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By D Lau

Traditionally X-ray diffraction (XRD) has not been significantly used by the cultural heritage sector, as the most commonly used technique, X-ray powder diffraction (XRPD), requires sample removal from the artwork or artefact, followed by grinding of the sample to a fine powder. With the development of micro-X-ray diffraction (micro-XRD) and other associated advances, non-destructive, in situ analysis of crystalline pigments on micro-areas of paintings and artefacts has become possible. This is illustrated with the application of this technique to the in situ analysis of propriety paints, paint cross-sections and small paintings. However, workers have noted that XRD can be insufficiently sensitive with pigment mixtures, due to matrix effects. This study obtained X-ray diffractograms of 17 single pigment preparations and determined relative amounts of crystalline content. The purity of single pigments was compared with Joint Committee on Powder Diffraction Standards (JCPDS) database diffractograms. The impact of pigments with high X-ray absorption coefficients on the detection limits of pigments with low X-ray absorption coefficients was further investigated by building on work done with the chromium oxide-zinc oxide series with the preparation of a second series of binary mixtures of zinc oxide (which has a high absorption coefficient and is almost fully crystalline) and ultramarine blue, which has a lower absorption coefficient but which is more crystalline. Semi-quantitative analysis, where baseline and absorption factor corrections are made, confirm detection limits as low as five per cent for chromium oxide and ultramarine blue when in a binary matrix with zinc oxide. However, this type of analysis is very time consuming. So in order to theoretically simulate issues that will be encountered with binary pigment mixtures, the single phase diffractograms were used to theoretically investigate the matrix effects of the three white pigments with the various coloured pigments. This illustrated that detection limits can be as low as five per cent or in non-ideal conditions, such as with partial peak clashes or where there are large differences in relative peak intensity, as high as 50 per cent. These results have significant implications for the analysis of painted surfaces on artworks or artefacts. It has been demonstrated that ideally this method is more suited to the investigation of surfaces where there is minimal mixing of pigments or where there is not a significant difference between the absorption coefficients of the mixed pigments.

Jan 1, 2008

The Central Extended Orebody is located within the Cracow Goldfield approximately 360 km northwest of Brisbane and approximately 220 km west of Bundaberg. It is an epithermal gold deposit hosted by the Late Carboniferous to Early Permian Camboon Andesite. The lode was mined by open cut methods and produced 170 458 tonnes of ore at 5.62 g/t gold.The geology of the rit is relatively simple, comprising two rock types, trachyandesite and rhyolite which have been sub-divided into several units. The trachyandesite is sub-divided into three rock types: brecciated trachyandesite which is the most widespread, hydraulically fractured trachyandesite hosts the mineralisation and the third sub-unit is chloritised hydraulically fractured trachyandesite and has no associated mineralisation. The mineralisation is confined to quartz veins in hydraulically fractured trachyandesite. Several phases of brecciation and subsequent quartz and quartz/adularia vein injection are evident although not all phases are mineralised. Two rhyolite dykes intrude the trachyandesite one is monolithic, the other is sub-divided into hydraulically fractured rhyolite (barren), silicified rhyolite and auto-brecciated rhyolite.

Jan 1, 1993

Spatial continuity as described by a variogram is a reflection of the underlying mineralisation/geology. Modelling of the spatial continuity (variogram) must account for both the quantitative data (ie sample grades), on which the variogram calculations are based, and the qualitative information as provided by the geological interpretation. An understanding of the geology and the variogram interpretation tie together the sample values and allow us to go beyond the actual data (Journel, 1995). Variography makes geology transportable and allows the geological interpolations to be channelled downstream into mine planning, ultimately affecting the economic decisions surrounding a deposit. As such the process of variography and resource modelling is critical. Thus consistent expert decisions need to be made which force geologists to have a closer look at the available information and the geological interpretations. The aim of this paper is to provide an overview of the latest developments in visualising variography and to demonstrate their usefulness in decisions regarding the spatial continuity of mineralisation. New ideas concerning potential future developments in visualising and modelling spatial continuity through variography are introduced.

