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By B. Krysa, A. Mitsui, T. L. Koehler

The presence of arsenic, even at trace levels, in copper processing leads to the risk of arsine gas where reducing conditions exist that can reduce any soluble arsenic present to its minus 3 valance state and generate hydrogen gas from the solutions. This risk is understood to be significant within the industry, particularly in the case of liberator cells where copper concentrations in solution are drawn down to remove the copper and impurities from the bleed stream. However, there are numerous other potential areas where the arsine gas risk exists including contact between active metal such as iron, zinc or aluminum and arsenic bearing solutions in pyrometallurgical dust treatment, refining and acid plant operations. In turn this breaks down to different mitigating strategies dependent on the risk scenarios considered; for example, how this risk interacts with Change Management, Confined Space Entry or Contractor Training. The ISO 45001 is an emerging standard meant to improve employee safety, reduce workplace risks and create safer working conditions all over the world. The paper shows a case study of how a framework consistent with the tenets of ISO 45001 has been used to provide a consistent assessment of this risk for a wide variety of copper operations and the expectations of how this may be used to effectively improve the effectiveness of barriers against future incidents. INTRODUCTION Arsine gas (AsH3), first identified in 1775, is a highly poisonous, colorless, non-irritating gas with a mild garlic odor that is heavier than air. Arsine gas is generated when reducing conditions are generated in the presence of hydrogen ions and arsenic compounds. Present permissible occupational exposure limit as defined by Occupational Safety and Health Administration (OSHA) as an 8-hour time-weighted average is ppm (0.2 mg/m3). Further increasing the risk, conventional respiratory protection utilizing half or full masks with gas filtering cartridges provide minimal protection against arsine. In copper processing plants, the risk of arsine generation is well understood in liberator cells, which are part of the electrolysis process. In this process, solutions containing copper are reduced in copper concentration removing not only the copper, but also arsenic, antimony and bismuth. The residual solution can be bled to control impurity build-up in the refinery. In this process, if the copper concentration is reduced to the point where As3- can form, arsine gas is generated via reaction with hydrogen ions generated during the plating process. The copper concentration at which arsine gas is generated depends on copper concentration at the cathode surface, the temperature and the acidity. As a result, there is always a risk of arsine gas generation in the liberator cell. Process measures to minimize or mitigate arsine evolution are tight control on final copper concentration, warm temperatures, fresh feed distribution and internal acid recirculation rates. Operator exposure protection measures are hooding, ventilation, arsine detection systems, restricted personnel access, automated shutdown controls and pre-defined evacuation plans.

Jan 1, 2019

By M. Abumiya, N. Onodera

Stabilization of arsenic via the precipitation of large-sized scorodite (FeAsO4·2H2O) particles usually involves the use of expensive autoclave systems operated under high temperature and pressure conditions. Alternatively, DOWA developed a novel scorodite synthesis process (DMSP®) wherein the Fe(II) ions in solution containing As(V) ions were oxidized by O2 gas under atmospheric pressure. In this process, crystalline scorodite particles were formed via the formation of a gel-like precursor containing Fe(II). Based on this concept, in this study, we have demonstrated the synthesis of scorodite particles by the addition of Fe(III)-containing solution to the experimental solution containing Fe(II) and As(V) ions, without the O2 gas oxidation process. Ferric sulfate (Fe2(SO4)3) was used as the source of Fe(III) ions. Results indicate the precipitation of scorodite particles, comparable to that of the O2 gas oxidation method.

Jan 1, 2014

By S. S. Dimov, B. R. Hare

This paper describes two micro-beam analytical techniques(Dynamic SIMS and TOF-SIMS) which have become an intricate part of a comprehensive analytical approach for precious metal (PM) ore characterization and process mineralogy or deportment studies. The value of the D-SIMS technique is its capacity for accurate analysis in the sub ppm range along with the ability to produce high resolution elemental maps. The TOF-SIMS is significant for speciating and quantifying preg-robbed Au on the surface of carbonaceous material. In combination with traditional assays, the two techniques can provide invaluable information regarding the distribution of PMs within an ore along with providing insight into potential sources of PM loss in processing or where losses have occurred in process streams.

