Search Documents

By J. F. Tavernelli, L. F. Coffin

The deformation and fracture characteristics of eight metals subjected to fully reversed cyclic strain ranging from 0.2 to 50 pct were investigated at room temperature. Strain-hardening characteristics unique to the interna1 structure of a particular metal were found. Complete removal of the strain-hardening effects resulting from prior deformation was brought about by subsequent cyclic strain. Further support for the validity of the inverse relationship between the plastic strain range and the square root of the number of cycles for failure is given. THE resistance of materials to cyclic plastic strain is of interest both from a fundamental and practical point of view. It is now a well-accepted fact that fatigue failure in metals is a consequence of the localized slip deformation which occurs within the individual crystals of metal.'-' Hence the failure process should be strongly dependent upon the magnitude of the gross cyclic plastic deformation of the metal under conditions where this is a measurable quantity. Therefore, an experimental investigation of metals in which the cyclic plastic strain is the independent variable should shed new light on some of the basic aspects of the problem. From the practical point of view, there are many uses for information relating to the cyclic strain resistance of metals. One is the case of thermal stress fatigue where fatigue failure can occur as a consequence of a com- paratively few cycles of thermally induced mechanical deformation. Another is the mechanical working of metals where large cyclic strains are employed. In recent years several publications have appeared relating to the cyclic-strain resistance of metals,8-11 dealing mostly with the fracture aspects where the temperature is cycled simultaneously with the mechanical strain. Some work has been reported on the cyclic-strain resistance of metals at constant temperature, again oriented more toward the fracture aspects of the problem than the deformation aspects. 12-16 The present research investigation was undertaken to obtain information regarding the deformation characteristics of several metals whose structure-property relationships were simple and straightforward under conditions of both cyclic and monotonic strain. It has been shown for example that under cyclic-strain conditions some materials will strain harden, while other materials, particularly cold-worked structures, strain soften and these effects required further clarification.8,17-19 It was also de-

Jan 1, 1960

By William Gleason

"The Colorado School of Mines has used the Edgar Mine in Idaho Springs as an experimental mine to teach students since 1921. Since the school acquired the former gold, silver, lead and zinc mine, countless students have received hands-on engineering lessons on their way to earning mining engineering degrees. On Dec. 14, the House Subcommittee on Energy and Mineral Resources held a historic field hearing about the future of mining education in the United States in a classroom about 300 m (1,000 ft) inside the Edgar Mine. Representatives Doug Lamborn (R-CO), Rob Bishop (R-UT), Cresent Hardy (R-NV) and Ed Perlmutter (D-CO) were on hand for the first ever congressional hearing held in a mine where they heard testimony supporting the Mining School Enhancement Act, which was introduced to Congress by Hardy and Perlmutter on Oct. 9, 2015. The act, which is part of a larger mining development and reclamation reform package, seeks to address the absence of a viable pipeline necessary to replenish current faculty vacancies in United States Mining Schools. “What better place to hold a hearing to discuss the need for future mining engineering experts,” Subcommittee Chair Lamborn said in his opening statement. “It is a need felt by industry, states, the federal government as well as nonprofits.” The Mining School Enhancement Act would redirect millions of dollars in fees that are being collected from active mining operations to fund the research and educational programs at engineering schools with mining programs. Those fees now are being used in the form of grants awarded by the Surface Mining Control and Reclamation Act of 1977 (SMRCA)."

Jan 1, 2015

By M. van de Vijfeijken

This paper will first give a short overview of the Copper Mountain project in British Columbia, which just has started commercial operation earlier this year. The grinding process with one 34' x 20' SAG mill and two 24' x 39.5' ball mills will be briefly discussed. All three mills are gear driven by a ring gear, dual pinion and two low speed synchronous motors. Copper Mountain has installed on all three mills, the new state-of-the art dual pinion mill drives. All the inherent operation and maintenance features of this drive technology will be discussed, as well as the advantage of having variable speed control also on the ball mills. The installation and commissioning of the mills and drives at Copper Mountain will be briefly reviewed. Finally the first field measurements on these low speed mill drives will be presented, with the main focus on the low mechanical stress impact of these mill drives on the pinion and ring gear, as well as the accuracy of the load sharing between the two motors.

