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By H. Huang, R. N. Gow

"EH-pH diagrams are useful tools in understanding how mineral surfaces react in solution and particularly how aqueous conditions can be changed to enhance mineral leaching processes. Successful application of these diagrams, however, requires that several considerations be kept in mind to prevent what had been termed as “gross errors” in their calculation and use. In this paper, the aqueous Cu-S system is used as the basis for explaining the mass-balanced method of calculating EH-pH diagrams with the STABCAL thermodynamic equilibrium software. A breakdown of the Gibbs’ Phase Rule and how it is used in STABCAL to modify the diagrams is included. The methodology was applied to the aqueous Cu-As-S system, and resulting diagrams were compared against examples of those generated using the predominant-ion method. The complexity of such diagrams increases with every additional component, and competition between species becomes more apparent, as can be seen by curvature in the resulting mass-balanced diagrams. The complete diagram for enargite (Cu3AsS4) is shown. It compares well with spectroelectrochemical measurements from Raman spectroscopy and cyclic voltammetry studies.IntroductionInnovation in the field of processing arsenicbearing copper ores has been of particular interest. Copper arsenic sulfosalt minerals such as enargite (Cu3AsS4) and tennanite (Cu12As4S13) are now frequently prevalent in ore bodies as the oxide and easily leachable sulfides become harder to find. These minerals, unless pretreated somehow, concentrate in copper sulfide flotation processes, in turn concentrating the arsenic levels. Increasing environmental restrictions on arsenic content for smelters makes the hydrometallurgical processing of these concentrates more favorable. While enargite is considered one of the more refractory copper sulfides, more so than chalcopyrite (CuFeS2), there are still several methods, both industrially proven and in development, that are capable of processing these ore types. Alkaline sulfide leaching can be used as a pretreatment method to solubilize arsenic selectively (Delfini et al., 2003; Anderson and Twidwell, 2008; Tongamp, Takasaki and Shibayama, 2010a, 2010b), or the entire metal content can be leached using acid-type leaches such as acidified ferric sulfate (Dutrizac, 1981; Hackl et al., 1995; Klauber, 2008), or the chloride assisted, CESL (McDonald and Muir, 2007) or nitrogen species catalyzed (Anderson, 2003) processes can be used.As development of these leaching technologies proceed, it is also important to develop an understanding of the mineral thermodynamics. To date, there are numerous studies on the Cu-Fe-S-H2O system, particularly as it relates to chalcopyrite leaching, yet few studies have done on the Cu-As-S-H2O system. Computer-generated EH-pH diagrams have been employed to illustrate the importance of thermodynamic calculations in providing insight into such a system."

Jan 1, 2016

By Stephen C. Tadolini, Raymond A. Mazzoni

The International Ground Control Conference in Mining has always provided an open forum for the publication, presentation, discussion, and often heated debate on roof bolting systems mostly with attention to how, when, and why they work. During the last 24 Conferences at least 170 papers have been presented by International Experts on these “simple” devices that range in length from 30-inches to 20 ft and from 5/8 to 2 inches in diameter. Roof bolts are primarily mechanically anchored, glued, cemented, or driven. Bolts are placed vertically, angled, or tied together with special fixtures (trusses and slings). They have been termed active, passive, stick-slip, and several other descriptive acronyms or mining slang expressions. This retrospective paper will present the changes in bolt types and usage, point out some of the biggest myths and hail the most significant advances (according to the authors’ opinions of course).

By Jian Yang

The mechanism of resulfurization in the desulfurization process with magnesium vapor produced in situ by aluminothermic reduction of magnesium oxide was clarified in the present work. The influences of various operating parameters on the resulfurization were studied and the methods that could prevent resulfurization were proposed. There are two kinds of mechanisms of resulfurization in the desulfurization process with magnesium. One is decomposition of the desulfurization product of MgS under the inert atmosphere. The other is oxidation of MgS under the oxidative atmosphere. Under the present experimental conditions, lowering operating temperature and oxygen partial pressure in the atmosphere could effectively prevent the resulfurization. Adding CaO onto the melt surface was an effective method for preventing the resulfurization due to transformation of the desulfurization product of MgS into the more stable compound of CaS. Since addition of the activated charcoal powders greatly decreased the transfer rate of oxygen in the atmosphere to the melt surface, it also reduced the resulfurization remarkably.

