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By L. Sun

In this work, strontium doped lanthanum ferrite (LSF) and their composite cathodes were fabricated by screen printing on yttria-stabilized zirconia (YSZ) electrolytes. Their electrochemical properties were evaluated by using electrochemical impedance spectroscopy and steady-state polarization methods. All the cathodes were screened by comparing their total polarization resistances before and after activation processes at different temperatures. The improved LSF composite cathodes were also screen-printed on YSZ/NiO half cells to fabricate solid oxide fuel cells (SOFCs), which have reached the output power densities of 170 mW/cm2 at 650 °C, 230 mW/cm2 at 700 °C, 304 mW/cm2 at 750 °C and 388 mW/cm2 at 800 °C.

Jan 1, 2005

By A. M. Reyes

Flow field hydrodynamics of serpentine flow channels was investigated numerically using computational fluid dynamics (CFD). The velocity profile simulated by the CFD model was evaluated with respect to experimental results from the literature. Rectangular and tapered flow channels were compared with respect to mixing and water management capabilities, and pressure drop. The CFD model was further developed to account for electrochemical reaction on the cathode side to determine which channel configuration was most effective in reactant conversion. The velocity profile differences between the channels were found to impact reactant conversion, as the rectangular channel had the highest conversion. With respect to water management, although the tapered channel was found to have a higher overall pressure drop, the rectangular channel was found to have higher shear and pressure forces acting on simulated liquid water droplets in the channel.

Jan 1, 2005

By Douglas Lay

Attention has been drawn in the publications of the Department of Mines to the view that veins of two different ages occur in the Cariboo district, namely, those of Jura-Cretaceous age and those of pre" Mississippian age. It has been further pointed out that while there is doubtless a wide distribution of veins of pre-Mississippian age in and about the Barkerville and Stanley areas, and in the vicinity of Round Top mountain and Yank's peak, there is no such wide distribution of veins carrying gold values of commercial significance. Veins of the latter type discovered to date occur almost exclusively within one or other of two comparatively narrow zones, both trending northwest and southeast, the one extending from Island mountain co Round Top mountain, and the other from a point somewhat north of Stanley co Yank's peak. In addition, there is some evidence of a third zone trending northwest from Spanish mountain, at or near the contact of the pre-Cambrian and Mesozoic rocks. In short, all the evidence from prospecting and lode-mining operations to date indicates that values are mainly restricted co zones having marked directional distribution. Moreover, it can be demonstrated that the placer deposits resulting from the erosion of the pre-Mississippian veins have a similar directional distribution, allowance being made for modifications due to glaciation. The observations offered in this paper are of the nature of a generalization which seeks to explain certain anomalies both in the vein-mineralization and in the -important auriferous-pyrite replacement deposits in limestone which have recently been discovered. For the sake of brevity, the Island Mountain-Round Top Mountain zone will be referred to as Zone No. 1, and the Stanley-Yank's Peak zone as Zone No. 2.

Jan 1, 1936

By G. Gauvin

Life span of aluminum smelting electrolysis cells can reach up to 3000 days. During this period, cathode blocks go under various physical and chemical changes that could result in an increase of electrical resistivity. The increase may be due to carbon migration from the cast iron to the steel bars, gap evolution between the cathode block and the cast iron, cathode cracking, etc. This paper focuses however only on the collector steel bar electrical resistivity evolution. To reveal the main phenomena responsible for the electrical resistivity increase, chemical analysis, metallographic and electrical resistivity tests were conducted on two steels bars picked from two Hall-Héroult cells after autopsies. Cathode voltage drop and temperature were measured using electrically insulated internal probes and thermocouples on 16 samples from each steel bar. Electrical resistivity can reach up to 1.21µO-m for a steel bar aged 2505 days compare to 0.142µO-m for steel AISI 1008 at room temperature.