Jan 1, 2012

By Dan Brown

This paper presents a case study of a cyclic lateral pile load testing program performed on two 18-in square prestressed concrete piles (PSC) in Savannah, Georgia. The load test program was developed to simulate the lateral behavior of a single pile under seismic loading conditions for the design and construction of a large LNG storage tank. The lateral load tests included cyclic loading to measure possible degradation in soil response followed by static loading to large displacements (around 6 inches at the loading point). The lateral load was applied through a reciprocating jack positioned to push and pull the piles against each other. The test piles were instrumented with multiple displacement transducers, downhole inclinometer, and strain gauges. This paper provides an interpretation of the test results regarding the pile performance and soil response to monotonic and cyclic lateral loading. A backfitted computational model of the soil resistance was developed to match the test results using the LPILE computer program. The load-deflection and deflection/moment versus depth comparisons suggest that this model appears to capture the behavior relatively well within the general range of suitability for design purposes. New design curves were developed based on the soil parameters derived from the lateral load test results.

Jan 1, 2003

By K G. van den Boogaart, U Mueller

"An accurate prediction of benefit for some types of ore may require not just the ore grade, but a whole compositional characterisation of the estimates; that is, its full mineral composition including waste composition and nuisance elements. An example is Nickel laterite ores, where Ni/Co content must be complemented by estimates of many other elements, as these might have a notable impact on ore processing.Estimates are often obtained with (co-)kriging or co-simulation; however, geostatistics applied to compositional data may yield spurious and inconsistent results because of the constant sum constraint. The log-ratio approach avoids such problems. It proposes a three-step procedure: data are mapped to a set of log ratios of components; for example, the additive log-ratio transformation (alr) transformed scores are modelled with an appropriate fully multivariate geostatistical toolbox; for example, direct/cross-semivariograms and co-kriging or co-simulation results are back-transformed to the original units.Some practical aspects may make the application of this technique difficult: the assumption of Gaussianity and the high dimensionality of the compositions combined with the need for using multivariate methods. This contribution compares several ways of treating compositional data (combining normal score transformation, log-ratio transformations, and minimum/maximum autocorrelation factor (MAF) decomposition) with respect to their ability to generate sensible simulations. The various approaches considered are illustrated with a Nickel laterite data set for which ten variables are available. Both theoretical considerations and illustration results suggest that the best combination is (log)ratio-normal score transform-MAF, in this order. The factors so obtained are closer to Gaussian, approximately spatially decorrelated and can be simulated independently. Simulations can later be recombined to alr-simulations, which in turn may be converted back to point compositions. The resulting simulated compositions are compared with a full Gaussian co-simulation of the raw data. The log-ratio methods show reasonable to good reproduction of mean values, and distribution of the data set and by construction satisfy the total sum constraint, in contrast to the simulations based on raw data for which the total sums fluctuate strongly.CITATION:Mueller, U, Tolosana-Delgado, R and van den Boogaart, K G, 2014. Approaches to the simulation of compositional data – a nickel-laterite comparative case study, in Proceedings Orebody Modelling and Strategic Mine Planning Symposium 2014, pp 61–72 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Nov 24, 2014

