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By Ahmad Ghahremaninezhad, Rebecca Radzinski

Arsenic is a highly toxic compound that is naturally found in the environment and is released through the processing of sulphide minerals. Arsenate (As5+) is less toxic than arsenite (As3+) and is soluble in water but can form insoluble precipitates when metal ions are present. The arsenic removal processes used in industry assume that arsenic is in its pentavalent state. Hydrogen peroxide can be employed to oxidize arsenite; however, it is expensive. It has been shown that activated carbon can be used to catalyze the oxidation of arsenite with oxygen as the only consumed reagent at ambient conditions with an efficiency of 99% in less than 24 hours. The mechanism which oxidizes arsenite is not yet understood; however, this study shows that a strong oxidizing agent is formed in-situ. The species and amount of oxidant formed were determined via iodimetric titration and electrochemical methods. The production of oxidant was optimized by comparing the amount of oxidant formed in-situ to the relative amount of arsenite oxidized.

Jan 1, 2015

The NorthMet deposit of PolyMet Mining contains a large reserve of copper-nickel-cobaltprecious metal mineralization. Historically it has been difficult to recover separate copper and nickel concentrates of a quality broadly acceptable to custom smelters using conventional mineral processing techniques. Recently, improved flotation methods have made it possible to produce separate and saleable concentrates which will be produced during initial startup of the NorthMet deposit and construction of the PLATSOL TM hydrometallurgical plant. After the initial transition period, it is planned that production of a bulk flotation concentrate will be followed by PLATSOL TM hydrometallurgical treatment to produce copper, nickel/cobalt and precious metal products. The PLATSOL TM process uses chloride-assisted total pressure oxidation treatment of a bulk concentrate to digest the base and precious metal content of the bulk concentrate into an autoclave solution. Following solid-liquid separation, the solution is then treated sequentially for precious metal recovery by reductive precipitation, copper solvent extraction and electro winning and finally, nickel and cobalt recovery by precipitation. During the pilot plant testing of the PLA TSOUM process for NorthMct bulk concentrate treatment, two variations on nickel and cobalt recovery were tested including mixed hydroxide precipitation with magnesia and separate nickel and cobalt hydroxide precipitation following solvent extraction separation with Cyanex 272. The results of the pilot plant testing of the nickel and cobalt recovery circuits for NorthMet arc presented.

Jan 1, 2009

By Yotamu Stephen Rainford Hara

"The aim of our work is to investigate a low energy and clean route for the recovery of copper and cobalt from complex sulphide mineral concentrates. The mineral concentrates were roasted in air, in the presence of CaO (MS + CaO + 202 =MO+ CaS04) at temperatures below 973K. The roasted products containing CuO, CoO and Fe203 were carbothermically reduced at 1073K within an hour to preferentially reduce copper and cobalt. The kinetics of reactions were studied using the thermogravimetric technique and by characterisation ofreaction products using the XRDSEM-EDX techniques. The effects of MS:CaO ratio, roasting temperatures and physical nature of the mineral concentrates were analysed. The method for capturing S02 by forming CaS04 was analysed for reuse in the process. The energy balance for the above process is compared with that of conventional continuous smelting/converting process.1.0 IntroductionCopper sulphide mineral concentrates from Zambia contains substantial amouot of cobalt. The cobalt metal content in the concentrates ranges between 0.7 and 2 % weight, which corresponds to 3 and 9 % weight copper, based on the spot price of copper ($7 386/tone) and cobalt ($31 000/tone). Although the traditional approach using a combination of roasting-leaching-electrowining steps can be applied to recover copper and cobalt from sulphide mineral concentrates [1-4], there are two major draw backs of the traditional process: (i) the S02 emitted during roasting is too lean for economical conversion for sulphuric acid manufacture, which causes serious environmental pollution. (ii) silver and gold which are normally present in the sulphide concentrates are lost out [5] because they are not leachable by H2S04 or HCl which are the common leachants. The above two problems have been overcome by adopting flash smelting in which a rich S02 gas above 20% is produced [1, 5] and successfully converted into sulphuric acid. The precious metals tend to partition to blister copper and recovered during refming. However, nearly all cobalt is lost into the slag phase uoder oxidising condition which prevails during flash smelting. It is important to note that the cobalt content in the slag can be up to 2.6 % weight [6]. The recovery of cobalt from the slag is a process which requires huge amouot of energy since the slag is smelted above 1873K [6]. With a view of minimising the amouot of energy and S02 emission during metal recovery, our investigation involves roasting the sulphide concentrates in the presence of lime and reducing the roasted samples with carbon."

