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By Harumasa Kurokawa

Since the initial start-up, the Toyo Smelter & Refinery has been operating in harmony with the ambient environment, and improvements have been implemented with technologies specifically developed for further protecting the environment. Toyo Smelter & Refinery is now planning to increase the copper production capacity from 280,000 tpy to 450,000 tpy, over a period of several years. In 2003, the first step of this smelter expansion and modernization plan was implemented. The production capacity of the P-S converter was increased dramatically, as it became possible to operate under a ?2 hot-2 blowing? schedule. In 2005, an additional converter will be installed, in order to allow operation under a ?3 hot-2 blowing? schedule. This report will describe the technical improvements on the P-S converters, as well as describe the Toyo expansion program and discuss the technologies applied to the fugitive gas collecting system.

Jan 1, 2005

By Peter W. Lotz

Contents of: ?Sampling for Cyanide in Metallurgical Processes? ?Sampling at process level of operation ?Sampling at environmental level ?Sample stability and integrity issues ?each citing possible objectives, practical example and reasons for surprises Overall recommendations on sampling plans and procedures to maintain sample integrity

Jan 1, 2005

Material sampling theory is well established in mineral process monitoring, improvement and control. It has been much enhanced by fundamental contributions due to Gy. When GyÆs sampling theory is applied to sampling inspection and monitoring, it provides estimates of average quality or extent of contamination. It also provides estimates of uncertainty, but these often ignore uncertainty in estimated variograms or other measures of variability. Risk assessment is often an implied task in sampling inspection and quality monitoring. A valid technique of risk assessment needs to take into account the uncertainty in the variational measures themselves. Standard statistical tolerance limit calculations which do take such uncertainty into account can be adapted to develop a technique for handling uncertainty in variational measures such as the variogram. Data from a published example is used to illustrate the technique.

Jan 1, 2005

By J Naser, M Tuck

This paper reports a computational study using computational fluid dynamics (CFD) in a mine ventilation system. Ambient air is injected to a rectangular mine drive through a circular duct. Moisture evaporates from shaft wall depending on flow properties of air in the drive-duct system. The physical process involves simultaneous momentum, heat and mass transfer. A species transport equation is employed to account for the moisture concentration in air. The momentum equation is solved using standard k- model, while energy and species transport equations are solved using standard expressions for moisture evaporation rate and heat flux from the drive wall. The aim of this paper is to investigate effectiveness of CFD simulation in relation to mine ventilation in a drive where a significant mass transfer phenomenon occurs. Results from simulation are compared with existing data from a site in Victoria.

Jan 1, 2005

In 1997, the Australian coal industry through Standards Australia committee MN-001 Coal and Coke recognised the need to produce a Standard giving some instruction on how to inspect and audit mechanical sampling systems. A Guide was developed by sampling subcommittee MN-001-04 and in 1999 the Standard was released as AS4264.5 æGuide to the Inspection of mechanical sampling systemsÆ Coal and Coke. Since that time the author has assisted with other committees in developing the Guide for other commodities such as concentrates and a generic standard for particulate materials. (AS4433.6 released 2000). The Coal and Coke guide is also currently a work item for ISO Standards. This paper is focused primarily on auditing and inspection procedures for coal mechanical sampling systems. It highlights the need for at least a three level inspection protocol where the operators manning the system maintain operational checks, the operators are regularly supervised by the company managing the system and once per year an independent auditor inspects the whole system to ensure compliance with design and standards. It does not cover short- and long-term maintenance of individual systems. With companies already certified to the ISO9000 series, this guide forms the framework to bring the operation and inspection of their mechanical sampling systems into line with these principles.

