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By Jung-Ah Kim

Precipitated Calcium Carbonate (PCC) is obtained through calcination, hydration, and carbonation. Thus, the change in each process condition determines the particle size or morphology of PCC. To date, studies on precipitated calcium carbonate have mainly focused on process manufacturing PCC, aimed matter. Still, few studies on calcination or hydration have been conducted. Therefore, this study sought to investigate the effect of hydration condition on the synthesis characteristics of aragonite PCC. Results showed that the particle size of calcium hydroxide changed based on the variation of the initial hydration temperature. In particular, higher initial temperature resulted in the larger particle size of calcium hydroxide used in synthesis. The particle size and yield of aragonite also increased when calcium hydroxide made at high temperature was used. The water/solid ratio or total amount at the hydration time had no effect on the manufacturing process of aragonite, however.

Jan 1, 2006

By Robert Thurner

The underground car park "Admonterhof in the historical centre of Graz is an example for the technical and economical success of a complicated structural design using a concept on the basis of the observational method. The intention to built a 20 m deep excavation beneath a protected monument was accompanied by some essential issues: the preservation of the existing state avoiding extensive displacements by means of a girder grid of reinforced concrete, its support on large bored piles and small steel-tube piles with possible active compensation of differential settlements, the excavation support in none built-up areas with secant bored piles, the underpinning of existing buildings with different structures by means of jet grouting. Furthermore the hydraulic gradient and the permeability of a rock formation in a part of the excavation had to be explored with the purpose to control the inflow of groundwater with a level difference of more than 10 m.

Jan 1, 2006

By F. Sachanidis

The lignite surface mines of Ptolemais basin operate according to special environmental terms regarding the concentrations of heavy metals and trace elements in water discharges. Based ?n the results of lab analyses and in-situ measurements conducted so far it is concluded that the concentrations of heavy - toxic metals and other trace elements are low or negligible. The deviations from the upper concentration limits specified by laws and regulations are rare and non-systematic both on their spatial or temporal distribution. The same results prove also the relation between water quality and type and nature of the sediments forming the Ptolemais basin and the carbonated and metamorphic rocks forming the surrounding mountain areas.

Jan 1, 2006

By M Scott, J J. McEwan

Silver and silver alloys tarnish readily by the formation of tarnish on the surface when exposed to a wide range of sulphur-containing atmospheres. This tarnish is unsightly and undesirable and can be removed either with a silver polish or a chemical dip. Polishes are, however, not suitable for irregular and embossed surfaces such as on coins, medallions and jewellery items, because of uneven removal of the tarnish layer and excessive wear. Successful tarnish protection can be achieved by either storing the items away from the aggressive atmosphere or by coating/treating the exposed surfaces with a protective layer. Storage is feasible for collections but is not suitable for items that are handled or worn regularly, such as jewellery. A number of commercial coatings and treatments have been developed, but to date there has not been a systematic evaluation of tarnish protection. This paper details the performance of a range of generic coatings in an accelerated tarnish test. The degree of tarnish was evaluated by means of loss in reflectivity and change in colour. Four coatings/treatments improved the tarnish resistance of silver by more than tenfold. These include an organic lacquer, rhodium electroplating and an organic self-assembled monolayer (SAM) conversion coating. Research is continuing to optimise these coatings. Keywords: silver alloys, tarnish resistant coatings, silver polishes.

Jan 1, 2006

By Carl Havemann

[PAPER PRESENTED AT THE 8thINTERNATIONAL CORROSION CONFERENCE HELD AT THE SA NATIONAL MUSEUM OF MILITARY HISTORY, SAXONWOLD JOHANNESBURG DURING 14-15 NOVEMBER, 2006.]

Jan 1, 2006

By Vasileios A. Drosos

The response of pile foundations to lateral loads is an important factor for the successful performance of several critical structures. A new numerical code for the analysis of single piles under lateral load is outlined. The code can simulate (through appropriately chosen parameter values) not only the non-linear behavior of soil, but also the inelastic structural response of the pile itself under lateral load. Emphasis is given on the calibration of model parameters and the verification of the code. For the calibration of the parameters, data is used (a) from the well documented in the literature p-y curves, and (b) from experiments conducted either in full scale or in the centrifuge. Results are compared to those of well known published codes for inelastic analysis of single piles under lateral load.