Jan 1, 2011

By P. Homola, M. Karlík, M. Slámová

"Aluminum sheets (AA1199, AA8006, and AA5754) were processed by accumulative roll-bonding (ARB) in the temperature range from 20 to 350°C. The microstructure of the sheets was characterized by means of scanning and transmission electron microscopy and electron backscattered diffraction. Mechanical properties were monitored by hardness measurements and tensile tests. Increasing strain (number of ARB cycles) led to incremental development of lamellar microstructure with a decrease of the spacing between high-angle grain boundaries in the normal direction of sheets. ARB process produced an important increase of strength while maintaining thickness and relatively high ductility, without accenting of the anisotropy of mechanical properties of sheets. The level of hardening decreased with the processing temperature and at 300 and 350°C ARB caused even the softening of the material due to the recovery of the deformed microstructure or partial recrystallization during heating to ARB processing temperature.INTRODUCTION Accumulative Roll Bonding (ARB) is a technique of grain refinement by severe plastic deformation (SPD) proposed by Saito et al. (1999). One ARB cycle consists in sheet cutting, surface treatment, stacking of two pieces, heating (optional), and rolling with 50% reduction in thickness. Since the sheet thickness remains unchanged by this cycle, ARB processing can be repeated as many times as desired. The goal of ARB is to impose an extremely high plastic strain on the material, resulting in structural refinement and strength increase without changing specimen dimensions. After several cycles, ultra-fine grained (UFG) materials with high strength and relatively high ductility are produced. An advantage of this method is that it does not require any special equipment as other SPD methods such as equal channel angular pressing (ECAP) (Valiev & Langdon, 2006), high pressure torsion (HPT) (Valiev et al., 2000), or cyclic extrusion and compression (CEC) (Richert et al., 1999), but only a conventional rolling mill and so it is seen as an economically viable and industrially scalable processing route. ARB processing has been successfully applied to various kinds of metallic materials at room or elevated temperatures (Tsuji, 2005). Besides processing single metals and alloys, ARB has also been used for creating ultra-fine grained and nanograined metallic composites (Wu et al., 2010; Qu et al., 2014)."

Jan 1, 2018

By W. A. MacDonald, C. M. McGibbon, J. H. Reynolds

This paper traces the development of the Seaboard Power Plant, which plays such an important role in the industrial life of Nova Scotia. It also shows the involvement of the plant in the siting of a heavy water production facility in Cape Breton. The paper concludes with an outline of the new installations which the Nova Scotia Power Commission has undertaken as an extension to the Seaboard Plant.

Jan 1, 1966

By J. F. Henderson

THE National Advisory Committee on Research in the Geological Sciences was established seven years ago - in 1949. In 1952, shortly after the Committee had really begun to function and had issued its first report, a paper ( l) was presented describing the objectives and organization of the Committee and the progress to that time. Another four years have gone by and the Committee feels a further progress report may be of interest. HISTORY Ten years ago, in 1946, the Geology Division of the Institute set up a Committee on Geological Research. This Committee, under the Chairmanship of Dr. J. E. Hawley, recommended that "a National Advisory Committ.ee on Research in the Geological Sciences be formed" (2). With the backing of the President and Council of the C.I.M. this recommendation went forward to the then Minister .of Mines and Resources and, with his approval, to the Committee on Scientific and Industrial Research of the Privy ?Council. As a result, the National Advisory Committee was set up in 1949.