Jan 1, 1996

By M J. Pascoe

The performance of 460 stope surfaces at WMC ResourcesÆ Olympic Dam Operation (ODO) has been used to investigate the confidence that can be placed in the Stability Graph Method for design of stope dimensions. A detailed database of stope performance and ground condition information was established for each stope. The database contains all the required stability graph information as well as other factors thought to influence stability, such as discrete major structures, poor shape and exposure time. The performance of each stope surface was quantified by calculating Equivalent Linear Overbreak/Slough (ELOS). The performance of stope walls and crowns was plotted on the supported and unsupported case history stability graphs. Based on this information an ODO design limit of HR = 3.3 x NÆ0.33 has been suggested for stope walls. Walls that plotted above this line were 80 per cent stable, 20 per cent unstable and zero per cent failed. Below the line 60 per cent were stable, 30 per cent unstable and ten per cent failed. Supported crowns that are flat or arched in shape and are not within the influence of major structures can be designed in the stability graphÆs æstable zoneÆ with a strong likelihood of stability. The Stability Graph Method did not reliably predict the performance of unsupported crowns at ODO.

Jan 1, 2005

By Gallet M, Watsford R. M S

The 1989 feasibility study of the chessy, france, copper, zinc, pyrite and barite orebody was based upon a classical flowsheet. The flowsheet included, three stages of crushing, conventional rod and ball mill grinding in series, and sequential flotation of four products utilising conventional mechanical flotation cells. To improve the profitability of the project the partners commenced a search for ways to reduce the projected capital and operating costs of the proposed development. This paper presents the improvements in the projected capital and operating costs as a result of design and concept changes. The major changes included: ò the simplification of the crushing section with the adoption of semi autogenous grinding (SAG) milling of primary crushed ore. ò the deferral of pyrite and barite flotation circuits until market conditions were positive. ò the simplification of the flotation circuit by the use of column flotation cells for combined rougher/cleaner duty. ò the purchase of second hand equipment. The result of these changes was to reduce the capital cost estimate of the plant from US$ 21 million to US$ 11 million and operating cost estimates from US$ 18.90 to US$ 13.60 per tonne of ore for a decrease of approximately ten per cent in potential revenues.

Jan 1, 1991

By S Vink, V Nanjappa, C J. Moran

Poor quality water resulting from interaction of surface run-off with saline mine spoil and soils can cause significant problems for water reuse on mine sites. Not only can this saline water lead to machine corrosion and increased maintenance costs, but may cause detrimental effects on the environment. Determining the geochemistry of mine spoil, and the likelihood of salt dissolution during rainfall events, may aid in more effective mine site management of water. Spoil samples were taken from three areas of the German Creek mine site, situated in the Bowen Basin coalfield, Queensland. Samples from two undisturbed areas on the lease were also collected for comparison. Analyses were performed using a variety of laboratory techniques: leaching tests, effective cation exchange capacity determination, X-ray diffraction, clay quantification, and total organic content determination. Results show that dissolution of surface (top 2 cm) salt minerals from spoil areas is an important contributor to surface run-off salinity during rainfall events. Equally, ion exchange with clay minerals appears to be a significant source of elevated ion concentrations in run-off waters. Findings from the undisturbed areas show undetectable quantities of salt mineral species, resulting in waters with low ion concentrations. More generally, monovalent cations (sodium, and to a lesser extent potassium) appear to be derived from dissolution of salt precipitated whereas divalent cations (calcium, magnesium) are more likely to be sourced from exchange reactions with clay minerals. Incorporating knowledge about the mechanism of cation mobilisation from spoil with the spatial distribution of spoil properties and understanding of the dynamics of water quality variations on the site will aid in development of integrated water quantity and quality management strategies.