Jan 1, 2013

By Norman Orr, J. W. Gregg, Jack Wahl

The Pembina Cardium pool is a low permeability, stratified, solution-gas drive reservoir. Water-flooding has proven to be an effective means of pressure maintenance for all areas of the pool in which an economic rate of water injection can be maintained. The majority of water injection wells in the pool are converted oil well~ with capacities greater than 100 millidarcy-feet. If the average injection rate per unit of capacity can be in-creased the lower capacity areas of the pool can be economically flooded. Theory, laboratory work, and two . early miscible-flooding projects with-in the pool suggested that average water injection rates for converted wells could be increased two to three-fold by the initial injection of natural gas liquids and natural gas. How-ever, these two early projects received volumes of natural gas liquid!:' and high-pressure natural gas which would be economically prohibitive for routine stimulation. Area D, one of the Five-

Jan 1, 1962

By Alessandro Marques

Based on a short overview regarding steel defects in the final product, several refractory approaches to maintain or increase steel cleanliness are reviewed in this publication. By applying a ladle to mold approach, one potential to maintain cleanliness is to reduce the probability of air ingress by selection of a suitable slide gate system. Following this path, also the influence of a special configured impact pot is presented to maintain steel quality. Finally, higher productivity as well as cleanliness can be provided by selection of PROIL as a revolutionary product at the casting machine.

Oct 30, 2017

By K. A. Svanstrom, W. R. Opie

Problems associated with deposition of titanium infused chloride baths using TiCl4 as a feed material are reviewed. A potentially workable cell design using Alumdum diaphragms is discussed. Problems inherent to diaphragm-type cells are emphasized and experiments described which led to the development of a cell without a diaphragm. INVESTIGATORS assigned the problem of developing a commercial electrolytic process for making titanium metal have found that they are faced with the difficulty of overtaking rapidly improving magnesium and -sodium reduction processes. The ultimate goal must be a simple process that can be conducted with low-cost raw materials in equipment that is inexpensive to build and operate. This paper deals with some work of a preliminary nature conducted by personnel of the Research Laboratories, National Lead Co., Titanium Division. Many others have reported on the general subject of depositing titanium from fused salt electrolytes. A partial bibliography is attached. PRIMARY CONCEPTS Anyone attempting to deposit titanium metal from fused chloride electrolytes using TiC14 as a source material is faced with at least the following problems: 1) Getting the titanium into solution in the bath. 2) Controlling oxidation and reduction reactions associated with multiple valency of titanium, which result in low electrical efficiency. a) Prevention of dichloride oxidizing to trichloride and trichloride to tetrachloride at the anode. b) Prevention of trichloride from being reduced only to dichloride at the cathode. 3) Prevention of metal formation away from the cathode thru disproportionation of titanium dichloride to satisfy the equilibrium. 3 TiCl2 == 2 TiCl3 Ti [I] 4) Protection of reduced chlorides in the bath from reaction with oxygen from the bath container or air. 5) Removing from the bath the deposited metal formed without allowing it to become contaminated with oxygen or nitrogen. 6) Selecting cell materials of construction which will not contaminate the metal product or cause cell inefficiencies. EARLY EXPERIMENTS The initial attempts made to electrodeposit titanium from fused chloride baths using TiCl4 as a source material indicated that TiCl4 was essentially insoluble in molten chlorides of alkali and alkaline earth metals. If, however, the TiCl4 was introduced close to a nickel cathode some metal could be formed and appreciable quantities of reduced chlorides would be present. These reduced chlorides reacted with any oxygen present in the atmosphere above the bath and would also diffuse quickly to the anode (graphite) where they would react with chlorine and be evolved as TiCl4. The net electrolytic efficiency of such a cell is essentially nil. The TiCl4 evolves from the anode at almost the same rate that it is introduced in the vicinity of the cathode although a small amount of titanium metal can be formed on the walls of the cathodic pipe. It becomes apparent from the operation of such a cell that: metal can be deposited on the cathode, although of small particle size and a nonadherent nature, and when reduced chlorides are present in the electrolyte, TiCl4 can be absorbed, probably by the following reactions: TiCl4 + TiC12 - 2 TiCl3 [21 2 TiCl3 + 2 faradays - 2 TiC12 + C12 [31 DIAPHRAGM CELLS These facts encouraged the development of cells containing diaphragms to prevent migration of reduced chlorides from the cathode area to the anode. Small-scale cells for process development are described by Alpert, Schultz, and Sullivan.20 A larger brick-lined cell incorporating internal heating by passing ac through the bath is shown in