Jan 1, 2011

By Z. Luo, China University of Mining & Technology, C. Duan

"The magnetic separation removal rate of pyrite could be improved effectively by increasing the susceptibility of pyrite. The electromagnetic characteristics and absorption response performance of high-sulfur fine coal were studied in strengthening the susceptibility of pyrite. In the process of treating the sample through the microwave, electromagnetic energy could be converted into heat energy due to dielectric loss and magnetic loss. The RL(dB) was evaluate the performance of absorption response of coal. The microwave improved the susceptibility was in ultra-high frequency region, which is the most natural resonance. The absorption fine coal to microwave was strengthened and microwave energy was improved by adding the magnetite powder with double loss characteristics as the microwave absorber. The dielectric properties and permeability characteristics of the fine coal trend were investigated by maxing magnetite powder. The microwave absorption in different coal thickness was surveyed through the reflection of energy loss.INTRODUCTIONMicrowave desulfurization is one of the most important research directions (Haque, 1999; Makul, Rattanadecho, & Agrawal, 2014; Su, Tang, Zhang, Jing, & Bai, 2014). The working principle of microwave absorption response can be briefly described as the interaction of the sample with microwave energy, which will result in the microwave energy converting into heat energy loss (Keangin & Rattanadecho, 2013). For specific samples, the polarization effect includes multiple polarization mechanisms(Meikap, Purohit, & Mahadevan, 2005). Different polarization mechanisms have different occurrence time and dominant mechanisms. Meantime, energy consumption will be occurred during the process of polarization effect (Chelgani & Jorjani, 2011; Rowson & Rice, 1990) . The absorption of microwave energy in the fine coal is a process of electromagnetic response (Znamenácková, Lovás, Mockovciaková, Jakabský, & Briancin, 2005). Microwave transfers the electromagnetic waves into the heat energy by microwave dielectric loss and magnetic loss for achieving the absorption of microwave energy in the treatment of samples (Lee, Kim, Kim, Chung, & Kim, 2004). The additive magnetic medium is Fe3O4 belonging to microwave energy absorber of double loss medium (Uslu, Atalay, & Arol, 2003)."

Jan 1, 2016

By A. Shakoor, T. P. Gautam

The long-term slaking behavior of clay-bearing rocks in the field can be quite different than the short-term slaking behavior in the laboratory. To assess this difference, 12 replicate samples of each of 20 clay-bearing rocks, including 5 claystones, 5 mudstones, 5 siltstones, and 5 shales, were exposed to natural climatic conditions for 12 months. After each month of exposure, one replicate sample of each rock was removed from natural exposure and its grain size distribution was determined. Disintegration ratio (DR), defined as the ratio of the area under the grain size distribution curve of the slaked material for a given rock to the total area encompassing all grain size distribution curves of the tested samples, was used to quantify the amount of disintegration under natural climatic conditions. DR values of naturally exposed samples were then compared with the corresponding values of second-cycle slake durability index (Id2) determined in the laboratory. The relationship between Id2 and DR after, 1 month of exposure, exhibits an R2 value of 0.65 but the relationship deteriorates when DR values for 6 and 12 months of exposure are used, with R2 values of 0.63 and 0.25, respectively. However, when DR values for laboratory samples, computed from grain size distributions of slaked material after second cycle, are compared with DR values of naturally exposed samples for the three periods of exposure, the relationship improves with the corresponding R2 values being 0.61, 0.71, and 0.41. These results suggest that DR may be a better parameter for assessing the long-term disintegration behavior of clay-bearing rocks than Id2.

