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By D Kotzen

Online cyanide analysers have been successfully used to control free cyanide in the gold/silver leach process for over 15 years. Use of such analysers leads to cyanide savings and improvement in recoveries. Plants with leach cyanide analysers show both lower and more consistent cyanide levels in tailings. Cyanide code compliance requires meeting residual cyanide targets in tailings. Monitoring and logging of the residual cyanide in plant tailings and effluent is required. Meeting targets may require cyanide recovery/destruction processes to be implemented. The operating cost of destroying cyanide is often the same order of magnitude as the cyanidation cost. Various cyanide destruction and/or recovery processes are reviewed. Choice of a process consistent with the environmental and operational requirements is illustrated. Online weak acid dissociable cyanide (CNWAD) analysers have recently been developed and introduced on gold plants. The application of a WAD 1000 online CNWAD analyser at a large gold plant is presented. The analyser ensures code compliance, reduces cyanide destruction process operating costs and forms a historical record of CNWAD values in tailings.

Jan 1, 2007

By M. Zuckerberg, E. Mader, R. Pasyar

We describe a new software product designed for the net present value optimization of multi-open-pit blended ore operations in which it is desired and/or necessary to dump some or all of the waste rock produced in the course of operations back into the voids created in the process of ore extraction. The software product simultaneously decides over the entire life-of-mine which material to mine in which year, once mined what to do with it, and where to put that material which it has decided to waste, all subject to annual blend and capacity constraints.

Jan 1, 2007

By I. Cifuentes

Chemical and physical characterization of copper electrodeposits obtained on mesh and plate cathodes in conventional and reactive electrodialysis lab-scale cells have been carried out. The effect of Fe, Mn, Cl and guar on electrodeposit composition and morphology were determined by means of metallographies, scanning electron microscopy (SEM), atomic force microscopy (AFM), inductively coupled plasma mass spectrometry (ICP-MS) and Auger electron spectroscopy (AES). Each impurity influenced the deposit morphology in a different way (e. g. grain size, surface roughness). AFM proved to be a very effective tool for quantifiying and classifiying surface quality.

Jan 1, 2007

By Steven K. Duke, Jay Arabshahi

An economic, real-time probe drill monitoring system was developed for Metropolitan Water District’s Arrowhead Tunnels project to quantitatively evaluate ground conditions ahead of a TBM. This system digitally records hydraulic feed, rotation, and percussion pressures and calculates drill advance rates during drilling. These data are computer synthesized to develop a digital representation of the ground ahead, and the resulting “picture” of the ground is distributed to the project team to assist with tunnel construction decisions (i.e., targeting grout holes, optimizing mine-cycle lengths, and avoiding becoming stuck). The analysis and interpretation procedure has now been calibrated and refined using over 5,000 m (3 miles) of geologic face mapping data.

Jan 1, 2007

By A. H. Mumin, A. K. Somarin, K. S. Oran

"Synvolcanic structures played a fundamental role in the genesis, morphology, and siting of volcanogenic massive sulfide ores and associated hydrothermal alteration in the Archean South Sturgeon Lake caldera complex. The most voluminous and persistent hydrothermal venting and massive sulfide deposition occurred along synvolcanic rifts and grabens associated with faults and tectonic fissures that created permeable fracture zones deep enough to access the underlying hydrothermal reservoir. The type of fracturing is highly variable and changes with the composition, competency, degree of consolidation, and alteration of host rocks. Synvolcanic structures and fracture styles also vary according to the amount and type of tectonic movement, including extension-related collapse, shearing and faulting perpendicular to the principal direction of extension, and orthogonal faulting and shearing. Permeable conduits were created by tension fracturing along fault zones, brittle deformation at the intersections of orthogonal faults, and by extensional fractures in stockworks. In texturally uniform footwall rocks, the distribution of alteration zones was controlled by the morphology of the structural conduit. In rocks with vertical and/or lateral facies, permeability, and competency changes (e.g., Lyon Lake graben), there was an additional stratigraphic control over fluid migration. Some crosscutting synvolcanic structures, alteration zones, and intrusions appear as stratiform units at the present erosion surface due to regional deformation and the present attitude of the volcanic stratigraphy.Hydrothermal mineral assemblages (e.g., quartz, carbonates, chlorite, pyrite, chalcopyrite) infilling structurally induced fractures provide good evidence of fluid migration pathways. However, mineralogy can vary significantly according to the fluid characteristics, host rock geochemistry, and subsequent metamorphic history of the area.Clearly, one of the best methods for locating volcanogenic massive sulfide deposits is to delineate the attitudes of synvolcanic structures, and explore those that show evidence of associated high-temperature hydrothermal mineral assemblages. Excellent exploration targets occur where synvolcanic structures with hydrothermal alteration intersect paleo-seafloor horizons."

