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By A. M. Engelbrecht

Paper written on project work carried out in partial fulfilment of B Eng. (Chemical) Membrane processes are vital to a diverse range of technical and biological systems, which also feature in mineral processing applications such as the treatment of mine effluent and extraction of metals. In this study, the use of cellular automata to model a semi-permeable membrane that separates two compartments is considered. Cellular automata are simple models that enable the analyst to represent well-understood local effects, such as the chemical or steric interaction between molecules themselves and between molecules or particles and their environment, which can lead to very complex behaviour on a macroscopic scale. Various physical phenomena, including reverse osmosis, were simulated. Initial results for the effect of temperature, membrane structure and chemical properties of the solutes on the performance of the membrane appear promising. Keywords: cellular automata, dynamic modelling, filtration, membrane fouling, osmosis.

Jan 1, 2007

By A. Warczokand

The cleaning of copper smelting slag requires magnetite and cuprous oxide reduction. The slag reduction with coke, injected coal powder or bunker oil is strongly endothermic and requires heat generation by fuel combustion or the use of electric energy. The reduction of fayalitic slag with calcium carbide is slightly exothermic and the formed calcium silicate modifies the slag. Thus, the additional energy is required only for covering furnace heat losses. Results of crucible scale tests showed the rate of slag reduction approximately five times higher in comparison of the slag reduction with coke under the same conditions. It seems that the effect of exothermic reaction and slag modification with CaO at the reaction interface results in very high rate of slag reduction. Industrial scale tests carried out in the Anglo-American Chagres Smelter demonstrated the possibilities of effective reduction and cleaning of the slags from a flash smelter and Peirce-Smith converters in a Teniente Slag Cleaning Furnace. The slag reduction was carried out without any reductant or stirring gas injection, simply by calcium carbide charging through a furnace mouth, and was very fast.

Jan 1, 2007

The rate of liquid copper deoxidation during top blowing of reducing flames has been investigated using a high capacity thermogravimetric unit at 1200 °C. For 1 kg copper samples, it was observed that the rate of deoxidation was proportional to the flow rate of the reducing reagent (H2 or CO). Under similar experimental conditions, it was found that H2 is more effective than CO even though both have similar thermodynamic potential to deoxidize liquid copper. The rate of deoxidation of liquid copper with reducing 0 2/CH4 flames was measured for 0 2/CH4 molar ratios of 1.5 to 2. The deoxidation rate depends on the 0 2/CH4 ratio and decreases as it approaches the stoichiometric ratio (02/CH4 = 2). Estimation of the rate of deoxidation of liquid copper with top blowing flames based on the thermodynamic composition ofH2 and CO in the product gases, agrees well with measured values.

Jan 1, 2007

By C. Tsiouvaras

Restoration of bauxite mining areas constitutes a difficult issue to address due to the destruction of the vegetation and soil decay of the excavated area. In this study woody species growth, in relation to altitude, heavy metal concentrations and mechanical texture of the underlying mining waste, were investigated. The research was implemented on restored sites of a bauxite mine in the Fokida Prefecture of Greece. These sites were located in three different elevations and the restoration took place in two phases, in 2001 and 1996. Heavy metals measurements showed some correlation among the different metals, whereas their concentration was also associated with plant growth parameters.

Jan 1, 2007

By I. M. Santos Moraes

The control of minor impurities (mainly As, Sb and Bi) in copper refineries has been a great challenge. Caraiba Metais' copper refinery produces a very high quality copper, registered in LME as grade A, and recognized as amongst the top ten in the copper world. At Caraiba's Tankhouse Bi and Sb are controlled by means of electrolyte bleed-stream removal after partial decopperizing in a set of electro-winning cells (liberators). Another way of reducing the Sb and Bi content in the electrolyte is by means of the arsenate precipitation chemistry. It is well known that the use of high arsenic concentrations in copper refinery electrolyte has the advantage of causing most of the bismuth and antimony to report in the anode slimes. However, the use of such mechanism of control may contribute to other undesired problems such as antimony and bismuth precipitation in the bulk of the electrolyte, what may cause severe contamination problems. This paper describes a period when some cathode contamination with Sb occurred at Caraiba Metais' Copper Refinery. It also presents an analysis of several process parameters related to the problem, the possible causes for the contaminations as well as the actions taken to correct the problem.

