific grinding energy is also described.

Jan 1, 1991

By N. C. Miller

In situ stope leaching is an innovative mining system that reduces the surface impacts of conventional underground mining. As in any leaching operation, stope leaching requires hydrologic site characterization and control of leaching solutions. Several tracer tests, using sodium chloride (NaCl) in various concentrations, were conducted by the U. S. Bureau of Mines (USBM) in an underground experimental stope to simulate a leaching environment. The tests were conducted in fractured crystalline rock that was partially saturated. As tests progressed, the surrounding fractures became more saturated. A predominant flow direction away from the stope was found during testing. Testing procedures, preliminary results, and remediation ideas based on field observations are presented in this paper.

Jan 1, 1995

By Richard Hogg, Heechan Cho

Investigations of long-time grinding of fine quartz (to about 80% passing 0.35 pm) in a 0.6 liter stirred-media mill are described. Breakage rates and primary breakage distributions have been determined based on extensive characterization of the ground products by laser scattering/diffraction and gas adsorption. The results indicate that, while there is qualitative similarity between the breakage parameters for ultrafine and conventional (coarse) grinding, there are important, quantitative differences. In particular, it is found that primary breakage distributions become significantly narrower in the submicron sizes. The trend can be described using double-truncated log-normal distributions in which both a maximum (breaking) size and a grind limit are specified. The breakage distributions become progressively narrower as the size being broken becomes finer. Breakage rates follow a typical, consistent pattern in which the rate decreases with size according to a simple power law. Further decrease in the rates seems to occur after very long grinding times when the entire mill contents become finer than about 1µm. The effect is explained as a result of changes in the rate/size relationship in the submicron range.

Jan 1, 1995

By A. W. Khair

This paper deals with the causes and mechanisms of pillar failure in a southern West Virginia coal mine. The conclusions are based on in-mine observations and analysis of mining methods, eyewitness account of the sequence of events, topographic and geologic conditions, and mechanical properties of mine roof, coal, and floor. The study indicated that massive pillar failure was caused by the collapse of the mine roof. The collapse of the mine roof was due to the combined effects of high lateral compressive stress and high extraction ratio causing excessive bending of the roof beyond its limit. It was assumed that the higher lateral compressive stress under such a shallow cover was probably due to the drastic change in the structural geology of the area and possible residual stresses. Eased on the analytical study it was concluded that the sudden release of elastic energy (shock) due to the rupture of the roof caused the squeezing of approximately eighty mine pillars.

Jan 1, 1983

Rendering a solid hydrophobic and solid-fluid particle* attachment in flotation are recognized as not necessarily related (1,2). The attachment is governed by forces of attraction and repulsion which need to be considered. The induction time required for attachment after solid and fluid particle are brought into proximity (3-8) illustrates the point. Laskowski(8) showed that a reduced induction time favoured flotation but detected no change in contact angle, a standard indication of solid surface hydrophobicity. Induction .time is observed in fluid-fluid particle coalescence, there being called a rest time (9-11) The induction time phenomenon is related to the presence of a metastable liquid film (disjoining film (2)) of the continuous phase (water in flotation) which must thin and rupture to permit attachment. The lifetime of this film, which is governed by the rate of thinning and the probability of rupture with thicknesss, depends on a complex interaction of forces. Investigating these forces should help clarify the attachment process. Practical benefits would be improved understanding of slimes flotation (12,13) This paper is concerned with the role of the mobile fluid particle-water interface on the film lifetime, in particular, the role of time-dependent or dynamic interfacial properties resulting from deformation of this interface.

Jan 1, 1975

By Mustafa Kumral, Mehmet Balci

Strategic mine planning focuses on cutoff grade selection, capacity planning and block sequencing. Despite significant knowledge accumulated, potential value can be added to mineral sourcing by addressing various aspects. A case study on a metallic deposit with a lognormal grade distribution examines if grade/metal distribution influences cutoff grade selection. Six data sets with different shape and scale factors, but the same ore tonnage and metal quantity, are analyzed. Results indicate deposits with lower shape and scale factors are more sensitive to metal price and discount rate changes. The study also investigates the effect of economies of scale (EoS) on project value, focusing on the ratio of variable cost to total cost (capacity factor). Two regression analyses are conducted for optimal capacity planning and cutoff grade selection. The first shows capacity planning is highly sensitive to the EoS of mining and mineral-processing costs, with grade variability and metal distribution being negligible. In the second analysis, grade variability and EoS of mineral processing costs are vital for cutoff grade selection.

