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By J. Madias, E. Benavidez, E. Brandaleze, L. Castella

Knowledge of the physical and chemical properties as well as the behaviour of the mould fluxes during melting, important in order to improve continuous casting operations. Lubrication and control of heat transfer in the mould are the more relevant functions of these materials. Values of physical properties like viscosity and surface tension at melting range temperatures are required, as much as the thermal behaviour under process conditions. The heat extraction from the liquid steel has an important effect in the final quality of products. Mould fluxes are constituted by different oxides, and may form glasses and crystal phases during cooling. The solidification rate and the chemical composition determine the proportion, type and crystalline morphology, which are responsible of the thermal transfer processes. In this paper, viscosity values are reported in the melting range temperatures calculated by means of the Riboud model and compared with fluidity results obtained by the inclined plane technique. Also the linear expansion of the mould fluxes at high temperatures was determined by dilatometry. The crystallization in two different fluxes was determined by DTA tests and correlated with the basicity index. Crystal phases were evaluated by scanning electronic microscopy on quenched samples at 1300°C. This information is relevant to increase the knowledge on the peritectic steel grades casting process in order to improve its quality. Keywords: mould fluxes, heat transfer, crystal phases, peritectic steels, thermal properties.

Jan 1, 2004

By J. Hop, A. Støre, T. Foosnæs

The carbon cathode for aluminium electrolysis is also part of the container of the process. In order to understand the behaviour and possible failure of the cathode, detailed material properties under operating conditions are needed. The paper reports experimental studies of bath and sodium in filtration, graphitization with time, loss of strength due to sodium, sodium expansion as function of pressure, as well as creep due to the developed stresses. As an example, sodium and thermal expansion data are used to calculate strain-stress models of realistic cell designs, and possible design weakness can be pointed out. Keywords: carbon, cathodes, sodium expansion, strength, graphitization, creep

Jan 1, 2004

By M R. Davidson, M P. Schwarz

A model for column bioleaching is investigated to identify and understand aspects of bacteria in bioleaching applications, which have implications in heap bioleaching operations. The model is used to simulate scenarios that would otherwise be time consuming to perform experimentally. This study uses a model of bacterial transport and attachment/detachment to ore particles, with a bioleaching model for the depletion of a copper-sulfide, also accounting for liquid and gas flow and gas/liquid oxygen mass transfer. The model includes aspects such as oxygen and ferrous ion consumption, coupled with leaching of a copper-sulfide via the shrinking core model. The model is used to investigate how the rate of leaching is affected by the bacterial concentration in the columns, by the bacterial regeneration of the leaching oxidant ferric ions. The model is also used to assess the impact of oxygen limitation and inoculation method on the copper leaching. Some comparison of the model with experimental data will be shown.

Jan 1, 2004

By J. Engesser

A research project supported by the Minnesota Department of Natural Resources and the Iron Ore Cooperative Research Committee was undertaken to reduce the dissolution of fluoride into process water during taconite processing. Leach tests were conducted using rod mill feed samples and water containing varying concentrations of calcium and sodium. Laboratory liberation grinds were performed to evaluate fluoride rejection during grinding and magnetic separation. Tube furnace tests were conducted to evaluate fluoride volatilization during pellet induration. The results indicate that fluoride concentration of process water is a function of both calcium and sodium concentration in process water. It appears that less than 1 percent of the fluoride present in rod mill feed will dissolve in process water during grinding. More than 90 percent of the fluoride present in rod mill feed is rejected with tailings during size reduction and magnetic separation. The furnace tests demonstrate that bentonite and fluxstone (calcite and dolomite) addition to taconite concentrate during pellet production increases the amount of fluoride that volatilizes during induration. Lime hydrate addition to pellets decreases the amount of fluoride that volatilizes during pellet induration. During acid pellet production approximately three times more fluoride enters the water during induration-off-gas scrubbing than during grinding. When fluxed pellets are produced three to eight times more fluoride enters the water during off-gas scrubbing than during taconite grinding.

