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By R. Rocca, M. B. Bever

THE adiabatic elastic deformation of a body is accompanied by a change in temperature. This phenomenon is known as the thermoelastic effect. Under adiabatic conditions the temperature of a metal bar is decreased by an elastic elongation and is increased by an elastic compression. All materials which elongate on heating behave in this manner. The sign of the thermoelastic temperature change is reversed for the few materials which have a negative coefficient of thermal expansion. The following equation for the thermoelastic effect can be derived from fundamental thermody-namic theorems, as shown in the Appendix: dT8 =-a1/cs T dss [1] Cs In this equation, T is the absolute temperature, S is the entropy, a, is the coefficient of linear thermal expansion, cs' is the heat capacity per unit volume at constant stress and s is the stress (positive in tension). Eq 1 can be applied to small, but finite changes in stress in the following form: ?Ts =- a1/cs T?ss [2] The sign of the temperature change AT is opposite to that of the change in stress s for materials which have a positive coefficient of thermal expansion. Eq 2 has been verified for many different materials and stresses at room temperature. No previous publication appears to have been devoted to an in- vestigation of the thermoelastic effect over a range of temperatures. Review of Literature Lord Kelvin (W. Thomson) presented a general theory of the thermoelastic effect in 1851' and later applied it to a solid, subject to an arbitrary system of stresses'. His analysis was based on a cycle of isothermal and constant-strain transformations and led to Eq 2 above. Even today, one of the clearest expositions of the thermoelastic effect is found in Lord Kelvin's article on elasticity in the Ninth Edition of the Encyclopedia Britannica (1878). R. ROCCA, Junior Member, and M. B. BEVER, Member AIME, are Research Assistant in Metallurgy and Associate Professor of Metallurgy, respectiuely, Massachusetts Institute of Technology, Cambridge, Mass. AIME New York Meeting, Feb. 1950. TP 2760 E. Discussion (2 copies) may be sent to Transactions AIME before APT. 1, 1950, and is scheduled for publication Nov. 1950. Manuscript received Oct. 15, 1949.

Jan 1, 1951

By W. W. Harvey, F. O. Dudas

Toward hot hydrochloric acid, the usual order of reactivities of the common copper sulfide and associated minerals is reversed, and the rates of H2S formation vary as [ ]. The iron component of chalcopyrite and bornite reports to the solution as ferrous chloride, while pyrite remains essentially unreacted. If a pressure of H2S is maintained in the reactor, copper solubilization is suppressed, and the primary copper sulfides are converted to finely divided secondary sulfides (principally covellite). The HCl leach reside then consists mainly of covellite, pyrite and acid-insoluble gangue. Copper can be selectively leached from this upgraded concentrate to yield a clean, strong copper sulfate solution for direct electrowinning. Preliminary analysis indicates competitive economics with respect to established hydrometallurgical processes. Other concentrate treatments based on an initial HC1 leach are proposed and relative advantages compared. The common denominator of the major process routes considered is the requirement to regenerate HC1 from an FeC12 solution. Five distinct concentrate compositions were employed in the experimental study, which included some attention to the fates of selected minor constituents of the copper concentrate, especially gold, silver, molybdenum, arsenic and selenium. Significant mineralogical features of reactants and products are described.

Jan 1, 1978

It is desired to call the attention of young men who have had technical training and experience to the fact that their abilities can best be put at the service of the country by selecting a branch of service in which their special qualifications will be of the greatest use. The submarine force of the United States Navy requires the services, as officers on board submarines, of young men who have had technical training in mechanical and electrical engineering and who have had experience in these professions. It is intended to enroll a number of such men as provisional ensigns in the Naval Reserve Force, give then a course of instruction in deck duties at Annapolis and a course in submarine work at New London. Those who successfully pass these courses will then be sent on hoard submarines for regular duty. It is requested that any men who desire this duty and who are qualified as below outlined send their names and addresses to the Commander Submarine Force, U. S. S. Chicago, care of Postmaster, New York. Qualifications required: Desire to serve in submarines. Degree of M. E. E. E., or E. M. Two and one-half years' practical experience in profession. Not over 35 years old. Physically strong and sound.