Sep 1, 2024

By Robert L. Bates

An industrial mineral, says the Glossary of Geology, is "any rock, mineral, or other naturally occurring substance of economic value, exclusive of metallic ores, mineral fuels, and gemstones; one of the nonmetallics." Probably most geologists and engineers would accept this simple and straightforward definition, at least as a general statement. On analysis, however, certain anomalies crop up. For example, what is metallic and what is nonmetallic? Bauxite and ilmenite certainly qualify as metallic ores, but both are also raw materials of important nonmetallic substances; hence they are included in this book. Another anomaly is that, by common consent, the term industrial minerals may include not only rocks and minerals but also certain manufactured products, such as cement and lime, and even mixed groups of natural and artificial products, such as abrasives and refractories. Thus the central realm of the industrial minerals is clear enough, but its boundaries tend to be indefinable. Since a definition that allowed for every irregularity in the outer fringes would be excessively unwieldy, the one quoted above may be considered satisfactory. The expression industrial minerals is commonly equated with nonmetallics, and with the somewhat more precise phrase industrial minerals and rocks as in the title of this book.

Jan 1, 1994

By J. B. Hedrick

Rare earths were not mined in the United States in 2008. However, processing of intermediate rare-earth concentrates continued throughout the year at the Mountain Pass Mine in California. Consumption of refined rare-earth products increased. U.S. rare earth imports were primarily from China, with lesser amounts, in decreasing order, from France, Hong Kong, Japan, Austria and Russia. The United States imported 100 percent of its supply of yttrium metal and compounds primarily from China. United States In 2008, lanthanide concentrates were processed by Chevron Mining Inc. (previously Molycorp Inc.) at its mine site at Mountain Pass, CA. Chevron Mining sold its entire holdings in the rare earths mine to Molycorp Minerals LLC in September and operations continued at the site through-out 2008. Major uses for these mineral commodities were in automotive catalytic converters, petroleum fl uid-cracking catalysts, permanent magnets, glass-polishing compounds, ceramics, metal-alloying additives, phosphors and recharge-able batteries. Three domestic companies produced and sold lanthanide intermediate concentrates and refined products. Chevron Mining sold its interests in the Mountain Pass Mine to Molycorp Minerals LLC on Sept. 30, 2008. Molycorp Minerals LLC is an investment company owned by Resource Capital Fund IV L.P., Pegasus Partners IV, LP, The Goldman Sachs Group Inc., Traxys North America LLC, Carint Group LLC and Mark Smith. The Molycorp operation previously mined the rare earth fluocarbonate mineral bastnäsite by hard-rock surface methods, and the mine remained on care and maintenance in 2008. Molycorp maintained significant stocks of bastnäsite concentrates, intermediate concentrates and high-purity rare earth compounds at its operations at Mountain Pass. In October 2007, Chevron Minerals completed phase one of its three-stage plan and restarted the rare earth separation plant at Mountain Pass. The company also processed intermediate rare earth concentrates from existing stocks during the first three quarters of 2008. Molycorp Minerals LLC maintained production in the last quarter of the year. The mine at Mountain Pass has been closed since 1998. Future plans are to restart processing of stockpiled bastnäsite concentrates followed by reopening of the mine.

Jan 1, 2009

By C. A. Summers

The U.S. Bureau of Mines applied process mineralogy to investigate a lead and zinc deposit located near Story Creek, Colville Mining District, Alaska. Mineralization is hosted by the Kayak Shale in veins, veinlets, and breccia. Sphalerite and galena, with supergene anglesite, occur in symmetrical quartz veins and between breccia clasts. The study sample analyzed 2.11 percent Pb, 5.37 percent Zn, 0.014 percent Cu, and 1.2 oz/ton Ag. Analyses of crushed products showed that 33 percent of the sample weight, and more than 50 percent of the Pb and 65 percent of the Zn, are in the minus 850 µ m fraction. Liberated grains of sphalerite and galena were found in crushed products finer than 300 µ m. Beneficiation tests indicate the material is amenable to processing by traditional gravity and flotation techniques.

