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By David R. Sadedin

The highly negative Gibbs free energies of hydrogen atom reactions suggest that refractory oxides such as titanium dioxide should be easily reduced by hydrogen atoms. These reactions appear to be most favourable at low temperatures; oxides should be reducible even at room temperature. Since hydrogen atoms are produced in plasmas containing hydrogen a number of investigators have used hydrogen plasmas of various sorts to test these possibilities for reducing refractory oxides, in particular TiO2. None of these attempts has succeeded, a small degree of reduction being achieved in only a thin layer near the surface. A deeper consideration shows that several factors complicate the reactions expected on the basis of the negative Gibbs free energy. One factor is that the back reaction by water molecules produces molecular hydrogen, not hydrogen atoms, and the metal atoms that have been reduced may be immediately re-oxidised. In plasmas there are complications due to diffusion, thermal and charge boundary layers and charged particle reactions. Interpreting the results of hydrogen atom reactions is difficult. Hydrogen is not detectable by electron dispersive spectroscopy and amorphous products are not determinable by x-ray diffraction. Another consideration is economics. The cost of producing hydrogen atoms has a large bearing on the metals for which hydrogen atom reduction may be competitive. In this paper these factors are discussed, some necessary basic studies are highlighted and the general principles of a laboratory reactor are given, together with the results of tests using ZnFe2O4, ZnO and TiO2 as test oxides.

Jan 1, 2006

One of the most frequently asked questions at the feasibility study stage of a project is, æhow big can one go?Æ This important question effects costing and efficiency of metallurgical equipment, the real estate required and the operating plant strategy.The presentation covers both engineering and process considerations and explains the limits that exist today and explores future trends.The paper is specific about large slurry application usually found in gold applications; however, it could apply to silver and uranium or other dense media leach duties.Agitator drive sizes are examined as well as process risks associated with large tank agitation. New technology has increased the maximum tank size and designers are now experienced in tank volumes in excess of 5000 m3. Tanks of 6000 m3 have been agitated and 10 000 m3 tanks are within present engineering know-how and scale-up.Fabrication techniques for shaft and impeller designs exceed the existing standards and new specifications will be needed to cover large mixer design. The paper covers certain aspects of mechanical design and proposes alternative standards that are more appropriate. Process considerations such as fluid natural frequency as well as typical superficial velocities for efficient operations are examined. Scale-up techniques based on existing and new technology are also examined to ensure a successful installation.The presentation therefore covers the majority of large mixer design questions that are frequently asked.

Jan 1, 2006

By Moo Eob Choi

The reduction of iron oxide particles by hydrogen is one of the most widely investigated gas-solid reactions. The search for new methods for producing iron by the direct reduction of iron oxide has resulted in a large number of exhaustive studies of the various aspects of this reaction. However, previous studies have largely been done with either pellets or lump ores. Little has been published on the hydrogen reduction of very fine concentrate particles smaller than 37 µm (-400 mesh). The kinetics of hydrogen reduction of fine iron oxide concentrates were investigated in the temperature range of 900 - 1300°C.

Jan 1, 2006

By R Norris, M Dunne

Mining and mineral processing is expected by society and obliged by law to operate in an environmentally friendly fashion, minimising the impact on and avoiding damage to the environment. Substantial efforts by the industry, as well as by process and equipment designers have resulted in many innovative developments, which show that operating in an environmentally responsible manner can be achieved in a cost-effective way. This paper showcases five emerging equipment best practices in industry including installation examples. Flip-flow screening machines are proven worldwide in the dry classification of coal and other minerals, reducing the size of beneficiation plants whilst reducing energy, water demand and media consumption. They also allow the screening of wet/sticky materials not able to be sized using conventional screens. The belt press filter is a small fraction of the operating and capital cost of alternative dry tailings technologies. This gives operators who must dry their tailings a competitive advantage and makes such ægreenÆ operations much more sustainable. The filtercake is disposed with other plant rejects, eliminating the need for tailings dams to be constructed and thus also often increasing mine reserves. Mining applications include coal tailings, sand tailings, sinter plant waste and power station fly ash. Screen-scroll and vibrating centrifuges are widely used in the coal, potash and salt industries to dewater the product to low surface moistures. Inclined plate Lamella separators are used for toxic water clarification and/or sludge thickening in many downstream metal industries with the underflow often dewatered in a belt filter press. Such low cost, high capacity thickeners could also be used instead of conventional thickeners at smaller mines. The simple and reliable continuous washing upward flow (CWUF) sand filters have been used for treatment of waste water from coal preparation plants and steel works as well as in the worldwide production of potable water. The filtered waste water from mining processes can then either be reused or discharged from site. Other installations include cleaning mine water to prevent the blocking of dust suppression spray nozzles.