Jan 1, 2007

By S. Gößling-Reisemann

Most copper ores contain valuable co-products such as molybdenum, gold, silver, nickel, etc. Sulphuric acid and steam are valuable by-products, which are generated dur¬ing copper production. The environmental impacts from mining and refining therefore need to be shared between these by-products and co-products, an issue in Life Cycle As¬sessment (LCA) referred to as allocation. There are different, recognised methodologies for doing so: burdens can be allocated based on the market values of these commodities, they can be allocated by mass, volume, molar amount, functionality, or other physical, technical or economic factors. All of these methodologies have their respective merits and restrictions, and the choice is usually case specific. Nevertheless, the choice between alternative methodologies can have dramatic effects on the LCA results. Recycling in LCA has to be handled in a similar way, as it essentially constitutes a special case of co¬production. The existing standards (ISO 14040 ff.) allow different methods for imple¬menting recycling and allocation into metal LCAs (open loop, closed loop, value cor-rected substitution, etc.), which are still a subject of discussion in the scientific community. However, the methodology used can significantly influence the ecological profile of copper and copper products. We will present an overview of the different methodologies available for including recycling and allocation and give an analysis of how the meth¬odological choice affects the final LCA results. This work will be followed up by quantitative case studies.

Jan 1, 2007

By N. Vayenas

Modern mines possess a wide variety of capital intensive equipment. Equipment failures and the associated down time contribute significantly to the overall maintenance, operating and production costs of a mine. Reliability investigations are becoming a standard practice, as the equipment becomes more complicated and the effective use of resources is critical for achieving higher productivity and mine safety. In view of the recent global initiative for sustainable development in the mineral industries, reliability of capital intensive machinery should be considered as a key indicator for sustainable development and growth. This paper discusses the application of equipment reliability as a sustainability indicator and proposes a methodology for its practical use. Reliability of equipment systems is useful for product life cycle assessment, mine performance measurement and evaluation.

Jan 1, 2007

By G. L. Spence

Prevention of cuprous and cupric oxide formation on stored ETP copper rod is a major concern for copper rod and wire producers. During normal storage periods copper oxide layers can increase from less then 100 A to more then 1000 A exceeding ASTM specifications and discoloring the rod surface. Various types of corrosion inhibitors are tested and compared in effectiveness for prevention of copper oxide formation on stored copper rod. Aromatic triazole compounds are also compared to a non-azole containing compound.

Jan 1, 2007

By Q-c Li, G-l Gao

Cyanided tailings produced by gold processing operations may cause environmental problems, because they contain pollutants such as arsenic, sulfur and cyanide compounds. Moreover, tailings containing economic metals such as Au, Ag, Cu, Pb and Zn, are potentially valuable resources. In this article, cyanided tailings are catalytically oxidised by nitric acid in the presence of air or oxygen. The resulting solids may be leached to recover Au and Ag. The solution can be used to prepare ferric sulfate or iron pigment. Gases released in the reactions were recycled and reused by oxidation and absorption. All of these greatly improve metal recovery and the reuse prospects of cyanided tailings. Under the following conditions where the initial temperature of oxidation is 80¦C; initial concentration of nitric acid is 30 per cent (by weight); feed proportion (nitric acid to cyanide tailings mass ratio) is 3:1 and reaction time is two hours, the conversion ratio of cyanided tailings is 90.06 per cent. At the same time pyrite in the cyanided tailings is oxidised effectively, gold recovery is as high as 92.3 per cent and nitric acid loss per cycle is only five per cent because of NOx recovery.