Jan 1, 2004

By Jiang Fan, Liu Shi, Wang Haigang

Winter-time natural convection in gravel embankments has been suggested as a technique to provide passive cooling and thereby avoid thaw-settlement of roadways located in permafrost areas. Numerical simulation by finite volume method on the proposed model is perf9rmed using the software FLUENT. A gravels model, in which the embankment is composed of stones and air, has been adopted to investigate the temperature and velocity fields in embankment. Simulation results show that in summer, a weak clockwise circulation of the pore air extending throughout most of the embankment. The pore-air motion is very weak which results in relatively straight horizontal isotherm lines. And heat transfer is mainly maintained through conduction. But in winter, pore-air velocities are higher and multiple vortexes are formed in the embankment. Natural convection then becomes the dominant influence on the isotherm shapes within the embankment. As a result of low ambient temperatures exerted on the embankment surface during winter months, an unstable air density gradient develops within the embankment. This convection increases the heat flux out of the embankment. Therefore, the winter-time convection can further reduce the temperature of the foundation soil beneath the open-graded embankment. In addition, the effects of the size of the stones within the embankment have been analyzed and compared in the gravel model. It shows that in winter, 200mm stones lead to stronger vortexes in the embankment compared with those of 60mm stones. Consequently, the zone oflow-temperature beneath the embankment is extended.

Jan 1, 2004

By S. H. Seyedein

A mathematical model was developed to study fluid flow and solidification in a single-roll casting system. Fluid flow coupled with energy equations were solved numerically using a finite volume method. A body-fitted coordinate transformation technique was adopted to handle the irregularly shaped domain. In order to couple the continuity and momentum equations, a SIMPLEC algorithm was used. A fixed-grid enthalpy method was considered to model the solidification in the system. The turbulence effect on flow field was modeled using a low-Re k-e model The model developed in this work was further run under various conditions to optimize the operating parameters of the process.

Jan 1, 2004

By K. Rainer Massarsch

"Part 2 of 2 (Continued from Summer 2004 edition) By K. Rainer Massarsch, Geo Engineering AB, Stockholm, SwedenVibrations, which are caused by the installation of piles in dry or permeable soils, can cause settlements. The magnitude of settlements depends on several factors, such as soil type and stratification, ground water conditions (degree of saturation), pile type and method of pile installation (driving energy). A method of settlement prediction due to construction-induced vibrations has been presented by Massarsch (2000). However, in many cases, an engineering assessment must be made at an early stage of a project. The following simplified procedure can be used to estimate settlements in a homogeneous sand deposit adjacent to a single pile, Fig. 5. This approach is based on extensive experience from soil compaction projects. It is assumed that intense densification due to pile penetration occurs within a zone corresponding to three pile diameters. The volume reduction resulting from the propagating vibrations will cause settlements in a cone with an inclination 2V:1H, with the tip at a depth of 6 pile diameters. Thus the settlement trough will extend a distance of 3D+L/2 from the centre of the pile, with maximum settlements at the centre of the pile. Maximum settlements, Smaxand average settlements, Smax can be estimated using the following relationship, choosing an appropriate a value of the soil compression factor, from Table 2.The driving energy depends on the method of pile installation, soil stratification and the pile type. The displacement volume of the installed pile has been neglected. The simplified method is applicable for estimating settlements at the perimeter of a pile group. It should be noted that settlements also occur outside the assumed cone, but these are often negligible. The effect of incompressible layers should be taken into account by adjusting the effective pile length."

Jan 1, 2004

By Pirooz Barar

The new Stanley Hall building will house the center for bio-engineering and technology research for the UC Berkeley campus. The structure is located at the northeast part of campus, adjacent to Donner Lab, on the west side of Galey Road, approximately 600 ft. from the Hayward Fault. The building site has a complex geological formation. To the east there are clayey soil shale formations, and to the west there is greywake shattered sandstone. The water table is at 10 ft. below grade. The structure will consist of 6 levels below grade and 8 levels above grade, which calls for an 83 ft. deep excavation on the northeast side. There is an approximately 35 ft. grade differential between the east and west sides of the building. Because of this severe grade differential, as well as high water tables, the lateral forces on the building due to uneven earth pressures would have been 2 times the magnitude of the seismic forces. To mitigate the lateral earth pressures, a permanent Soil Nailed Wall, integrated with the structural system of the building was designed. PB&A, Inc.?s in-house design program ?Winslope? was utilized to design the system and the data obtained from a rigorous monitoring program, were used to calibrate several computer runs using Plaxis program.