Jan 1, 1956

By A. Vasenev

The quality and durability of asphalted roads strongly depends on the final step in the road construction process; the profiling and compaction of the fresh spread asphalt. During compaction machine operators continuously make decisions on how to proceed with the compaction accounting for project specific aspects as: ambient conditions, road geometry, roller type, asphalt mixture characteristics and behavior of other machines. In discussions over quality improvement in road construction it is often suggested to robotize rollers. To operate such robots would of course require operational strategies and routines. The reality of this moment is that these operational strategies and routines are not documented. To identify the existing best working practices and, ultimately, to proceed with developing automated robotized compactors, the knowledge of machine operators should at first be explored and described in a formalized way. Unfortunately operators have difficulty verbalizing their expertise. Observation of behavior, as machine movement patterns, could be helpful to extract the operational strategies, but such observations are time and labor consuming. To overcome this burden we developed a Virtual Reality (VR) environment. In this VR environment operators perform compaction virtually, and their operational choices are traced and analysed. This paper describes this VR development and explains how it helps in following machine operators and extracting their (tacit) professional knowledge. The road geometry and the working conditions are visually represented; the operators show - rather than explain - how they would proceed with the compaction process in the given conditions. Movements of virtual machines are documented, analysed, visualised and discussed. This VR approach is expected to contribute to learning, to more formal description of operational strategies; stepping stones towards compaction algorithms for roller robotisation.

Aug 1, 2013

By Martin Encinas, Jesús L. Valenzuela, Jose R. Parga, Salvador Aguayo, Roy G. Lewis

Continuous laboratory solvent extraction of gold from cyanide solutions using LIX?79 guanidine based extractant has been investigated. Different variables that affected the selectivity and extraction include aqueous pH, extractant concentration, and modifier concentration. The extraction isotherms of the aurocyanide complex with respect to the other cyano anions were compared, and the following order of selectivity Au > Ag > Zn > Cu > Fe was observed. According to the pH isotherms, aurocyanide can be extracted in an alkaline media, and a better separation with respect to the other cyanoanions was obtained in the pH range 10.5-11.2. From the McCabe Thiele diagrams, better recovery was predicted when using LIX?79 extractant and tridecanol modifier at 10 vol.%. Stripping of the gold from the loaded organic was carried out at pH > 12 using NaOH and NaCN solution. The continuous tests indicate that a two-stage extraction followed by a single stage strip is adequate to obtain an overall process efficiency of >90%. Better results were obtained using a copper wash stage before gold stripping.

Jan 1, 2014

By M Reza Afshar

In this work a mathematical model was developed to study the effect of electromagnetic force on the magnesium melt containing nonmetallic inclusion in an electrical isolated channel. The electromagnetic force exerted on the inclusion induced by DC current field was calculated. A three dimensional turbulent flow equations were solved numerically to compute the velocity field within the channel. On the basis of computed velocity and magnetic fields, the trajectories of inclusions were calculated using the equations of motion for inclusions. Parametric studies were carried out to evaluate the effect of various parameters such as current density, channel diameter and particle density on the removal efficiency of inclusions from magnesium melts.

Jan 1, 2004

By E. S. Moore

In the townships of Genoa and Marion, Subdury Mining Division, Ontario, there is a group of twenty-three mining claims known as the Jefferson claims. They are controlled by the Jefferson Mining Corporation and they were staked in 1908 by W. E. Smith, formerly of Sudbury, Ontario, and now of Smith & Reitz, a law firm of Minneapolis, Minnesota. These claims were staked for iron ore and in 1910 about 4000 feet of diamond-drilling was done on them. During the drilling operations galena and sphalerite ~were found in the iron formation in cores from holes, Nos. 2 and 3, claim W. D. 717, Genoa township. This discovery lead to a search for galena and sphalerite in the vicinity and a streak of rock containing these minerals was found in the iron formation a short distance to the east of. the drill holes. A shaft was sunk on this outcrop in 1912 to a depth of 8 feet and bottomed in an attractive lens of galena. Stripping revealed other small exposures of galena and sphalerite in the iron formation.

Jan 1, 1926

By N. Bahrani

Knowledge of the state of stress in the Earth?s crust is very important to the safe and efficient development of underground excavations in mining and civil engineering projects. A number of methods have been developed over the past 40 years to assess the stress field in the rock mass. These range from local estimates derived from compilation of regional stress databases to back-analysis of field observations to dedicated in situ measurements. The Geomechanics Research Centre (GRC) at MIRARCO has a long history of undertaking in situ stress characterization and measurement. In this paper, the stress measurement techniques used by the GRC, including overcoring and undercoring in addition to borehole breakout back-analysis, are briefly reviewed. The limitations and application of each technique for different ground conditions and the challenges involved during the field work and in interpretation of the results are discussed. A successful stress measurement campaign is not limited to acquiring valid local measurement, but must include a careful interpretation and integration of the measurement with other geological and geotechnical context information. Based on our experience, it is suggested that all available stress indicators and data are combined and integrated with the local geological and geomechanical conditions to derive a consistent stress characterization for a given site.

