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By B. R. Satio, P. G. West-Sells, D. B. Dreisinger, B. J. Y. Leong, G. A. Kordosky

Electrolytic techniques have historically been used to remove arsenic, antimony and bismuth from copper refining electrolytes. However, both solvent extraction and ion exchange techniques have been heavily researched and in a number of cases commercially introduced. In this study a large number of solvent extraction reagents and ion exchange resins were screened to determine the selectivity of the reagents for impurity removal. Solvating extractants were found to efficiently remove arsenic from electrolyte. The extent of arsenic extraction increased in the following order: TBP < DBBP < DPPP < Cyanex 925 < Cyanex 923. Antimony and bismuth extraction from electrolyte were demonstrated with the reagent 2EHAP04. The ion exchange resins UR-3300 and Duolite C-467 were found to strongly extract antimony and bismuth from electrolyte. C-467 appeared to be superior to UR-3300.

Jan 1, 1993

By J. W. Leonard, C. L. Jiang, B. K. Parekh, X. H. Wang

The selective depression of pyrite from the Kentucky No. 9 coal seam was systematically examined using various kinds of inorganic and organic chemicals. Most of the organic chemicals tested showed little selectivity in pyrite depression. It was found that both orthophosphate and pyrophosphate were effective for the selective depression of coal pyrite in coal flotation using fuel oil as a collector. At substantially low concentrations of pyrophosphate, the flotation of coal pyrite was completely depressed over a wide pH range, while the coal flotation remained unaffected. The mechanism of the selective depression of pyrite by phosphates was explained with the help of thermodynamic calculations of iron-phosphate-water systems and zeta-potential measurements. It was shown that pyrophosphate reacts strongly with the iron ions of pyrite to form stable hydrophilic iron pyrophosphate complexes on pyrite surfaces.

Jan 1, 1999

By C. Maltesh, P. Somasundaran

The ever increasing need for treating fine complex mineral bodies has led to the evolution and rapid development of advanced processing techniques for fine grinding, classification an if mineral separation and purification. With the introduction of these new technologies and understanding of underlying fundamental principles, mineral processing is now being applied to materials ranging from ceramics and composites to superconductors. In this review, current and potential applications of mineral engineering techniques to advanced materials processing are discussed. Particularly, material processing involving ultrafine grinding, dispersion and flocculation and thin film formation is examined. Novel techniques of solid/liquid separation involving manipulation of interfaces and use of high intensity high gradient superconductor magnetic equipment for solid/solid separation are discussed.

Jan 1, 1990

By E. W. Hawk

The power generation industry may be required to reduce CO, emissions if regulations related to global climate change are enacted. Coal-fired generation, which emits 82% of the power sector CO2, would be a likely target for CO2 reduction. Compliance with the Kyoto protocol will require a 30% reduction from the projected year 2012 emission level even with moderate load growth. This paper describes an analysis of power industry CO2 reduction options and their costs to assess how a generator would make compliance decisions under a mandatory CO2 emissions reduction program. Carbon sequestration, fuel switching and new plant construction are considered.

Jan 1, 1999

By Estban M. Domic

The modem copper industry presents an excellent opportunity for the application of clean, environmentally friendly techniques using currently available hydrometallurgical technologies. This paper briefly reviews key events in the development of modern hydrometallurgy in Chile. Discussion is given to those prominent events whose impact continues to be felt on most projects currently underway. Mention is also made of the foundations of heap leaching technologies, preceded by agglomeration and acid curing, known as the T.L. Leaching Process, the cornerstone of more recent developments. A review is also presented of the leading copper hydrometallurgy projects of the 1990s. A list of those projects, their tonnages and the estimated date of implementation is provided. The conclusion provides an overview of developments in research and the trends in the implementation of copper hydrometallurgy projects in Chile for the coming years.

Jan 1, 1998

By E. M. Hill, D. E. Walsh, J. T. Hollow, H. K. Lin

Fairbanks Gold Mining, Inc. (FGMI) began blending and processing True North ore at their Fort Knox mill on April 12, 2001.Gold extraction subsequently dropped from 88% to 71% during the last week of April 2001. 25% of the gold values remaining in the leach tailings were gravity recoverable free gold. Significant quantities of stibnite and arsenopyrite were also identified in the tailings. In laboratory bottle roll tests, the gold extraction from a composite of leach circuit feed collected during the same period was 72.6%, when leached at an average NaCN concentration of 0.16 g/kg. The extraction increased to 82.4% and 91.7% with 0.5 g/kg NaCN, and 0.5g/kg NaCN plus 0.075 g/kg Pb(NO3)2, respectively. A passivating layer surrounding liberated gold particles and resulting from sulfide mineral dissolution, likely contributes to reduced gold recovery, which can be substantially increased by the addition of lead nitrate. Lead species remain in the solid residues after leaching and were not mobilized using Meteoric Water Mobility Procedure.