Jan 1, 2007

By G. Whittle

An important aspect of the project evaluation process is the achievement of a clear and quantitative understanding of the primary drivers influencing project value and risk. A business scenario-based approach is required to ensure that the project meets value and risk hurdles over the short, medium and longer term. Adopting an optimising approach can aid significantly in the development of a project concept into a business that is optimal and sustainable in the longer term. Through the application of case studies, based on work performed with various mining organisations during the last five years, this paper will demonstrate how project value and robustness can be optimised. Experience has demonstrated that applying this approach results in significant value improvements and risk reduction - primarily by application of a rigorous, fact-based analysis and optimisation process that rapidly increases management team understanding and insight of key driver of value and risk.

Jan 1, 2007

By A F. Cooper

The northeast-southwest trending ~25 km2 area incorporating Bald Hill is located 18 km northeast of Haast, and 5 - 7 km west of the Alpine Fault in South Westland, New Zealand. The geology consists of Greenland Group greywacke overlain by a Cretaceous-Tertiary sedimentary sequence and fluvio-glacial/marine terrace deposits of Quaternary age. Alluvial gold in Cole Creek, draining west from the summit of Bald Hill, may be derived either from vein mineralisation in basement rocks or from fluvial or marine terraces.   This paper focuses on the potential for in situ gold and base-metal mineralisation in sporadic, siderite-rich quartz veins that cut basement greenschist facies metasediments that have been overprinted by contact metamorphism.   Throughout the area, vein compositions are dominated by quartz and commonly feature zoned plagioclase. Alteration adjacent to veining within the contact aureole is dominated by 1 - 2 mm, coarse grained biotite, with small amounts of sulphide, and is pervaded by abundant siderite veinlets. Outside the aureole, wall rock alteration to veins consists of fine grained chlorite. Trace element XRF analysis has been used to ascertain base metal concentrations within samples of vein and alteration zones collected from throughout the area. Vein and alteration zone mineral assemblages containing <5 per cent sulphide, with low concentrations of As, Cu, Pb and Zn indicate low potential for gold and base-metal mineralisation in the Bald Hill region. Contact metamorphism of Greenland Group basement in the northeast of the region, is likely due to emplacement of a poorly exposed Cr- and Ni- enriched gabbro. The presence of biotite and andalusite in hornfelses indicate contact metamorphism occurred at temperatures >350¦C and at depths <10 km. Widespread vein distribution does not appear to be related to contact metamorphism or gabbro emplacement. Further research is required in order to establish the fluid source from which the veins were precipitated.

Jan 1, 2007

By G. Tranell, L. Kolbeinsen, S. Gaal, J. Safarian

The effect of carbon material properties on the rate of MnO reduction from ferromanganese slag by solid graphite was investigated. A sessile drop technique was used to study the reduction rate of a synthetic slag containing 45 wt% MnO at 1500 and 1600 ºC. Different types of graphite substrates were used and the con-tact angle between slag droplets and substrate were measured in-situ. Moreover, the slag droplet volume during the interaction with the graphite substrates was calculated and normalised. The mathematical relationship between the slag density during the reduction and the normalised slag droplet volumes during the reduction were derived and the MnO reduction curves were then calculated. A method for measuring the slag reactivity of solid carbon was defined and used to qualify the propensity of the different graphites to react with the liquid slag. Some supplementary studies such as manganese evaporation measurement and EPMA analysis for determining the extent of MnO reduction were also carried out. It was observed that there is nota significant difference in the wetting angle of the graphite substrates by the slag, and the wetting is not changed within the temperature range of 1500-1600ºC. However, the changes in the contact angle during the slag reduction at 1600ºC are more than at 1500ºC. The kinetics of MnO reduction is dependent on the type of graphite and it is more dependent on the graphite properties at lower temperatures. On the other hand, the dominant properties of graphite on the reduction rate vary with temperature. A multivariate analysis on the graphite properties and the parameters related to the slag reactivity indicated that the kinetics of MnO reduction is mainly dependent on the temperature, and then on the graphite properties. It was also found that at1500 ºC the surface area and the CO2 reactivity are the most important graphite properties for the slag reduction, suggesting that the reactivity of carbon is rate controlling at 1500 ºC. However, the porosity related parameters are the most important graphite properties at 1600 ºC, suggesting that CO gas desorption is rate controlling at high temperatures.