Jan 1, 1960

By Frederick G. Tickell

GEOLOGISTS have been quick to adopt new methods in locating new oil fields and in finding the extensions, laterally or at depth, of the old fields. For most of these new methods he is indebted to the physicist, the engineer, and the chemist, although he has also drawn from such ordinarily unrelated sciences as bacteriology and protozoölogy. These last-named sciences have been of help in problems dealing with the origin of petroleum and, although not of direct application to oil finding, have furnished evidence of value in learning what oil is made from and what are the natural agencies involved in its formation.

Jan 1, 1932

By A. Y. Senchenko, Y. V. Kulikov

"In recent decades HPGR technology has proven itself in comminution circuits of mining plants. High technical and economic performance, lower specific energy consumption and reliability of HPGR equipment makes it an efficient alternative to conventional circuits using stage crushing and rod/ball milling, as well as to AG/SAG circuits. However, despite all the advantages of this technology the correct selection of key and auxiliary equipment is very important since errors at testing and design stages may lead to discrediting of the whole concept of HPGR application. There is a great variety of possible circuit configurations using HPGR, e.g. with circulation of edge product, with crushing of the whole discharge and circulation of screen oversize, successive two-stage crushing, etc. Each type of minerals will require its own optimal crushing circuit. In this context the testing methodology for selection of an optimal configuration becomes of prime importance. It is common knowledge that the best simulation of material crushing and softening within a HPGR can be obtained only in the course of a large-scale pilot test. The main approaches applied to this kind of testworks are described in this article. Special aspects of HPGR technology design and industrial operation are revealed as well. Some operational issues of HPGR equipment and of circuit as a whole were detected. They are related to regions specifics, plants location, and other factors. Process solutions proposed to deal with these issues are also indicated in the article. INTRODUCTIONDesign and construction of the processing plants involving High Pressure Grinding Rolls (HPGR) technology becomes more and more common in mining as this technology has specific technical and economic advantages against the circuits with autogenous/semiautogenous mills (AG/SAG) and other circuits. The main advantage of the technology is low energy consumption and low operation costs respectively. The presence of microcracks and increased content of fine size fractions in the crushed product contribute to reduction of energy required for further ball grinding. Besides, HPGR technology applies a special wear resistant liner that enables significant reduction of operation costs of grinding media and liner comparing with AG/SAG circuits."