Jan 7, 1918

WILLIAM YOUNG WESTERVELT, Chairman, Representing A. T. M. E. and M. and M. Soc. of Am. ALFRED G. WHITE, Secretary, Representing U. S. Bureau of Mines. W. 0. HOTCHKISS, Representing Association of American State Geologists. DAVID WHITE, Representing U. S. Geological Survey. The organization and purpose of the War Minerals Committee was explained in a special war notice in the-August Bulletin. The first work of this Committee is to secure and condense information as to the relative importance of different properties from the standpoint of domestic mineral production. When the possibilities of ore deposits are known, involving, in some cases, further examination through the voluntary services of, Engineers and Geologists, then the necessary policy required to stimulate such development can be determined. Proper recommendation has been and will be made to .the various agencies controlling the situation during the war. This will insure a complete presentation of the needs of the situation. Every legitimate effort will be made to stimulate the production of domestic minerals and to put the industries on a permanent basis. The following information forms indicate the type of information required by the Committee. Engineers and Geologists can assist in one of several ways in furnishing information to the War Minerals Committee:

Jan 10, 1917

By J. W. Goss, M. J. Coolbaugh

A survey of literature published in the U.S. on grouting indicates that most such work has been done to stop water flow in mines and for stabilizing foundations of various man-made structures. Apparently San Manuel is one of the first mines in this country to use grout extensively underground for the strengthening and stabilizing of ground about drifts, shafts, and stations.

Jan 3, 1961

By Alvin Kaufman

At the turn of the century the U.S. had a gross ALVIN KAUFMAN Mineral Economist U.S. Bureau of Mines area slightly in excess of three million square miles, a population of 76 million, a gross national product of $37 billion (constant 1929 dollars) and a mineral production valued at $2 billion (1929 dollars). Some 60 years later its area had increased by 600 thousand square miles, population had risen 140%, gross national product was seven times greater and mineral production had grown to a value five times that of 1900. Of perhaps greater significance, however, were the changes wrought by technology. It was during this period that the "American Way of Life" was revolutionized by the introduction of the airplane and the automobile; man also took his first probing steps in the utilization of nuclear energy and pre- pared to unlock the secrets of space. It was during these six decades, also, that he learned to create additional new materials, some of which were from old sources such as plastics from petroleum and coal. These new materials have created competition and attendant problems for the traditional materials such as iron, copper, lead and zinc. Additional problems undoubtedly will be created by technologic advances in the future.

Jan 2, 1963

By E. N. Cameron

Graphite has been included in U. S. lists of strategic minerals since the problem of mineral deficiencies was revealed during World War I. Since 1918 the domestic graphite industry has led a precarious existence, and there has been much uncertainty as to the amounts of usable graphite of various grades that would be available from domestic sources in time of emergency. In 1950-1951 therefore, the writer, assisted by Paul L. Weis, undertook a review of domestic graphite sources for the U. S. Geological Survey. The conclusions of this study are presented here, with a discussion of some technologic and politico-economic factors bearing upon the problem. Uses of Graphite: Natural graphite as marketed exhibits a wide range of properties, which determine the uses to which it is put. The most essential uses are in the manufacture of crucibles and related refractory articles, in lubricants and packing materials, and in the manufacture of batteries, foundry facings, pencils, and carbon brushes. Numerous specifications covering the mineral in its various applications must be met by producers and processors of graphite. The problem of supply is therefore not simply one of procuring a sufficient total tonnage, but the more difficult problem of procuring enough of each different grade to meet foreseeable needs.

Oct 1, 1956

By W. F. Shinners

Ozark Ore Co.'s Iron Mountain mine utilizes optimum mechanization to provide ever increasing output from underground as production declines from open pit. Trackless equipment gave flexibility to meet varied mining conditions-required minimum of pre-production development.