By Christophe Bragard, Rebecca Reeve

The Regional Connector Transit Corridor (RCTC) Project is a 1.9-mile-long metro light-rail extension project that traverses the historical core of downtown Los Angeles, California. This project aims to improve mobility throughout downtown LA with fewer transfers for riders. It is designed to connect two existing rail lines for a more seamless travel. The project consists of twin bore tunnels, three new stations, and is scheduled to be completed in 2022. The design-build contract was awarded to the Regional Connector Constructors (RCC) in 2014, a joint venture of Skanska and Traylor Bros, Inc. with Hatch Mott MacDonald as the designer. One of the challenging aspects of the project was the construction of a crossover cavern in a narrow public right-of-way surrounded by historical structures. RCC used Sequential Excavation Method (SEM) to construct the crossover cavern measuring 287 ft long by 58 ft wide by 36 ft tall. The initial lining of the cavern featured a 12 in. fiber reinforced shotcrete lining. The initial lining was separated from the final lining by a hydrocarbon resistant membrane, as specified by the standard requirements of Metro. The cavern features a cast-in-place final lining with a thickness of 5 ft 9 inches in the invert and 18 inches in the crown and walls. The structure also features a nonload bearing plenum slab and interior walls for ventilation.

Jun 13, 2021

By Charles L. Kimbell

The year 1980 on the whole was not a good year for the world's mineral industry. The general upturn of activities in 1979 after a rather poor 1978 showing was not maintained with a number of key measurement standards showing downturns. Most notably, the world's steel and petroleum industries recorded significant reductions in output, the former in response to markedly lower demand levels and the latter partly in response to lower industrial consumption owing to general economic conditions and partly owing to successes in campaigns for the reduction of energy use in general and petroleum product use in particular among major importing nations that were feeling the trade balance pinch of ever-higher oil prices. During 1980, a number of political events-some international in scope, some confined to single nations-had significant influence upon world mineral industry activities and mineral commodity supplies, and other political happenings had the potential to significantly affect the industry in future times.

Jan 1, 1982

By Mike Amick

As virgin coal reserves dwindle, more and more mines are being opened in areas with previous mining. As addressed in this conference before, there are solutions available for designing mines extracting coal from reserves with known underground workings above or below the target seam. Often times, however, mining begins with limited knowledge of the underground workings. Even with careful planning, the proposed design has limited success because the ?facts? as presented during planning turn out not to be as accurate as one would like. At National Coal?s Mine #14, mining the Walnut Mountain seam, after driving the main entries in some 34 crosscuts, it was found during routine mine examinations that the pillars had separated from the roof in a few areas of the mains. Immediate roof conditions proved to be sound but questions arose concerning the stability of the main roof and floor. Core tests were done to better determine the rock strengths and characteristics. The paper presents the ideology used to tackle the effects of mining over old works in an operating coal mine. This paper discusses the analysis of the symptoms observed and the steps taken to ensure that this pillar separation was caused by the underlying old workings and that the separation was expected and controllable.

Jan 1, 2009

By Anthony J. Deevy

"Abstract -The Magino gold mine is located 45 km northeast of Wawa, Ontario. There was limit­ ed gold production in the Iate thirties. The present operation was officially opened in October 1988 and produced gold until September 1992. It was a 635 tonnes per day, decline-accessed mine, with ore coming from several small blast hole and shrinkage stopes.The host for the gold is the Webb Lake granodiorite stock which was intruded into the Goudreau Lake Deformation Zone. This east-northeast-striking deformation zone overprints the generally east­ west-striking isoclinally folded metavolcanic and metasedimentary rocks, which make up the east end of the Michipicoten greenstone belt. The ore-shoots are controlled by dextral delatancy associated with the Goudreau Lake Deformation Zone. Shearing, bleaching and silicification accompanied the gold emplacement."

Jan 1, 1994

By Matthew Janes

Statnamic load testing is becoming widely accepted as a method to quickly and economically determine the load-deflection behaviour and ultimate static resistance of high capacity deep foundations. Strain instrumented large diameter bored shafts were tested at four locations for the federal and state Departments of Transportation in the United States. Tests were conducted vertically (to 30 MN) and laterally on the shafts and, in some cases, testing was completed over water. Instrumented shaft test results provided shaft load distribution with depth and shaft shear transfer stress throughout the soil stratum. Shaft end bearing and ultimate end bearing stress values were provided. On two projects, Osterberg load cells provided comparative static data for skin friction and end bearing. Correlations between Statnamic derived static load-displacement results and Osterberg load-deflection results are very good. Statnamic lateral load test results were correlated with static lateral results in addition to providing useful dynamic response and damping data.