Jan 1, 2016

[Separates of all the Technical Publications published in 1930 are available at Institute headquarters. All the papers are on file in public, university and technical libraries, and when so indicated in the list, may be found in the Transactions.] Metal Mining Technical Publi- Title Author Meeting Tran~. cation Volume No. and Page* 264-A.29 Quicksilver Industry in 1929. Im- L. H. Duschak San Francisco T30, 283, 319 provements in the Metallurgy of C. G. Maier and Oct., 1929 Quicksilver and Symposium on The others Present Status of the Quicksilver Industry (With Discussion) (37) 271-A.30 Observation on Ground Movement R. E. Palmer New York T30. 168 and Subsidences at Rio. Tinto Feb.. 1930 Mines, Spain (20) 274-A.31 Development and Installation of the C.L.Berrien New York T30, 139, 166 Hawkesworth Detachable Bit (29) Feb., 1930 276-A.32 Protective Measures . Against Gas 0. A. Glaeser New York T30, 129. 167 Hazards at United Verde Mine (11) Feb., 1930 287-A.33 Use and Cost of Compressed Air (12) R. S. Lewis New York Feb., 1930 314-A.34 Miami Copper Company Method of F. W. Maclcnnan New York T30, 39, YO Mining Low-grade Orebody (44) Feb., 1930 319-A.35 How Human Beings Respond to W. J. McConnell New York Changing Atmospheric Conditions Feb., 1930 (9) 324-A.36 Vertical and Incline Shaft Sinking at Arthur B. Foote San Francisco T30, 87 North Star Mine (21) Oct., 1929 32bA.37 Governmental Control of the Pro- W. E. Colby New York duction and Sale of Mineral Re- Feb.. 1930 sources (With Discussion) (16) 333-A.38 Some Recent Developments in Open- E. E. Hunner New York T30, 106, 117 pit Mining on the Mesabi Range Feb.. 1930 (25) 334-A.39 Mining Methods and Costs at Presi- V. D. Howbert El Paso dio Mine of American Metal Co. of R. Bosustow Oct., 1930 Texas (15) 339-A.40 Operation of Pressure Fans in Series W. 8. Weeks New York (8) V. 6. Grishkevich Feb., 1931 364-A.41 Top Slicing with Filling of Slices as H. Willey El Paso Used at the Charcas Unit of Com- Oct., 1930 pania Minera Asarco, S. A. (17) 373-A.42 Drill Sampling and Interpretation of H. T. Matson New York Sampling Results in the Copper G. A. Wallis Feb.. 1931 Fields of Northern Rhodesia (17)

Jan 1, 1930

By H. E. Epstein, B. K. Parekh, W. M. Goldberger

Comminution is the single most expensive operation in mineral processing. It consumes about 50% of the energy required for mineral extraction (Agar, 1976). Current comminution technology is both energy-intensive and inefficient. A novel noncontact comminution process concept was developed in this study, whereby selective lib¬eration of minerals from an ore could be potentially achieved. The process involves application of electric and ultrasonic energy to liberate minerals from gangue particles. Introduction The mineral industry is a large user of energy in the US. Energy usage is increasing as the grade of ores processed decreases. It is es¬timated that comminution of ores uses about 32 000 kWh (115 trillion kJ), or 2% of the electric power produced in the US (NMAB-365, 1981). Among other minerals, ce¬ment, iron, and copper processing plants are the largest users of en¬ergy in comminution. Very little of this energy used in conventional grinding (about 1%) is used to gen¬erate new surface. The remainder is wasted (Table 1). Thus, there are substantial energy-saving and economic incentives to improve the efficiency of crushing and grinding techniques for mineral recovery. With an energy efficiency of only 1%, it would seem possible to devise methods to significantly improve comminution technology. This requires that breakage force be applied only where needed, not indiscriminately as in a conven¬tional ball mill (NMAB-365, 1981). Can apparatus and methods be de¬ veloped for large-scale commer¬cial use that allow energy to be fo¬cused at intergranular bounda¬ries? If this can be done, mono¬mineral grains would remain in¬tact and the grinding action would be selective and substantially more efficient. The novel comminution process concept described in this paper uses a combination of electric and ultrasonic energy. This energy breaks the ore and selectively lib¬erates minerals. The process has also been termed a two-stage or electroacoustical comminution process (Goldberger, Epstein, and Parekh, 1982). The mineral grain boundary is usually the weakest area in an ore. By applying electri¬cal energy to the ore, the rock frac¬tures mostly at grain boundaries. At the same time, the electric shock creates secondary hairline fractures in the ore. Additional application of ultrasonic energy to this ore provides further break¬age. The concept was proven on a molybdenum porphyry ore but needs additional study. Technical Background There have been substantial im¬provements in milling machinery and grinding operations, but rela¬tively few attempts have been made to develop alternatives to conventional impact milling. Sev¬eral methods, however, have been investigated that relate to this study. In the early 1970s there was considerable interest in a size re¬duction method known as the Snyder Process (Cavanaugh, 1972). It involved charging coarse ore into a pressure chamber, pressur¬izing with a gas, and activating a quick-opening (15 msec ) dis¬charge valve that connected the chamber to a discharge duct. This allowed solids to fluidize and ac¬celerate, subjecting the material to a variety of impulse phenomena that caused the desired size reduction. Other nonimpact means of achieving breakage and selective size reduction have been de¬scribed in technical and patent literature. Kanellopoulos and Ball (1975) considered using heat to induce thermal stress in quartz¬ite. This would cause cracking and, thus, increase grinding efficiency. The use of electrical energy to induce thermal stress was studied by the General Elec¬tric Co., in cooperation with the Montana School of Mines, under a research grant from the Anaconda