Jan 1, 2009

By R Balusu, P Humphries

In combination with detailed field studies and goaf gas characterisation, computational fluid dynamics (CFD) models have been used to develop optimum and effective strategies for inertisation during longwall sealing operations to achieve goaf inertisation within a few hours of panel seal-off operation. This study has combined detailed analysis of the performance of various inertisation field trials together with CFD modelling results of different inertisation operations in order to develop the optimum inertisation strategies. A number of parametric studies were conducted on the base case CFD models that had been calibrated and validated based on the information obtained from previous inertisation studies and goaf gas monitoring. These studies included changes in inert gas injection locations, inert gas flow rates, seam gradients, and different inertisation strategies to investigate their effect on goaf inertisation. Studies indicate that the strategy of inert gas injection through the MG seal was not as effective as the alternative strategy of inert gas injection at 200 m behind the face. Innovative inertisation strategies have been developed and subsequently implemented at an underground coal mine in Australia. Further investigations have been carried out in the development and demonstration of proactive inertisation strategies with the objective to suppress the occurrence of spontaneous heatings in active longwall faces, in particular under unexpected scenarios such as during slow retreat/face stoppage due to difficult geological conditions. Initial trials at two Australian longwall panels have demonstrated the great potential of this practice to contain the onset of heatings in the goaf.

Jan 1, 2005

By Baoqi S, Zhengbing C, Wenguang L

A new flotation method is introduced for separating zircon from rutile and other Ti-bearing minerals at normal temperature, using a mixture of cationic and anionic collectors without any acid, alkali or fluoride as regulators. By combining the method with gravity concentration and magnetic separation to process the seabeach placer, the technological flowsheet can be simplified and the pollution of environment and the corrosion of acids, alkalis and fluorides on equipment can be removed.

Jan 1, 1993

Renison Goldfields is one of Australia's largest mining companies with annual sales revenue over $600 million. It has ten operating mines and processing plants, with operations in most States of Australia and in Papua New Guinea, Indonesia and the United States. The exploration division is active in,other parts of the world, including Europe and South America. RGC produces gold, copper, tin, coal and mineral sands. RGC is typical of companies in the mining industry in that by contrast to the typical pattern in other industries, it is necessary to have systems to handle a variety of different types of operations, a range of size of operations, and operations in remote locations.

Jan 1, 1995

By S R. Hencher

The development and availability of modern software for cavern design over recent years has provided design engineers with a range of usable design tools. The paper discusses the range of modern software available, presents a design methodology, reviews ground investigation requirements and software available for data processing and management, and discusses requirements and common analytical considerations with reference to typical packages. Caution is given of the tendency for readily available and user friendly software to be used without a full appreciation of the underlying engineering principles.

Jan 1, 1999

By A L. Hemphill

Conventional models, based on pulp kinetics, were regressed directly to steady-state data from a nine-stage platinum flotation plant, to provide a basis for optimisation studies. æFroth factorsÆ were used to characterise the froth in each stage and a ædepressant factorÆ was used for gangue minerals, to account for addition of depressant to the cleaners. These factors improved the fit, but differences between plant and model of up to 50 per cent were still present in a number of streams in the cleaning circuit. A new model was developed, which incorporated two rate constants for the recycle of particles from the froth. These parameters provided a workable approximation of the distribution of probabilities of particles being recycled in plant cells, depending upon where particles appeared at the surface. The feed streams were characterised by two pulp kinetic parameters and the above recycle parameters, for all minerals and all stages. The fit to the data was improved very significantly, when compared to the use of conventional pulp-based models with several pulp rate parameters. This relatively simple model did not require additional data from batch tests and it was suitable for plant simulations.Simulations of various strategies for plant operation were tested, allowing the simulator to vary the concentrate flows from all or some of the stages, in order to maximise platinum recovery. The simulator was imbedded in an automatic optimiser and constraints on chrome content or mass flow of final concentrate were used. The simulations of the existing circuits demonstrated that an improvement in recovery, (for a constant concentrate mass) of about 0.5 per cent was possible, by optimising all concentrate flows. A significant reduction in the flow of scavenger concentrate and an increase in the recycle flows in the cleaners were noted. The results of simulations of various changes to the circuit configuration are also discussed. An increase in recovery of 1.4 per cent (for constant concentrate mass) has been achieved in recent simulations, through circuit changes. However, it was necessary to keep the mass pull of concentrate, per unit area, within typical limits.