Jan 4, 1953

[OH. O'C. Acker '86 Jinzoc Adachi '88 *Truman H. Aldrich '78 Walter H. Aldridge '89 *Anson W. Allen '87 *John H. Allen '84 *Thomas Andrews '94 *William R. Appleby'90 *W. Lawrence Austin '82 . S. Ayres'73]

Jan 1, 1946

PRESIDENT AND DIRECTOR D.C. JACKLING SAN FRANCISCO, CALIF. PAST PRESIDENTS AND DIRECTORS NEW YORK, N. Y. R. C. ALLEN- CLEVELAND, OHIO VICE-PRESIDENT, TREASURER AND DIRECTOR KARL EILERS-* NEW YORK, N. Y. VICE-PRESIDENTS AND DIRECTORS HENRY KRUMB NEW YORK, N. Y. PAUL D. MERICA . NEW YORK, N. Y. H. G. MOULTON NEW YORK, N. Y. HARVEY S. MUDD Los ANGELES, CALIF. WILFRED SYKES CHICAGO, ILL.

Jan 1, 1938

By M. J. Mullikin, J. B. Conway

for use in describing combined first- and second-stage creep data. In the above ?o represents the instantaneous strain on loading, ?t the limit of transient creep, ?S the steady-state creep rate, t the time, and ? a constant leading to the exhaustion rate of transient creep. It was noted that this equation was similar in form to that proposed originally2 by McVetty. This type of equation was also suggested by Andrade and Aboav3 in studies of the shear strain of cadmium. Calculation of the constants ?o, ?t, ?, and ?s, in Eq. [ l] is somewhat involved due to the slight complexity of this relationship. In the paper by Garofalo a computer approach based on a least-squares analysis was recommended. Such an approach involves a trial and error solution but when a computer facility is available the difficulties in this calculation are of little consequence. It does mean however that the evaluation of this type of equation would become quite tedious if computer facilities were not available. Some recent studies have identified a fairly straightforward method for calculating the constants in the Garofalo equation. While not leading to a least-squares evaluation the approach is accurate and is recom-

Jan 1, 1967

By John D. Morgan, Sylvain J. Pirson

AN instantaneous and continuous analysis of a mineral suspension should be of great value in controlling various mineral preparation processes. Described herein is a method of analysis based on the use of high-frequency alternating current, which, under certain restrictive conditions, could be of use. THEORETICAL CONSIDERATIONS In a suspension of conductive minerals, the electrical effect primarily responsible for the variations in electric conductivity is the capacitance. In Fig Ia, let an alternating voltage E be applied across two electrodes F and F', between which are two rows (S and T) of mineral particles, all of approximately the same size, immersed in a fluid. Let the number of rows of particles between the electrodes be R and the number of particles in each row be N. If A is the area of a particle, D is the distance separating two particles, and K is a constant depending on the fluid, the capacity, Co, of the particle system will be given by: [KRA C0 ND] Referring now to Fig Ib, let R, the number of rows, be held constant, but let N, the number of particles in each row (S and T), be increased X-fold. The capacity, C1, of [ ]

Jan 1, 1947

By C. W. Crispell

The four nomograms presented in this article were designed to simplify and make more rapid the calculations connected with the compression and transmission of air. The formulae involved are rather complicated, but the graphic solutions are simple; their use requires an ability to follow explicit directions and to interpolate values on a logarithmic sca1e. † For the sake of convenience, the nomograms will be divided into two classes, and the purpose and accuracy of each will be discussed. Power foR CompREssion It is frequently desirable to determine the horsepower necessary to compress a given amount of free air from atmospheric pressure to a certain final pressure. The nomograms in Fig. 1 and 2 present a rapid method of calculating the horsepower required to compress 1 cu. ft. of free air per minute by single or two-stage compression. The general formula for the horsepower required to compress air adiabatically is: S X 144 PVn [(P')n-1/sn -1 (1) where: P = absolute atmospheric pressure at compressor, in pounds per square inch. P' = final absolute pressure of compressed air, -in pounds per square inch. V = volume of free air compressed per minute, in cubic feet. S = number of stages. n = exponent of the compression curve.