Jan 1, 2015

By Z. Wu, L. N. Y. Wong

The present study develops the numerical manifold method (NMM) as a tool to investigate the progressive failure in rock slopes. The entire processes of the progressive slide surface development related to crack initiation, propagation, coalescence and degradation to eventual catastrophic failure are successfully captured. To overcome the limitation of the original NMM associated with an improper removal of the interface cohesion of the discontinuities, the displacement-dependent cohesion removal method is adopted. Simple examples of failure of rock slopes containing different arrangements of discontinuities are modeled and their results are compared with those based on the popular limit equilibrium method proposed by famous pioneers Jennings and Jaeger. In cases of coplanar non-persistent discontinuities, close results are obtained despite the differences in the consideration of the stress concentrations at the crack/discontinuity tips. In cases of non-coplanar discontinuities, since the influence of the tensile strength is considered by both the Jaegers model and the NMM, the Factor of Safety (SF) values are similar despite the difference in the failure path trajectories predicted by these two models. The results also reveal that the original NMM without the displacement-dependent cohesion removal method is always more conservative due to the improper removal of the interface cohesion. The displacementdependent cohesion method can to some extent alleviate such a limitation.

Jan 1, 2015

By Kazuhide Nakaniwa

In this research, we devised a measurement method using total stations (TSs) which have ?the Baum? which is a concentric circle reticle, as substitute for crosshairs. The Baum owes its name to the similarity between the concentric circles and trees (Baum in German). By setting one circle on both of edges of cylinders, operators can set their sights on points on the center line of the cylinders, and also can measure positional coordinates of the points. Also, by measuring two different points on the center line, operators can measure the position and tilt of the axes of the cylinders. Furthermore, we developed a pile driving navigation system. Foundation piles are used for various structures, and their forms are generally cylindrical. Especially, although it is difficult to drive tilted pile foundations, their usage are expected to expand due to their high earthquake resistance. Yet, a method to accurately measure the tilts of piles has not been established. However, we proved that operators can obtain adequate accuracy to control foundation piles through the measurement experiment using this system. Using this system, the information of the pile is measured using a TS, transferred to a PDA, and displayed from the operator?s view of the piling machine.

Aug 1, 2013

By J. Bhattacharya, S. K. Mukhopadhyay, S. K. Pal

"While time and again many authors have categorically stressed the restoration of the environment, very little effort has been made in the mineral industry to develop the economy of environmental control. There are many abatement procedures that search a maze of variants. Among them pricing environmental damage seems to be more logical and easily implementable.IntroductionMining as an operation has a severe impact on the Earth's natural resources. While economical environment control is much sought after, solutions are often varied and complex, and can differ in the problems of single or multiple mine sites.Determination of Optimum use LevelsIn “mining environmental control"" it is required to strike a balance to find optimum use levels. The solution is to find where the welfare benefits equal the cost involved to curb the degree of environmental damage (Fig . I) . In the mining industries this can be done by modifying the production/extraction process itself. For most pollutants, the marginal costs of control will exceed the benefits from further reduction of damage long before the zero pollution damage point is reached (Fig. I). From an economic perspective the optimal alteration of environment by mining would occur at z; pollution continues to be caused by ""zy"" control units, but it would be inefficient to pursue the redemption efforts further because the marginal cost involved would exceed marginal welfare benefits."

Jan 1, 1992

By Toivo Toivanen

The paper begins with a brief history of the nickel industry in Finland, and then deals with the introduction of the flash smelting process. The main part of the paper is devoted to nickel refining, which is studied under four main headings -grinding, leaching, electrolyte precipitation, and nickel electrowinning. Flowsheets are illustrated, and the equipment used is described. Analyses of the material in the various stages, from concentrate to high-grade nickel matte, are also presented. N ICKEL made its appearance in the Finnish mining industry forty years ago, when a nickel deposit was discovered at Petsamo in Lapland. Mond Nickel Co. received the concession for this deposit from the Finnish Government, and the Petsamon Nikkeli Company constructed a mine and a nickel smelter (1), the completion of which was prevented by the 1939 Winter War. The mine and smelter were, however, completed soon afterwards in spite of World War II,

