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By Jie Li, Zhongliang Tian, Xun Hu, Kai Zhang, Yanqing Lai, Hongliang Zhang

The Al-Sc Alloys show many advanced properties for a wide range of engineering applications. But the metal Sc must be added into the metal Al in the form of the Al-Sc master alloy, which is usually produced by the thermal reduction process. In this paper, the decomposition voltages of Sc2O3 and Al2O3 in Na3AlF6-K3AlF6-AlF3 melt were calculated based on the Nernst equation. And the Al-Sc master alloy was prepared in the melt at 950°C by electrolysis. The results show that the Al-Sc master alloy can be prepared by the co-deposition of Sc3+ and Al3+ at the cathode if the concentration ratio of Sc2O3 to Al2O3 in the melt is more than 2:1 under the condition of the aluminum electrolysis. SEM and ICP analysis of the product indicates that the Al-Sc master alloy is made of the phase Al and the phase Al3Sc.

Jan 1, 2016

By Tianzu Yang, Weifeng Liu, Lin Chen, Wei Chen, DUCHAO ZHANG

Ni-M (Metal=Cu, Fe, Co, Mn, Zn, Cr) aerogel catalysts were tested for CH4 oxy-CO2 reforming. It was found that the Ni-Co bimetallic aerogel catalyst had the highest activity and stability in methane oxy-CO2 reforming among all the Ni-M aerogel catalysts. It exhibited a steady activity of 79 % (in terms of CH4 conversion) at 750 oC, which is the highest activity under a similar reaction condition as compared with those published in literature. Characterizations for the reduced catalysts indicated the formation of Ni-Co alloy, while other transition metals separated from Ni during the reduction process. Therefore, the active species in the Ni-Co bimetallic catalyst showed a stronger interaction than those in other Ni-M catalysts, which might be one of the main reasons for the better catalytic performance of the catalyst.

Jan 1, 2016

By Yang Hai-long, FAN Gang, LI Cun-xiong, WEI Chang, LI Min-ting, LI Xing-bin, DENG Zhi-gan

Hydrothermal sulfidation of pure cerussite with elemental sulfur has been reported in the present paper. The variables considered in the study were temperature, time, particle size and elemental sulfur fraction in the reacting mixture. Temperature was the most important factor at temperatures above 180 , PbS and PbSO4 were the only stable reaction products in the sulfidation of cerussite. The experimental data indicated that under the hydrothermal conditions with a particle size of -74+58 μm and sulfur fraction in reacting mixture of 15% at 200 °C for 120 min, and 92% of lead sulfidation rate was achieved.

Jan 1, 2016

By Xudong Liu, Feng Chen, Yufeng Guo, Wei Chen, Tao Jiang

Willemite is typically found in oxidized zinc ores and metallurgical secondary resources but without effective extraction method yet. Based on the ideas of zinc phase reconstruction in the willemite, the extraction of zinc from willemite by calcified-roasting using CaO as additive and ammonia-leaching process was studied in this paper. The influences of CaO dosage, roasting temperature, roasting time on the phase transformation and zinc leaching rate were studied, which were characterized by XRD. The results indicated that Zn2SiO4 was transformed into ZnO or Zn2CaSi2O7 .After roasted with 1.4 times of theoretical CaO dosage at l280 for 40 minutes, willemite was thoroughly transformed into ZnO. The zinc leaching rate of the roasted sample was 97.45% in NH4Cl-NH3 H2O leaching system, which increased by 91.40 % compared with zinc leaching rate of 6.05% when willemite was directly leached in NH4Cl-NH3 H2O system.