Jan 1, 1918

By C. W. Crispell

THE four nomograms presented in this article were designed to simplify and make more, rapid the calculations connected with the compression and transmission of air. The formulae involved are rather complicated, but the graphic solutions are simple; their use requires an ability to follow explicit directions and to interpolate values on a logarithmic scale. ? For the sake of convenience, the nomograms will be divided into two classes, and the purpose and accuracy of each will be discussed. Compression It is frequently desirable to determine the horsepower necessary to compress a given amount of free air from atmospheric pressure to a certain final pressure. The nomograms in Figs. 1 and 2 present a rapid method of calculating the horsepower required to compress 1 cu. ft. of free air per minute by single or two-stage compression. The general formula for the horsepower required to compress air adiabatically is: HP = S X 144/33,000 PVn/(n-1) [(P'/P) n-1/Sn -1] (1) where: P = absolute atmospheric pressure at compressor, in pounds per square inch. P' = final absolute pressure of compressed air, in pounds per square inch. V = volume of free air compressed per minute, in cubic feet. S = number of stages. n = exponent of the compression curve.

Jan 6, 1917

By James E. Howard

At the request of the Council of the Institute, I have the honor to submit the following remarks upon the Program of Tests under which the current work of the Watertown Arsenal Testing Laboratory is carried on, which comprises, among other items, the tests of steel ingot metal and derivative shapes. The intended scope of the tests may be illustrated by extracts from the descriptive part of the program as submitted by the Laboratory under date of April 17,1907, and subsequently approved by the Chief of Ordnance, U. S. A. Under Item 1, Ingot Metal—Open hearth, acid and basic; Bessemer, acid and basic; crucible; fluid compressed and uncompreesed—descriptive remarks were made as follon-s: "A thorough, fundamental inquiry into the physical properties of steel necessarily begins with the ingot metal. Investigations, having for their object the improvement of steels, should also begin with the ingot. A knowledge of the ingot structure is essential for judging of the subsequent behavior or appearance of the metal. Under ordinary conditions, so little information is obtained from the ingot in individual cases that practically none of importance is acquired. These remarks have particular reference to the state of physical and structural

Jan 1, 1909

DISCUSSION, G. Derge and D. J. Girardi presiding N. A. Gokcen (Michigan College of Mining and Technology, Houghton, Mich.)—While the authors present very interesting results on the effect of sulphur upon the solubility of oxygen, they have not established convincingly the lines of two-fold saturation (the valleys in Fig. 2) and the ternary eutectic point. Their contention that sample S-7, upon melting at

Jan 1, 1954

IN the decade beginning 1850, the development by William Kelly in I the U.S.A. and Henry Bessemer in England of the pneumatic method of refining pig iron, known as the Bessemer process, gave the world the first method of producing low-cost steel in large volumes. Briefly, the Bessemer process consists of blowing air through liquid blast furnace iron in a refractory-lined vessel known as a converter. The air enters the iron in the furnace bottom through tuyeres, and during its passage through the iron removes the carbon, manganese, and silicon by oxidation. The heat produced by oxidation is sufficient to raise the temperature of the liquid metal to normal steel casting temperatures and, in addition, to melt some scrap. In the 1860's, the open hearth process was introduced which in the early part of the twentieth century surpassed the Bessemer process in steel production. In the early 1870's, Thomas and Gilchrist discovered that phosphorus could also be removed if lime were added and the converter lined with basic refractory; the modification is known as the basic Bessemer process and is used in Europe. Bessemer steel usually contains between 0.010 and 0.020 per cent nitrogen and between 0.05 and 0.10 per cent phosphorus which influences the properties. Henry Bessemer,1 in 1856, recognized the possibility of using oxygen in the converter process, but the cost was prohibitive. This interest was associated with the theoretical balance of the Bessemer process. Experimental work' has indicated that bottom blowing with pure oxygen results in serious converter bottom and tuyere erosion. Dilution of the oxygen by steam has been observed to be an effective means of maintaining low-nitrogen content of the steel and at the same time reducing bottom and tuyere erosion. A further advantage is that the fume emission characteristic of Bessmer operation is reduced. The addition of steam to the oxygen, however, reduces scrap-melting capacity due to the endothermic reaction characteristics of steam. The possible advantages of refining methods for steel using high-purity oxygen have been recognized for over a hundred years, but the develop-

Jan 1, 1964

By EDWARD B. DURHAH

The illustration Fig. 12, of the paper of Edward B. Durham, "Electrolytic Refining at the U. S. Mint, San Francisco, Cal.," printed in Bulletin No. 58, October, 1911, p. 830, contained an error. The corrected diagram is printed below.