Jan 1, 2006

By Francis Vanbellen

Umicore Precious Metals Refining operates an integrated precious metals smelting and refining plant in Hoboken, Belgium. Once a smelter and refiner of complex concentrates, the plant today?s feed consists exclusively of industrial and consumer recycled products, making it the world?s largest recycling facility for precious metals. Unlike the fairy tale of the Frog Prince, it took much more than a princess? kiss to successfully realize this makeover. A completely renewed plant has been built over the past decade. The most visible technological innovation was the commissioning of the Pb-Cu smelter. Its flexibility towards very different types of feed makes it perfectly suited as main entry to the Hoboken flow sheet. A new Cu-leaching & electro winning plant and precious metals refinery make up the Precious Metals Operations (PMO) whose targets are fast throughput and maximized yields for gold, silver and the platinum group metals. The Base Metals Operations (BMO), flexibly process the by-products from the PMO, valorizing ?impurities? like indium, tellurium, selenium and others. Off gas and waste water treatments ensure compliance with strict environmental standards. Precious metals recycling is an art that goes beyond mastering a unique flow sheet. Umicore Precious Metals Refining offers a complete recycling service, taking care of sampling and assaying, metals management and logistics. The quality of this integral service is recognized through the attribution of ISO certifications for our operational activities, sampling and the environmental care. And it?s an art that follows Michelangelo?s experience: ?Art is 5% of inspiration and 95% of transpiration.?

Jan 1, 2006

By A. V. Tarasov

The natural resources of lead and zinc are primarily constituted by polymetallic and lead-zinc ores. Beneficiation of these types of ores to produce standard nonmetallic concentrates inevitably results in an increase in the loss of base and precious metals with tailings. An improvement in the grades of lead and zinc concentrates can be achieved by re-cleaner flotation, but it results in production of intermediate products (middlings) to which substantial amounts of lead, zinc, copper and precious metals report. Without an appropriate technology for treating such intermediate products, the recoveries of valuable constituents from lead-zinc ores would remain unsatisfactory. A process has been developed in the Gintsvetmet Institute for processing of polymetallic intermediate products produced at the ore beneficiation plants. This process is based on electrothermic smelting to produce lead bullion containing precious metals, commercial-grade copper-lead matte and high-zinc slags (up to 15-20% Zn) from which zinc can be extracted by slag-fuming or Waelz process. Tests have indicated that the recovery of lead from intermediate products into lead bullion and matte is about 83-85% and 13-14% respectively (the total recovery is 97-98%), while copper recovery into the matte and zinc recovery into the slag is 90-92% and 95-96% respectively. Precious metals (about 96-97%) report into the lead bullion.

Jan 1, 2006

The Committee for Mineral Reserves International Reporting Standards (CRIRSCO) was formed in 1994 to promote development and adoption of international standards for estimation and reporting of exploration results, mineral resources and mineral reserves. The CRIRSCO standards have been accepted by most mining companies and professional societies worldwide. Market regulators from Australia, South Africa and Canada require that these standards be followed when releasing public information. Among these requirements is the use of specific definitions for what constitutes exploration results, mineral resources and mineral reserves. If such information is publicly disclosed in must be estimated by a Competent or Qualified Person. In the United States of America, public disclosures are regulated by the US Securities and Exchange Commission. The SEC does not recognise the CRIRSCO guidelines, and some of the SEC requirements for public release of information are materially different from those applicable in other countries. The CRIRSCO definitions and the Competent Person requirements are reviewed and compared with those of the SEC. The organisation of the SEC and its rule making process are briefly discussed. Ongoing efforts to bring the US regulatory requirements closer to those applicable in other countries are presented, as well as other activities that CRIRSCO is entertaining with the United Nations, the International Accounting Standard Board and other international organisations to reach the objective of worldwide standardisation of reporting procedures.