Jan 9, 1984

By V. Srivastava, T. Ghosh

The modeling and simulation of semiautogenous (SAG) mills have been widely used in the design and optimization of mill performance in terms of its power draw, processing capacity and product size distribution. However, these models are solved under steady approximation and do not provide any information on mill charge distribution in real time. 7KLVSDSHUDWWHPSWVWRFKDUDFWHUL]HPLOOFRQWHQWVE\VROYLQJ:KLWHQ¶V¿UVW RUGHUFRQWHQW EDVHGPRGHOLQWKH0$7/$% Simulink environment. The parameters in the model, such as breakage rate constant, discharge rate and appearance function, were estimated using process and design data collected from a gold mine operating in Alaska coupled with a nonlinear parameter estimation scheme. This model was then used to predict the dynamic responses of other key operational variables, such as mill power, bearing pressure, charge level and product size distribution. The transient response of mill behavior with respect to changes in feed size distribution, tonnage and mill feed water is also presented. This dynamic simulation approach can be used for practicing different control strategy and training purposes. The observed response of mentioned variables was validated using dynamic response data from the plant to encompass operational characteristics of SAG mill behavior.

By W. J. Wenger

Colorado has been producing petroleum since 1863 but only recently has become a major oil State. The first well was drilled on Oil Creek near Florence, but out-put was relatively small until discovery and development of the Weber sandstone reservoir at Rangely. Oil was discovered in the Weber sandstone in 1933, and the reservoir was developed after 1940, bringing Colorado, in 1949, to 11th place among the 48 States as an oil producer. Colorado's output increased further because of the discovery and development of many fields in the Julesburg Basin since 1949 By 1954 Colorado was in ninth place and maintained that position through 1955.4/ Between 1946 and 1951, Colorado's oil production more than doubled, while the total United States production increased only 25 percent. It seems probable that production will continue to expand in Colorado for many years. This report presents analyses of 92 crude oils from 73 fields representing 90 percent of the production in 1955. Abridged analyses are listed for easy comparision, and complete analyses arc given in the appendix. Oil samples were collected for study from many different sources. Although many of the newer fields were not sampled, their oils probably are very similar to those from corresponding formations that were studied and tabulated.

Jan 1, 1957

By Ravi Vancheeswaran

The consolidation of ceramic fiber reinforced metal matrix composites is a key process step in the synthesis of high performance composite systems. A simulation tool has recently been developed for predicting the evolution of the composites internal state microstructural variables (eg. relative density, fiber microbendinglfracture, and chemical reaction layer thickness at the fiber-matrix interface) during the consolidation processing of spray deposited composite mono-tapes. A Generalized Predictive Control (GPC) scheme is used in conjunction with the simula-tion tool to design near optimal process paths that minimize fiber damage and reaction product thickness while simultaneously maximizing the composites relative density. The microstruc-tural evolution depends nonlinearly on the process conditions and therefore the scheme uses a constantly updated linearization of the model to optimize the input process variable vector. A control simulation is presented to illustrate the performance of the design scheme and to assess the feasibility of its use for the achievement of goal state microstructures at the completion of consolidation cycles.