Jan 1, 1964

By Jeffrey D. Eisenman

FRP is a proven material for the solvent extraction processes of copper production. There is a history of successful applications of FRP piping and equipment in hydrometallurgical processing. The performance of FRP equipment has not always been consistent, but at no fault of the material. Its non-metal attributes and behavior vary from those of more typical materials of construction, such as steel and alloys. FRP is a mainstay material in many areas of solvent extraction and electrowinning and yet not well understood by all. We will discuss the critical concerns, which are key to reliable performance of FRP systems. This paper will include discussion of key elements, which are fundamental to reliable FRP piping design and considered best practices. Essential design and construction considerations to maximize reliable service life of FRP equipment, such as thickeners and process vessels, used in copper extraction and processing, will be discussed. Additionally, we will expose potential pitfalls and share lessons learned from previous copper processing plant projects, which can aid and impact other copper processing projects to ensure best system performance and reliability. INTRODUCTION The corrosion resistant attributes of fiberglass reinforced plastics (FRP) make it an attractive and cost effective material of construction in corrosive service applications that are found in copper processing. FRP is used all over the processing plant in seawater, brine and sulfuric acid services where the corrosive nature of these services would challenge most ferrous materials and coatings. FRP is a fully customizable material to meet the specific needs of each service and process. FRP piping and equipment can be found throughout the hydrometallurgical process, in the acid plant, desalination, leaching processes, solvent extraction and electrowinning to name a few. Beyond its superior corrosion resistant characteristics, FRP can be made abrasion resistant by introducing particulate additives into the resin, such as silicon carbide and alumina oxide. Because many of these services have combustible organic elements in the flow streams with accompanying safety concerns, the linings can be made conductive with carbon fibers to dissipate static charges that might collect on the surface of the equipment otherwise. Further, FRP can be made flame retardant as well, where flammability may be of concern.

Jan 1, 2019

By J. H. Starkey, P. A. Scinto

"In Canada and other countries, legislation dealing with accurate factual disclosure for mining projects is being expanded to include more metallurgical design information. Grinding characteristics, metallurgical recovery of contained metal and environmental hazards associated with tailings disposal will be part of the Canadian package. This paper will examine only that portion of the plant design standard practice that relates to grinding – in SAG mills and ball mills that grind ore from as received crushed material to final ground product that is fed to downstream plant recovery processes. Since grinding plants represent a significant portion of the overall concentrator cost, accountability in grinding design should no longer be left to chance, opinion, or hidden proprietary information. This is the 21st century. It is reasonable to expect that a factual basis will be needed so that a Qualified Person (QP) reviewing the grinding mill design can understand it. That will also involve how many and what quality of samples are taken to define the characteristics of the deposit, the accuracy of the tests used to measure ore hardness and the method by which the dimensions and power of the mills are determined. If these criteria are not met, the QP may have no choice but to call attention to the lack of convincing information regarding the grinding mill design for the project. At the same time clients are expected to demand getting the correct design information at a cheaper price, results in a more timely way, and accurate design to the point where the risk of tonnage shortfalls are reduced or eliminated.Tables will be presented to show how this can be done to current standards using existing technologies. At the same time it is acknowledged that current standards are ill-defined and that to achieve consensus among those involved in SAG mill design work, it may require that a consortium funded project be set up to establish what tests and methods for grinding design are suitable to meet the new standards for metallurgical disclosure. By running parallel design methods on several major projects over a period of 5 years, the process of how to design grinding circuits will be better understood because the projects will start at the design stage, include procurement of the mills and will end with a benchmark test on the plant.Selecting the samples and the best schedule for doing test work on core samples submitted and mill design, will be discussed in this paper. The issue of completing the grinding design in time for early procurement decisions is on the critical path for most major projects. Discussions between mining engineers, geologists and process engineers are needed early in the development cycle, at the scoping study level (SS), preliminary engineering assessment (PEA), prefeasibility study (PFS), and at the feasibility study stage (FS), to ensure that proper planning for design sample selection is done. Using adequate sampling and testing methods in a timely way allows early procurement of the grinding mills and minimizes project risk."