Jan 1, 2006

By S. Saptharishi

Selenium, which is a 6A group element of the periodic table, constitutes about 7x10-5 % of the earth?s crust. Even though selenium is a dispersed element with respect to its commercial exploitation, it is capable of forming number of minerals and nearly forty selenium minerals have been identified, out of which the copper ores are the richest sources of selenium. Electronics industries and glass industries are the major consumers of selenium, while pharma grade selenium used as micronutrient for humans and animals. Various methods have been developed to recover selenium as a by-product from copper anode slime during copper refining. Selenium being amphoteric in nature, it is soluble in both acid and alkali. While acid roast process is widely used, considerable work has been carried out in Russia for recovering selenium through alkali route. This paper enlightens the process developed at Central Research and Development Laboratory, for recovering selenium from decopperised slime through alkali pressure leaching. The decopperised slime is pressure leached with alkali under oxidizing conditions by which almost all the selenium present is converted to alkali selenate, which is easily separable from the rest of the decopperised slime. The solution so obtained is neutralized, during which, most of the impurities are precipitated out. Then selenium is precipitated in its elemental form upon purging sulphur-di-oxide under warm acidic medium. The purity of the selenium obtained by this process is higher than that of the selenium from acid roast process. Moreover selenium can be crystallized as sodium selenate and it can be marketed. The acidic content of the effluent is recovered and it is recycled back to the process. The sodium content of the effluent is converted into high purity sodium sulphate, which is marketable. The hazardous waste containing arsenic is precipitated as its sulphide and can be disposed off as landfill.

Jan 1, 2006

By R. L. Grayson, J. R. Warneke

The mining industry has searched for a message that will resonate with the public while focusing on the industry’s positive contributions to society. Thus far environmental groups remain unconvinced, and the public is still largely uninformed. In the authors’ opinion, a number of recent events and experiences have converged to help shape a more effective public communication on mining’s important role. This paper presents a fresh and cogent perspective on coal’s role in sustaining society by anchoring the message in a transparent material flow analysis that links coal’s impacts across a broad range of social and environmental aspects.

Jan 1, 2006

By J. Ndlovu, R. Hundermark

Keywords: Anglo Platinum, Polokwane Smelter, pyrometallurgy, metallurgy, platinum, platinum group metals, PGM, base metals, nickel, copper, sulphide smelting, electric furnace, Söderberg, electrode, matte, slag, flash drying, matte casting, crushing, granulation Anglo Platinum?s Polokwane Smelter is situated outside Polokwane, in the Limpopo Province of South Africa. Wet concentrate is received from various concentrators along the Eastern Bushveld Complex, with 60% of the total concentrate received being from UG2 reef and 40% from Merensky reef. The concentrate grade differs from 35 g/t to 110 g/t, and from this a PGM-rich nickel-copper matte is produced. The furnace matte produced is sent to the ACP converter in Rustenburg. The Anglo Platinum concentrators, from which concentrate is received, are Lebowa, Potgietersrus, Amandelbult, and Union, as well as the joint venture Modikwa. The concentrate is fed to two flash dryers that utilise coal-fired, fluidized-bed hot-gas generators to produce the hot gas that will drive off the moisture, leaving a fine bone-dry concentrate to feed to the furnace. The dry concentrate is pneumatically transferred to a storage silo before being transferred to the feed bins situated above the furnace. Lime, if required as a flux, may be transferred separately to the furnace feed bin by a pneumatic system. The concentrate and lime is fed from the feed bins onto airslides and into the furnace. The feed rate is automatically controlled, and the system is set up to optimize the power to feed ratio. The electric furnace is nominally rated at 68 MW and the power is transferred into the furnace using six 1.6 m diameter Söderberg electrodes. Concentrate is melted by energy generated when electric current passes through the electrodes and resistive slag layer. On melting, two immiscible phases form: slag and matte. Furnace matte, containing the bulk of the base metal sulphides and PGMs, is denser than slag and collects naturally at the bottom of the furnace. The furnace is constructed of a combination of refractory brick and water-cooled copper coolers. The furnace sidewalls and hearth are cooled by air drawn through the area by cooling fans. The hearth and matte zone are constructed from refractory bricks. The copper coolers reside only in the slag zone of the furnace along the entire perimeter of the furnace. One staggered row of plate coolers is installed above the waffle coolers along the perimeter of the furnace. Matte is tapped periodically through one of the two matte tapholes into 35-ton refractory-lined ladles, and cast into matte ingots on a casting machine. The cooled matte is discharged onto a concrete slab for cooling and then transferred by front-end loaders to the crushing plant. The matte is first crushed in a jaw crusher and then a Rhodax cone crusher to a size of 2 mm before it is loaded into tankers and sent to the ACP. The low-grade slag is tapped from the furnace through a water-cooled copper insert into a short water-cooled copper ?hot launder? which discharges into a granulation cold launder. The granulated slag slurry flows to three rake classifiers, from which the coarse slag is discharged onto a conveyor to dewatering silos. The dewatered slag from the silos is dumped. The water overflow from the classifiers reports to two thickeners where the water is clarified, and the thickener underflow is returned to the rake classifiers. The smelter is a zero-effluent plant and all the water from the slag silos where the slag is dewatered, as well as the storm water, is pumped to the process water dam from where it is pumped back into the plant for process water use. The off-gas from the furnace is drawn through a forced draught cooler and into a high temperature baghouse. The dust collected in the baghouse is pneumatically transferred into bins above the furnace and is fed via the concentrate airslides. The cleaned off-gas is then vented through the main stack.