Jan 1, 2007

In the future, Illawarra Coal, the primary metallurgical coal producer in the southern coal fields of New South Wales, will face many unique challenges not found in other coal or minerals production areas. To manage these challenges and determine the best strategy for the business, Illawarra Coal has adopted a systematic strategic planning process, which starts from the broadest possible options analysis and culminates in a ægo-forwardÆ operating case that individual mine sites use as the basis for short-term planning. This paper will discuss two major topics. Firstly an overview of the Illawarra Coal and BHP Billiton strategic planning processes. This will demonstrate the range of variables and inputs that are required for the planning process, and the system which is followed to evaluate different alternatives for the extraction of the resource. Secondly, having discussed the primary external and internal factors that must be accounted for in the planning process, and the main issues affecting the viability and likelihood of each alternative, the paper will discuss the particular challenges that Illawarra Coal will face in the coming decades. These challenges include: market and price uncertainty; managing impact on surface features, infrastructure and environment; community interaction; transport and logistics constraints; unknown mining environments; lack of geological knowledge; limited surface access for new mining domains; changing attitudes to longwall mining in the Illawarra; ageing workforce; and cost and overhead management. The paper intends to discuss how these issues impact the business currently and how they are incorporated into Life of Asset plans and overall corporate strategy for Illawarra Coal.

Jan 1, 2007

By H. Jeram

The ilmenite, rutile and zircon processes of the mineral separation plant generate tailing streams, which still contain valuable mineral. This is due to a combination of factors, which include separator equipment efficiency, particle size effects and inefficient operating practices (equipment overloading, blockage, etc.). Recent developments by metallurgical equipment suppliers have led to increased mineral separator performance enabling recovery of previously lost valuable mineral. Mineralogical studies were conducted using QEM*SEM and MLA techniques to identify and quantify gangue mineral species and determine mineral association. Laboratory and pilot-scale test work was then conducted to develop suitable process flowsheets for the recovery of ilmenite, rutile and zircon from current and stockpiled tailings.

Jan 1, 2007

By C. Bucknam, M. McComb

Mercury and silver polythiocarbonate sludge that was generated from the pilot testing of optimized mercury removal from cyanidation pregnant eluate solutions prior to Merrill-Crowe recovery of gold and silver were tested for long term stability at Newmont Metallurgical Services. Sludge samples were mixed with heap leach residue to simulate disposal of the sludge in spent or active areas of the heaps and leached for twenty weeks with water and cyanide leaching solution, respectively. Leach testing results are presented as well as analysis of the sludge using scanning electron microscope techniques down to the <1000 nanometer scale.

Jan 1, 2007

By L. Voisin, K. Yamaguchi, D. G. Mendoza, K. Ltagaki

The behavior of arsenic and antimony in the Cu-0 system was thermodynamically investigated to understand their elimination during a blister-making stage in copper smelting. Firstly, the phase relations in a miscibility gap composed of the liquid slag and copper phases in the Cu-0-As and Cu-0-Sb systems at 1523 K were established by a quenching technique. It was found that arsenic and antimony distributed preferentially into the slag phase in the miscibility gap. Secondly, the activities of arsenic and antimony in the miscibility gap of these systems were determined at 1523 K by using a double Knudsen cell - mass spectrometer method. It was clarified that the activity of arsenic in the copper and slag phases showed the negative deviation from ideality while that of antimony in the copper phase a slightly positive deviation. These data obtained in this study suggest a possibility to eliminate arsenic and antimony by means of over-blowing in a converter after discharging the slag.

Jan 1, 2007

By A. Moyano

The development of the traditional converting process performed in a PeirceSmith or Hoboken converter is limited by the investment magnitude associated to the fulfillment of the environmental regulations. Thus, the continuous converting process rather than a conceptual process alternative is becoming a necessity for a smelter facing limited converting capacity and/or lacking of fulfillment of the environmental regulation with its maximum converting capacity. The objective of this paper is to present the progress of the Codelco continuous converting process evaluated at pilot-scale level when converting solid mattes or white metal into blister copper. These tests allowed for gathering of relevant data to be considered for a new stage of evaluating the Codelco continuous converting at industrial-scale test. The pilot-scale tests were done in a Teniente Converter pilot scale unit at the Codelco Norte Smelter. The results of processing solid copper mattes (65-75% Cu) and producing low sulfur content blister copper with production of a constant S02 gas concentration, and the production of liquid slag with low copper solubility was achieved and is discussed in the present paper.