Jan 1, 2012

By Denni Nikols

"Planning for coal beneficiation in the electric utility industry is relatively complex, involving the coordination of experts and specialists in a broad range of fields, as well as compliance with a wide variety of government regulations.This paper examines the role of the planner, reviews possible benefits of coal beneficiation, identifies potential problems and illustrates a typical planning schedule.The steps involved in the planning process are:Step I-Bench- and pilot- washability studyStep 2- Wash plant designStep 3- Power plant and boiler designStep 4-Mine designStep 5-Major environmental and technical problems to address.IntroductionElectrical utilities and coal have a long and intimate relationship . Cleaned coal is becoming an increasingly popular fuel with the utilities for a variety of reasons. Generally, the greatest impetus to burn a cleaned or prepared coal fuel comes from the need to control airborne pollutants.Long-range planning is a standard practice for electric utilities, forecasts of demand must be made well into the future. Since the lead time required to provide new facilities is often as long as 10 years and the cost very high , planning becomes an important task.For a utility that owns and directs the operation of its coal mines, the mine planning or fuel acquisition planning takes on the magnitude of other corporate planning functions. It is from this perspective that a utility would view coal preparation. Except for the interaction of a coal-fi red plant on the actual mine design the planning considerations o f a beneficiating facility for a captive mine or a contract raw coal supply are about the same. Because TransAlta Utilities is currently supplied from captive mines, this discussion will tend to focus in that direction.It is the role of a planner to plan. This is easy to say but it is not always easy to do. Often we are working within a context that resembles the geological time scale. Frequently the objectives are not clearly defined when we begin and ultimately our plans are tested in the waters of government regulations and cost benefit analyses .Planning for beneficiation of Plains coal, or any coal, provides just such a test. The planner's role in this endeavour requires a wide vision. While parts of the process may be amenable to classical methods of project scheduling, the broad range of subjects and interaction of seemingly unrelated tasks is sure to obscure some of the considerations that must be made. Therefore, the planner's chief role is coordinating the work of many experts and specialists toward the final objective.Among the specialists are combustion , geo technical, mining, civil , and mineral processing engineers , geologists, hydrogeologists, soil, and reclamation experts to list a few.When one considers coal beneficiation, the planning part o f that consideration is probably more complex than any other single engineering function. Due to the company's location in the Alberta Plains and the proximity o f the mine to the thermal generating station, this paper will tend to emphasize that situation.Beneficiation may offer some advantages over run-of-mine coal to the power plant opeator. Some of these advantages are: removal of a contaminant, power plant efficiency gains , lower plant capital costs (for new plants), possible lower mining costs."

Jan 1, 1984

By A Hitchen

A general outline is given for the determination of copper, nickel, cobalt, zinc, lead, cadmium, bismuth, manganese, uranium, molybdenum, vanadium, sulphate and fluoride by polarographic or amperometric methods in a variety of ores or metallurgical products. The detection of oxygen in gas mixtures by an amperometric method used as a safety device is also discussed. Introduction I N this paper, a general outline will be given of the polarographic and amperometric methods used for the chemical analysis of various ores and metallurgical products in the Chemical Analysis Section of the Extraction Metallurgy Division of the Mines Branch. The methods to be discussed will be confined to those based on the use of normal D.C. polarography and will not include those methods which utilize a cathode-ray, square wave, pulse or A.C. type of polarograph. For the sake of convenience, ? the polarographic methods will be discussed according to the type of supporting electrolyte employed, as the same electrolyte may serve to determine more than one element in more than one type of ore. Amperometric methods will be discussed according to the element to be determined rather than