Jan 1, 2006

By John E. Lens

How much trouble can narrow vertical fissures in bedrock cause on a shallow bedrock site? Enough trouble so end-bearing H-piles range between 8 and 100 feet long in a single pile cap and tiebacks range from 40 to over 100 feet long within a 10 foot wall span. Sloped bedrock surfaces also complicated the tieback installation as the drill casing followed the sloped rock surface while drilling and caused unanticipated bending (and sometimes breaking) of the drill string. Warned via pre-construction rock probes and cores reaching over 80 feet deep at the Winooski, Vermont project site, the design and construction team expected anomalies in pile driving and tieback drilling due to fissures in the bedrock filled with soil and weathered-rock. The degree of abruptness in the variability in the rock surface, and its impact on pile driving and tieback drilling were less predictable. Close monitoring of pile and tieback installation, redesign of pile caps, and lengthened tiebacks overcame these anomalous fissures. This paper shares the lessons learned for overcoming these geologic challenges to benefit designers, contractors bidding the work, and ultimately, the owner, with lower contingencies.

Jan 1, 2006

By Eun Duck Park

The gold catalyst supported on iron oxide was prepared from gold dissolved in aqua regia by a deposition-precipitation method and applied to CO oxidation in the absence and presence of hydrogen. Some characterization methods such as X-ray diffraction (XRD), nitrogen adsorption, transmission electron microscopy (TEM), temperature programmed reduction (TPR), temperature programmed oxidation (TPO), and the pulsed CO chemisorption with temperature programmed desorption (TPD) were conducted to explain different catalytic activities of Au/Fe2O3 catalyst pretreated at different conditions. The particle size of gold was about 10 nm for Au/Fe2O3 calcined in air at 373 and 573 K. For complete CO oxidation, the decreasing CO conversion with a reaction time was observed at low temperatures but its initial catalytic activity can be restored by a heat treatment at high temperatures. This catalyst was quite active for the selective CO oxidation in the presence of hydrogen especially at low temperatures. In the presence of hydrogen, the deactivation was significantly diminished.

Jan 1, 2006

New method for processing of copper and nickel production feed has been developed and tested at pilot unit having 10 t/hr capacity. The process allows single-stage treatment of ore feed including that with high magnesium oxide content and resulting in the production of rich matte, high-grade matte, or moralised alloy for further leaching, as well as dump slag and off-gasses suitable for production of elemental sulphur, liquid sulphur dioxide, or sulphuric acid. Tests results and principal technical and economical parameters are presented.