Jan 1, 2016

By Chen Chen, Wang Yanze, Hong Xin

Furnace superalloy was applied in harsh environment within the erosion of high temperature and oxidizing atmosphere. With plasma powder surfacing technology, iron-based alloy powder was sprayed on the surface of 310S stainless steel to form oxidation layer that increases the oxidation resistance and reduces the cost of materials. With optimum technological parameters, in this paper, oxidation test of 100 hours on iron-based cladding alloy and furnace alloy were carried out at 1200 . The technique of XRF, XRD and EDS were used to characterize composition, oxide morphologies and surface mechanical properties. The results showed that Element composition of cladding layer formed by Plasma powder surfacing was well distributed. Its oxidation weight gain rate of 100 hours was 0.4552g/m2h, belonged to antioxidant level. The oxidation weight gain rate of furnace alloy was 1.4617g/m2h, belonged time-antioxidant level. And on the mechanical comparison test, surfacing alloy is relatively excellent than furnace alloy.

Jan 1, 2016

By Bart Blanpain, Tom Peter Jones, Muxing Guo, Liugang Chen, Huayue Shi

Fayalite based slag is formed during the smelting process of secondary copper resources. It was found that with the presence of high ZnO, the slag became viscous, causing a slag tapping problem. In the present paper, the phase relations of the slag system ZnO-“FeO”-SiO2-Al2O3- CaO (ZnO = 0-12 wt%, Al2O3% = 0-15 wt%, CaO = 0-1.5 wt%, with iron saturation) at 1150 °C is studied by using quenching technique followed by phase identification and compositional analysis of equilibrated samples. The dependence of FeO and Al2O3 solubility in the liquid slag on the chemical composition of slag is characterized. Based on the experimental data, the solid fraction of the slag, which may considerably, influences the slag viscosity, at the tapping temperature can be reasonably estimated and, therefore an appropriate modification of the slag composition can be made.

Jan 1, 2016

By Qiang Zhong, Qian Li, Yongbin Yang, Tao Jiang

Thermogravimetric analysis (TGA) has been used to research the pyrolysis and combustion processes of coal used in rotary kiln of iron ore oxide pellet. Furthermore, the effects of air flow and oxygen concentration on the combustion behavior of coal were examined with TGA. The results showed that two individual stages can be distinguished for the pyrolysis of coal, the water evaporation stage and the de-volatilization stage. And the information on ignition and burnout characteristics can be obtained from the combustion process analyzed by TGA. Large air flow almost has no effect to the combustion process except that it enhances combustion intensity. However, the combustion process is further accelerated under oxygen-enriched conditions. With all experimental results, it could provide an attractive approach of analyzing coal for the rotary kiln process.

Jan 1, 2016

By Chang Wei, Zhigan Deng, Yizhao WANG, Cunxiong Li, Gang Fan, Xingbin Li

During the process of hematite precipitation, the transformation of Na jarosite convert into hematite has been studied in a batch reactor at different temperatures, ranging from 170°C to 200°C with 3h of the retention time in the presence of 30g/L Fe ( ) and 4g/L Na+. The composition of precipitation was seriously depended on the temperature, at 170°C hematite and sodium jarosite are the reaction products of iron precipitate, with an increasing in reaction temperature the sodium, sulfur content in precipitated decreased and sulfur mainly exist in forms of SO4 2-, and when temperature over 200°C hematite was the only phase in product. An increasing temperature was not only beneficial to iron precipitation, also conducive to jarosite conversion to form high quality hematite precipitate.

Jan 1, 2016

By Yanhui Liu, Xuewei Lv, Pingsheng Lai, Chenguang Bai

The purpose of this paper is to study the effect of slag basicity on the Si content in stainless steel master alloys prepared by smelting reduction of Fe-Ni-Cr sinters. Theoretical analysis focusing on the gas, slag and alloy phases of the smelting reduction process at 1600°C was carried out by thermodynamic calculation software----FactSage, showing that the increase of CaO within the slag can result in the decrease of Si within the master alloy. Experiments were also carried out in vacuum melting furnace at 1600°C , and chemical analysis method was used to detect Si content in the alloys. When the MgO content is 9.00%, the experimental results were consistent with the calculated values. However, when the MgO content rises up to 14%, the content of Si in the alloy reaches the maximum when SiO2 equals to 22.81%.