Jan 1, 2005

By R Lloyd

Coal Services (Health and Safety Trust) funded ARRB Transport Research Ltd to investigate fatigue and performance of truck drivers over consecutive shifts. The main questions were to assess: What is the most important contributor to acute fatigue in mining? Is it length of shift (eg eight hours versus 12 hours) or is it time of day (eg circadian effects)? What is the limit of successive day or night shifts before chronic fatigue affects operator performance in open cut mines? The project methodology included utilising ARRB Fatigue Monitoring Devices (forced-choice stimulus reaction) in eight haul trucks, testing 24 subjects over several weeks. Each subject filled in a Fatigue Risk Questionnaire on lifestyle and health. Operators worked a 14-night, one day off, 13-day roster of 12-hour shifts in a fly-in/fly-out operation with excellent opportunities for restorative sleep between shifts. A total of 3500 hours of real-time data was collected, representing the first set of objective, real-time driver performance data for Australian mining. The data showed that for a single night of driving haul trucks, there appears to be no effect on operator fatigue from the amount of time on task (for the 12 hours). In fact performance was worse through the first eight hours than the last four. The circadian influence had a stronger affect than working more than eight hours. Of the 14 nights worked at the site, nights 13, 14, seven and two respectively, were the worst. This presents a conundrum for policy makers who may like to place caps on working hours or rosters in the hope that it will alleviate the fatigue issue. It will not. The major finding within this study is the combined influence of circadian rhythms (human body clock) and individual variability on performance. The lifestyle habits and the health of individuals have a profound effect on operator performance as shown by the strong positive correlation between high fatigue risk scores from the Fatigue Risk Questionnaire and poor performance. An individualistic approach would appear to have the best chance of reducing high potential incidents due to fatigue through successive nightshifts.

Jan 1, 2005

For many years the mining industry at Broken Hill, New South Wales, Australia, was carried on with just sufficient attention to underground ventilation and hygiene conditions as to keep pace with necessity. However, the campaign against industrial diseases in other mining centres (notably South Africa) some years ago, brought the subject more prominently before local mining engineers.Throughout a period of several years, gradual improvement has been effected, and at the present time industrial hygiene is considered an essential part of the production operations of the various companies.In June, 1918, a move was first made by the Board of Trade advising an inquiry respecting the health of employees engaged in the metalliferous mining industry in the State of New South Wales. At the end of that year, a recommendation was made to the State Government by the Board of Trade that a Techni.cal Commission of Inquiry be appointed to examine and report upon the dust conditions of the metalliferous mines at Broken Hill. Following this a second report presented in 1919 made specific recommendations in respect to the scope of such a Commission. A Technical Commission of Inquiry was accordingly appointed and arrived in Broken Hill to inquire into the prevalence of miner's phthisis and pneumonoconiosis in the mines. Early in March, 1920, the examination of all mine employees commenced, and the work was completed in June, 1920. The full report of the activities of the Commission and the conclusions arrived at was officially published at a later date. Based on the recommendations...

Jan 1, 1940

By Canterford JH

Current and future methods of data acquisition in hydrometallurgy are reviewed. Hydrometallurgical operations involve a wide range of chemical and physical processes for the recovery of metals and other products from ores and concentrates. Control of such operations requires information on the different liquid/solid and liquid/liquid mixtures being processed. Continuous. data acqui-sition for the liquid phases uses procedures already commercially exploited in other types of chemical plant. The major problem is the lack of robustness of measuring probes. Continuous analysis of the solid phases is much more difficult to-achieve because of the sampling and analytical techniques involved.

Jan 1, 1985

Modern Management Systems for Higher Margins By Malcolm Roberts, Catalyst for Corporate Performance Ltd Malcolm Roberts put the case for changing systems in order to change behaviours and attitudes and improve productivity. ""The key to lifting margins is changing systems."" A system is anything that drives ways of doing things. Sometimes these are formal, and documented, and sometimes they are not. Improving productivity The way to dramatically improve performance is to use the systems. Roberts stressed that if systems and processes are under control, the benefits of automation are huge. If they are not, the benefit of automation will be lost. To improve productivity, you need to: ò identify what to change in the process, ò use the proven methodology to systematically improve the process, and ò change what people do - change work practices.