Jan 1, 2005

By C. O. Aksoy

There is a long history of coal production in Turkey with electric energy generated from power plants since the 1950s. However, the cost of power generation is high. Therefore, it has become necessary to find a means of decreasing production costs to become more competitive in a global market. This paper attempts to economically minimize the overall operating costs of a dragline-shovel-truck system applied at an open pit mine that has fed the Yatagan power plant since 1979, lowering the lignite production cost, and indirectly, the overall electricity generation unit cost. Systems currently in place, as a result of former optimization studies, are time-consuming and expensive to re-implement to comply with today’s very different geometric and economic conditions affecting mining operations. In such cases, rather than re-optimization, it is more viable to identify the parameters that affect the minimum unit cost, via a cost minimization study, allowing present mine equipment to be utilized more efficiently. Unit cost minimization analyses are subject to the capacity of the pool of mining equipment available, combined with the mining block geometry from pre-stripping onwards. In this overall unit cost minimization study, P&H shovels and CAT 777 trucks with capacities of 15 yd3 and 77 tons, respectively, were used in truck-shovel pre-stripping operations. A 65 yd3 Marion 8050 dragline was used to expose the overburden immediately over the coal seam. Pre-stripping bench heights varied from 8 m to 20 m and dragline bench heights from 20 m and 25 m were evaluated to minimize the unit cost of field operations. Total overburden extended to a depth of 60 m (35 m to 40 m for pre-stripping). Minimization analyses performed on the pre-stripping truck-shovel operation, prior to dragline operations, determined that the shovel bench height should be 15 m requiring a dragline bench height of 25 m.

Jan 1, 2005

By A M. Sherwood

The Otago and Southland lignite deposits represent by far the largest known fossil energy resources in New Zealand. Despite their size they have remained virtually untouched since exploration in the 1970s and 1980s defined their extent. In total there is an estimated 10.9 billion tonnes of lignite in 13 defined fields in Otago and Southland. Much of the exploration work only targeted seams at shallow depth and it is highly probable that there are further resources at depth in the fields that have been explored to date.   L&M Lignite Limited (L&M) holds exploration permits over a number of lignite deposits and is currently engaged in pre-feasibility studies to investigate the potential of the lignites for gasification. L&M is focussing its studies on the Hawkdun and Ashers-Waituna deposits. Coal quality in these deposits, particularly Ashers-Waituna, is highly suitable for gasification. In total the two deposits contain 1647 Mt of potentially recoverable lignite. L&M has engaged a variety of consultants to progress this project. The Hawkdun and Ashers-Waituna deposit databases have been re-evaluated and the resources remodelled. Further drilling has been carried out and the coal quality database has been expanded. The baseline project is to develop a mine to feed a plant that will produce liquids, specifically low-sulphur diesel and naptha, using the Fischer-Tropsch process. The project anticipates a staged development of 10 000 barrel per day units, each requiring mining at the rate of 12 700 tonnes of lignite per day. The production of other products including ammonia-urea, methanol, hydrogen and electric power is also under study.

Jan 1, 2005

By Haydn H. Murray

A hydrothermal bentonite located in the high Sierras in Nevada is being mined and processed for use as a natural dietary supplement. Because hydrothermal clay deposits are normally zoned and not uniform in composition, a special stockpile was constructed to assure uniformity of processed products. The stockpile of clay was layered and rectangular in shape. Channel samples were taken from 10 locations around the stockpile and were mixed and quartered to provide representative samples. The samples were then chemically and mineralogically analyzed. The results showed excellent uniformity. The mineralogy and chemical analyses will be discussed in the paper.