Jan 1, 1996

By R. McNeill, D. E. Weiss, E. A. Swinton

In a continuous countercurrent exchange process, an alteration in any one of the operating conditions has a complex effect on the others, which can only be predicted by employing the transfer unit or the theoretical stage theory on a basis of trial and error. A simple method is described for illustrating diagrammatically the behavior of a counter-current system, the equations being simplified by means of a concept the maximum hypothetical exchange performance. An example based on a typical metallurgical system is given, in which a divalent metal is recovered from a dilute solution, the resin being regenerated continuously by a monovalent ion. Useful conclusions are drawn from a study of the theory. Practical methods for performing continuous ion exchange are discussed, and the development of equipment based on modified ore dressing jigs is described. A swinging sieve jig contactor is evaluated experimentally. DURING the last decade, the new synthetic ion exchange resins have been applied extensively in industries outside the field of water treatment, but there is no record of a continuous counter-current process operating on an industrial scale. Attempts have been made to devise a satisfactory process but many problems remain to be solved. The basic principles of continuous processes will be outlined, as well as the major problems in their operation and the progress made in the CSIRO laboratories toward the development of satisfactory industrial techniques. In the metallurgical field ion exchange resins can be used for various applications such as the recovery and concentration of valuable metals from mine waters,' the regeneration of pickling and plating liquors," the prevention of pollution by waste effluents and the recovery of the constituents from them," and the purification of valuable metals such as the rare earths by chromatographic fractionation on columns of ion exchange resins.7,8 . Turther applications undoubtedly will be found in the field of hydrometallurgy where the use of ion exchange resins would enable direct extraction of the desired metal ion from the filtered leach liquor or the leach pulp. For example, an ion exchange process has been described recently for the extraction of gold from a cyanide leach pulp." A continuous process would have advantages in many applications over the usual process employing a fixed bed and intermittent cycle. In a recovery process, it would yield a product stream of steady purity and concentration, it would waste less water in rinsing, and if the contacting apparatus were efficient less resin would be used, since each portion of the resin would be cycled as soon as it was loaded instead of lying idle until the whole bed was ready for regeneration. A very major advantage is that it would be simpler to control automatically. It is probable that continuous operation will be the key for really large scale applications of ion exchange. The flow sheet of a continuous ion exchange recovery-concentration process is illustrated diagrammatically in Fig. 1. Dilute liquor containing the valuable ion flows through the stripping section countercurrently to a moving bed of resin and leaves after a final contact with freshly regenerated resin. The resin leaves the unit almost in equilibrium with the incoming liquor and then flows to the regenerating unit where it is treated by a slow countercurrent flow of concentrated regenerant solution. The adsorbed ion is displaced from the resin and appears in the concentrated product stream. The resin then must pass through a rinse unit or section where regenerant entrained by the resin is washed back into the regeneration section by water. The regenerated and washed resin is then recycled back to the stripping section. I. Theoretical Operating Behavior of Continuous Ion Exchange Stripping System The simple theory of continuous ion exchange is analogous to that of solvent extraction and other diffusional transfer operations and is governed by the equilibrium relationship, the mass balance, the rates of mass transfer, and the contacting efficiency of the unit. Equilibrium Relationship—The relative affinity of two ions A and B, for a particular resin immersed in their solution, can be expressed by plotting compositions of the solution against compositions which exist in resin in equilibrium with those solutions, i.e. C/Co vs q/a where C, is the total normality of the solution, C is the normality of ion A in the solution, a is the total exchange capacity of the resin in gram equivalents

Jan 1, 1956

By Ernest Baafi

A simulation model RoadSIM using the ARENA modelling system has been developed to evaluate roadway development options for a given development panel configuration. The RoadSIM simulation system has provisions for variability/randomness in operations including cutting and loading at the face, tramming and discharge of coal to the boot end and availability of equipment. The modelling system provides a means for assessing the operational limitations of roadway development practices at a particular coalmine. It is a ?what if? tool that allows a range of equipment, configurations and operating practices to be assessed in terms of achievable advance rates and equipment utilisation. Output from the system is in the form of a dynamic visualisation as well as summary reports and detailed logs of operations over time.