Jan 1, 1965

By Namavari. H., M. Ashouri, M. R. Sarhadi, S. H. Mansouri, A. Sarrafi

The splash phenomenon and its effective parameters in metallurgical converters have been studied thoroughly for decades. The detailed studies of processes such as tuyere blockage, wave formation during air injection, entrapped phases, and also processes which control the formation of bubbles in viscous fluids are not feasible yet. In this research, we have used a converter-shaped vessel made of flexi-glass. Water and oil have been used as matte and slag phases respectively. The effective operational factors responsible for creation of splashing have been studied such as air flow rate, tuyere angles, depth of tuyere submergence, tuyere blockage, density and viscosity of liquids, liquids heights, etc. The results have been found as follows: the amount of splashing increases slowly as air flow rate increases. However, as the air flow rate reaches a critical value (depending on the physical specification of converter) the amount of splashing rises sharply, because the flow of air inside the liquid changes from bubbling into a jet stream; and most of the splashed materials are in the form of filaments instead of droplets. Changing tuyere angle from horizontal towards vertical position will increase the turbulence level on the fluid surface and causes an increase in the amount of splashing. The effect of tuyere submergence is related to the converter opening angle. As the converter opening angle is shifted towards the hood position, the amount of tuyere submergence and splashing will increase. As density of the liquid increases, the number of droplets splashing increases with a decrease in drop size. Therefore, the total amount of splashing decreases. However, as viscosity of the liquid increases, the splashing material increases due to the changes in the splashed material from droplet shape into filament form. The height of liquid inside the converter, depending on the relative height of heavy phase and light phase, is an important parameter regarding splashing. As the relative height of heavy phase to light phase increases the splashing will decrease. The tuyere blockage will cause the pressure in the inlet manifold to increase; and in real cases will increase the splashing. Finally, we have development a model based on dimensional analysis to relate the above parameters in order to calculate the amount of splashed material.

Jan 1, 2007

By J. M. Ortiz, J. Haas, W. Kracht, G. Pamparana

This work explores the effect of ore hardness variability on the design of a solar photovoltaic system with battery storage and grid backup, to operate a semi-autogenous grinding mill (SAG). First, a case of two synthetic ore populations was studied, without any consideration of spatial distribution. The mean and variance of the ore hardness (measured in specific energy consumption) of both populations were subjected to a sensitivity analysis. The operation was evaluated with one and two stockpiles. The latter allows classifying according to ore hardness to adapt the SAG energy consumption to the solar cycle. The results show that using two stockpiles allows achieving a larger autonomy (i.e., fewer energy imports) at lower total costs, especially when the difference of mean hardness between the two populations is large. The difference in variance (between the two populations) has a smaller impact on the design recommendations. Second, a case study was performed considering the spatial distribution of geometallurgical units. Two cases were considered: (a) brownfield, when there is historical information of the actual variability of the ore hardness; and (b) greenfield, when the system design relies mainly on geometallurgical modeling. Brownfield and greenfield planning result in similar sizing recommendations of the solar power plant if precise drill cores are available. In this case, geometallurgical modeling is an effective tool for forecasting the energy demand necessary for designing the power plant. INTRODUCTION Solar energy can help make mining more sustainable (Moreno-Leiva et al., 2017). With falling battery costs, an autonomous solar supply is soon to become an economical alternative in many parts of the world, even in the presence of a larger power grid (Child et al., 2017). Although this, places with high solar radiation such as the Atacama Desert in Chile, nowadays show a large potential of incorporating solar energy as a supply of energy. Many of the Chilean copper mines are in this zone making it interesting to study their compatibility and potential of integrating this renewable source to their operation. The power demand in a copper mineral processing plant is determined by the main power loads in grinding and flotation, with grinding typically the largest power consumer, especially the semi-autogenous grinding (SAG) mills (Wei and Craig, 2009). In Chile, it corresponds on average the 50% of the electrical energy consumption (COCHILCO, 2013). Solar energy production is determined by the irradiance perceived into the solar photovoltaic (PV) panels (which varies through the geographic location) and several other climatic parameters such as the current season, humidity, temperature, altitude, and others (Molina et al., 2017). Also, solar energy is only generated during the sun hours, getting to a maximum generation at a certain peak hour during midday, and finally dropping to zero during the night. This shows a cyclic parabolic profile as shown in Figure 1. Due to the SAG mill operated continuously, the power supply always must be available. During the night, to continue supplying the energy, it is necessary to complement the solar power generation with a battery energy storage system (BESS), which will act as a power backup and a buffer. For the optimal sizing of this PV- BESS system, information of the demand profile is needed (Pamparana et al., 2017). In the case of the SAG mill operation, the resulting demand relates to the ore-hardness for a specific throughput and grind size (Morrell, 2004). Therefore, for a given throughput and target grind size, a harder ore would require more power, and variable hardness results in more variable demand and a subsequent need for larger energy storage (Bueno et al., 2015). Due to the ore-hardness variability and the operation of the mill, the power demand profile in inherently variable.