Jan 1, 1996

By J. P. Rider, T. W. Beck, J. A. Organiscak

"The National Institute for Occupational Safety and Health (NIOSH), Pittsburgh Mining Research Division (PMRD) has recently developed a series of models utilizing computational fluid dynamics (CFD) to study gas distribution around a continuous mining machine (CM) with various fan-powered flooded bed scrubber discharge configurations in an exhaust curtain working face. CFD models utilizing species transport model without reactions in FLUENT were constructed to evaluate the redirection of scrubber discharge toward the mining face rather than behind the return curtain. The study illustrates the gas distribution in the slab (second) cut. The following scenarios are considered in this study: 100% of the discharge redirected back towards the face on the off-curtain side of the continuous miner; 100% of the discharge redirected back towards the face, but divided equally to both sides of the machine; and 15% of the discharge redirected toward the face on the off-curtain side of the machine, with 85% directed into the return. These models were compared to a model with a conventional scrubber discharge where air is directed away from the face into the return. The models were validated based on experimental data and accurately predicted sulfur hexafluoride (SF6) gas levels at four gas monitoring locations. One additional prediction model was simulated to consider a different scrubber discharge angle for the 100% redirected, equally divided case. This paper describes the validation of the models based on experimental data and the gas distribution results of the CFD models. INTRODUCTION To control methane gas and dust concentrations on continuous mining operations, it is important to provide sufficient quantity of fresh air from the end of tubing or curtain to the active face. In this region, operating machine-mounted water sprays and fan-powered, flooded bed scrubbers can significantly increase the amount of airflow reaching the face [1-3]. However, when an entry is large, especially in higher coal seams, the water spray configuration and the scrubber capacity may not be adequate to maintain sufficient forward airflow to confine the dust cloud to the face. Dust can roll back toward the machine operator as a result [4]. Currently, several coal mines having negligible gas emissions in higher coal seams (2.4 to 3.0 m [8 to 10ft.] thick) with exhaust tubing systems redirect the scrubber discharge back towards the face in an effort to improve dust collection. NIOSH studied the redirected scrubber exhaust techniques for dust and gas control in a full scale CM gallery to assess its potential for industry-wide application [5]. For a CM face, previous studies have concluded that the behavior of gas and respirable dust is a complex process. The distribution/dispersion and transport of gas and respirable dust after they are liberated at the face are governed mainly by their mass properties, the movement pattern of the ventilation air, and interactions with the mining machine and water droplets created by the external water spray systems used for dust control [6-10]. To understand these behaviors in a complex CM environment and to evaluate the effectiveness of various control techniques, numerical modeling has become a necessary supplement to laboratory experiments and field studies."

Jan 1, 2017

By M Hilden, K Barbosa, M Yahyaei, C Ndimande, K Runge, V Jokovic

Classification devices provide a link between comminution and flotation. Basically, it determines which particles are diverted back for additional grinding and which ones pass to downstream flotation. Therefore, the classifiers play an important role in the performance of a mineral processing circuit. Hydrocyclones are the most common classifiers used in wet grinding, despite being associated with poor classification efficiency. Hydrocyclones are widely used due to advantages related to low maintenance as well as reduced capital and operating cost. Other classifiers, such as fine screens, have much better classification efficiency compared to hydrocyclones. The major challenge of using screens in an operation, however, is their large footprint and increased maintenance requirements relative to hydrocyclones. Some researchers have demonstrated that switching from hydrocyclones to screens, as the classifier device in a ball milling circuit, resulted in a 20 per cent increase in plant throughput and significant improvements in coarse particle recovery, resulting in a 6 per cent increase in overall flotation recovery. However, it is known that these benefits of improved classification are very much ore specific, ie depending on the ore response. Therefore, there is a need to estimate the benefits of improved classification in pilot scale testing before the plant could consider the potential classifier upgrade. This paper presents the results of two pilot-scale grinding tests where the ore sample was processed using different classifiers: a traditional hydrocyclone and hybrid classification involving the use of a semi-inverted hydrocyclone followed by a screen. The size specific energy and circulating load were used to compare the performance of the grinding circuit. The grinding product was subject to mineral liberation analysis and the impact of classification efficiency on the mineral liberation is discussed in the paper.