Oct 1, 2009

By H. Y. Jennings

An extensive field and laboratory experimental program was carried out to compare the waterflood behavior of carefully preserved soft and unconsolidated cores with measurements on the same cores after extraction. Results obtained from using idealized consolidated and unconsolidated porous media in which wettability could be carefully controlled were contrasted with the preserved core data. The controlled tests on idealized porous media investigated the effect of wettability, flood rate, core length, core permeability and consolidation on the displacement of high viscosity oils. It was concluded from these studies that waterfloods are more favorable when carried out with crude oil in preserved soft and unconsolidated cores than with the same cores after they have been extracted and re-saturated. Waterfloods are usually more favorable when carried out with crude oil in extracted .soft and unconsolidated cores than with refined oil of the .same viscosity in the same cores. The less favorable behavior of extracted soft and unconsolidated cores compared to preserved cores is due to alteration of the core by extraction. Preserved cores saturated with native water and oil should be used for laboratory displacement experiments because they more accurately reflect true reservoir behavior INTRODUCTION The demand for low gravity crude oil created by refinery modernization has focused attention on increasing the production of this viscous crude oil. Billions of barrels are in place in fields that are depleted, or nearly depleted, by primary production mechanisms. Since low gravity reservoirs are relatively recent, geologically, the solid matrix material is usually soft and unconsolidated sand. Such formations are also characterized by a high clay content. Evaluation of sophisticated oil recovery processes with the associated high capital investments has increased the demand for special core analysis tests on material from these soft and unconsolidated sand reservoirs. Data in this paper have resulted from an extensive field and laboratory experimental program. The initial objective vras to provide soft and unconsolidated sand cores for laboratory measurements with as little alteration as possible from their reservoir condition. A secondary objective was to compare the waterflood behavior of these carefully preserved cores with measurements on the same cores after they had been extracted and resaturated. When the comparison showed markedly different behavior the final objective was to attempt to explain the difference by making measurements on idealized porous media free of clay in which initial wettability could be carefully controlled. EXPERIMENTS MATERIALS Core Material The preserved cores used in this study were obtained with as little alteration as possible from their reservoir conditions. Special techniques were developed to satisfy this objective. The cores were cut with native crude whenever the crude had the necessary properties to satisfy the minimum drilling fluid requirements. A pure hydrocarbon chromatographic tracer was added to the crude to provide a simple, safe and inexpensive method to distinguish between oil filtrate and formation oil. Details of the tracer technique used in this study and the procedures used to handle and process the soft, unconsolidated cores have been published.' The core samples were then preserved and packaged at the well site with a dip-applied strippable plastic, or by using a rubber sleeve from a rubber-sleeve core barrel. The final step was to insure that the carefully taken and preserved samples were not altered by processing in the laboratory. Some soft and poorly consolidated sands were carefully shaped in the lab and encased in a protective mounting without disturbing their three-dimensional integrity. Many samples were so poorly consolidated that they literally flowed from the package when the seal was broken. A technique was developed to obtain cylindrical plugs from these samples by using liquid nitrogen as the drilling fluid in a conventional core-drill, drill-press assembly. The idealized porous media consisted of sintered rods of Alundum RA 139, outcrop sandstone identified as Al-hambra sandstone and packs of No. 130 Nevada sand. This sand is 95 per cent 140-200 mesh. (Physical properties of these porous media with those representative of preserved cores are in Table 1.) The natural cores and most of the idealized porous media were 1 1/2-in. in diameter and 3-in. long. The samples used to study the effect of core length were 1 1/2-in. in diameter and 12-in. long. Liquids Water and oil produced from the formations being studied were protected from the atmosphere and collected in carefully cleaned glass or plastic-lined containers. The production was free of chemical additives such as emulsion breakers and corrosion inhibitors. The crude oil was

Jan 1, 1967

By Julian Glasser

Starting with rutile, containing more than 55% TiO2 and of the proper particle size, the commercial production of titanium tetrachloride via fluidized bed chlorination is relatively very simple and economical. As compared to shaft chlorination, it operates at a much higher capacity for given sizing of equipment, and appears more foolproof, requiring less attention. Operating data were obtained on a 53" diameter fluidized bed chlorinator using Australian rutile and petroleum coke of controlled particle size. Production rates varied from 20 to 50 tons of crude TIC14 per day for a campaign extending over one month. Close to theoretical yields and efficiencies were obtained from the viewpoint of chlorine and/or rutile consumption. Details of important equipment design, critical operating conditions and pertinent results are described.

