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By Hubert Bril, Priscilla Pareuil, François Bordas, Emmanuel Joussein, Jean-Claude Bollinger

"According to the legislation, valorization type, origin and characteristics of waste material, various standard procedures are available to evaluate environmental impacts. A Mn-rich slag was sampled from a metallurgical plant. After its characterization (elementary analysis and mineralogy), five standard procedures were carried out (i.e. TCLP, EN 12457-1). Each fixed parameter of the standards was systematically studied in a large range: pH, Liquid/Solid ratio, contact time. For example, EN 12457-1 led to a low ME mobilization, increasing with the L/S ratio, the contact time and an acidic pH. As a conclusion, the representativeness of the considered parameters and their potential variations are predominant to assess of the real environmental impact during slag reuse. Introduction Recent studies have been carried out about environmental impacts of waste containing metallic elements (ME) because of their potential mobility [1-7]. Indeed, slags are either dumped or valorized in various activities such as building materials. In order to assess environmental risk, various standard procedures are used depending on country legislation, origin of waste and valorization way. Results of leaching tests are linked either to special legislation (e.g. Dumping: EC, Council Decision 2003/33/EC, Construction products: EC, Council Directive 89/106/EEC) or to legal levels used in drinking water (Directive 98/83/CE) when leachates could migrate to groundwater. If ME in leachates are lower than drinking water authorized levels, the waste will be considered as non-hazardous. On the contrary, if the leachable amounts exceed them, the question about the risk has to be posed. Beyond the abundance of leaching tests available, variety of operational conditions induced by these regulatory tests does not make the choice easier. According to operational conditions induced, ME release could vary from one test to another one. ME concentrations in leachates depend on pH, Liquid/Solid ratio, contact time and particle size [3]. To highlight the importance of these operational parameters, potential risk for valorization of a manganese-rich slag was assessed by comparing several standard leaching protocols [8-12] with a global study dealing with the influence of operational conditions. For each regulatory protocol, the most influential parameters (L/S ratio, pH, particle size and contact time) have been studied in a large range."

Jan 1, 2008

By Courtney Young, Jerome Downey

"The various technologies developed for treating spent potlining (SPL) from primary aluminum smelters have been reviewed on several occasions. The technologies generally involve physical, chemical, and thermal processes, either individually or in combination, with the primary objective of total recycle, waste minimization, or complete disposal. In general, those technologies geared for recycling involve separations and are therefore subject to recovery inefficiencies that are attributed to several factors. However, the inefficiencies could be reduced or possibly eliminated if the pots were designed for recyclability. This concept is applied to SPLASH, a recently developed SPL management technology.IntroductionAluminum is produced by molten salt electrolysis via the Hall-Héroult process. The process is conducted in an electrolytic “pot,” which is comprised of a steel frame first lined with insulating refractory brick, and then conductive graphite blocks, which serves as the carbon cathode [1, 2]. These materials are collectively referred to as “potlining.” Anodes comprised of petroleum coke/pitch are suspended above the pot and extend down into the molten cryolite (Na3AlF6) electrolyte. The electrolyte temperature is maintained at approximately 980 °C by resistance heating as low voltage (4-5 volts) and high current (50,000-300,000 amps) are applied across the two electrodes.High purity alumina is added to the cryolite bath, where it dissolves and becomes amenable to aluminum reduction at the cathode:"

Jan 1, 2008

By Susana Caballero, Lourdes Yurramendi

Air Pollution Control (APC) ashes from Municipal Solid Waste Incineration (MSWI) plants need to be treated prior to landfilling due mainly to their heavy metals content. This research evaluates the capacity of the APC residues to sequester carbon dioxide, while the ash becomes stabilized for storage. It has the benefit of using two wastes, with no addition of any raw material. APC samples from different MSWI plants were treated by gas/solid accelerated carbonation at different temperatures and carbon dioxide concentrations to evaluate the residue behaviour to the process. The extent of carbonation was evaluated by means of weight gain upon carbonation and by the measurement of the final carbonate content. The APC residues were analyzed before and after the treatment in order to know their composition and their leaching behaviour according to the criteria for the acceptance of wastes at landfills established by the European Council Decision 2003/33/EC.

Jan 1, 2008

By Doss Brittain

The term ground breaking is taken to include the process of so loosening the ground as to enable it to be readily loaded into buckets or cars and hoisted from the shaft or drift. In the Joplin district are encountered two varieties of ground, the hard and the soft. Hard ground consists of massively bedded rock requiring heavy blasting to loosen it. Such ground is to be found throughout the district in the same localities as the soft ground but more extensively, even to the exclusion of the appearance of soft ground in the sheet formation in the vicinity of Webb City. The Yellow Dog Mine at Webb City and the Grace mine on the Granby land at Joplin furnish well known examples of hardground mining which has become the most extensive in the district.