Aug 24, 2022

By V. A. Leão, A. M. Silva, S. M. Bertolino, B. C. S. Ferreira, D. Guimarães

Although not considered a high risk pollutant as compared to toxic metals and acidity, environmental agencies worldwide are proposing regulations to control sulphate in effluents and drainages by setting a threshold value varying between 250 mg/L and 500 mg/L. The aim of this study was thus to compare four different techniques for removing sulphate ions from mining/metallurgy effluents. The first alternative studied was sulphate removal by precipitation as ettringite. Treating a synthetic solution containing 1650 mg/L sulphate at 22±1 ºC resulted in removals close to 85% during continuous precipitation. Sulphate sorption was also investigated using three different ion exchange resins as well as limestone. Fixed bed experiments produced sulphate loadings of up to 70 mg SO4 2-/L resin, at pH 2.0. In neutral wastewaters, limestone is also a potential adsorbent producing a maximum particle loading of 19 mg/g. Sulphate sorption on limestone seems to be an alternative to treating mine waters with sulphate concentrations below the 1200-2000 mg/L range, where lime precipitation is not effective. Subsequently, sulphate removal by sulphate reducing bacteria was also investigated and it was observed that reactor’s hydrodynamic conditions and the choice of substrate are important factors for the process. The different technical aspects of each technology are addressed.

Jan 1, 2014

By E. R. Mitchell

When we grow up in an urban environment and choose to become a part of a way of life, it is sometimes difficult to appreciate the cost of this decision in terms of pollution. Explained in this article is our dependence on technology and the amount of pollution that technology produces. Inventories of air pollution on both a personal and a national basis are given so that the reader may judge the magnitude of the problem. In doing so, it is hoped that the reader will understand the need for a responsible attitude toward pollution by everyone and how he can make a personal contribution.

Jan 1, 1971

By Ted C. Mathews

Pre-concentration by sorting is as old as the mining industry. Inevitably waste rock is broken with ore. Separation may take place in the stopes by selective mucking and transport, or selective loading and transport of ore and waste by 12-cu, yd. shovels and 100-ton trucks in large open pit operations. Hand sorting of 1" to 16" pieces, formerly widely practiced at underground chutes and prior to or following first stage crushing, has greatly diminished in the United States with its high per hour labor cost, although still widely practiced in other countries and, surprisingly, in some of the most modern mills where inexpensive labor is available. The economics of pre-concentration by sorting is attractive since elimination of waste at any cost less than the total milling cost will show a profit. The size at which sorting should be under- taken is determined by the size at which liberation is secured to yield a product of ore and waste, and greatly influences cost and the point in the flowsheet where sorting can be undertaken. In some instances mining costs can be reduced where an inexpensive sorting system to eliminate waste is combined with a less selective and less costly mining method. This is particularly true in deep mines where hoisting capacity determines the rate of extraction and sorting is performed underground, with waste utilized for fill. Hand sorting, while efficient, is expensive because of low sorting rates. Peale (1) quotes man hour capacity at 1/3 ton per hour on sizes 3/4" to 3" copper ore, and up to 5 tons per hour on rich iron ore sized from 4" to 16".

Jan 1, 1974

By L. M. Sekhukhune

The atmospheric leaching of copper-bearing matte by acidic ferric chloride solution was studied at the laboratory scale. The aim was to achieve maximum copper and nickel recovery by investigating the mechanisms of leaching, as well as identifying the effect of temperature, and concentration of ferric chloride and oxygen. Djurleite (Cu1.96S), hazelwoodite (Ni3S2), and Ni alloy were the primary phases detected in the matte. The quantitative composition of the matte was Cu 31%, Ni 50%, S 13%. Fe and Co constituted 2%, with platinum group metals (PGMs) accounting for 0.5%. A maximum nickel extraction of 98% was achieved using two-stage oxidative leaching at 90°C and 11 g/L Fe3+ as compared to 65% under non-oxidative conditions. A copper extraction of 99% was achieved in the first 45 minutes using two-stage non-oxidative leaching, and copper was recovered from solution by cementation. Three processes took place simultaneously throughout the leaching process, namely: dissolution, cementation/ metathesis, and oxidation. The leaching process was found to be diffusioncontrolled.