Jan 1, 1993

By Grażyna Dzik, Adam Mirek, Krzysztof Król

The Upper Silesian Coal Basin is located in the area of the Upper Silesian Syncline and belongs to one of the most complex tectonic units in Europe. It occupies 5,650 km2. In 2020, there were 20 hard coal mines operating in the area. Seismological research in this area consists of observation of precursors/symptoms of shock generation and understanding of their effects. Studies (Teisseyre R. 1972, Mutke G. & Stec K. 1997, Stec K. 2007, Dubiński J. & other 2010, Idziak A. 2010) of complex impacts of rock mass provided a background for determining the conditions for the formation of exploitation and regional seismic shocks. Issues related to tectonic and exploitation stresses, successive extraction of coal seams at higher depths, operation in the vicinity of fault zones, often complex geological and organic conditions result in the activation of a discontinuity surface due to stress caused by deformation of rock layers, which, as a result, causes the emergence of strong shocks above 107 J. The article was based on analyses of extraction value, high-energy shocks, both of mining and tectonic-mining (so-called regional shocks) origin, against the background of changing operating conditions, which, as a result, creates an image of periodically changing seismic activity and location of strong shocks. Observation results show that, with an increase in exploitation depth and declining extraction, the number of strong shocks caused by tectonic stress (107 - 109 J) and exploitation stress (≥105 J) has been steadily increasing over the last 25 years.

Apr 26, 2022

By J. T. Graves

Bauxite, dolomite, and magnesite are natural occurring minerals that are used extensively in the manufacture of refractory products. In addition, magnesia produced from seawater or brine finds its way into the production of refractories. All of these materials must be processed at high temperatures, 1500°C to 2200°C, to produce an intermediate raw material (refractory grain) , which can then be used in the final manufacture of refractory bricks and shapes. During the last 20 years, the major supply of refractory bauxite has been from Guyana, and at times the annual production has ranged up to 1,000,000 tons per year. More recently, China has become a major source of refractory grade bauxite by supplying over 300,000 TPY. Other sources of bauxite in lesser quantities have been Surinam, Brazil, and the U.S.A. During 1980, the estimated available world tonnage amounted to slightly more than 1,300,000 tons. The bulk of this material has been calcined in rotary kilns except for some of the Chinese production, which was treated in shaft kilns. Recent work has indicated that an excellent product can be produced in the Nichols Shaft Kiln using much less fuel than the conventional rotary kiln. Details of the Nichols Shaft Kiln will be provided later in this paper.

Jan 1, 1982

By A. E. Foscolos

British Petroleum (BP, 2005), indicates that world reserves for oil to be 1198 billion barrels, for natural gas the equivalent of 1156 billion barrels of oil and for coal the equivalent of 3219 billion barrels of oil. If we take into consideration the mean aver-age annual increase in demand of the last three years for oil, 2.6%, for natural gas, 3.9%, and for coal, 6.6%, then their respective reserves? lifespan are calculated to be 27, 34 and 38 years. Without taking into account their annual increase in demand, lifespan increases to 38, 67 and 161 years respectively. Since zero increase or perpetual increase in energy demands on finite resources is unrealistic the selection of the most suitable energy commodity for power generation rests upon the law of supply and demand of each commodity. This defines its price hence its selection for the production of cheap electricity. When the ratio of supply to demand is less than one, peak production is achieved. Any further increase in demand results in price increase to quench its demand. The Association for Oil and Gas Peak (ASPO) has calculated that when oil demand exceeds 84 million barrels/day, Peak Oil Production will be attained thus prices will start to increase in order to even demand with supply. Correspondingly, Gas Peak Production is expected to take place when demand exceeds 9.1 or 10.2 billion cubic meters/day. Peak Oil production has been calculated to take place in the current year, 2006, while Gas Peak production is estimated to take place between 2020 and 2025 provided that gas will not cover the energy deficit created from the lack of oil otherwise Gas Peak production could arrive as early as 2010. The use of coal for power generation is considered a better alternative than oil and gas if new combustion technologies with an energy efficiency of 43%, Germany, and 47%, Denmark, are adopted. These not only extend the lifespan of coal reserves but reduce also CO2 emissions by 25% and 31%, respectively. In the very near future CO2 sequestration and fixation in deep geological strata will eliminate its emissions thus rendering the use of coal the cheapest feedstock for power generation.