Jan 1, 1997

By Trutwin W, Tracz J

The outbreak of open fires underground cause disturbances to the conditions of the mine ventilation process. Thermal and chemical effects due to fire create unsteady, transient states in airflow and the spread of combustion products in the mine ventilation network. Changes in airflow have an influence on the fire, constituting a sort of feed-back between the fire and the ventilation process. This paper deals with a numerical simulation method, which enables the determination of transients caused by fires. The mathematical model, of the simulation method considered, has been based upon a: simple model of combustion of fuel in the airway, unsteady exchange of heat between the fire, airflow and surrounding rocks, airflow in mine ventilation networks and the theory of heatflow in the rocks. Initial and boundary conditions allow the determination of a set of parameters describing the airflow, the propagation of combustion products, the tempera- ture of the fire and flow etc. due to the fire. The simulation method, facilitates a graphical presentation of the spread of combustion products throughout the network. The simulation method has been prepared for an IBM PC/AT Computer.

Jan 1, 1988

By Zieg GA

The Sheep Creek Project lies 30 km north of White Sulphur Springs in the Little Belt Mountains of central Montana. Homestake Mining Co. discovered base metal anomalous pyrite beds downdip from gossans in 1974. Cominco American began exploration in 1976, consolidated adjacent properties, and joint ventured with BHP-Utah International in 1985. High . grade Cu and Cu/Co mineralization intersected in a 1985 drill hole led to discovery of two separate deposits. The project area now covers over 175 km2 and is being actively explored for Cu, Co and Zn in a shale hosted bedded sulphide system.Proterozoic Belt Supergroup sediments host the Sullivan Pb/Zn deposit, stratabound Ag/Cu ores of the Revett Formation at Troy and Rock Creek, and base metal rich pyrite beds at Sheep Creek.

Jan 1, 1990

Secondary steelmaking (or ladle metallurgy) has been developed as a post- steelmaking ladle treatment to produce steel of superior quality. Its rapid growth has resulted from quality improvements, productivity increase, operational flexibility and process route economics. Advances in secondary steelmaking are very impressive during the past decade, and many commercial systems have been developed for performing one or more of the following unit operations: degassing, atmosphere regulation, reheating, refining with synthetic slag, rinsing gas treatment, injection of solid materials and alloying. The metallurgical requirements imposed by the current competitive steel market include more precise analysis tolerances, minimum level of detrimental elements, improved cleanness, demanding service performance and better processability. In most cases, these requirements could only be realized by the application of appropriate secondary refining facilities. Continuing developments in simplicity of design, cost advantage, quick cycle time, improvements in peripheral services such as refractories, instrumentation and in-situ analysis, extensive exploration of new applications, and the use of computer, can be expected. An exciting future is predicted for the widespread adoption of secondary steelmaking to perform most of the major refining functions over a variety of steel quality. It will also become a vital link in the total steelmaking process for production of tonnage steel at the large integrated steelworks and the mini-steelmills.

Jan 1, 1986

Diversity is a key strength for Western Mining Corporation. An international corporation with assets of about $A10 billion, WMC is engaged in both mining and downstream processing of minerals including nickel, gold, alumina, copper and talc, as well as having interests in oil and gas production and agricultural fertiliser. The company is focusing on several core commodities that will maintain its strength in the years ahead. Although most current mineral assets are within Australia, it plans to have 25 per cent of its operations off-shore by the turn of the century, and be a major producer in at least six core commodities. WMC's strategic and management focus has shifted from a regional approach to a commodity focus so that it can more readily cater for different markets with differing sensitivities. This document is an ABSTRACT ONLY - no paper was published for this presentation

Jan 1, 1996

By Chaves AP, Delboni H. Jr

Thermal comminution is an industrial process specially suited to very abrasive material, when contamination with Fe from wearing parts of conventional crushing and grinding equipment must be avoided. It involves an initial step of heating the material to be comminuted, followed by sudden cooling (quenching) and finally by a conventional mechanical process to disassemble the particle aggregates. The thermal step is, in fact, a pre-fracturing process. The heating operation causes changes in phase of the minerals and changes in volume of these minerals and other substances included in pores and cracks. The cooling operation causes thermal shock reversions or the phase transformation and consequent generation of internal stresses, high enough to fracture the solid.

Jan 1, 1993