Jan 1, 2008

By Alain Blanchier, Pascal Bernasconi

Blasting operations took place on Channel coast NW of France to extend Flamanville Nuclear Power Plant (EPR new generation). The closest operating reactor building was monitored by a 24 remote vibrations transducers network to fulfil, on one hand, the severe environment constraints and satisfy high degree of productivity required by the project, on the other hand. Although these requirements usually are incompatible, this challenge compelled to introduce a seismic modelling technique to optimize blast designs using electronic initiating system. The “Hybrid Seismic Modelling” (MSH) uses blastholes signatures (seismic vibrations records) which are greatly dependent on geology and alteration of rock mass, explosives, charge geometry, blast configuration, and the final excavation shape. In order to respect severe vibrations limits, excavation layout was divided into areas with specific blasting modules - type and number of charges, single charge, initiating sequence. Thanks to this technique, it has been possible to reach lowest blasts vibrations levels and a better productivity compared to classical blasting operation at the same location in the past. After the modelling method presentation - principle and use precautions, technical improvements are reported.

Jan 1, 2008

By Lazar Kricak, Zoran Teodorovis, Dragan Bogunovic

Scattering of delay interval around nominal value is an important issue in blasting practice. The scatter interval, as becomes wider, increases a probability of time delay overlapping adjacent blastholes. An excessive flyrock, ground vibrations, air blast and poor fragmentation are the symptoms for scattering related problems. Utilization of the short delays in the blastholes and longer delays on the surface are recommended solution to overcome mentioned problems. In contrast to global trends manifested through the application of electronic detonators and non-electric shock tube systems, revitalization of inexpensive electric detonators in combination with an accurate initiation system may be an acceptable solution. An extensive work was carried out at the Blasting Center Laboratory at the College of Mining and Geology, University of Belgrade, to develop a precise initiation system. As a result, Sequential Blasting Initiation System – Radio Frequency (SBIS-RF) was developed. It is expected that this system will increase blasting productivity, and reduce negative environmental impacts and total blasting costs.

Jan 1, 2008

By Neale R. Neelameggham

"Ferrous and non-ferrous metal industries are used to handling several billion tons a year of ore bodies, fuel and fluxing agents by mineral processing techniques and varieties of extractive metallurgy ""Reduction"" processes. Metal industry know-how can be applied to meet the challenge of Reducing CO2 in the atmosphere. Processes for generating alloys of carbon and hydrogen by Reducing the CO2 and water mixture, [carbonated water or water vapor] called Soda, to easily stored fuels are normally endothermic. The processes are similar to generation of hydrogen alone from water which is also endothermic. But hydrogen is more difficult to store than compounds [or alloys] of carbon and hydrogen. This recycling of CO2 and water are possible by using other forms of energy by innovative carbon capture methods.Thermodynamic Diagrams developed for Soda [CO2 and H2O] - metal reactions provide hints for using low cost unused stored energy in un-recycled metallic waste for thermal conversion. Choices for conditions for the electrochemical approaches [using solar - wind - hydropower] are also discussed.INTRODUCTIONIn 2006, I was reading some of the arguments put forth by learned scientists on the benefits and lack of benefits of bio-fuels. I found that the arguments rose partly from the differing system boundaries that were chosen by one versus the other. Some part of the argument may have been based on political climate or atmosphere rather than the analytical science. This situation is seen when scientists discuss which came first - the chicken or the egg, the fuel or biological matter, the oxide or the element, and so on.Then I thought –[just like many of the learned persons participating in this symposium] that common fuels - regardless of them being simple hydrocarbons or oxygenated hydrocarbons or carbohydrates - can all be made from the respective oxides of carbon and hydrogen by simple chemical reductions efficiently carried out in an economical fashion. This is the systematic approach we take when designing a chemical or metallurgical process facility."