Jan 1, 2006

Mill #4 processes mildly refractory ore from Carlin Trend deposits. Diagnostic analysis of plant operating data was used to generate a mathematical model containing the key parameters influencing the gold recovery. The model was used to direct modifications to plant operating practice. The cyanide dosing strategy was changed to reduce preg-rob gold masses and cut reagent consumption A finer grind was achieved without capital investment. The density in CIL was lowered, and tighter control was exercised over plant throughput. These changes resulted in a recovery increase of at least 2%, worth $111,000/month at $300/oz, and concomitant reagent cost savings of $55,000/month.

Jan 1, 1999

By R. M. LaDouceur, C. A. Young, W. Nicholas

"Salicyl hydroxamic acid (SHA) adsorption on two rare earth oxides, lanthanum and yttrium, was studied. Adsorption at both surfaces occurred in two stages. Initially, the monovalent anionic collector appears to adsorb significantly and instantaneously in stage one and then becomes sluggish in stage two presumably because the initial stage passivated the surface. By comparison, adsorption during the sluggish second stage with lanthanum oxide did not stop but with yttrium oxide essentially stopped. Surface monolayer formation could not be observed in either of the two cases. Both stages appear to be due to multilayer formation of a surface precipitate as proven by Raman Spectroscopy for lanthanum oxide but inferred for yttrium oxide. Unlike the use of octyl hydroxamate as stated in the literature, increasing temperatures do not increase adsorption such that flotation of rare earths with SHA may be performed at room temperature leading to improved recoveries as well as significant energy savings. INTRODUCTION Rare Earth Elements (REEs) are comprised of the 15 lanthanides along with scandium and yttrium. The REEs with lower atomic numbers are relatively more abundant and are categorized as light REEs. On the contrary, the REEs with high atomic numbers are less abundant and referred to as heavy REEs. They are not really “rare” and, in fact, some of them are quite abundant in the Earth’s crust; it’s just that they “rarely” exist in concentrated deposits but rather are found dilute and practically everywhere. REEs share very similar physico-chemical properties but, because many of these properties are unique, they have gained enormous importance in recent times making several critical and strategic pending their use. For example, REEs have found extensive application in phosphor coatings, magnetics, and automobile cracking catalysts. Early technology was not advanced enough to produce commodity level production of the REEs and can be attributed to REE-bearing ores containing many rare earth minerals (REMs), not just one. In this regard, there are numerous REMs but bastnaesite, xenotime and monazite are considered to be the most common. Bastnaesite is a fluorocarbonate whereas the other two are phosphates. The separation of the individual REE-bearing minerals from the ores is not an easy task since they also exhibit very similar properties. Consequently, when flotation is used, it is done to produce bulk REM concentrates. For REM flotation, it is well established that octyl hydroxamate is more selective than fatty acid collectors (Pradip and Fuerstenau, 1983 and 1991). Liu et al. (2006) indicated that hydroxamates are the most common collectors for REMs. Pavez et al. (1996) studied the adsorption of oleic fatty acid and octyl hydroxamate on REM surfaces. Cui et al. (2012) studied the interaction of octyl hydroxamate with various REMs surfaces using various spectroscopic techniques such as XPS, FT-IR and Raman along with electron microscopy and concluded that such techniques offer ample information to establish adsorption mechanisms. Ren et al. (1997) studied napthalenic hydroxamic acid as a unique collector for flotation of REMs from bastnaesite ore and indicated that more selective collectors were needed. From these studies, it is clear that the quest of more selective collectors is essential but understanding how they adsorb at mineral surfaces is prerequisite to improving flotation performance."

Jan 1, 2016

By A. K. Bakshi

Slurry rheology affects autogenous grinding performance by changing the rock's breakage characteristics. In this study pilot scale batch autogenous grinding was carried out to observe the effect of viscosity on the breakage characteristics of the rocks (the media), and on the overall specific energy consumption. Clay/fines content, and temperature of the initial charge, were varied to alter the viscosity of the slurry. Results showed that at higher slurry viscosity, rocks became more difficult to break, resulting in an overall increase in the specific energy consumption of the mill. Also, it was observed that viscosity had a significant effect on the amount of critical size material present in the grinding circuit, where the critical size material is the material which is too large to be effectively ground in the mill, and too fine to act as grinding media.