Nov 1, 1911

By William G. Pariseau, H. Douglas Dahl

Recent subsidence legislation indicates that mining engineers would be welt advised to be able to predict and control surface damage caused by mine subsidence. To date, such an ability is practically nonexistent. Model analysis is suggested as one of the alternative paths available which might yield fruitful results. Similitude requirements developed for a self-loaded body in static or quasi-static equilibrium indicate that complete similitude without centrifuging is an impracticability. However, a pilot experimental study which used a simplifying assumption to correctly model mine subsidence has produced results in qualitative agreement with field observations. The purpose of this paper is to present a discussion of the various approaches that can be taken in the study of mine subsidence phenomena. Particular attention is focused upon the rational selection and use of laboratory models. Broadly interpreted, mine subsidence is the deformation of the rock mass enclosing a mine. Depending upon a number of factors, the movement of the subsiding rock mass may disrupt gas and water lines or other buried utilities, damage surface structures such as buildings and bridges, dislocate streams, roads, and rail lines, aggravate acid mine drainage and fire problems, and generally mar the landscape. It is clearly a problem that no mine manager can safely ignore. It is also a problem that will grow with the general population increase. In the following discussion, a summary review of past and present approaches to subsidence studies is given. The possibilities of duplicating subsidence phenomena in laboratory models are examined, and an analysis of a particular type of model is presented. Some preliminary results obtained from a model of the particular type analyzed are then discussed. REVIEW OF PREVIOUS WORK Historically, subsidence investigations have been empirical studies in the field and laboratory or theoretical analyses of mathematically idealized media. Empirical and theoretical work in the United States has generally lagged behind investigations abroad. In the United States, field studies are mostly pre-World War 11. These are summarized in the Mining Engineer's Handbook. ' Field studies in Europe are more recent and more extensive. Those made in Great Britain are summarized in the Subsidence Engineers Handbook2 and represent observations made at 157 different collieries. Such studies by themselves are of limited usefulness as are all empirical studies. One can never be certain that conditions at one mine will be similar enough to those at another to warrant the drawing of like conclusions. European subsidence formulas rely heavily upon the "angle of draw" and "critical area" concepts. The angle of draw is defined as the angle between a vertical line through the face, and another line extending from the face to the surface at the point where movement is zero. The critical area is defined in relation to the least extraction necessary to produce maximum subsidence. Fig. 1 illustrates the angle of draw and critical area concepts. First and second "limits of influence" are also shown. The angle of draw and associated critical area concept are obviously not well defined, being dependent upon the accuracy of the surface survey. In Great Britain, the angle of draw has increased through the years from about 26 to 35°. In the United States, zero and negative angles of draw have been reported. In the authors' opinion, these purely geometrical concepts represent an oversimplification of subsidence phenomena and their use, in the United States at least, should be discouraged. Empirical observations of laboratory models containing layers of earth, sand, clay, and plaster were made by Fayol (cited by Peele) as early as 1885. An outgrowth of his work was the "dome theory," a verbal description of what is assumed to occur in subsiding rock masses. The dome theory has since fallen into disrepute. Theoretical analyses worthy of the name treat a subsiding rock mass as a deformable body. In these analyses, the actual rock mass is replaced by an idealized material that deforms according to a simple stress-strain relationship. The stress equations of equilibrium expressing the Newtonian laws of mechanical action and the geometry of strain furnish additional equations that must be satisfied. A loading criterion-generally understood, and in some cases stated explicitly-completes the theory.

Jan 1, 1969

Freeport's Floating Mine Begins Sulphur Operation Eight years of research were culminated when Freeport Sulphur Co.'s floating mine plant went into operation on Bay Ste. Elaine in the remote Louisiana bayou country 60 miles southwest of New Orleans.

Jan 1, 1953