Jan 1, 2005

By M Ljunggren, M Lundh

Dissolved air flotation (DAF) in wastewater treatment as a separation process of submillimetre biological flocs is based on the generation of bubble/floc aggregates. DAF is a complex process but has got advantages, such as allowing a high hydraulic load, compared to sedimentation. A thorough knowledge of the physics of the DAF process is, however, still lacking. This paper will present results of experimental studies on three aspects of significance to the separation process û the flow structure in the flotation tank, rise velocities of aggregates, influence of floc size on the separation efficiency. Flow structure. Measurements were performed in a pilot plant mapping and visualising the velocity field. The dispersion water (bubbles) had a decisive influence on the flow structure due to the effect of the bubbles on the bulk water density. Stratified conditions with a less dense, bubble-containing upper layer and a clear water, denser bottom layer were important for a good separation. A simple model of the stratified flow structure was elaborated making it possible to interpret the function of the aggregate rise velocities. Bubble/floc aggregates. The dynamics of single flocs, bubbles, aggregates were visualised using a borescope + CCD video camera + digital recorder + image analysis. Sequences of video frames made it possible to determine the rise velocities of the single aggregates. These velocities were found to be in the range 1 - 9 mm/s with a tendency for large flocs to have higher rise velocities. Separation versus floc size. The floc size distribution was measured in the DAF process. Data from three different DAF cases showed, that large flocs (> about 100 ¦m) were entirely separated, whereas small flocs experienced a less good separation. It was, moreover, found, that a very significant separation of flocs took place in the very upstream end of the separation zone in a pilot plant case.

Jan 1, 2005

By Don Phelps, John Hawley, David P. Field

In recent years observational techniques of tunneling have become increasingly popular methods to facilitate complex underground infrastructure projects. The traditional design and construction management practices developed in Europe have been adapted for application in North America to suit a more restrictive management and legal culture. This paper will discuss three recent projects, the San Diego Mission Valley East Extension, Washington Dulles International Airport People Mover, and the Seattle Beacon Hill Station and Tunnels, with the objective of identifying the challenges of applying observational tunneling methods to established contractual practices in North America.

Jan 1, 2005

By O. Konovalov, M. Zhuravkov

In report the results of performance of research works on building up of the connected geoecological and geomechanical monitoring system for modelling and study of a state of mining massif in a region with large-scale underground mining works are discussed. The connected geoecological monitoring requires radical change of methodology of carried out works. To carry out modelling and researches it is impossible without construction of the integrated connected information model of region. Basis of construction of information systems and databases for all sections of Earth Sciences is the set of the approaches, among which, for example, methods of remote sounding, GIS- and GPS-technology etc. Computer technologies are basis on the "supercomputer" technology. The results of performance of some researches for regions of excavation of deposits of potash salts in Russia and Belarus are presented.

Jan 1, 2005

With the theme of û æUnderground Ore Handling SystemÆ, Kopanang Mine completed an extensive project on a specific system with technologies for the handling of ore from a dedicated drawpoint to the shaft system. The intended rail haulage tramming system had to be capable of handling the shaft design and Life of Mine (LOM) requirements. Kopanang is an AngloGold Ashanti gold mine situated in the province of the Free State in South Africa. In the Sotho language the name æKopanangÆ means to come together as a team. ItÆs an appropriate name given that 25 companies worked on this project. The future focus at Kopanang is to establish four mining levels between 3 to 4 km south-west of the shaft and two mining levels to the west. The mine has an expected life of almost 20 years and capital was approved in order to access this reserve to establish the infrastructure to handle the ore, hence this exclusive rail haulage tramming system of close to R40 million (SA rands), which took three years to construct. Apart from the fact that this system had to be capable of handling 6500 t per shift at a depth of over 2 km over a length of 3.2 km, some of the major considering factors were: safety, economic factors with improved labour productivity, efficiency and reliability, risk termination, and ergonomics. The system comprises two 20 t locomotives operating in a double header configuration from a dedicated draw point to a dedicated tip area for the reef and waste ore. With the objective of handling high speed and high capacity, this 200 t payload train is capable of running at 35 km/h powered from a 500 volt ac overhead line. Each loco consists of two 90 kW dc motors with ac/dc power conversion on the locomotive. For the system to operate at this speed, the rail system is constructed with Class 1 rails over the entire hauling distance. The tipping mechanism is unique and the span of 11 hoppers each with a load of close to 20 t is capable of tipping the pay load of 200 t in about 20 seconds hands free.