Jan 1, 2006

By Art Cooper

Granulation systems are customarily viewed as problem areas in metallurgical operations. The inherent risk of explosion when combining a high temperature melt with water creates a safety hazard. Separation of the granulated material from the quenching medium generally involves equipment that can have significant maintenance and operating costs. Granulation systems' reliability and availability can negatively affect the plant production. Against this background, granulation systems have been treated by design firms and producers as an add-on and a necessary evil. The technology is becoming better understood and solutions to common problems are being found. This paper will discuss typical problems in common systems, and some of the improvements that have been made, with particular reference to non-ferrous applications.

Jan 1, 2006

By Du Sichen

The present paper presents the modeling of gas-solid reactions in the case of the decomposition of CaCO3, describing the reaction kinetics on the basis of heat-transfer concepts which could be compared with thermogravimetric results. In the case of solid-solid reactions, the present paper describes the model developed for describing solid-solid reactions from dynamic X-ray diffraction technique, developed by the present team. The model has been successful in explaining the formation of spinel from MgO and Al2O3.

Jan 1, 2006

By O. Naiker, T. Riley

Keywords: Pyrometallurgy, furnace, Xstrata, ferrochromium, Premus Technology The presentation will give a basic overview of Xstrata Alloys. Included will be a brief history of the Alloys division as well as of each plant within the division. The Xstrata chrome plants utilise a wide variety of production processes, including Xstrata's Premus process, the Outokumpu process, and the conventional process. Xstrata?s Lion Project is underway, with commissioning expected in the third quarter of 2006. The new smelter will utilize Xstrata?s patented Premus process, and the competitiveness of the Premus process is discussed.

Jan 1, 2006

By Charlie Adcock, Rob Farnfield, Andy Wetherelt

The ISEE Blasters Handbook gives guidance on the level of air overpressure likely to cause occasional window breakage (151dB) and general window breakage (171dB). A long-term safe level of 140dB is also suggested. This guidance is widely used by demolition and other contractors to assess damage zones in the region of explosive applications employing unconfined charges. Other reference material gives more detailed guidance relating to window area, aspect ratio and glass thickness. Despite the guidance given in these references, complaints by members of the public regarding window breakage continue to be received by explosives engineers from air overpressure levels well below the longterm safe limit. Such complaints are not limited to the use of unconfined charges but can even be generated from the highly confined use of explosives in quarry blasting. This paper describes a series of experiments with explosive charges fired in unconfined conditions close to various window configurations. The aim of the work was to test the existing guidance levels and to extend the knowledge base in this area. Topics covered include the role of differential pressure across windows in the walls of an enclosed space such as a room.

Jan 1, 2006

By Joachim Lemke

The stainless steel sheets of permanent cathodes at Norddeutsche Affinerie (NA) were damaged by corrosion after nearly 11 years in operation. The necessary raising of the strength for stripping the copper had increased the deformation of the stainless steel blades. Current efficiency declined. After investigating the possibilities, like buying new cathodes or treating the steel surface, i.e. by sliding, a repair process was developed whereby the stainless steel sheet was exchanged. Special laser technology for cutting used blades und welding new stainless steel sheets underneath the used hanger bar was applied because the energy input into steel is the lowest of all welding methods. The new stainless steel sheet was welded with the rolling line in a horizontal direction. The achieved flatness of the repaired cathode blades amounted to less than 4mm per meter. During 11 months NA repaired nearly 36,000 permanent cathodes and put them back into operation. Repair costs were much lower than the costs of buying new ones and current efficiency increased again to more than 96% with a current density of 340 A/m².

Jan 1, 2006

By James F. Kvitkovich, George V. Weisdack

Editor’s note: This is the second part of a two-part series on longwall mining in the United States. Part one was published in the December 2005 issue of ME (pp. 21-26). It provided a history of longwall coal mining in the United States. It also discussed the technology involved in the productivity gains and operational improvements. Boyd anticipates that U.S. coal production will increase by 61 Mt (67 million st) (6 percent) from 2004 to 2010. A combination of higher surface and underground mine production will be required to meet the projected market demand. Boyd’s projections of coal production by major mining methods are shown in Table 1.