Jan 1, 2006

By P J. B Fransen

Several spatially and/or temporally distinct phases of epithermal activity can be recognised in the Horohoro-Matahana Basin area of the Taupo Volcanic Zone. In the northern Matahana Basin a 140 - 350 ka age range is proposed for mineralised debris flow clasts and related (?) epithermal  mineralisation intersected in a recent drillhole. To the east, a ca. 40 - 50 ka age range is suggested for epithermal activity in the Waikaukau alteration zone which was focused along the Guthrie Fault. Hydrothermal explosion breccias occur over 13 km within the Guthrie Graben, and are probably sourced from vents in the south. Assuming a common origin, these breccias are constrained to a 45 - 50 ka age range. Within the Horohoro hydrothermal system (around the present hot spring), older (15 - 50 ka) and younger (0 - 15 ka) features can be distinguished.

Jan 1, 1991

By I. Caraconcea, M. Cousineau, S. Gariepy

"Several base metal plants operate in low grade/high tonnage conditions which impose strict cost control on all fronts for their operations to remain profitable. This leads to decisions regarding plant design, procurement, operations and maintenance that often favor cost minimization over value optimization. This may hinder the representativeness of the metal accounting systems while this should be a priority in a low margin environment. Such poor representativeness not only creates confusion in plant scheduling but can also hide suboptimal metallurgical performance. Furthermore, this situation can run undetected for a while since one dominant feature of a poor metal accounting system is its poor self-awareness. During their practice, authors have particularly identified measurement bias and reproducibility, as well as their impact on metal recoveries as areas of concern. These issues have not been extensively reviewed in the specific context of precious metals in base metal plants. Pragmatic solutions are proposed either at the design stage for a new project or to retrofit an actual operation. These solutions should be based on a business analysis that set a value of information matching the contribution of precious metals as well as the potential to use such information to act toward increasing plant profitability. Conclusions are that trade-offs are an inherent part of the design/audit/retrofit of any metal accounting system in any plant processing either base or precious metals. However, compromises must be evaluated on economic/technical ground.INTRODUCTION Every mineral processing plant must produce metal accounting reports (Morrison, 2008) where estimated saleable metal flows and inventories are published. These metal accounting reports are delivered to a variety of stakeholders who use them for internal management purposes (day-to-day plant production planning, plant operation optimization, capital spending, etc.) as well as for external management (royalty settlements, tolling agreements, etc.). Hence, there should be no doubt that state of the art metal accounting is instrumental for mining companies to reach and sustain high-quality corporate governance (Gaylard, Randolph, & Wortley, 2014). However, producing a metal accounting report involves much more than just printing it (Lachance, Leroux, & Gariépy, 2015a). The underlying metal accounting system (Figure 1) is responsible not only for the reliable production of the metal accounting reports but also for the quality of the outcome. As such, the crucial tasks of its design/audit/retrofit should neither be seen as ancillary nor be left as an afterthought."

Jan 1, 2017

Jan 1, 1972

By Renato Ferreira Lima e Corrêa Pereira

Na manufatura de produtos metálicos, o forjamento é o processo de transformação a quente de materiais dúcteis, como aços e ligas, através de conformação mecânica efetuada com esforço de compressão por uma prensa, de modo que eles assumam os formatos desejados. Este processo normalmente é utilizado para produzir peças de formas complexas e com uma maior precisão dimensional de acordo com a especificidade exigida pelo cliente final. Para obter resultados de qualidade, foi necessária a implantação de técnicas de medição indireta de última geração, que proporcionam ganho de tempo e a redução de desperdício de energia e material, além de aumentar a segurança, reduzindo a presença de pessoas próximas aos materiais para medições manuais. O presente trabalho trata da criação de um sistema de visão que, por meio de análise de imagem, é capaz de coletar a medida do perfil de barras em uma Forjaria em tempo real, podendo ser utilizado durante a operação da prensa, para garantir que o material está em conformidade com o especificado. A execução do sistema em produção aponta que as medidas realizadas apresentam desvio máximo de 2mm em relação àquelas realizadas pelos operadores.