Jan 1, 2016

By Yuzhe Zhang, Xiaodi Huang, Xinli Wang, Bowen Li, Matthew Andriese, Jiann-Yang Hwang, Zhiwei Peng, Likun Li

With the development of the world, the waste tires have been a serious environmental problem. There are about 2 billion waste tires produced all over the world every year and about 500 million waste tires are produced in the United States. Most of the waste tires are land filled, which waste a lot of space. It takes hundreds of years to resolve the macromolecules of waste tire into the standard which does not pollute the environment. Microwave irradiation is a thermal processing way for waste tires decomposition. In this study, the relative dielectric loss factor of the tire at various temperatures was determined to understand the behavior of tires under microwave heating.

Jan 1, 2016

By Saeid Pournaderi, Ahmet Geveci, Ender Keskinkilic, Yavuz A. Topkaya

There are mainly three commercial nickel laterites in Turkey: Gordes, Caldag and Sivrihisar. The first two appear in Western Anatolia. The third one, Sivrihisar (Yunusemre) laterites have been found in the first decade of the millennium, in the Central Anatolia region of Turkey. Since then, mining facilities have been continued in Yunusemre. Calcination, prereduction and smelting of Sivrihisar laterites have been extensively studied and published. In the current work, some results of the studies related to characterization of Sivrihisar laterites will be presented.

Jan 1, 2016

By Huimin Lu, Zhijiang Gao

Reduction reaction can happen among Al, V2O5 and TiO2 powders. Al can deoxidize metal V and Ti from the metal oxides. The electric igniter can be used to trigger the reduction. The reaction between Al and V2O5 is very intense and release large amounts of heat, but the heat which is needed to initiate the reaction between Al and TiO2 is not enough. These two reactions have been initiated first and V-Al and Ti-Al alloys can be obtained with a higher metal recovery percent. Through adjusting the ratio of Al, V2O5 and TiO2 powders, the system which combines these two reactions can ensured enough heat to react. KClO3 is added to the system, as the ignition agent, in order to make the reaction much complete. Finally, Ti-Al-V alloys can be obtained and need remelt to adjust the constituents.

Jan 1, 2016

By Nobuaki Sato, Tetsuo Fukasawa, Akira Kirishima

To apply the fluoride volatility process for the treatment of fuel debris formed in the damaged nuclear reactors, study on the fluorination behavior of main constituents, such as fuel and cladding is essential. The mixture of uranium and zirconium oxides is formed under severe conditions such as high temperature and oxidizing atmospheres. In this paper, fluorination and volatilization behavior of uranium and zirconium oxides have been studied by TG-DTA method in the presence of fluorine. From the TG-DTA result of UO2 in F2 atmosphere, the weight gradually increased up to 7% at 350 oC followed by rapid weight decrease with exothermic peak showing the vaporization of uranium as UF6. ZrO2 showed similar fluorination behavior to that of UO2. However, fluorination of UO2-ZrO2 seemed to be suppressed with increasing ZrO2 amount. This may be caused by the formation of solid solution.

Jan 1, 2016

By D. R. Willmer, E. J. Haas

As national and international health and safety management system (HSMS) standards are voluntarily accepted or regulated into practice, organizations are making an effort to modify and integrate strategic elements of a connected management system into their daily risk management practices. In high-risk industries such as mining, that effort takes on added importance. The mining industry has long recognized the importance of a more integrated approach to recognizing and responding to sitespecific risks, encouraging the adoption of a risk-based management framework. Recently, the U.S. National Mining Association led the development of an industry-specific HSMS built on the strategic frameworks of ANSI: Z10, OHSAS 18001, The American Chemistry Council’s Responsible Care, and ILO-OSH 2001. All of these standards provide strategic guidance and focus on how to incorporate a plan-do-check-act cycle into the identification, management and evaluation of worksite risks. This paper details an exploratory study into whether practices associated with executing a risk-based management framework are visible through the actions of an organization’s site-level management of health and safety risks. The results of this study show ways that site-level leaders manage day-to-day risk at their operations that can be characterized according to practices associated with a risk-based management framework. Having tangible operational examples of day-to-day risk management can serve as a starting point for evaluating field-level risk assessment efforts and their alignment to overall company efforts at effective risk mitigation through a HSMS or other processes.