Jan 1, 1996

By T. Guler

Turkey has important celestite reserves in Sivas. These reserves have gypsum and/or calcite as gangue minerals. Celestite-calcite ore cannot be concentrated by gravity methods due to the low efficiency of gravity methods in fine sizes. Research was tried to concentrate celestite to a market grade by flotation. Parameters such as pH, particle size, dosage and types of collector and depressant were examined. Cyanamid A-845 and Na-oleate combination as collector, sodium silicate as depressant, and Aerofroth-65 as frother were found as the optimum flotation reagents. By applying 3-stage cleaning, a concentrate assaying 95,34 % SrS04 was obtained with 84,93 % recovery.

Jan 1, 1999

By Karoly (Charles) Kocsis, Jeff Johnson, Felipe Calizaya, Tulio Dias, Natanna Nunes

Two pressure balancing chambers were constructed at a Colorado coal mine to reduce the risk of spontaneous combustion. Each chamber was established by installing a Kennedy stopping at about 10 ft (3 m) in front of an isolation seal, and equipped with two safety doors, a nitrogen injection system, and a set of environmental monitors. Several pressure balancing tests for different ventilation conditions were conducted in these chambers. During each test, pressurized nitrogen was injected into the chamber and the pressure differentials across the stoppings and seals monitored. This study presents a summary of the results achieved, lessons learned, and the basic requirements to operate a pressure chamber effectively.

Feb 1, 2024

By Stanley R. Riggs

The rocks exposed in the phosphate district are of Neogene age and consist of clayey quartz and phosphorite sands overlying phosphatic dolomite. The Bone Valley Formation is redefined as a marine phosphorite containing primary phosphorite and abundant terrigenous sediments. It contains a Middle Miocene vertebrate and invertebrate fauna and conformably overlies the Hawthorn Formation containing similar invertebrate fauna. A new, unnamed formation, with Pliocene and Pleistocene fauna and containing reworked phosphorite, overlies the Bone Valley disconformably. Its phosphorite is derived from the subjacent Bone Valley by post-Middle Miocene erosion and deposition in stream channels and marginal marine environments. The Bone Valley contains two main types of primary marine phosphorite. Orthocbemical phosphorite, a direct precipitate of microcrystalline phosphorite (microsphorite), occurs as a cement or binder in thin beds. Allochemical phosphorite consists of clastic phosphorite particles that were originally formed as microsphorite on another part of the shelf. Microsphorite was deposited in a very shallow open marine environment which had an abnormally high phosphorous content caused by upwelling currents. The mechanism of deposition is still in doubt, but organisms probably were a major factor. Soon after deposition, microsphorite was indurated, periodically torn up, and the resulting fragments transported and deposited elsewhere on the shelf. These processes account for a great portion of the clastic phosphorite in the Miocene deposits of Florida. The primary fossil skeletal material is of minor importance.

Jan 1, 1965

By G. W. Mannard

The large massive sulphide deposits present a formidable challenge to the economic geologist. They represent such huge concentrations of iron, sulphur, base metals and precious metals that it is difficult to conceive how they were derived from the crust or mantle of the Earth. The problem of the origin of massive sulphide deposits has generated a geological controversy which has lasted two hundred years and shows no sign of abating. The economic incentive to solve this problem is great, as the massive sulphide bodies are the moat important source of the world's zinc, lead, and silver, as well as yielding large amounts of copper and gold. Using the criteria of abundance, size, age distribution and gross value of contained metals, the predominant sub-group of the massive sulphide deposits is that which comprises the crudely conformable pyritic (or pyrrhotitic) deposits which occur in stratified volcanic and sedimentary rocks or their metamorphosed equivalents. Examples of this sub-group are: the Buchans, Bathurst, Noranda, Kidd Creek, Flin Plon and Sullivan deposits of Canada; the Mt. Isa and Broken Hill orebodies of Australia; the Cyprus, Rio Tinto, Meggen and Rammelsberg deposits of Europe; Ducktown and the United Verde in United States; and the Kuroko deposits of Japan.

Jan 1, 1973

By E. E. Maurer

Kerr-McGee has operated the Ambrosia Lake uranium mill since startup in 1958. Tonnage milled per day has varied from 3500-7000 tons. The mill capacity is currently rated at 7000 tons per day. The process consists of two parallel circuits following crushing and sampling, \\lhich include open circuit rod mill grinding, sulfuric acid leach, cyclone classification, and counter-current washing circuits of sand classifiers and slime thickeners. Pregnant solution is clarified and polished by precoat pressure leaf filters prior to amine solvent extraction. Yellowcake is precipitated from the pregnant strip solution with ammonia, filtered and dried.

Jan 1, 1972