Jul 30, 2018

By G. W. Jones

In a previous report,6 results were given that showed the amount of natural ventilation in a manhole having a capacity of 74.l cubic feet when the number of ventilation openings in the cover was varied. from no openings to a maximum of 48. The results showed that the ventilation (air changes per day) in the manhole was proportional to the area of the openings in the cover, and also that the number or area of the openings was the factor that chiefly affected the ventilation.

Jan 1, 1937

By Arthur Dubé

An account is given of the developments brought about in the last fifteen years by metallurgical research in the field of heat treatment of steels. The practical aspects of these developments are especially emphasized. Methods of representation of the phase-change during austenitizing and sub-critical transformation of austenite are described and the importance of time-temperature-transformation charts for the planning of heat treatment cycles is shown. Special copies such as retained austenite and internal stresses developed on quenching are also discussed in some detail. Due to the interest shown currently in these problems, it has been thought advisable to describe briefly the underlying principles and present some of the results already available.

Jan 1, 1945

By David Corke

The paper presents the development of Federation of Piling Specialists (FPS) calculation of rig track loading, the production of the Building Research Establishment document “Working platforms for tracked plant” (BR 470), working platform testing and considerations of rig stability. The paper also discusses the importance of rigorous and well documented procedures and proposed future development of rapid working platform testing methods. Topics presented include the fundamental requirements and principles involved in the testing, design and maintenance of working platforms, rig track loading, the BRE design method and site testing analysis. The paper stresses the need for testing and design processes to be robust and simple and quick to perform as there is often little time between the award of a contract and the need to start work on site. Also, it is vital that all aspects of working platform design can be carried out with information that is available to the platform designer. Developments in the UK over the last two decades have resulted in improved quality and safety of working platforms that will hopefully be further enhanced as design and testing methods continue to improve.

May 1, 2022

By R. Clarkson

"Free gold particles occur in many base metal and precious metal mines throughout the world. Due to the high density and malleability of gold, large circulating loads of free gold particles can build up over time in grinding circuits. This gold is often deposited in unintended traps throughout the mineral processing system.These unidentified free gold deposits represent a serious security risk as well as an inaccessible inventory of gold. Deposits of free gold particles often remain undetected by mine management until they are accidentally discovered while repairing mill equipment.Nuclear tracers have been used to determine the free gold recovery efficiency of gravity recovery equipment, drills, and sampling equipment (Clarkson, 1994, 1995; Walsh and Rao, 1986; Walsh and Kelly, 1992). In November, 1993, the author inspected the grinding circuit at La Mine Doyon in Rouyn-Noranda, Quebec and made recommendations to recover coarse gold and to eliminate gold traps from the circuit. In 1995, the author salted mineral processing circuits with radioactive gold particles. The gamma and X-ray radiation from gold’s nuclear isotope (Au198) were detected through steel, in pipes, and in moving equipment using scintillometers. The radiotracers proved to be a safe, rapid and accurate method of identifying gold traps and improving security.Nuclear TracersWhen particles of gold are placed in a nuclear reactor, some of the gold atoms (Au197) absorb another neutron in their nucleus to form gold’s radioactive isotope (Au198). In the process of radioactive decay, this isotope emits high energy gamma rays and X-rays which are easily detected (even through steel) with scintillometers.Radioactive gold (Au198) has a very short halflife of 2.7 days. At the relatively low activity levels used for tracing, the particles remain detectable with a small hand-held scintillometer for about 10 to 14 days. After 14 days the irradiated gold is close to background levels and within two months it is essentially non-radioactive. The radiation has no effect on the recovery characteristics of the gold particles. The gold radiotracers are very safe due to their very low level of radiation, short half-life, and their inherent physical and chemical stability. However, the use and possession of even mildly irradiated gold is strictly licensed and regulated."