Jan 1, 2019

By G. P. Contractor

Many factors affect the forge ability of steels. One of the major factors is chemical composition.' This article discusses the individual effects of alloying elements and the effect of the resultant modification of microstructure onforgeability. INTRODUCTION T HE use of alloy steels is expanding considerably and the fabrication procedures for such alloys are becoming more complex. An attempt is made in this article to describe the effect of alloying elements on the hot-workability of steels. Most of the data reported here are taken from the studies of Ihrig, Clark and others (Refs. 1-4). Chemical composition is not the only controlling factor. Grain size and surface condition of the material, forging temperature, and speed of deformation are also important. Certain conclusions can be drawn regarding the effect of various alloying elements on the hot-work-ability of forging stock. The results of hot-twist tests are considered useful in this connection as the number of twists to failure has been taken as the level of forgeability at a particular temperature. The peak in the "Number of Twists -Tem--

Jan 1, 1962

By J. Stiksma, J. Dennett, R. Kalanchey, J. Ji, M. Collins, T. Chan, R. Berezowsky

A pilot plant campaign has been conducted by Sherritt Technologies in support of Eldorado Gold Corporation’s evaluation of pressure oxidation technology for the treatment of refractory gold concentrates from the Certej deposit in Romania. Four separate concentrates, containing 3.5 to 5.4 g/t Au, 13.0 to 14.5% S2- and 12.0 to 32.5 g/t Ag, were tested in the eight-day campaign. The major gold-bearing mineral was pyrite. Preliminary batch tests indicated that gold extraction from the oxidized concentrates in subsequent cyanide leaching was adversely affected by the presence of organic carbon in the pressure oxidation feed when chloride in solution was at an elevated level. As such, the process conditions that were tested during the pilot plant operation were selected to either counteract the negative impact of the organic carbon, or to deactivate it during pressure oxidation. Both process routes proved feasible, yielding gold extraction of 95 to 98% in cyanide leaching of the oxidized concentrates. Silver extraction was typically in the range of 80 to 90%, provided that the oxidized concentrates were also processed in a lime boil step prior to cyanide leaching.