Jan 1, 1962

By P. A. Rusin

Many manganiferous silver deposits remain undeveloped because standard chemical extraction methods yield poor recoveries or are ' environmentally unacceptable. Biotreatment of such ore deposits in our laboratory resulted in manganese and silver recoveries of greater than 90%. Ore and sediment samples were collected from mining sites in Colorado and Arizona. Portions of samples were incubated in a semi-solid mineral salts medium amended with 20 mM glucose mid manganese dioxide (Mn medium). The cultures were incubated at 3(fC until manganese reduction was detected by a .color change fr:om .black to clear. Bacteria from these cultures were purified on Tryptic Soy Agar and individual isolates were retested for Mn reduction by an agar overlay method. Bacteria were identified according to Bergefs Manual ?of Systematic . Bacteriology. Most of the Mn-reducing bacteria are Bacillus species. Bacterial manganese reduction kinetic experiments were performed in 52 ml mineral salts broth supplemented with manganiferous silver ore instead of manganese dioiide. These cultures were incubated with agitation for 16 d. Aliquots were removed periodically and analyzed for solubilized manganese by atoniic absorption (AA). Cyanide (1,0 M) Vias added to the remaining ore-medium mixture for a 24 h bottle roll. The supernatant was analyzed for soluble silver by AA. Similar experiments were conducted on a larger scale using 15% pulp density. After bfotreatment of the ore, standard bottle rolls were performed. The pregnant solutions and the residues were analyzed for manganese and silver?using AA or fire assay as appropriate. In sterile. controls-which received no biotreatment, manganese and silver recoveries were 0.3% and 10% respectively; During biotreatment, total manganese solubilizatiori was as high as 99.8%. The reduced manganese could . be stripped from ?the growth medium using hydrometallurgical techniques. Silver recovery vaned from 70% to 92.5%. Microbial treatment of refractory mangairlferous ores can result in high recoveries of manganese and silver. Retention time varies depending upon the relative concentrations of manganese, silver, and other metals in the ore with only two days required in some cases, The biotreatment of ore is environmentally' acceptable while the use. of chemicals such as sulfur dioxide is less so.

Jan 1, 1991

By K Cameron, S Strohmayr, J Wallace

In 2012, a single module heavy medium cyclone plant (HMP) was installed at the Glencore Zinc’s (then Xstrata Zinc) McArthur River lead zinc mine. The HMP formed the first part of the MRM Phase 3 Project to increase run of mine (ROM) capacity from 2.4 to 5.5 Mt/a.The purpose of the HMP is to remove liberated gangue from the crusher product at minimal loss of valuable mineral. The McArthur ores are very finely disseminated requiring a fine primary grind size prior to rougher flotation. Rejecting waste prior to grinding therefore offers significant power and grinding media savings. The plant was designed to treat only those ores with a reasonable upgrade ratio at the target zinc recovery across the HMP of 95%.On this basis, a 1.8 Mt/a single module plant was built based on 250 t/h feed rate and 82% availability. In contrast to existing base metal heavy medium plants in Australia, the MRM Flow sheet utilised the principles in modern coal heavy medium cyclone plant design. Since commissioning, the plant feed rate has been significantly increased and is now normally operated up to 540 t/h (dry basis).Although this throughput increase is partially due to debottlenecking work, it is also attributable to the conservative design parameters for base metal heavy medium cyclone circuits in comparison to those used in equivalent coal circuits.This paper discusses Flow sheet design and compares traditional base metal design parameters with those achieved at MRM and those of modern coal plants. It provides information on plant capital and operating costs and the net savings realised by its installation. In addition to power and grinding cost savings, the paper also highlights the savings in water through rejection of near dry waste and reduction of tailings pumped to the storage dam.CITATION:Wallace, J, Strohmayr, S and Cameron, K, 2015. McArthur River Mine heavy medium plant – the benefits of applying modern coal plant design principles to base metal heavy medium separation, in Proceedings MetPlant 2015, pp 311–323 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 7, 2015

By C. Don Sullivan

Paraphrasing the poetic repetition of Gertrude Stein - "Research is research, is research, is research --- ad infinitum." But research takes many forms and involves many facets. Perhaps the most simple of definitions is that attributed to the late "Boss" Kettering of General Motors who in advising a young trainee said, "Research is an intelligent effort to satisfy the curiosity of the human mind." Reclamation research is complex and requires a diversity of scientific knowledge. The overall aim of land reclamation research is directed to finding practical ways to develop efficient methods to restore mined lands to productive use, compatible with use of adjacent lands, as soon after mining as possible; and, finding practical ways to reduce or prevent damage to surrounding resource areas, which may be affected by the mining process. Research in the field of mined land reclamation is not entirely new, although in some respects we are exploring new areas each day.

Jan 1, 1967