Jan 1, 2003

By Gary A. Kordosky, R. Brantley Sudderth

The solvent extraction process as it applies to the recovery of metals from solutions on a comnercial basis is described. The four types of classes of sol vent extraction reagents are explained: 1) solvation, 2) acidic, 3) ion-pair, and 4) chelation, and examples of each type of reagent system are given. The uranium and copper extraction examples, using the ion-pair and the chelate reagent types respectively, are presented in greater detail to illustrate the more subtle aspects of reagent evaluation and selection. Practical experiences in the laboratory and at some operating plants are a1 so discussed.

Jan 1, 1986

The Longwall Strata Control and Maintenance System (LoSCoMS) is designed to monitor shield pressures in real-time from longwall faces and to provide on-line information related to underground strata behavior and longwall mining operation. The information includes shield pressure data with statistical analysis of setting, developing and final pressures, prediction of shield pressures for the following shift or day, etc. and maintenance data on the shields. The LoSCoMS has been installed and tested at Shoal Creek Mine operated by Drummond Company, Inc. The system is providing valuable information to mine operators for better understanding of underground behaviors. As a result, it has become an effective tool for minimizing ground control hazards and reducing out of seam material.

Jan 1, 1997

By Erich U. Petersen, Robert B. Coleman, William J. Tafuri, Donald M. Hausen, P. R. Taylor, Douglas N. Halbe, D. W. Rodolff

The definition of refractory gold ores and concentrates, including mineralogical characteristics, is reviewed. The chemistry of roasting and process conditions such as feed size, temperature, and time are discussed. A typical metallurgical program for developing a roasting process scheme is presented. The application of various types of furnaces for roasting is described. Requirements for scrubbing off-gases to meet environmental air emission regulations, and general information regarding engineering design parameters for roasting are presented. Roasting is sound technology for processing refractory ores and concentrates, but it is essential that the metallurgy of each ore or concentrate is well defined before commercialization. A fluid-bed roaster is the preferred type of furnace for roasting. Environmental regulations for air emissions must be carefully addressed.

Jan 1, 1990

By Victor Rudenno

Cut-off grade is one of the most critical parameters affecting project cash flow. Its sensitivity is due to the number of other parameters that are correlated with any change in its value. Changes in cut-off grade, average grade and ore tonnage vary and they in turn can affect such parameters as capital and replacement costs, recovery, life of the project and operating costs. Perhaps one of the best definitions of cut-off grade is that of Taylor (1), "... any grade that, for any specific reason, is used to separate two courses of action, e.g. to mine or to leave, to mill or to dump ... . Obviously the most likely specific reason is one governed by economics, involving the return of investment and sufficient profit to motivate development and mining of the deposit. In this paper the cut-off grade is defined as that mining limit which will maximise the economic return for a projected mining venture. The following brief literature survey indicates that when computing the optimum cut-off grade there is a need to be able to directly compute the Discounted Cash Flow Rate of Return (DCFRR) or Net Present Value (NPV), as economically as possible, while allowing for parameter dependencies and variation in project structure.

Jan 1, 1979

By J. D. Grenia

The Buick Mine is a joint venture of American Metals Climax, Inc., and Homestake Mining Company located 120 miles by road southwest of St. Louis, near the village of Boss, in the &apos;New Missouri Lead Belt&apos; (See Figure 1). Since start-up in 1969, over four million tons of lead-zinc ore have been mined and milled at Buick. Situated about 1,100 feet below the surface at an elevation 270 feet above sea level, the flat lying sinuous ore bodies are up to 250 feet wide, 85 feet high and several thousand feet long. Mineralization is galena, sphalerite and chalcopyrite in dolomite, Access to the mine is through two 18&apos;Ø concrete lined vertical shafts - one for servicing and the other for hoisting ore (See Figure 2). The mine is being worked by a modified room and pillar method using both rubber tired equipment and a sub-level rail haulage. Ore is broken from first pass headings, back and bench faces and transported by load-haul-dump units to ore passes located on 900 foot centers. The ore is pulled from chutes on the sublevel 90 feet below into 15 ton bottom dump cars and delivered in 10 car lots by a 15 ton diesel locomotive to a 42" gyratory crusher (See Figure 3). A recent innovation has been the introduction of two 50 ton trucks with plans to haul up to 60% of the ore on the mining level to an ore pass feeding directly to the primary crusher (See Figure 4). Ventilation raises up to 16&apos;Ø, which were originally planned for 900 foot centers, are now driven on 450 foot centers.