Jan 1, 2004

With the continued implementation of stricter limitations on the discharge of excess process water from all existing and future mining and metallurgical operations, the design and operation of the entire process water circuit must form an integral part of any total operational package. It is far better to æanticipate and circumvent the problemÆ rather than be forced into an expensive remediation program after the event. By far the greatest problem relates to the treatment and disposal of what is generically known as acid drainage. In simple terms, an acidic metal sulfate solution is generated by a series of chemical and biological reactions as soon as most sulfide minerals are exposed to air and water. Treatment of this solution by one or more of a wide range of chemical and physical options can involve substantial capital and operating costs, although there are recent processing options that yield saleable by-products, thereby reducing the financial liability of what is effectively a waste stream. This presentation provides an overview of the Australian situation compared with the rest of the world and outlines the basic features of a number of the more advanced passive and active acid drainage options.

Jan 1, 2004

By K. Morikawa, K. Asano, J. Yoshitomi

The quality requirements for ladle shrouds have become stricter year by year to the pursuit of higher productivity and improved quality in the continuous casting of steel. The ladle shrouds must be sufficiently durable under severe conditions, such as operation without preheating and during several sequential castings. The consideration is that ceramic fibres, which have been applied in shrouds for thermal insulation during casting, could pose a risk to the worker's health. We realized materials for the ladle shrouds which show high strength and low elasticity. At the same time pursuing effective insulation, a coating which contains no fibres (Foaming Coat) has been developed, replacing the conventional one containing fibres. These materials are durable under conditions of repetitive use and consequently satisfy the customer's demands. The ladle shrouds which were improved in this way have achieved an excellent durable life in hot service of three times that of conventional ones. This paper reports the recent technological developments in ladle shrouds as well as their performance under hot operating conditions.

Jan 1, 2004

By D Craw, C Smith, C Martin

The Wangaloa coal mine closed in 1989, and an attempt to grow Pinus radiata on quartz-rich overburden dumps was not successful. The site is currently being rehabilitated with re-profiling and native plant establishment. Plants are being established in a range of substrates that consist of variably disaggregated Tertiary coal measure sediments derived from the mine sequence. This material has low organic matter content (typically <10 %), originating from coal fines or carbonaceous sediment. Substrate samples were collected during December 2003 from a range of sites varying in age, slope, and parent material. Nutrient analysis includes nitrate, ammonia, total N, total P, available P and readily exchangeable base cations. Total nitrogen and phosphorus are low on areas of recently disturbed, quartz-rich overburden, with total N =1200 mg/kg, and total P =200 mg/kg. Background forested areas have total N ranging between 2800 - 3300 mg/kg and total P of 420 - 500 mg/kg. Quartz-rich overburden sites contain available nitrogen levels of less than 6 mg/kg, while background forested areas are generally >20 mg/kg. The soils and water runoff are generally acid, with pH down to three. Water samples have been collected from both ground and surface resources on a monthly basis since December 2003. The main lake on the site had pH of 4.6 in 1999, and this remained relatively unchanged when 850 tonnes of lime were added in 2002. However, the lake pH changed to 6.4 within a one month period in 2004, and has fluctuated since that time.

Jan 1, 2004

This paper examines the integration of risk management into the design philosophy of a project to produce a æzero baseÆ design, which targets a minimum capital cost without adversely impacting upon the operating costs of the resulting plant. The concept of zero base design is similar to zero base budgeting and the desired outcome is to improve the economy of the design. Design requirements are questioned in an attempt to distinguish preference, prejudice and myth from necessity. Where doubt remains a risk management approach is adopted. The key to risk management is not risk elimination, but risk mitigation. Risks can be managed by designing them out, but often this involves considerable capital cost penalties and it is more attractive to accept the risk and design an operating strategy to deal with it. The paper discusses this with some examples of real world risk mitigation strategies that resulted in substantial capital cost savings. The paper concludes that as much as a quarter of project capital costs can be eliminated by a combination of zero base design and carefully crafted risk mitigation strategies.