Jan 1, 1997

By M. Hesham El Naggar, Osama F. E. Drbe

"Abstract: The use of micropiles has greatly increased the last twenty years, including applications involving low capacity micropile networks, seismic retrofitting, underpinning of existing foundations and high capacity foundations for new structures. This paper presents a field study of the behaviour of single hollow core micropiles in firm to stiff lean clay. Eight micropiles were installed using hollow bars (76 mm OD and 48 mm ID) with air/water flushing technique and advanced to a depth of 5.75m: six micropiles were installed using 228 mm (9 in) drill bit and two micropiles were installed using 178 mm (7 in) drill bit. All micropiles were instrumented with linear potentiometers to measure the vertical displacement of the micropile head and vibrating wire strain gauges to measure the axial strain at three points along the micropile length. Twelve full scale tests were conducted on the eight micropiles, four monotonic compression, four cyclic compression and four tension tests. Only the results of micropiles tested under monotonic compression is presented in this paper. The full scale load tests and a comparison of the performance of the micropiles with 228 mm and 178 mm drill bit are presented and discussed in terms of load-displacement curves, bond strength and tip resistance. The results showed that the proposed values of bond strength in FHWA give a conservative design of the hollow core micropiles. The micropiles constructed with 228 mm drill bit performed marginallybetter than the micropile with 178 mm drill bit in terms of the ultimate capacity.IntroductionMicropiles have been defined in a variety of ways, but can universally be classified as small diameter (less than 300mm), bored, and grouted in place piles (FHWA, 2005; Bruce et al., 1999; and Scherer et al., 1996). They can sustain axial (compression and tension) and/or lateral loads. Dr. Fernando Lizzi used micropiles in 1952 for underpinning of historic buildings damaged during World War II (Bruce D. A., 1988). Since then, micropile applications have expanded rapidly to include underpinning for existing foundations, in situ reinforcement, and seismic retrofitting and foundations for new construction. In particular, micropiles have graduated from use in low-capacity micropile networks toapplications as single high-capacity foundation.Micropiles capacity is affected by the construction technique, which involves drilling, placing reinforcement, and placing or pressurizing the grout. For example, the drilling method influences the degree of bonding between the grout and the ground, and the placement of reinforcement and the choice of grouting method have an impact on the development of the bonding. Bruce et al. (1997) showed that grout/ground bond is most affected by the grouting method. Based on the type of pressure applied during the grouting process, micropiles are classified as follows (FHWA, 2005): Type A: grout is placed under gravity pressure only using either sand-cement mortars or neat cement grout. Type B: pressures typically in the range of 0.5 MPa to 1 MPa are applied in order to inject the neat cement grout into the drilled hole while the temporary drill casing is withdrawn. Type C: involves two-step process; neat cement grout is first placed in the hole under gravity pressure head only as in type A, and prior to the hardening of this primary grout, a similar grout is then injected via a preplaced sleeved grout pipe at a pressure of at least 1 MPa. Type D: like type C, this type is a twostep process: neat cement grout is placed in the hole under gravity pressure head only (but pressure could be applied in some cases), additional grout is injected via a sleeved grout pipe at a pressure of 2 MPa to 8 MPa once the primary grout has hardened. In some cases, a packer is used inside the sleeved pipe, enabling specific horizons to be treated. Recently, Type E micropile is proposed, which involves"

Jan 1, 2014

Smart defense: that?s what the industry needs to play for the next four years, according to panelists at the 118th Annual Meeting of the Northwest Mining Association (NWMA), which met December 2-7 in Spokane, WA. The conference was well attended, with approximately 2,200 attendees, 244 booths in the two packed exhibition halls, and a rich offering of short courses, field trips, social events and technical sessions. Speakers at the packed legislative session articulated many of the frustrations felt by members of the mining community after the U.S. elections in November, and offered words of advice. Matthew Ellsworth, the new Government Affairs hire at NWMA, stated it best: ?Elections are like Christmas: you find out who?s naughty and nice ? and it?s always going to come again.?