Jan 1, 1973

By Earl F. Mathers

Few people would question that coal is king in the Campbell County, WY area. Other industries, such as oil production and ranching, also contribute significantly to the economic base, but coal mining and related industry development dominate. In recent years, Gillette has become the commercial hub of northeastern Wyoming. This development has been largely a response to the growth of the coal industry in Campbell County. Historically, Campbell County developed as a ranching area, a process that was aided by the passage of rail lines through the area, allowing early ranching interests to get their livestock to market. For decades, the Gillette-Campbell County area was predominantly a ranching area that experienced only incremental population growth.

Jan 1, 1994

By Steve Kral

The success of the industrial minerals end of the mining industry is often overshadowed by the high price of copper, the glamour of gold, and the nation&apos;s huge reserves of coal. Those three segments of the industry, however, along with every other business in the world, could not function without the products that are composed of a variety of industrial minerals. And, according to Haydn H. Murray, past president of SME, the value of industrial minerals in the United States is more than triple that of metals, about $19 billion a year versus $6 billion. In the developed countries of the world, he said, the value of industrial minerals is nearly always greater than the value of metallic minerals. Murray, also a professor of geology at Indiana University, was the luncheon speaker at the SME-sponsored Grinding of Industrial Minerals conference held in Asheville, NC this past September. Producers of industrial minerals know they must squeeze the maximum value out of the industrial mineral being mined and processed, Murray told the audience of about 100 people. Grinding and particle size, then, are vital to a commodity&apos;s profitability.

Jan 1, 1990

The feasibility of exploiting a mineral deposit by developing a surface mine is closely related to the environmental protection and land reclamation costs. This issue has utmost importance for West Macedonia Lignite Centre (WMLC) of Greece, where there is still a lot of interest for opening of new mines and for further development of the existing open-pits. The decision-making process in these cases can be based on a decision tree that takes into consideration the various cost components of environmental management, the alternative solutions, the environmental permits and the cost reports of environmental management actions carried out so far. Moreover, the mine planning procedure is affected indirectly by numerous uncertain environmental and socioeconomic parameters, such as the delays caused by the bureaucratic procedures and the settlement of arguments in the Court.

Jan 1, 2006

By Peter W. Harben, Edward M. Dickson

The distribution of metallurgical grade bauxite deposits will be discussed with the aid of a comprehensive table and a reference map. Information will include operating companies, mine locations, ore grade, and chemical analysis, geological environment, and production capacities. General comments will be made on the distribution of production and its relationship with major consuming regions. The pattern for the future will be assessed, including potential new producers, changing specifications and industry structure.

Jan 1, 1984

By E. A. Devuyst

A unique process for removing cyanide and base metal complexes from industrial waste streams was patented by Borberly et al. (1984). The process uses S0, (liquid or gas, or solutions of sulfite salts, or from burning elemental sulfur), plus air that is dispersed in the effluent using a well agitated vessel. Acid produced in the oxidation reactions is neutralized with lime at a controlled pH generally in the range 7 to 10. The reaction requires the presence of soluble copper as a catalyst that can be supplemented by copper sulfate if necessary. The process can be applied to the detoxification of gold and silver mining waste streams, such as carbon-in-pulp (CIP) tailing pulps, barren solution bleeds, pond waters and heap leach rinse solutions and also to plating shops waste waters. The S02/Air process has substantial advantages over two of the main alternative methods of cyanide destruction, namely alkaline chlorination and hydrogen peroxide. Alkaline chlorination is highly penalized in terms of reagent consumption. Chlorine is a strong oxidant reacting with species other than cyanide present in the effluent such as thiocyanate and sulfides. Furthermore, alkaline chlorination is an incomplete detoxification process. Iron cyanide is not removed and the potential for harmful byproducts species exist. Consequently, final effluents may be subject to additional treatment in order to comply with regulatory demands.