Jan 1, 2007

By E. J. M. Jahnsen, I. Jauhari, T. Badrujaman, F. A. Stober, B. O. Wasmund, L. R. Nelson, T. Miraza, J. M. A. Geldenhuis, A. Taofik Hidyat

The role of dedicated operational support in the ramp-up and stabilisation of the FeNi-II furnace for ferro-nickel production at PT Antam?s smelter located in Pomalaa, Indonesia is described. The furnace was uprated to 32MW capability in a rebuild performed in 2005. This primarily involved installing a larger transformer, coupled with adoption of HATCH water-cooled copper plate, waffle and flanker coolers with integrated metal and slag tapblocks, HATCH air-cooled copper fin lower sidewall cooling and HATCH vertical sidewall binding system ? ?holddowns?. Following a smooth commissioning period, the progress in attaining the preliminary ramp-up target load of 24MW is described. This initial target was set by Antam, subject to some prevailing smelter equipment constraints, particularly kiln capacity. Stabilisation of the furnace operation is discussed, together with some of the specific commissioning and operational challenges surmounted by the joint Antam-HATCH team. These included: ?Mastering furnace integrity monitoring and operation with copper coolers, especially metal tapblock planned maintenance and repair strategies; ?Transition from traditional ?immersed electrode? to ?brush-arc? mode of operation approaching as closely as possible to the productive ?shielded-arc? mode of operation within existing equipment constraints; ?Reductant selection and control issues; ?Utilising the sophisticated furnace monitoring to provide detailed indication and warning of potentially destructive furnace upset conditions such as Si reversion and CO boils.

Jan 1, 2007

By B. Nanthakumar

The impact of stockpile oxidation on chalcopyrite was studied through collectorless and collector-induced flotation conditions. In both cases, the Cu grade-recovery performance of stockpiled ore showed relatively poor concentrate grades with respect to that of a fresh sample. However, the oxidation had a minor effect on chalcopyrite recovery itself. The poor concentrate grades resulted from dilution effect primarily by excessive flotation of pyrrhotite. Size-by-size analyses indicated that for the collectorless flotation, the recoveries in the coarse and fine particle-size regions, were higher for fresh ore than for stockpile sample. A greater impact was seen in the coarse size regions for both types of sample, compared to the collector-induced case. The Cu recoveries showed a remarkable increase in the coarse size range for both samples when a collector was used. However, the case for stockpile sample was a marginally higher compared to the fresh sample. This difference has been offset by an opposite trend that was observed between these two samples in the fine size region. It is concluded that in contrast to the case with nickel-bearing sulphides, stockpiling conditions do not show a significant adverse effect on behaviour of chalcopyrite due to its strong floatability, regardless of oxidation.

Jan 1, 2007

By T Raynlyn, J J. Campbell, J M. Young

In order to correctly predict the performance of beneficiation processes, such as hydrocycloning or ultrasonic treatment of iron ore fines, it is important to understand possible changes in size distribution, mineral composition and textural peculiarities. During beneficiation processes, iron ore can be subjected to various physical actions which may result in changes in size distribution. In the case of soft or friable ores, attritioning and/or deagglomeration may have a significant effect on both separation performance and product stream specifications. Optical image analysis tools, which give statistical information on a particle by particle basis, can help in better understanding the response of the ores to these processes. An experimental study has been conducted to investigate the response of a haematitic-goethitic iron ore to a combination of stirring and ultrasonic treatment. The effect of stirring and ultrasonic treatment on the size and mineral distribution has been quantified using image analysis and automatic ore texture classification. This approach has been applied to several size coarse fractions of the initial feed and product. The results show that, following treatment, the mass proportion of ore texture classes which contained higher amounts of ochreous goethite and kaolinite had significantly decreased compared with that in the feed, while the proportion of texture classes where haematite was the major mineral had increased. Liberation analysis also showed a significant increase in the proportion of particles with more than 95 per cent haematite and vitreous goethite.