Jan 1, 2014

By P. Personnet, D. Wheaton, E. Couzinie, V. Demetriou, Brooks. W., G. Girault, M. Meyer, L. Charbonnel

A common problem in Gas Treatment Centers (GTC) from primary aluminium smelters is the temperature of the gas to be treated : above a threshold, filtering media are irreversibly damaged. The traditional way of dealing with high gas temperature is to dilute with fresh air, which implies over sizing - and therefore higher cost for - the GTC in order to have the capacity to treat this dilution air without compromising on pot suction. A system was developed which decreases gas temperature without having to use dilution air. This system is based on water pulverization in gas collectors. The water vaporization leads to a temperature decrease of the gas. A pilot system was trialed in our R&D unit. Satisfactory results led to the development of an industrial system based on Envirocare equipment (partnership), which was trialed in our production plant in Tomago (NSW, Australia). This patented system was then generalized in this plant, which is now using it with success during austral summer.

Jan 1, 2006

By Saieb Haddad, Henry Pate

"Building retaining walls in an urban area is becoming more difficult due to right-of-way restraints. Using standard concrete cantilever walls requires a construction easement behind the walls for installation, which for the most part is unavailable. To install these types of walls in a limited right-of-way requires extensive temporary walls to minimize the construction easement. Top-down construction walls utilizingtie-back anchors for support require either the purchase of the right-of-way or underground easements in the area of the anchors.These problems faced the Department on Interstate 75 widening in Knoxville, TN in an area of a large cut. A multi-story Insurance Building and a large commercial Retail Center were located at the top of the cut. To prevent any impact on the buildings, the walls had to be placed within a limited area. The option of buying the properties was prohibitively expensive. Due to the height of the two walls and the variability of the underling rock line, contiguous caisson pile cantilever walls were contemplated as the only wall type that would be appropriate. The cost of the two walls was estimated to be very close or even higher than the cost of purchasing the two buildings. The Department believed that there must be a better way to deal with the problem. A vertically tied-down pile frame wall constructed from the top-down with a concrete facing was developed. This allowed the construction of the walls to be restricted to the available limited area and provided substantial savings for the State.INTRODUCTIONThe widening of I-40/75 has been a major transportation project in the Knoxville area which is being constructed by the Tennessee Department of Transportation. The project includes 18 Retaining Walls and 13 Bridges.Two of the 18 Retaining Walls, refer to Figure 1, are to support two valuable properties, one being an insurance company housed in a multi-story office building and the other a suburban shopping center which were appraised at $13.0 million and $5.0 million respectively. Due to the 31 ft. (9.5m) maximum height of each of the two Retaining Walls and the limited Right-of- Way of 15.0 feet (4.6m), a contiguous caisson pile cantilever wall was proposed for each of the two retaining wall sites with an estimated cost of $12.0 million each. The contiguous pile cantilever Wall is comprised of a line of caisson piles socketed into underlying competent bedrock. The design required that 4 ft. (1219mm) dia. piles be installed at 6 ft. (1.83m) centers, socketed into rock in order to provide lateral stability and restrict lateral wall movement to acceptable limits. The line of caissons would be fronted with a cast-in-place concrete face wall"