Jan 1, 1991

By Eric Jones, Leslie C. Thompson

Biological processes for cyanide detoxification in mine waste are receiving attention as an alternative to conventional chemical treatment options. Some of the advantages of biological treatment include: Low comparative treatment cost * Shorter treatment time * In Situ Treatment * Complete Detoxification - Ends long-term liability - Eliminates in-perpetuity monitoring - Natural Re-Vegetation potential Natural and non-toxic nutrients, by-products and process end-products Hecla Mining chose a bio-neutralization process developed by Pintail Systems, Inc. for cyanide detox in spent are and process solutions from heap leach operations at the Yellow Pine Unit. The Yellow Pine operation is located 50 air miles east of McCall, Idaho, in the Stibnite Mining District. This district is a historic mining district dating back to the early 1900's. During World War II, this district produced a majority of the antimony and tungsten the United States using for the war effort. More recently, the Stibnite district has been known for its gold production. Hecla Mining Company is based in Coeur d'Alene, Idaho, and is a leading domestic producer of precious metals and a major supplier of specialty aggregate and industrial minerals. Pintail Systems, Inc. is a company specializing in the development of biological treatment processes for mine waste remediation. PSI has offices in three states and a laboratory, pilot plant and field office in Aurora, Colorado

Jan 1, 1993

By David J. Herzog

There are two steps in evaluating potential mine waste impacts on ground and surface waters. Characterize the mine waste (characterization methodologies) and assess potential impacts (assessment strategies). One or both may be required for mine permitting, operation and closure. The first step is to characterize the waste. Determine if it has the potential to release chemical constituents or acid rock drainage to the environment. If no potential exists for release to the environment, the evaluation process is complete. A monitoring plan is then established. If the potential exists for release of chemical constituents or acid rock drainage to the environment, a strategy to evaluate potential impacts must be implemented. Strategies discussed here to evaluate potential impacts were developed during investigations at precious metal and base metal mines in Nevada. Water resources in Nevada consist mostly of ground water. So the strategies discussed focus on potential impacts to ground water. However, several of these strategies also apply to assessing potential impacts to surface water. Implementing these strategies has helped determine the potential for impact and has been successful in permitting mine expansion as well as allowing continued operation and obtaining mine closure at several mine sites in Nevada. These strategies were carried out in accordance with Nevada Division of Environmental Protection (NDEP) regulations and through the National Environmental Policy Act (NEPA)

Jan 1, 1995

By Michael Fahey, Ravi M. Damodaran, Brij M. Moudgil

The flotation behavior of Florida phosphates was studied using statistical design of experiments to evaluate conditioning parameters and their effect on flotation performance. The solids loading, conditioning time and agitation speed during conditioning were identified as the important variables affecting the reagent coating onto particles. Flotation of the conditioned slurry was carried out at fixed collector dosage and flotation conditions. Phosphate recovery upon flotation was statistically modelled as a function of the conditioning variables. The results indicated that the conditioning variables had an interactive effect on the phosphate flotation performance. Statistical optimization revealed two conditioning regimes in which optimum flotation recovery was obtained. It was determined that optimal recovery can be obtained at lower conditioning energies.

Jan 1, 1995

By John T. McDonough

The Climax Mine of AMAX&apos;s Climax Molybdenum Division is currently producing approximately 34,000 tons of molybdenum ore per day from two underground levels (see Figure I), and initial design is underway for the next deeper (1200) level. The aim of this report is to present the methods of site evaluation used at Climax for cavability determinations and underground support design. Climax succeeds with its panel caving system of mining (Julin, 1973) (Figure 2) largely because of the presence of pervasive geologic structural discontinuities. The stockwork ore body at Climax was formed by the multiple intrusion of mid-Tertiary rhyolitic magmas into Precambrian granite, schist and gneiss, and the hydrothermal emplacement of molybdenite into the network of fractures that were generated during the forceful upward intrusion of magma. Subsequently, intrusive events that were more deeply seated refractured the overlying, ore- bearing stock and propagated a complex system of axial and radial fractures. Post-ore movement along the Mosquito Fault (Wallace, 1968) and its associated stranded shear zones further fractured the ore body and disordered the existent geologic structure. The result of these structural events is a brittle, crystalline ore body that is transected by a complex pattern of faults, shear zones, and joints that augment cave initiation and enhance comminution of the ore blocks. Generalizations can be made about the structural trends within the ore deposit (King, 1946; Kendorski, 1973), however, the intensity and orientation of geologic structure is by no means uniform throughout the ore body. The relative intensities of silicic and argillic alteration are also highly variable (Vanderwilt and King, 1955). As a consequence, no single rock-mass model suffices as a standard for mine design, and site characterization for cavability and support design is a continuous process.

Jan 1, 1977