Jan 1, 2004

By D. Lunt

Telfer bulk concentrates typically contain 8% chalcopyrite, 8% chalcocite, 45% pyrite and 80-120 g/t gold. Although very high copper and gold recoveries can be obtained by subjecting the concentrate to a "conventional" high temperature pressure oxidation step followed by copper recovery by solvent extraction and electrowinning, and cyanidation of the leach residue for gold recovery, the cost of lime required for neutralisation and power for oxygen generation was such that the process was uneconomic in terms of operating costs. The challenge therefore was to develop an alternative flowsheet that maximised copper and gold recovery in which the reagent costs were commercially attractive. An additional objective was to reduce the capital cost so that the overall NPV and IRR values would enhance the economic viability of the total project. Following a series of batch and locked cycle testwork programs, supported by Metsim modelling, it was established that the same high levels of overall copper and gold recoveries can be obtained by use of a novel two-stage split leaching circuit in which the chalcocite component is leached in a low temperature (90-110°C) circuit with the chalcopyrite component treated in a high temperature (220-250°C) circuit. This split circuit has a number of advantages, including minimising the required capacity of the high temperature autoclave, as well as reducing the overall lime consumption and simplifying the total process water balance. The paper outlines the basis for the development of the flowsheet and discusses the integration of the leaching stages into the overall circuit.

Jan 1, 2004

By Robin M. Forbes. Jones, Suhas V. Patankar, Ramesh S. Minisandram, Jr. Carter, Kanchan M. Kelkar

"The nucleated casting process currently under development has the potential for production of Ni-base superalloy preforms that possess superior microstructure to product made by conventional casting processes, primarily for gas turbine applications. In this process, electroslag remelted (ESR) clean (i.e., free of ceramic inclusions) molten metal is conveyed via a watercooled copper Cold-walled Induction Guide (CIG) to a gas atomizer. The spray of clean metal droplets is then directly cast into a water-cooled crucible for ingot production. The microstructure of the resulting ingot preform evolves within the length scale of the individual droplets and is a function of the thermal state of the incoming metal droplets. This, in turn, depends on particle size, flight time and heat exchange with the gas phase.In the present study, computational models is developed for the analysis of the flow and heat transfer in the gas-metal spray system under axisymmetric and steady-state conditions. The gasphase flow is analyzed using an Eulerian framework and turbulent mixing within the gas phase is modeled using the two-equation k-e model. The dynamics of the metal particles is analyzed using a Lagrangian framework that involves calculation of the trajectories of the metal droplets. A two-way coupling is considered whereby the transport and heat transfer in the gas and the metal phases influence each other.The analysis is developed at two levels. The spray model performs a detailed calculation of the spray dynamics in the vicinity of the spray and is intended for predicting the temperature and mass flux distributions of the metal spray depositing into the mold. The chamber model enables prediction of gas flow and motion of metal particles in the entire spray chamber."

Jan 1, 2004

By Y. I. Rabinovich, S. C. Brown

In the Florida phosphate industry, fatty acid collectors are used to separate phosphate ore from silica during the rougher flotation stage. However, the presence of multivalent ions (in particular Ca++) in the processing water has been reported to result in the activation of silica with respect to oleate adsorption, rendering it floatable. Hence, adequate separation may not be achieved during the rougher flotation stage. In this study, the direct measurement of surface inter-action forces via atomic force microscopy was used to delineate possible mechanisms for calcium activation under phosphate flotation conditions at oleate/calcium concentrations both above and below the calcium dioleate precipitation limit.

Jan 1, 2004

By W. D. Gould, F. Goodazi, W. F. A. Duncan, A. G. Mattes

A biological treatment system designed to passively remove high concentrations of metals from leachate collected from a landfill near a large integrated zinc lead smelter has been in operation intermittently for the past five years including winter time operations. High metal removal efficiencies in the system were achieved. After 729 days of operation and treating over 8 million L of water the original anaerobic bioreactor constructed in 1997 was taken apart and rebuilt. The deconstruction of the bioreactor allowed systematic sampling at all depths of the biological matrix. Samples were analyzed for metal, S and TOC concentrations; as well bacterial populations were determined. Results of this sampling procedure are examined and compared at various depths within layers and between layers using one-way ANOVA and linear regressions. Metal concentrations were positively correlated with sulphur and negatively with total organic carbon. This is in concurrence with a model of biogenic precipitation of metal sulphides.