Jan 1, 2005

By Theodore W. Vogelpohl

Augered cast-in-place piles have proven to be effective, adaptable and economical for projects throughout the Ohio River Valley. Specifically, they have been used extensively for high-rise structures, sports stadia and large commercial developments along the Cincinnati, Ohio and Northern Kentucky Riverfront. They have been designed and utilized as relatively short toe resistance piles in bedrock, and intermediate to long toe and shaft resistance piles in granular outwash deposits above the bedrock. They have been designed for large axial compression loads as well as moderate axial tension loads and lateral loads. This paper presents a few load test results that demonstrate the range of capabilities of augered cast-in-place piles in the variable subsurface profile along the Cincinnati, Ohio/Northern Kentucky Riverfront.

Jan 1, 2005

By P A. Gow, J L. Walshe, G J. Masterman

The Eocene-Oligocene porphyry belt of northern Chile contains the worldÆs largest accumulation of porphyry-related copper metal. Conflicting models exist regarding the relative importance of strike-slip and reverse faulting during the emplacement of the porphyry and epithermal systems, based on regional studies and also from work at the Chuquicamata deposit. In contrast, at the Collahuasi district, high sulfidation state copper-silver mineralisation was superimposed into the core of the Rosario copper-molybdenum porphyry deposits along normal faults during gravitational collapse of the Domeyko Cordillera. Exhumation of the porphyry environment occurred rapidly during this event, allowing near-surface epithermal mineralisation (<200 m paleodepth) to be juxtaposed into the potassic altered core of the porphyry deposit (estimated depth of formation: 1300 m) in the space of approximately one million years. Mass wasting after major episodes of tectonic uplift provides an effective method of hypogene upgrading of porphyry ores by high sulfidation mineralisation.

Jan 1, 2005

By K. A. Allison, D. R. Van Orden, R. J. Lee

Continuing analysis of environmental samples for asbestos content has resulted in the misidentification of non-asbestos amphibole particles as asbestos fibers. These errors have received wide publicity (such as in the asbestos-in-crayon story) and have caused unnecessary reformulation of products. The primary cause of these errors has been a poor understanding of mineralogy and analytical techniques among the many asbestos laboratories that arose following the passage of the AHERA regulations. Presented here is a procedure based on published data that can be used to correctly classify an elongated particle as asbestos or as non-asbestos.

Jan 1, 2005

By A. Chaisantikulwat

Most solid-oxide fuel cell (SOFC) modeling emphasizes steady state cell operation. However, understanding the dynamic behavior is essential to predict the performance and limitations of SOFC power systems. In this work, we demonstrate a dynamic model of a SOFC, and we simulate a feedback control scheme that can maintain output voltage despite load changes. Dynamic response is determined as the solution of coupled partial differential equations derived from conservation laws for energy, mass and electric charge. From such a model, the step responses to system input variables can be determined. Low order dynamic models that are sufficient for feedback control design can be derived from the step responses. The development of the partial differential equation model is outlined, and the limitations of the control system are discussed.

Jan 1, 2005

The Pike River Coal Company is set to develop the Pike River Coal Mine in the Paparoa Ranges of New ZealandÆs South Island. The mine will be developed to extract a coking coal deposit of the Brunner Seam, some 46 km north-east of Greymouth, using a combination of continuous miners and hydraulic extraction.   The mining area is located within Department of Conservation (DOC) land and is adjacent to the escarpment of the Paparoa Range and the Paparoa National Park. As such, the major restriction to planned extraction is protection of:   +        the western escarpment, +        vertical and sub-vertical rock faces, +        permanent water courses, +        significant vegetation, and +        steep slopes.   The mine will use its elevation advantage to hydraulically flume coal from the working faces to the pit bottom area where it will be slurried to approximately 35 per cent density of solids and pumps down a slurry line to the coal prep plant some 10.5 km down the Pike River Valley. The coal will be sold on the export market as a high quality coking coal for international steel making.