Jan 1, 2013

By Mustapha A. Raji, Alafara A. Baba, Christianah O. Adeyemi, Aishat Y. Abdulkareem, Rafiu B. Bale, Malay K. Ghosh

The increasing demand for pure aluminum and aluminum compounds of industrial quality from kaolinite ore cannot be overemphasized. Nigeria is one of the African countries endowed with abundant solid mineral resources that have not been sufficiently exploited to assist its indigenous industries. A wide array of applications of pure aluminum and its compounds are available, such as paper filling, refractories, adsorbent, catalysis, and paint additives. In this study, the upgrading of a Nigerian biotite-rich kaolinite ore by a hydrometallurgical route was investigated in oxalic acid media. During leaching studies, the effects of parameters including reaction temperature, lixiviant concentration and particle size on the extent of ore dissolution were examined. At optimal conditions (1.0 mol/L C2H2O4, 75 °C), 92.0% of the initial 10 g/L ore was reacted within 120 min. The dissolution curves from the shrinking core model were analyzed and found to conform to the assumption of surface diffusion reaction, and the calculated activation energy of 33.2 kJ/mol supported the proposed model. The unreacted product (~8.0%) analyzed by XRD was found to contain siliceous impurities and could serve as a valuable by-product for certain industries.

By Mustapha A. Raji, Alafara A. Baba, Christianah O. Adeyemi, Aishat Y. Abdulkareem, Rafiu B. Bale, Malay K. Ghosh

The increasing demand for pure aluminum and aluminum compounds of industrial quality from kaolinite ore cannot be overemphasized. Nigeria is one of the African countries endowed with abundant solid mineral resources that have not been sufficiently exploited to assist its indigenous industries. A wide array of applications of pure aluminum and its compounds are available, such as paper filling, refractories, adsorbent, catalysis, and paint additives. In this study, the upgrading of a Nigerian biotite-rich kaolinite ore by a hydrometallurgical route was investigated in oxalic acid media. During leaching studies, the effects of parameters including reaction temperature, lixiviant concentration and particle size on the extent of ore dissolution were examined. At optimal conditions (1.0 mol/L C2H2O4, 75 °C), 92.0% of the initial 10 g/L ore was reacted within 120 min. The dissolution curves from the shrinking core model were analyzed and found to conform to the assumption of surface diffusion reaction, and the calculated activation energy of 33.2 kJ/mol supported the proposed model. The unreacted product (~8.0%) analyzed by XRD was found to contain siliceous impurities and could serve as a valuable by-product for certain industries.

By Stan Merjan

Composite piles with precast concrete tapered pile tips (TPT Composite Piles - U.S. and foreign patents) are a new and important addition to the piling types available to the construction industry. TPT Piles were invented by Stanley Merjan, Vice President of Underpinning & Foundation Constructors, Inc.. U. F. C. installs these piles in the Northeast United States and licenses piling contractors in other parts of the country. TPT Piles have been developed for use in sandy subsoils at depths to 70 feet or greater. The TPT system (see Figure 1) is simple. A pile stem of conventional material (shell, pipe, steel, wood, precast concrete) is connected to a socket formed in a precast concrete tapered pile tip (TPT). This composite assembly is then driven as a unit by ordinary pile driving methods until adequate driving resistance (established by formula or load tests) is met in a suitable soil strata. This driving resistance develops from the displacement and densification produced by the TPT. Many combinations of tip shapes and stems are available to suit particular job requirements with respect to subsoil conditions and pile capacities. TPT Piles should be considered for use on a wide variety of jobs. The advantages offered by a TPT installation include: ? High capacity piles in marginal soils ? Minimal lengths required to produce these capacities ? The use of conventional pile driving equipment and procedures ? Pile inspection techniques that are the same as for ordinary pile driving Furthermore, TPT piles are economical due to a combination of a low cost per ton of pile capacity and high productivity, both of which lead to significant savings in foundation costs and time required to complete foundation work.