Jan 1, 2006

By Ashutosh S. Dhar

Cast-in-place piles were examined in this paper from the viewpoints of construction quality, axial capacity, and load-displacement responses. The results of ten 450 mm diameter (18? f) bored piles, installed in a soil deposit of silt to medium dense sand using the method of percussion drilling, were tested under static loads. The results of the pile load tests were used for evaluation of various design methods of calculating pile capacity. The study revealed that the design methods based on the concept of critical depth underestimated the ultimate skin fiction. Thus, the applicability of the critical depth concept for design of bored piles under the soil condition considered may be unreliable. The estimated skin friction factor, ß, was too low in these methods. The Tomlinson method and the Neely method provided the best prediction of the ultimate skin friction. The methods used for calculating end bearing resistance were found to provide a conservative estimate of the resistance. During pile load tests, a settlement of 5 to 6 mm was required for full mobilization of skin friction for the piles in loose sand, while larger settlements (> 10 mm) were required for piles in denser soil. The ultimate skin frictional resistance was observed to be low for piles in loose sand.

Jan 1, 2006

By Dinabandhu Ghosh

The stability diagram of the ternary system Ti-C-O is drawn in the present work for four temperatures, 1473 K, 1573 K, 1673 K and 1873 K, showing the stability fields of TiC, Ti, TiO, Ti2O3 and TiO2. An analysis of the system reveals that it is not possible to produce Ti in a carbon-saturated system; instead, the stable product is TiC. However, Ti can be an equilibrium product in a carbon-unsaturated system at prohibitively low values of pCO and pCO2; for example, at 1873 K, these limiting values are: pCO = 10-6.76 atm and pCO2 = 10-13.36 atm, which, when exceeded, produce TiC and TiO respectively. The magnesiothermic reduction is examined through the stability diagram (log pO2 vs. 1/T) of the system Ti-Mg-O, drawn for a number of pMg values, presenting the pairwise stability fields such as Mg(l) + Ti(s), Mg(v) + Ti(s), MgO(s) + Ti(s), etc. The diagram shows that magnesium reduction of TiO to Ti is possible only at T < 1641 K with pMg = 1 atm and only at T < 1569 K with pMg = 0.5 atm. An experimental scheme for Mg vapor reduction of TiO2 is proposed in which an argon stream is passed over a Mg(liquid) evaporator at temperature T1 (say, 1234 K); the resulting Ar-Mg mixture at 1 atm is subsequently flown over a bed of TiO2 at temperature T2. A thermodynamic analysis establishes that complete reduction to Ti is possible and that the best results are obtained when T1 = T2.

Jan 1, 2006

The Pilbara region, located in the north-west of Western Australia, is significant as the second-largest source of iron ore on the planet. Iron ore mines owned and operated by Pilbara Iron are located within the Hamersley Basin. This paper refers to the Greater Paraburdoo mines, the 4WEST and 4EAST pits, located on the southern margin of the Hamersley Basin. The groundwater model refers to ephemeral watercourses: Seven Mile and Pirraburdoo creeks, which are adjacent to the two pits, and Ratty Springs, located upstream from 4WEST and within Pirraburdoo creek. The spring and creeks hold cultural heritage significance for local Aboriginal communities. Two of these, the Gobawarrah Minduarra Yinhawanga (GMY) and Innawonga native title claim groups, initiated hydrological work on the two creeks and Ratty Springs, with the aim of determining the affects of dewatering on the natural water flows of these systems. The numerical model used to simulate drawdown in the Pirraburdoo and Seven Mile Creeks was derived from PMWIN Pro software and covered an area of 77 km2. The modelling period was from January 1998 to December 2004, and the prediction period was from January 2005 to December 2015. The model has four layers and incorporated effects caused by mining voids, 4WEST and 4EAST pits, creek bed material, weathered bedrock below creeks and surrounding banded iron formations (BIF). The model has been calibrated using the trial-and-error method set down by Middelmis et al (2001). The current dewatering schedule (12 ML/day) in the 4WEST and 4EAST mining areas does not affect the water table levels in the adjacent creeks significantly or for any considerable periods of time. However, changes to mine plans may occur, for example, in response to changed commodity price and may lead to significant increase in rates of vertical advancement. This, in turn, affects dewatering schedules, as greater vertical advancement requires increased dewatering effort. When an accelerated mine plan is applied to the model and dewatering rates increased to 18 ML/day, drawdowns in the creeks are more noticeable. The model has therefore helped to indicate the extent to which increased dewatering rates may be acceptable, especially in terms of immediate and longer-term damage to riparian species, ie Melaleuca and Eucalypt. Predictions from the model may also allow mine planners to schedule decreased rates of vertical advancement, where these are required to meet environmental constraints.