Jan 1, 2006

By I. Tsolas

This paper presents the use of the Jaggi-Freedman model for deriving composite environmental sustainability indicators at the mine level (i.e. indicators which focus on both the environmental and economic dimension of the sustainable development) using environmental, economic and/or integrated indicators (i.e. indicators which inter-relate two dimensions of sustainability). The derivation of composite environmental sustainability indicators by means of the Jaggi-Freedman model concerns the South-Field lignite mine of Public Power Corporation (PPC) in Western Macedonia. In the light of the results of the present paper it is evident that the performance of South-Field mine, during 1986-1990, was the exclusive domain of large production yearly activities. The considerably low indicators? scores during the 1986-1987 period are attributed to the increased environmental impacts and electrical energy consumed. The merit of this framework is that it can be used both internally, for benchmarking purposes and externally, for sustainability reporting.

Jan 1, 2006

By Qingxiang Huang

Shallow seam coal field has the largest coal reserve in China. Mining in shallow depth causes serious problems. One of them is subsurface dewatering. In this paper, the physical simulating model was performed to study overburden movement and aquiclude stability in the shallow seam mining of Yushuwan coal field, China. According to the characteristic of clay aquiclude in the overburden, the proper simulation materials and proportions of mixture for simulating the plastic clay aquiclude layers and brittle bedrock layers were determined by the stress-strain tests. The physical simulating model was carried out to simulate the failure and caving process of the roof and overburden. Based on the simulating tests, it was found that the movement of clay aquiclude follows the movement of the underlying bedrock layers. The basic caving mechanism of the overburden roof strata was also presented. The tests also showed that the best way to control the stability of aquiclude is to reduce the subsiding gradient Ts. This research provides a foundation for further study on mining dewatering and water conservation.

Jan 1, 2006

By Chai Liyuan

Chromium-containing slag was detoxified by the method of microbial treatment using Ch-1bacteria isolated from nature by our research group, belonging to achromobacter sp. and with the characteristic of reducing high concentration of Cr(VI) in alkaline solution. The detoxifying process of Ch-1 to chromium-containing slag was studied by column-leaching techniques respectively. The results indicate that Cr(VI) in leachate can not be detected when chromium-containing slag has been column-leached for 7 days, and Cr(OH)3 content in precipitate is up to 32.8% with great value of resource recycling. Flowchart of engineering experimentation was ascertained based on the parameters of column-leaching experiments. Using the technique of pelletization of chromium-containing slag heap-leaching by Ch-1,the leaching rate of water-soluble Cr(VI) existing in chromium-containing slag reaches up to 100%, while the leaching rate of full chromium is up to 90%, when the process has been operated for 7-10 days under the conditions of 25-40C and consecutive spray by circular leachate. The content of Cr(VI) in chromium-containing slag after detoxified meet the national identification standard for extraction procedure inxicity for hazardous wastes(GB5085-1996) in China, moreover approximately 90% of Cr(VI) existing in chromium-containing slag has been recycled.

Jan 1, 2006

By N. Schreithofer

The deposition of octadecylamine (ODA) at the KCI crystal/NaCI-KCI brine interface was investigated using atomic force microscopy (AFM). The AFM images of freshly cleaved KCI specimens immersed in KCI-NaCI saturated brine at room temperature reveal disappearance with time of the atomic steps and formation of cubic NaC1 crystals. These crystals were found to form when the specimen was withdrawn from the saturated solution. Depending on the way of contacting the specimens with the octadecylamine dispersion, the AFM images show huge differences in the deposition patterns of ODA on KCI crystals. Adequate dispersion was found to help the formation of quite even ODA coverage. The coverage was several monolayers thicker when air/brine/solid contact took place, suggesting that in the potash flotation the collector is likely to be carried to the solid surfaces by air bubbles. The presence of methyl-isobutyl carbinol (M IBC) enhanced the dispersion of ODA in brine, thus helping the spreading of the surfactant on the KCI crystal surface.

Jan 1, 2006

Mine pit slopes in the Pacific Rim are a geotechnical challenge because of the complex geology in which they are developed. Mines are currently being fast-tracked to meet the increase in commodity prices, often resulting in some reduction in ground studies and short-cutting of design procedures. In addition, the resources boom means that skilled personnel are in relatively short supply. At a time when mine pits are getting bigger and deeper, and the engineering is getting more demanding, there is an increased demand on managers to effectively implement the work.   Experience both in New Zealand and the Philippines, display the complex range of geological environments in which pits are being excavated. Working in these conditions has shown that successful geotechnical design requires a strong geotechnical model based on sound geology. An appropriate level of investigation and analyses results in a certain level of understanding for the mine design. There is a point where additional expenditure (on investigation and analyses) is not warranted based on the expected minimal impact on decreasing the level of perceived risk on the project. For most projects in our experience the analytical methods and complexity of geotechnical assessment changes increases as the level of knowledge grows.