Jan 1, 2005

By Allison

During the 1980’s, laboratories opened throughout the United States to serve the analysis needs of a rapidly growing asbestos abatement industry. The samples analyzed were either collected during the abatement of known asbestos-containing materials or were suspect asbestos-containing construction materials. Many asbestos analysts received minimal training and used analytical protocols that were industry specific. False positives (reporting a sample as containing asbestos when none is present) went unnoticed or had minor repercussions. The mindset of the industry was to err on the conservative side – it would be better to identify a non-asbestos fiber as asbestos than visa versa. With growing public awareness of the health hazards of asbestos, other materials began to be tested for asbestos content. Rock and ores began to be tested for naturally occurring asbestos by these laboratories using the same protocols or an in-house protocol. Analysts were given no additional training and accreditation, in most cases, it was not required. With no consistency in sample collection, testing protocol or expertise in analysis, significant discrepancies in final results can be expected. If we further complicate this scenario with misidentification of naturally occurring look-a-likes for asbestos, expensive false positives are likely. To avoid the repercussions of misidentification of naturally occurring chrysotile asbestos from look-a-like fibers in rock and ores, correct sampling and analysis protocols with more stringent scientific diagnostic criteria are needed.

Jan 1, 2005

Commercial SOFC systems will likely utilize hydrocarbons or hydrogen produced from hydrocarbon fuels and therefore will likely be exposed to sulfur impurities. Conducting-Atomic Force Microscopy (C-AFM) is a scanning probe microscopy technique which maps both sample topography and conductivity with tens of nanometers resolution. In Ni-YSZ, C-AFM measures the resistance of the metallic network at scanned locations, with the ability to differentiate between interconnected and isolated metallic particles. We have applied C-AFM to Ni-YSZ SOFC anode materials, with the goal of monitoring changes in the conductivity of the Ni anode network resulting from SOFC degradation processes, such as H2S poisoning.

Jan 1, 2005

By F J. Rios

In the eastern high-strain domain of the Quadrilßtero Ferrffero, Brazil, hard and soft high-grade hematite ore may occur as schistose bodies in shear zones mainly related to the Cambotas-Fundpo thrust system. These orebodies are almost entirely constituted of oriented specularite platelets that develop both as a product of crystal-plastic deformation of hematite and solution-precipitation processes. Both mechanisms interact in the partitioning of the strain, while solution-precipitation is responsible for the precipitation of hematite and localised leaching of silica resulting in the formation of syntectonic ores. The analyses of fluid inclusions from specularite crystals of the Conceitpo and Timbopeba deposits, located in the northern and southernmost areas of the eastern high-strain domain of the Quadrilßtero Ferrffero, were studied using infrared microthermometry and Synchrotron x-ray fluorescence. The results indicate the participation of highly saline aqueous H2O-NaCl fluids containing other additional cations (Ca, Fe, K and probably Ti) in solution and homogenisation Temperature (Th) averaging between 130¦ - 190¦C. However, the partial fusion of metastable saturation phases indicates crystallisation temperatures of approximately 400¦C. The mineralisation process produces high-grade orebodies as well as Fe-rich specularitic itabirites that are explored in that area. The shear zones are related to thrust faults mapped and interpreted as related to the PanAfrican/Brasiliano Orogeny that affected the Quadrilßtero Ferrffero, thrusting the Paleoproterozoic platform sequence of the Minas Supergroup over Mesoproterozoic quartzites of the Espinhato Supergroup. They intersect and even overprint an early metamorphic and tectonic fabric of Paleoproterozoic age (Transamazonian Orogeny). The geological and fabric relationships lead to the conclusion that the fluids involved in the mineralisation were most probably of external origin, of still unknown source (possibly igneous), during the closure of the Spo Francisco Craton.

Jan 1, 2005