Jan 1, 2014

By J. Stachulak

In recent years more emphasis has been placed on the control of nitrogen dioxide (NO2) emissions from mining diesel equipment. Worldwide, diesel engine regulations to control emission and protect the environment are also driving the development of the diesel engine technology to reduce oxides of nitrogen NOx (Nitric oxide, NO + NO2). NOx are toxic gases produced in mines during the operation of diesel equipment. Most of the diesel equipment used in underground operations are equipped with Diesel Oxidization Catalysts (DOCs) designed to reduce carbon monoxide (CO) and hydrocarbons (HC). The effects of DOCs on NO2 production from diesel powered equipment is not well understood. DOCs do not alter NOx concentration, but may promote the oxidization of engine exhaust NO to the more toxic NO2, thus increasing the undesirable NO2 exposure of workers in the mine environment. In 2012, the ACGIH reduced the NO2 TLV concentration value from 3 ppm to 0.2 ppm. Vale and CanmetMINING have been involved in several research projects to reduce diesel emissions exposure to workers. One aspect of the current program is to determine the effects of in-use DOCs on NO2 production. Several in-use DOCs taken from mining equipment were selected for testing in the laboratory using ISO 8178-C1 and mine LHD transient test cycles. The paper presents the laboratory test results and effects of DOCs on NO2 production. The results indicate significant reductions in CO concentration, by over 77%, while increases in NO2 varied from 46% to 315% based on the ISO 8178-C1 8-mode steady state test cycle. The mine LHD transient test cycle showed the same pattern, although the magnitude of CO reduction was less. Consequently, it is recommended the use of only those DOCs that have been properly evaluated and shown not to significantly increase NO2 emission in the environment be used on mine equipment.

Aug 1, 2013

By N. E. Nelson

"The Hidden Creek mine is about l~ miles north of the north end of Granby bay; a nearly landlocked body of water on the west side of Observatory inlet; 90 miles north of Prince Rupert; British Columbia.The main haulage way of the mine at 385 feet above sea-level has been driven north into the somewhat precipitous end of a north-south ridge that rises from the tide flats between the east and west forks of Hidden creek. The outcrops of the principal orebodies, two prominent bluffs of stained rocks and sulphides, were higher on the face of the ridge and extended from about 530 to 850 feet elevation. North from the bluff tops, the ridge comb rose gradually to about 1,200 feet elevation. The name of the discoverer and the date of discovery of the Hidden Creek orebodies are probably unknown, but the discoverer is believed to have been an Indian from one of the reservations along Observatory inlet. The deposit was brought to the attention of John Flewin, Government Agent at Post Simpson, near the beginning of the present century. Mr. M. K. Rodgers, developer of the Nickel Plate mine at Hedley, did the first organized work on the deposits. Next the Hidden Creek Copper Company prospected the property. Rodgers acquired the prospect a second time, did more work, and finally in 1910 optioned the property to the Granby Consolidated Mining, Smelting and Power Company, Limited, at that time operating at Phoenix and Grand Forks in the Boundary district of British Columbia. The optionees stepped up the development work and brought the property to production in 1914. The ores were direct smelted until 1924. In that year a mill was built. From 1930 until the end of the productive life of the properties in 1935, all of the ore was milled and the concentrate smelted. From March 17, 1914, until July 31, 1935, the production from the Hidden Creek mine was, in round numbers, 18,000,000 tons of 1.70 per cent copper ore and 6,000,000 tons of low grade dilution rock. The Hidden Creek mine ""died with its boots on"". During 1934 the average monthly production was 146,377 tons of 1.06 per cent copper ore. For 7 months of 1935 the average was 161,750 tons of 1.03 per cent ore, and for the final month, July 1935, the production was 156,950 tons."

Jan 1, 1954

By Juergen Antrekowitsch, Stefan Steinlechner

"Within the last decades, mainly the base metals, like zinc, copper and lead were recycled from different industrial residues without taking into account that accompanied minor side-elements are often also present. A high supply risk for critical raw materials derives mainly due to the high share of the worldwide production in a limited number of countries. Examples include indium and germanium in China, PGM in South Africa and Russia or cobalt and tungsten in the Democratic Republic of Congo. By taking the market of critical metals into account, the recycling of potential residues does not only contribute to an economic treatment but also to the European strategy to decrease the supply risk of certain metals. Depending on the metal discussed, political unrest, decreasing primary resources leading to supply risks in different countries or also simply economic interests moved these mentioned side elements and with this the residues where they are present in, into the focus of the recycling industry.Because of this, the typical routes of lead, zinc and copper production are evaluated concerning generated residues and their typical contents of contained minor elements. Finally, the paper tries to answer the questions how a possible treatment of these wastes could contribute to the overall supply of for example silver but also other minor elements."

Jan 1, 2016