Jan 1, 2016

By K. W. Harris, K. A. Perry

Underground coal mines beneath Black Mountain in the Harlan County district of the Central Appalachian coalfields have an extensive history of bump events, which yields an elevated probability for significant injury or fatality to underground miners. According to Mark (2009), Harlan County has had the greatest concentration of deep-cover retreat mining in the United States. Combined with the extensive multiple seam mining history, room-and-pillar coal bumps have had a disproportionate impact on coal operations in this region. The Harlan seam, one of the principal, economically recoverable coalbeds exploited beneath Black Mountain, has a significant burst history that extends into modern times. A numerical investigation using the LaModel software of 17 bumps that occurred at the same mine in the Harlan seam was conducted and used to create a calibration methodology which serves as the quantitative basis for current and future numerical efforts in an adjacent mine exploiting the same reserve. In addition to this numerical study, a qualitative assessment of the geologic factors that are believed to contribute to the bump potential was completed. Combined with stability prediction using the numerical basis, these geologic factors will be used for recognition of high bump potential areas with the goal of reducing the potential for future bumps, helping to ensure the highest level of safety and productivity for underground personnel.

Jan 1, 2016

By P. T. Bissert, D. S. Yantek, L. Yan, M. D. Klein

Federal regulations require that refuge alternatives (RAs) be located within 305 m (1,000 ft) of the working face and spaced at one-hour travel distances in the outby area in underground coal mines, in the event that miners cannot escape during a disaster. The Mine Safety and Health Administration mandates that RAs provide safe shelter and livable conditions for a minimum of 96 hours while maintaining the apparent temperature below 35 °C (95 °F). The U.S. National Institute for Occupational Safety and Health used a validated thermal simulation model to examine the mechanisms of heat loss from an RA to the ambient mine and the effect of mine strata composition on the final internal dry bulb temperature (DBT) for a mobile tent-type RA. The results of these studies show that 51 percent of the heat loss from the RA to the ambient mine is due to radiation and 31 percent to conduction. Three mine width and height configurations and four mine strata compositions were examined. The final DBT inside the RA after 96 hours varied by less than 1 °C (1.8 °F) for the three mine width/height configurations and by less than 2 °C (3.6 °F) for the four mine strata compositions.

Jan 1, 2016

By D. S. Yantek, R. J. Matetic, A. K. Smith, E. D. Thimons, J. Srednicki

In a 2007 report to the U.S. Congress, the Office of Mine Safety and Health Research of the U.S. National Institute for Occupational Safety and Health (NIOSH OMSHR) stated that built-in-place refuge alternatives (BIP RAs) provide significant advantages over mobile refuge alternatives. At present, the requirement to locate refuge alternatives within 305 m (1,000 ft) of working faces makes BIP RAs impractical in most coal mines. BIP RAs would be practical if three issues are addressed: (1) allowing BIP RAs to be located at greater distances from the working face, (2) developing a reliable process for the design and approval of BIP RA stoppings that meet the 0.1-MPa (15-psi) design criteria, and (3) developing systems that reliably deliver breathable air to the refuge alternative. In 2015, NIOSH OMSHR conducted a study of these three issues and issued a report. In the report, justification was provided for allowing the placement of BIP RAs at greater distances from the working face than the currently mandated 305 m (1,000 ft), guidelines were developed that could be used by industry when submitting BIP RA stopping design applications for approval which are patterned after the Mine Safety and Health Administration guidelines for coal mine seal design applications, and insights were provided into options for providing a reliable supply of clean, breathable air to BIP RAs. This paper presents a summary of the study’s findings and also addresses issues discovered during the building and designing of a BIP RA that OMSHR researchers constructed in NIOSH’s Experimental Coal Mine in Pittsburgh to research the testing and improving of BIP RAs. These issues include several issues related to the delivery, distribution and exhaust of ventilation air to the BIP RA and some general construction issues that require further investigation.