Jan 1, 1987

By D Matthews

With a brownfield project comes control integration challenges. The Khumani Iron Ore Mine’s second phase expansion posed a number of challenges as there was substantial brownfields work conducted. The fi rst phase was the compilation of the modifi ed process functional specifications for the project. The second phase was an audit on all of the operational sequences; this included a comparison between the SCADA sequences, sequential starts analysed from the historian data (with the potential for improvements made by the plant operators in manual start-ups) and what was proposed in the process functional specification. Differences, inclusions and missing equipment were highlighted. The third phase was the comparison of interlocking and control in the PLC with the updated process functional specification; this was done during the coding process. Running parallel to the three phases was the SCADA integration; tie-ins to the existing SCADA were conducted on maintenance days and shutdowns, in many instances with ‘dummy’ equipment to get the operational staff accustomed to the new interface. This paper details each of the phases, the success of this methodology as well as the pitfalls experienced.

Jul 11, 2011

By Russell J. Foster

Many important materials are derived entirely or partially as byproducts of primary copper, lead, and zinc production. This U.S. Bureau of Mines report examines the collective role of byproducts with regard to the economics of domestic mineral production, and their individual significance in terms of dollar value, end uses, and strategic considerations. The study also analyzes circumstances that have affected the competitiveness and structure of the U.S. copper, lead, and zinc industries, and factors that impact byproduct availability. These factors include production capacity at smelters and refineries, process technology, changing sources and composition of ores, regulations, foreign ownership, and byproduct demand and price. Policy considerations regarding stockpiling, regulations, and research are assessed.

Jan 1, 1991

By H. R. Appell

The Bureau of Mines is experimentally converting cellulose, the chief constituent of organic solid waste, to a low-sulfur oil, All types of cellulosic wastes, including urban refuse, agricultural wastes, sewage sludge, wood, lignin, and bovine manure, have been converted to oil by reaction with carbon monoxide and water at temperatures of 350° to 400° C and pressures near 4,000 psig, and in the presence of various catalysts and solvents, Cellulose conversions of 90 percent and better (corresponding to oil yields of 40 to 50 percent) have been obtained. A continuous reactor for use at maximum conditions up to 500° C and 5,000 psig has been operated successfully, Using sucrose as a feedstock, operation in this system has permitted a simplified and preliminary chemical study of the conversion process. Oil yields of over 30 percent have been obtained with this unit.

Jan 1, 1971

By E. G. Davis

The Bureau of Mines investigated gaseous direct reduction of low-grade iron ore concentrates in a continuous fluid-bed reactor. These studies were made in a 4-inch diameter fluid-bed reactor using hydrogen alone, and oxygen-or air-reformed natural gas as the reductants. The percent reduction is directly dependent on the mole ratio of hydrogen in the reducing gas to the oxygen associated with the iron oxide in the ore. Two-and three-stage fluid bed tests were simulated by repeated continuous tests. The results showed that percent reduction of the final product was dependent on the mole ratio of the quantity of hydrogen in the gas of each stage to oxygen in the iron oxide of the initial ore feed. Reduction as high as 87 percent in the single stages and as high as 94 percent in the multistages was obtained when either hydrogen or reformed natural gas was used as the reducing gas. Magnetic separation and concentration of the highly reduced fluid-bed product yielded a high metallic iron concentrate analyzing 85 percent total iron and 80 percent metallic iron with total iron recovery as great as 90 percent. Agglomeration of the high-grade metallized concentrate produced hard pellets analyzing 85 percent total iron and 78 percent metallic iron. Green pellets, with good strength, were made without any binder in a drum pelletizer. Direct melting of the high-metallic fluid-bed product in a basic lined arc furnace produced a nearly pure iron which contained 0.09 C and 0.01 P with 95 percent recovery of the metallic iron in the metal.

Jan 1, 1972