Jan 1, 2007

By O. N. Mohanty, S. Mohan Rao, N. D. Rao, T. Mukherjee, P. V. T. Rao

"Chromite ore is an indispensable raw material in the manufacture of ferro-chrome and charge-chrome, which are used for the production of stainless and other alloy steels. The demand for chromite ore is ever increasing because of increasing consumption of these steels. Keeping this in view, Tata Steel is keen to recover values from fines and wastes, and also to produce value added products from their captive chromite mines and its processing plants.Tata Steel has its captive chromite resources at Sukinda, Orissa. They contain two ore types, i.e. (i) Ferruginous and (ii) Siliceous. The generation of off-grade ores is an increasing trend and simultaneously customer quality requirements are becoming ever more stringent. The ferruginous type ore also contains a considerable quantity of in-situ fines (~20% particles below 0.5 mm) that compound the beneficiation problem.In many places, in India and abroad, mined non-marketable off-grade and low grade chromite ores are upgraded by using either simple classification techniques like screw classification, hydrosizing, hydrocycloning or conventional gravity concentration processes such as Heavy media separation, Jigging, Spiraling, Tabling etc.At Tata Steel, the ferruginous type ores are treated in Chrome Ore Beneficiation (COB) Plant that comprises: a crushing and grinding circuit; a classification circuit using hydrocyclones; and a beneficiation circuit using 4 stage spirals in the coarse circuit (-0.5+0.1 mm) and 3 stage spirals & tables in the fine circuit (-0.1+0.038 mm). In this process, 3 types of tailings are being generated and together analyses about 17 % Cr2O3, which is high. From the present operation the chromite recovery is around 70% and could not produce coarse concentrates (+0.5 mm size). Whereas the siliceous type ore is treated in the Lumpy Ore Processing (LOP) plant, consisting of crushing-washing & classification-hand sorting operations, to produce marketable grade lumpy ore and –10 mm de-slimed fines. These fines are intermittently treated in the COB plant. The higher silica content (greater than 1%) and low Cr/Fe ratio (less than 2.8) are the problems with these concentrates."

Jan 1, 2003

By B. M. Larsen

IN endeavoring to put the art of the steelmaker on a more scientific basis, as a means of securing closer control of the product, we must be severely critical of the basis of any theory we use. In particular, we must be careful to distinguish between factors that are primary and those of only secondary importance. The concentration relations that determine the slag-metal equilibria, which are usually more or less closely attained, are of course of primary significance, but a clear picture of the whole process requires that the actual rates of the several reactions be taken properly into account. At the high temperature of the steelmaking furnace, all reactions might be thought to be very rapid, but some of them in fact are not; the essential causes of this condition are important to a proper understanding of the process. This paper aims to present, and to justify, the viewpoint that the most significant reaction is the oxidation of carbon in the metal, the progress of which determines the oxygen pressure levels in slag and metal and produces stirring effects, all of which influence the course of the process as a whole. REACTION RATES AT STEELMAKING TEMPERATURES General experience in reaction rates makes it almost certain that at steelmaking temperatures equilibrium is attained practically instantaneously when the reactants are well distributed in a single liquid phase -that is, in the so-called homogeneous reactions. The actual slowness of some of the reactions in the open-hearth furnace must therefore be attributed to a relatively slow rate of diffusion within the slag or metal phase, which limits the rate at which the reactants can meet each other in the liquid steel or at its surface. That the reactions can be made to go with great rapidity, by proper mixing and stirring of the reacting phases, is indicated by the following illustrations: I. In the Bessemer process there is intimate contact between air and the whole mass of metal, and the reactions are complete in a few minutes. 2. Perrin1 has demonstrated that by pouring liquid steel into slag contained in a deep ladle, and thereby producing almost a slag-metal emulsion, the phosphorus or oxygen content of the steel is adjusted immediately. 3. Barret, Holbrook and Woods observed a quite rapid rate of desulphurization when powdered calcium carbide was stirred vigorously into liquid iron. 4. When a spoonful of liquid steel is poured into a mold containing aluminum wire, the formation and precipitation of alumina occurs in the fraction of a second required to freeze the surface layer of the tiny ingot. The first three examples all show that any means of increasing the effective surface between slag and metal and promoting intimate mixture of the reacting phases, thereby obviating the limitation imposed by diffusion, will enhance the speed of the steelmaking process.

Jan 1, 1941