Jan 1, 2008

By J Johansson

The aim of this paper is to discuss how to form work and organisations in the mines of the future. The Kiruna underground iron ore mine in the far north of Sweden is used as an example on how technical development affects organisational issues like skills, work identity and gender. Over a period of 50 years one can see a transformation of work from manual underground work to automation and remote control from surface level. What characterised the old underground workface was the close relation between man and the hard rock and with arduous physical work under dangerous conditions. Today, the face miners are located on the seventh level of an office building close to the mine. There is also an emerging, and in many aspects already evident, knowledge transformation û from the old and obsolete physical and tacit knowledge and skills (for example the ability to æread the rockÆ) to something new, which can be described as abstract æhigh-techÆ knowledge and skills. The modern technology has created a new type of work û new in terms of competencies and knowledge as well as workload and organisation. At the same time the mining company are recruiting more women and promoting the former pure male work as attractive workplaces for both women and men. All this has effects on how individuals and company create and recreate skills, identity and gender. To some extent the technological development predestines these changes, but there are some choices to be done when forming good work and organisations for the mines of the future. The traditional mining workplace culture and behaviours and the old type of masculinity, the æmachoÆ style, will be challenged by the new æhigh-techÆ work and new competency demands. The changes risk meeting restoring responses, which can have negative impact on the performance of the organisation, for example making it inflexible and perhaps ælaggingÆ behind the technological development. These questions need to be handled when planning future mining.

Jan 1, 2008

Sixty years after its inception, after an alternation of periods of admiration and rejection by the industry, Sampling Theory can now be seen as going through its golden age. A brief history of its successive transformations and progresses achieved by its author, Pierre Gy, and his followers, reveals the theoretical as well as practical difficulties that had to be vanquished to reach this point. Its current level of acceptance and corresponding trends are discussed and illustrated, with an insight on its increasing real role in the industry and future prospects for its further development.

Jan 1, 2008

By Dan Brown

Improvements in construction equipment and techniques in recent years have made possible the use of drilled shaft foundations in diameters and lengths not previously considered practical or feasible. Many highway bridge and other structures are now routinely founded on drilled shafts which are 2.5 m to 3.0 m (8 to 12 feet) in diameter and extending over 60 m (200 feet) in depth below grade. There are unique challenges associated with constructing such large and deep cast-in-place foundations and engineers should be aware of the special needs associated with site investigation, construction specifications, material requirements, and quality assurance. This paper outlines a number of special considerations for these foundations, along with strategies that may be employed to improve the reliability and quality of large drilled shaft foundations.

Jan 1, 2008

By Kokichi Iizasa

Modern Kuroko-type deposits have been much reported in submarine calderas and cauldrons in the EEZ of Japan since 1988. Some of them have been found based on heavy mineral analysis of sediments in which sulfide particles may be derived from hydrothermal sources in the ambient areas. From the end of August to early September 2007, in the middle Izu-Ogasawara arc south of Tokyo, ROV expeditions were carried out in submarine calderas in order to examine mineralogical features between intact heavy particles spouting out from sulfide chimneys and heavy minerals such as sulfides in sediments around sulfide mounds in Kuroko-type deposits, and to find more newly formed hydrothermal sulfide fields in those areas. Some preliminary results from the ROV expeditions are reported here.

Oct 15, 2007

By Nobuyuki Okamoto, Bhaskar Rao

For a period of twenty years - from 1985 to 2005 - the Japan Oil, Gas and Metals National Corporation (JOGMEC) and Pacific Islands Applied Geoscience Commission (SOPAC) have jointly conducted surveys of deep-sea mineral resources in the EEZs of SOPAC’s twelve member countries. The overall Programme has obtained excellent results and has identified numerous sites with potential marine mineral resources of manganese nodules, cobalt-rich manganese crusts, and polymetalic massive sulphides. The survey cruises have identified numerous sites with potential marine mineral resources such as: manganese nodules in the Cook Islands; cobaltrich manganese crusts in the Marshall Islands, FSM, and Kiribati; and polymetalic massive sulphides in Fiji. Based on collected samples and acoustic data, inferred resources for manganese nodule, cobalt-rich manganese crusts, and polymetalic massive sulphides, have all been estimated to be about- 200 million tons in the central Cook waters- 200 million tons in the three seamount selected Marshall waters- and 500 thousands tons around the triple junction of the North Fiji Basin.

Oct 15, 2007

By B. S. Ingole, S. Jai Sankar, A. B. Valsangkar, R. Sharma, B. Nagender Nath, N. H. Khadge, P. A. Loka Bharathi

After the simulated ‘mining’ experiment (INDEX) in the Central Indian Ocean (in 1997); the restoration of benthic environment was monitored for 4 years (2001-2005) at 5 locations in and around the test site and at 3 reference stations (20-80 km) from the test site. A comparison of long-term monitoring data with the pre-mining and post mining observations has shown that: • The concentration of silt fraction which was the highest (50-60%) at most locations during ‘pre-mining’ and ‘post-mining’ phases, had reduced (40-50%) during monitoring phases. • There was a corresponding increase in clay concentration (50-60%) during the monitoring phase, implying change in the size of sediment particles settling on the seabed, a trend that was also observed at the reference locations. • The initial increase in water content and decrease in shear strength after the experiment, which appeared to be returning to normal in monitoring-1 (2001), was reversed during subsequent monitoring phases (2002-2005), indicating changes in benthic environmental conditions. • Sediment organic matter and pore-water chemical data have not only indicated partial restoration of geochemical properties after the experiment, but also cyclic changes during the monitoring period.