Jan 1, 2007

By J. Pflieger

The International Iron and Steel Institute (IISI - http://www.worldsteel.org) has initiated the development of a comprehensive freely-available, internet-delivered package of highly interactive e-learning resources for undergraduate students and steel industry employees. The resulting e-learning environment (http://www.steeluniversity.org) creates a ?one-stop? shop covering all aspects of steelmaking, steel products and applications, the underlying scientific and engineering principles, industrial and academic collaboration, as well as environmental and sustainability issues relevant to the steel industry. The module entitled ?Sustainability, Steel and the Environment? of the steeluniversity.org provides interactive e-learning resources on the following topics - Sustainability. - Principles of Life Cycle Thinking. - Environmental Life Cycle Assessment. - Application of Life Cycle Assessment. The aim of this particular module is to enable the learner to identify relevant environmental parameters over the life cycle of steel products as well as to learn about the resulting environmental effects and impacts. Furthermore he/she will be enabled to explain the basic idea of Life Cycle Thinking and Life Cycle Assessment (LCA) in terms of Goal and Scope definition, System Modelling, Life Cycle Inventory (LCI), Life Cycle Impact Assessment (LCIA) and Interpretation. In addition, the learner can explore selected LCA scenarios facing the steel industry and its customers in the automotive and construction sectors.

Jan 1, 2007

By L Reynolds

The portable infrared mineral analyser (PIMA) was trialled to determine the extent and intensity of any hydrothermal alteration halo associated with gold mineralisation in the Hyde-Macraes Shear Zone (HMSZ) of the Otago Schist. &nbsp; Twelve diamond drillholes through the HMSZ were analysed with the PIMA at a sample spacing of 1 m. The drillholes were selected on two traverses along the line of strike and down-dip of the mineralisation in and around Panel 2 of the Frasers underground development. &nbsp; The study showed that the Hangingwall shear of the HMSZ has a more distinctive infrared signature in intersections with high grades. The Hangingwall shear in these drill holes is defined by a shift in the wavelength of the Al-OH absorption feature from ~2220 nm to &lt;2210 nm. This shift is attributed to a change in the mineralogy from phengite to muscovite. Overprinting this trend in some of the drillholes is the presence of the 2210 nm Al-OH absorption feature, ascribed to kaolinite. Kaolinite also tends to be present in numerous other regions of the schist above the Hangingwall shear associated with steeply dipping faults and foliation parallel joints. In drill holes with low grades the Hangingwall shear does not exhibit any obvious infrared signature. &nbsp; At the scale of study, the PIMA does not provide evidence for an alteration halo associated with hydrothermal mineralisation above the Hangingwall shear. Possible tectonic movement may have displaced any alteration halo that once existed, away from the zone of mineralisation. For this reason, PIMA apparently cannot be used for predicting the location of the Hangingwall shear during exploration drilling. However, the study did show that the PIMA could define the Hangingwall shear when the rocks were sufficiently altered and mineralised.

Jan 1, 2007

By J. Dienenthal

Automatic Charging and Stoking Machines for use at ferroalloy furnaces are in operation for more than 20years. Dango & Dienenthal Maschinenbau GmbH (short: DDS) has developed several machine generations. Today advanced solutions help to achieve better charging and stoking results to minimize cost and to improve the working environment around the furnaces. Three different alternatives can be considered: Rail-mounted solution The machine(s) travel(s) on an overhead monorail to one or several furnaces and is locked in the desired working position from where charging and stoking is performed. Mobile solution This machine travels on the charging platform and is also locked at the respective working position to perform charging and stoking. Automation of a standard mobile charging and stoking machine A standard charging and stoking machine can be adapted for automation. A reliable navigation system is included. Charging and stoking is performed with the moving machine. Advantage versus other solutions: considerable lower investment cost and possibility to upgrade the mobile charging and stoking machine for later automation. Overall, automatic charging and stoking can save up to 10 per cent of the specific smelting energy. A better and more consistent furnace operation can be achieved. Different programs are used to cope with different furnace conditions and changing raw materials. All machine movements can be recorded and correlated to other furnace parameters. Working environment on the charging platform is greatly improved.

Jan 1, 2007

By O. A. Bascur

Several new hydrometallurgical plants have been built in the past years, new processes and equipment as well as advanced process control systems are being used to deal with the increasing requirements of safety, quality and production. Plant Information Management Systems are now being recognized as a key infrastructure component of the plant, giving the management, the operators, process engineers, finance, maintenance, and regulatory agencies an integrated view of the operation and providing the links for the (increasingly) multidisciplinary organization. This paper reviews several implementations of Plant Information Systems; real time performance management infrastructure examples are reviewed as a key component of business strategies, such as Mine to Port Planning and Supervision, Metallurgical Mass Balances, Solvent Extraction Composition Statistical Process Control, methods to minimize organic losses, reduce variable costs and to improve metal extraction. Several examples are provided to illustrate how companies are using the real time and historical information from assets and metallurgical processes to enable and empower people to improve the operations quality, safety and throughput, as well as continuous improvement and innovation initiatives.