Jan 1, 2004

By J. A. Kromhout, J. Trouw, A. A. Kamperman, M. Kick

Mould powders play an important role in the stability of the continuous casting process. The main functions of mould powders are to provide sufficient lubrication and to control the horizontal heat transfer. Because process control of thin slab casting is more stringent, it is generally assumed that mould powder properties become more critical as well. In 2000, the Direct Sheet Plant at Corus IJmuiden (DSP) was commissioned, incorporating a thin slab caster designed for casting speeds up to 6 m/min. During commissioning, several operational problems with mould powders were encountered i.e. insufficient liquid pool depth and the formation of rims/lumps. To investigate the operational mould powder problems, some of the mould powders were characterized using physical and mineralogical methods. The results were linked to operational experiences. It was concluded that for thin slab casting, a stable slag formation is obtained with a proper choice of free carbon and an even distribution of the carbon particles within the granules. The physical properties of mould powders are not as critical as expected when the additional mineralogical requirements are taken into account. Keywords: mould powder, characterization methods, thin slab casting.

Jan 1, 2004

By Eugene Nel, Johan Theron, Chris Martin, Hans Raabe

"Impala Platinum Limited is the world’s second largest platinum producer, producing more than 1.7 million ounces of the precious metal last year, much of this from the UG-2 reef located in the Bushveld Complex, South Africa. As part of Impala’s ongoing expansion programme, tonnage through their principal UG-2 processing facility, near Rustenburg, was increased 40% in 2001.To accommodate the increased throughput, the role of the existing primary mills was converted from conventional semi-autogenous grinding units, to attrition and selective grinding units, operating in fully autogenous mode. The finer chromite and coarser silicate components in the mill discharge are then separated by screening and processed in dedicated circuits downstream. This way, the need to spend considerable capital to increase primary grinding capacity was averted.In the last year, considerable work has been conducted to evaluate and optimise the two downstream circuits. This has involved an optimisation programme of sampling and diagnostic flotation testing, supported with QemSCAN analysis. This paper will describe the operation of the new circuit. It will also describe some of the more novel aspects and interesting findings from the optimisation programme.INTRODUCTIONThe South African platinum industry is the world’s largest producer of platinum and the world’s second largest producer of palladium. Located in a wide area north of Johannesburg, the industry mines ores from the Bushveld Complex, one of the world’s great mineral treasure chests, containing over 70 percent of the world’s platinum, as well as extensive reserves of the other PGE (platinum group elements), chrome, manganese and vanadium. The industry employs about 180,000 people in, predominantly, underground mines, which together form an almost unbroken circle of mining operations 200 km in diameter."

Jan 1, 2004

By Larry M. Southwick

Considerable process and equipment development and analysis were conducted during design of Freeport Sulfur's laterite nickel facilities in the late 1950's. These covered ore concentration at Moa Bay, Cuba, and concentrate refining at Port Nickel, Louisiana. Both facilities utilized acid pressure leaching and product refining steps that were similar to those later used elsewhere in the laterite processing industry. Unfortunately, developments in Cuba removed the Moa Bay facilities from Freeport control. This deprived the project of a start-up that would have allowed thorough resolution of difficulties and a quicker attainment of production capacity. This meant lost opportunity to positively prove and complete the technology when optimum resources and staff were available. This paper reviews the original rationale of how design was developed via laboratory, bench scale and pilot studies by Freeport Sulfur. Some later operating problems will also be discussed. This case is unusual, but the lessons learned may be instructive in the application of difficult and complicated technologies, as well as the need to understand and retain access to the original development and design activities Keywords: Moa Bay, Freeport Sulfur, Port Nickel, acid pressure leaching, pilot plant, pachuca, Chemical Construction, pressure letdown, cobalt, titanium

Jan 1, 2004

By Paul Hagan

A diverse range of rockbolt designs and resin anchors are available for use in underground mines. Despite their wide spread use, the factors that affect the performance a rockbolt is not fully understood. The laboratory-scale rockbolt test facility at the UNSW Mining Research Centre is being used to gain a better understanding of the behaviour of rockbolts leading to an improvement in ground support. A test program investigated the nature of load transfer between a fully encapsulated rockbolt and the surrounding rock mass. It was found that with all other factors held constant, there were differences in the behaviour of load transfer depending on the method of loading. The typical pull-out arrangement as used in most field test work resulted in a different load transfer function to that observed when the load on the rockbolt was induced through bed separation.

Jan 1, 2004