Jan 1, 2016

By C. V. Deutsch, D. A. Silva

The geologic modeling of multiple domains is required for the prediction of mineral resources and reserves. In general, explicit methods have wide acceptance among modelers due to the ability to manually add deemed important trends and geological features into the models. As an alternative, implicit geologic modeling techniques are increasingly adopted to reduce professional time requirements. These methods aim for objective, repeatable and flexible models by replacing the manual time-consuming interpretation of sections with the interpolation of signed distance values. These techniques, however, have been developed for the binary case of two domains at a time. The current paper presents an algorithm that extends the binary case to multiple domains. The method is able to transfer large-scale geological features from data to geologic models. A case study illustrates the benefits of the algorithm and practical implementation considerations.

Jan 1, 2016

By W. R. Reed, D. E. Pollock, T. W. Beck, J. A. Organiscak, J. D. Potts

In underground continuous mining operations, ventilation, water sprays and machine-mounted flooded-bed scrubbers are the primary means of controlling respirable dust exposures at the working face. Changes in mining arrangements — such as face ventilation configuration, orientation of crosscuts mined in relation to the section ventilation and equipment operator positioning — can have impacts on the ability of dust controls to reduce occupational respirable dust exposures. This study reports and analyzes dust concentrations measured by the Pittsburgh Mining Research Division for remotecontrolled continuous mining machine operators as well as haulage operators at 10 U.S. underground mines. The results of these respirable dust surveys show that continuous miner exposures varied little with depth of cut but are significantly higher with exhaust ventilation. Haulage operators experienced elevated concentrations with blowing face ventilation. Elevated dust concentrations were observed for both continuous miner operators and haulage operators when working in crosscuts driven into or counter to the section airflow. Individual cuts are highlighted to demonstrate instances of minimal and excessive dust exposures attributable to particular mining configurations. These findings form the basis for recommendations for lowering face worker respirable dust exposures.

Jan 1, 2016

By G. J. Joy, J. P. Rider

Technical advances in longwall mining over the last several years have resulted in much larger and faster shearers that have the capability of mining at speeds over 30 m/min (100 fpm). This has resulted in a substantial increase in the amount of dust that is generated at the shearer and during shield advances. Meanwhile, increased underground coal production has put a greater demand on longwall dust control systems as some operators have had difficulty maintaining consistent compliance with federal dust standards. To address this need, the U.S. National Institute for Occupational Safety and Health (NIOSH) is investigating the effectiveness of a water spray manifold mounted on the tailgate end of the shearer body. The sprays are oriented parallel to the tailgate ranging arm, and these sprays create a water curtain confining the dust plume near the face, preventing the dust from drifting into the walkway. This redirection of dust provides a clean air envelope for the tailgate shearer operator and jacksetters working near the tailgate drum. Three different tailgate spray manifold designs were tested and evaluated at the Office of Mine Safety and Health Research (OMSHR) Pittsburgh Longwall Test Facility. Manifolds were equipped with hollow cone or flat fan water spray nozzles and evaluated at three face air velocities — 152, 213 and 274 m/min (500, 700 and 900 fpm)— and at water pressures of 689, 1,034 and 1,379 kPa (100, 150 and 200 psi). Reductions in dust concentrations were observed at six face sampling locations for all the tailgate manifold systems at each of the tested spray pressures and face velocities. Average reduction efficiencies of at least 90 percent were seen at the three sampling locations closest to the shearer for all three manifold systems at nozzle spray pressures greater than 689 kPa (100 psi). Based on results from the laboratory tests showing reductions in dust concentrations at sampling locations downwind of the shearer, a spray manifold was fabricated and evaluated at an underground operation.

Jan 1, 2016