Oct 15, 2007

Objective: Improve the dust control effectiveness of enclosed operator cabs on surface mining equipment.

Oct 1, 2007

By Verónica Zeballos

"Las empresas mineras deben mantener una economía dinámica y eficiente que genere costos competitivos basados en la calidad de sus productos. En ese sentido, el planteamiento de un Proyecto de Modernización de la Fundición Southern existente contribuye a alcanzar el éxito que puede ser medido a través del impacto de éste sobre las condiciones ambientales generadas. Por ello, el presente texto revisa la aplicación de tecnologías ambientalmente aceptables tomadasen cuenta en la Modernización de la Fundición de Ilo, mostrando un enfoque orientado a la gestión, a su ejecución y a la creación de valor."

Sep 9, 2007

By Jorge Castillo

"El presente trabajo describe las nuevas opciones tecnológicas para optimizar la recuperación de oro libre por procedimientos no convencionales, sobre la base de resultados experimentales realizados por diversos investigadoresy que están al alcance de los profesionales peruanos como alternativas de optimización metalúrgica. "

Sep 9, 2007

By Orlando Bernal

El presente texto aborda el aspecto termodinámico del sistema de lixiviación -en tanto predice los fenómenos que ocurren en el interior de la pila para luego continuar con el análisis del mecanismo cinético. La metodología aplicada en cuanto a los mecanismos de lixiviación, difiere de otros trabajos porque aquí se considera los tres mecanismos por separado (óxidos, sulfuros secundarios y primarios) basados en el análisis secuencial del cobre. Asímismo la cinética per se obedece las leyes de la termodinámica ergo, cuyo aspecto no puede ser ignorado en un análisis global. En este sentido, se presenta el modelo de desarrollo matemático como una herramienta óptima que controla y predice este proceso del lixiviación por medio de la simulación utilizando la ecuación de continuidad, la cual supone flujo tipo pistón de la fase líquida en el interior de la pila.

Sep 9, 2007

By Lytman Jordán

En la actualidad, el proceso de Ore Control de Tintaya se convierte en un reto porque la naturaleza del yacimiento Metasomático de Contacto Tipo Skarn presenta una mineralización compleja a manera de pasas en una torta. En ese sentido, la cultura Sigma -que presenta poderosas herramientas estadísticas y de gestión de procesos-, logró conceptualizar el proceso de ore control e identificar y optimizar tres sub-procesos críticos: el muestreo de Blasthole, preparación y análisis de Muestras de Blasthole y el Ore Control Operativo. Por ello, el presente texto señala la optimización del oro control de Tintaya a través de la metodología Six Sigma, donde se logra mejorar el proceso desde el muestreo de blasthole hasta el envío de mineral a las plantas, se minimiza los eventos de fuga de mineral a los botaderos y con la data confiable de los blasthole, se elaboran modelos de corto plazo que permiten generar planes predecibles de minado.

Sep 9, 2007

By Víctor Siña

El presente trabajo describe una alternativa de sistematización de las observaciones preventivas generadas en las áreas operativas de la minera Antamina a través del programa de Prevención de Riesgos para así reentrenar, reforzar y evitar perdidas por accidentes en cualquier tipo de industria. En ese sentido, cada miembro ya sea propio o socio estratégico de Antamina, es conciente de la prevención mediante la observación. Dicho enfoque evidencia no solo lo malo, sino también todas las consecuencias que esto conlleva. Por ello, la base de dicho programa es la detección anticipada de los actos y condiciones que nos puedan generar pérdidas.

Sep 9, 2007

By Aquiles Vivar

Ante los problemas de sismicidad inducidos por el sistema de minado en la Compañía minera Milpo, se planteó una solución a través del sistema de monitoreo sísmico único, donde se da una distribución espacial de 20 censores entre uniaxiales y triaxiales distribuidos en 3 niveles de producción en el área de influencia de las actuales operaciones para así ubicar, cualificar y cuantificar el fenómeno a efectos de realizar los análisis interpretativos del caso. En ese sentido, el presente texto describe el sistema de monitoreo, cuyo software sísmico está diseñado para determinar nuevas estructuras formadas a partir de los eventos sísmicos pre existentes reactivadas por la sismicidad inducida, así como el desarrollo de planos de isocontornos que permiten la diferenciación entre zonas de altos y bajos esfuerzos.

Sep 9, 2007