Jan 1, 2007

By W. K. Buah, R. K. Amankwah

Waste-activated carbon generated by gold ore processing plants that employ carbon adsorption technologies may contain very high gold values and represent a potential source of extra revenue. In this research, two methods that augment combustion of waste-activated carbon are evaluated. These are mechano-chemical activation and charcoal-enhanced ashing. It was found that mechano-chemical activation caused structural transformation of the waste carbon, which resulted in a reduction in the temperature for complete oxidation from above 700oC to 450oC. Complete oxidation was also achieved at the same furnace temperature, for a combined sample of waste-activated carbon and 50% by weight of wood charcoal. In both cases, gold was extracted from the ash by conventional cyanidation, with recoveries greater than 98% from a head grade of 3.2 kg/t.

Jan 1, 2007

By David Brown, Dirk van Dyk

Horizontal rotating mills are being used all over the world associated with different mineral and power generation industries. David Brown South Africa, with over 140 years of experience in gear manufacture and design, has been supplying these industries with innovative designs at exceptional quality. The gearing systems associated with these industries are challenged daily with operating conditions with are not always fully understood. Failures are therefore experienced, over time in the industry, which can therefore not always be fully explained. David Brown South Africa has developed a gear monitoring system, the Intelligent Gearing System, in association with Transmission Dynamics (UK), in order to monitor and analyze these operating conditions in real time. The system has been designed on the principles of Six Sigma, incorporating Design for Six Sigma. The purpose with this system design is to monitor the operating conditions on the pinion, record the information and analyze the data in relation to the rate of fatigue damage to the girth gear and pinion. This is done in real time and unattended. The output from the Intelligent Gearing System can be fed back into the operating system of the mill user, in order to display an alarm for operating conditions exceeding the design criteria as well as information on the rate of fatigue damage due to these operating conditions. When the mill operating conditions are better understood, and the effect on the fatigue life of the mill gearing components, mill users can forecast critical spare holding levels with an increased accuracy. The Intelligent Gearing System also allows early actions to remove reasons for system overloads.

Jan 1, 2007

While some of the practical details of ilmenite smelting are not well documented, there is a substantial body of literature on the principles of ilmenite smelting, and the behaviour of solidified titania slag. This information is summarized, focusing on the basic reactions, departure from equilibrium, the behaviour of impurities, and reactions of solidified slag. The emphasis is on the South African operations.

Jan 1, 2007

Over 800 mines have closed in Australia in the past 25 years. This paper summarizes the data obtained from those closures and includes all Australian States and Territories and all commodities, including metalliferous, coal and industrial minerals. Twenty five percent of the mines closed due to resource exhaustion or depletion; 24% due to high costs, price drops, or declining grades; 8% due to open pit resource depletion (but with underground reserves remaining) or underground reserves depleted (but plans to open cut remainder) and 7% due to receivership or voluntary administration. The environmental, social and economic impacts of these closures are also significant and include acid mine drainage and impact on mine employees. An understanding of the causes of premature mine closure will better equip mining companies and governments to better manage future mine closures, wherever in the world the mines are operating.

Jan 1, 2007

CFD (Computational Fluid Dynamic) models have been developed and validated for a pulsed column with disk-doughnut internals, as used for solvent extraction. First a single phase model was developed to simulate the turbulent oscillating flow around the internals of the column. This model was successfully validated using detailed PIV measurements of velocity taken at eight different phases through the pulse cycle. Second, the CFD model was extended to allow for a continuous aqueous phase and a dispersed organic phase (kerosene) flowing counter-currently. The model was a two-fluid model that accounts for droplet breakup and coalescence, and solves for droplet size distribution using a population balance model incorporated into the CFX4 package. PDIA (Particle Droplet Image Analysis) measurements were taken on a pilot scale solvent extraction pulsed column to determine droplet size distribution for calibration and validation of the CFD model. The measurements were made under pulsing intensities ranging from 10 mm/s to 32.5 mm/s.

Jan 1, 2007

By H. Do, R. Yoon

Mineral flotation is effective over a relatively narrow particle size range of approximately 10 to 100 µm. If the upper particle size limit can be increased, however, a run-of-mine ore may be coarse ground, and only the middlings are ground further to achieve required grades. This will result in significant energy savings and increased throughput. In this communication, methods of increasing the upper particle size limit will be discussed on the basis of a flotation model that can predict flotation from both hydrodynamic and surface chemical parameters. An example of increasing flotation recovery by control of a chemistry parameter is given.

Jan 1, 2007