Jan 1, 2007

By T. Maruyama

Tamano Refinery started its operation in 1972 with the cathode production capacity of 84,000 tons per year. After several expansions, the production capacity increased to 228,000 tons per year in 2001. In this paper, we are introducing our next expansion projects starting October 2006. The project expands the production capacity of cathode from 228,000 tons to 260,000 tons per year. The main modification of this project is the conversion to the ISA process and the installation of additional seventy-two cells in the No.2 Tankhouse. The No.1 Tankhouse remains the same, using the conventional process. Half of our starting sheet cells are converted to commercial cells. The other expansions are to enlarge our purification plant. And the incidental facilities are enlarged, for example, circulation tanks, heat exchangers, filtration system, etc. Finally, this paper describes those improvements to our refinery performance and preparing for future expansions.

Jan 1, 2007

By T. C. Alex, K. M. Godiwalla, R. K. Jana

Manganese nodule, available in ocean beds, is a potential resource of the future for copper, nickel and cobalt. Recovering only these metals, containing less than 3% by weight, will result in the generation of large amount of residue. In addition to the material losses, several environmental and ecological problems arise out of this. The present study has been aimed at reducing the environmental and ecological problems associated with massive generation of this residue together with utilization of the resources. Presence of ~ 20% manganese and ~16% silicon in the residue has prompted us to check its suitability as a raw material for silicomanganese production. Lower manganese content and lower Mn/Fe ratio of the residue than that required for silicomanganese production has been corrected in this study by suitable blending. The efficacy of blending and its thermodynamic aspects using FACTSAGE software are discussed. The studies conducted indicate viability of bulk utilisation of the residue through silicomanganese production and thereby reducing the burden on environment to a great extent.

Jan 1, 2007

The heap leaching of base metal ores can be applied within a number of different scenarios, each requiring its own set of parameters to be determined during the metallurgical testwork programme. The occurrence of acid-gangue reactions and its concomitant precipitation reactions is a factor common to all cases, and requires that the optimal irrigation acid strength be found that optimises the combination of extraction kinetics, acid consumption and possible premature blinding of the heap due to precipitation reactions. For the heap bioleaching of base metal sulphide ores the oxygen requirement needs to be determined for the design of the aeration system, and the operating conditions employed need to also facilitate bacterial growth over and above the acid strength optimisation mentioned above. For the heap bioleaching of chalcopyrite, the need to preserve heat in the heap becomes yet a further parameter of critical importance. For the heap leaching of uranium ore a choice is required between either chemical or bacterial oxidation, based on economic and processing factors. Frequently the operating parameters need to be determined for a circuit in which heap leaching is combined with tank leaching and/or pressure leaching. The processing implications and metallurgical testwork approach for each case is discussed.

Jan 1, 2007

By Terri Jordan, Kenneth Hollingshead, Mary Jo Barkaszi

The Port of Miami, Miami-Dade County, Florida (Port) is the largest container port in the State of Florida. However, it is located in the center of a diverse ecosystem. Biscayne Bay surrounds the Port and portions of the bay have been designated as a National Park, a Florida Aquatic Preserve and a state Critical Wildlife Area. The bay is home to many protected, threatened and endangered species including the Florida manatee, five sea turtle species, American crocodile and bottlenose dolphin, in addition to important recreational and commercial fish species.

Jan 1, 2007

By S. Orzecki

The KGHM Copper Refinery Plant, Glogów 1, has operated for 35 years and -increased its capacity almost ten times.Cathode quality, expressed in terms of the total impurity content, has undergone a five-fold improvement. The present refining capacity is equivalent to 240,000 metric tonnes of copper cathode, with a total impurity content of 20 ppm, inclusive of 10 ppm Ag. These accomplishments result from combined implementation of current technological progress in electrolytic refining and KGHM's own solutions applied to the Glogów Refinery. The quality improvement measures feature both lowering actual current density, despite an increase in nominal current density, and diminishing the role of non-ion mechanisms which transfer impurities to cathodes. The paper contains a detailed discussion of these issues and outlines possible measures aimed at further production and quality improvements.

Jan 1, 2007