Jan 1, 2006

By V. Arslan

In this study, effects of the inert constituents, such as ash, and the effect of blending coals with differing rank and composition on the plasticity of coal blends were investigated. The reference coal originated from the Zonguldak region, in the north-west part of Turkey. Firstly, the effect of coal ash on the plasticity of Zonguldak coal was determined. Secondly, the relationship between the plastic properties of the individual coals and those of the blended coals were identified. Some important relations were found, related to the characteristics of the individual coals. Ultimately, the manner in which the plasticity of Zonguldak coal was affected by blending with low volatile coals was investigated. Keywords: coal blending, coal plasticity, coke, fluidity, rank.

Jan 1, 2006

By Raj P. Singh

Two design-of-experiments studies were carried out to investigate the leaching of technical grade molybdenum tri-oxide (TGM) in the presence of hydrochloric acid and the mother liquor of ammonium di-molybdate crystallization used as an ammonia source. Results indicated that leaching of TGM in HCl is possible only when used at about 1N concentration. In high concentrations of HCl, technical grade MoO3 had very high solubility (7.5 to 40 g/L Mo). The most suitable conditions for HCl leaching of TGM were obtained at a slightly elevated temperature of 80°C. Using about 1N HCl at 80°C, potassium in the leached solids (TGM) decreased to about 110 ppm, a value typically obtained in TGM leached in HNO3 - NH4NO3media (3.5 - 4.0 moles /L HNO3 + 0.5 ? 1.0 moles/L NH4NO3). Mo losses under these conditions were 0.8-0.9 g/L Mo. The HCl-leach method, presented here-in, has a significant advantage in chemical cost and environmental benefits over HNO3 ? NH4NO3 purification method.

Jan 1, 2006

By David R. Beadman

The Fleming method is widely used for the analysis and prediction of single pile behaviour under maintained loading. The method does not distinguish between bored and driven piles. Driven piling avoids the need to dispose of spoil from the pile installation and is therefore becoming increasingly attractive. This paper considers the theoretical effects of the possible preload at the base of a driven pile after installation, using the hyperbolic functions as defined by Fleming. The Fleming method is reviewed and the equations and analyses are adapted, using spreadsheets, to allow for a possible preload. The simplifying assumption of the effect of the elastic compression of the pile is also reviewed and a more analytical method adopted to assess the elastic compression. Some driven pile test data is analysed to consider the possible effects of the preload on the performance of a driven pile and to test the theoretical relationships that are developed in the paper.

Jan 1, 2006

By Thomas J. Weaver

Piles extending through soft soil near the ground surface will have a relatively low lateral stiffness. As a result, lateral serviceability limits may control the number of piles required for foundation support. Improving near surface soil properties may significantly increase lateral pile stiffness and thus reduce the number of piles required for the foundation. A series of analyses have been performed to assess the depth and lateral extent of soil improvement required to significantly increase lateral foundation stiffness. Analyses consisted of Winkler type beam on a spring foundation and three-dimensional, linear elastic finite element analyses. Results from the analyses show that lateral pile foundation stiffness can be doubled when soil properties are improved to a depth and lateral extent of 5 pile diameters. In order to achieve this increase in foundation stiffness, the modified/improved soil modulus of elasticity needed to be approximately 5 times greater than adjacent unimproved soil. This magnitude of soil improvement over such a limited lateral extent suggests that limited soil improvement can result in more economical foundation designs at soft soil sites.

Jan 1, 2006

By Wang Youlai

Sichuan province is the richest province for its waterpower resource in China, perfectly suited to develop a high consuming energy industry. Sichuan Aostar Group Company has two Aluminum smelters, Guangyuan Aostar smelter and Sichuan Aostar Smelter. The production capacity of Aostar Group was 240,000 tons in 2004. The construction scale of Sichuan Aostar Aluminum smelter is 250,000 tons per year. The first 168 GY-300KA pre-baked anode cells (125,000 tons/year) were put into production in 2003. This company has taken the lead in the use of the transfer gantry technology in China. Besides making the process of calibration the pot shell it has concentrated the efforts to construct cell lining elsewhere. This company also has taken the lead in China for using the EIRICH force mixing and cooling technology as well as in the world for the CP Company?s vertical ball mill technology that produces the pre-baked anodes. The carbon anode system completed its 190,000 tons/year production scale. This is the most advanced technology and the biggest scale pre-baking anode manufacture in China. Since the Sichuan Aostar 300KA cell was put into production, it runs normally and smoothly. Up to now the current efficiency is higher than 94% and the specific energy is only 13300kWh/T-Al.

Jan 1, 2006