Jan 1, 2006

By S. Johnson

Introduction The mining of aggregates underground has grown steadily over the last 25 years. Growth has come in both production volume and in the importance this segment of the industry is playing in the continuing supply of construction aggregate. Underground aggregate mines will continue to grow in both number of operations and complexity, as the replacement of zoned reserves in metropolitan areas becomes crucial. This growth will result in a shortage of qualified mine managers, possibly limiting the success of these facilities. The aggregate industry will have to modify current practices in order to meet the growing demand for this specialized skill. Segment Growth Underground mining for aggregates is not a new idea. Martin Marietta has been operating underground mines since 1969, and currently operates 16 underground mines ranging in size from 250,000 tpy to 2,500,000 tpy. These mines represent less than 4% of the total number of operating locations, but contributed 9% of the annual production in 2004. Though they range in size and production capacity, the importance is evident. The 2000 United States Census revealed several trends that are of interest to the aggregate mining industry. For the period 1990-2000 the U.S. population grew by 33 million or 13%. There were nine major metropolitan areas with a population of five million or more. These nine areas accounted for 30% of the total U.S. population. More significant was the fact that the population growth in these nine metro areas was 25% of the growth for the entire country. These statistics tell us that the population is expanding in these major metropolitan areas at a staggering rate. The same thing is happening to some degree in every population center. Population growth increases the demand for local aggregate while reducing the available area to mine that aggregate. The need for an economical supply of aggregate to support community expansion is a problem that will grow as older quarries are mined out and closed. This will be an issue that communities of all sizes will have to deal with. A reliable and cost effective supply of quality aggregate is crucial to support community expansion.

Jan 1, 2006

By P. D. Georgescu

Gold, like no other metal, has a fascinating and special place in the world. It is used in a range of every day applications essential to modern life. Gold has long been considered the most precious metal in the world. Gold is used mainly for making jewellery as well as for dentistry, adornments on building and artistic expression. For thousands of years it has been used as an ornament of kings, a currency and standard for global currencies, and more recently, in a wide range of electronic devices and medical applications. Gold?s many unique properties have secured in a central role in history and human development. Today, more often than not, gold is extracted from ores. It occurs in vein and alluvial deposits and is often separated from rocks and other minerals by mining and processing operations. Some of these processes cause environmental concern (cyanidation, amalgamation, roasting). Besides primary gold ore resources, a series of secondary resources can be taken into account and processed for gold and silver recovery. There are two main types of waste produced. The first type is process waste, which includes tailing consisting of processing residues and waste rock. The other type is refuse from other different processes and recyclable materials. Among other secondary resources and/or by-products containing precious metals, which have been studied some processes and technologies with low ecological impact are presented in this paper. Heaps and tailing ponds resulted from gold-bearing ore exploitation and processing, refractory gold-bearing pyrite concentrates, slag resulted from electrolytic slime melting, gold-bearing chlorous slime are taken into account. In order to establish environmental friendly technologies for precious metals recovery from these secondary resources, laboratory experiments have been carried out on a pilot scale and in some cases on semi-industrial scale by applying specific technological processes, namely hydro-gravitational concentration, bio-oxidation, non-ionizing electromagnetic radiation (microwaves), solubilization without utilizing cyanide and gold recovery by ion-exchange resin. This paper presents the research results, technological principles as well as the possibilities of applying combined processes in order to treat different secondary gold-bearing resources.

Jan 1, 2006