Aug 1, 2013

By J. R. Smith

"The Lake Dufault orebodies were discovered by deep surface diamond drilling. When a reasonable amount of outline drilling had been completed, the decision to go into production was made. The fact that shaft sinking, lateral development, the detailing of the orebodies and stope preparation were to be carried out as rapidly as possible necessitated very close scheduling.After a study of varions possible mining methods, an open-stoping system using long-hole blasting was chosen. Diesel-powered Transloaders were selected for the mucking and transportation of ore from the drawpoints to the orepass.At the time of writing, the choice of mining method appears to have been fully justified, although more time will be required to arrive at true operating costs and efficiencies."

Jan 1, 1966

By E. O. Chisholm

Synopsis The colour changes effected in a solution of dithizone by trace amounts of copper, lead, and zinc mineralization provide a sensitive field test for these metals. The method has been used with success by the United States Geological Survey to trace zinc orebodies under residual soils. The dithizone test is used here on samples of non-residual soil overlying a gold-bearing zone in which the gold is associated with disseminated sphalerite, galena, and chalco-pyrite. A gold-bearing zone was successfully traced under overburden ranging from a few inches to five feet in depth by means of this method. The method may prove useful in guiding preliminary trenching through light overburden, by outlining the extent of copper, lead, and zinc mineralization. Introduction The dithizone test affords a rapid, simple, and delicate test for the presence of zinc in soil and water and is suitable for use under field conditions. It has recently been used with success by the United States Geological Survey to outline a zinc-rich area in the residual soil over a primary zinc deposit in Tennessee. The purpose of the present study was to ascertain whether the method could be used to trace a gold-bearing zone, containing associated zinc mineralization, under shallow, non-residual, glacial overburden. The results obtained indicate that the method can be used to guide preliminary trenching in overburden up to six feet in depth. Tests made of the water near lake-shore outcrops also indicate that favourable prospecting zones may be located from the water, within five feet of the shore. It is felt that this simple field test should find a wider use in prospecting, because, under certain conditions, it can outline favourable zones and thereby reduce the amount of blind trenching necessary. The following pages describe the type of deposit tested, the method used, the .results obtained, and the difficulties encountered by a novice in the use of this chemical procedure. The author is indebted to the officials of Nor-Penn Mines, Limited, for their co-operation while the tests were being made; to the late Richard Bouska, Kenora prospector, for helpful suggestions; and to F. W. McCamus, University of Toronto undergraduate student, who ably assisted with the work.

Jan 1, 1950

By P. R. G. Brandão, E. E. Ferreira

The presence of metallic cations in solution will affect the aggregation or dispersion of the fine hematite particles, depending on the type of cation adsorption: either specific or non specific adsorption. In this work, the zeta potential measurements were carried out on a sample of pure hematite as a function of pH and metallic cations concentration (Ca2, Mg2+, Mn2+, K+, Na+ and Al3+). The objective of these studies was to clarify the effect of these metallic cations on the surface chemical properties of pure hematite. The cations K+ and Na+ adsorbed as non-specific species and caused only the reduction on the values of zeta potential (in terms of absolute value) over the entire range of pH values tested. For the Al3+ cation, in the acidic pH range it adsorbed as a specific species and increased the zeta potential values. The cations Ca2+, Mg2+ and Mn2+, adsorbed as a non specific species at pH levels less than 6.0 and caused the reduction of zeta potential due to the compression of the electrical double layer. However, for pH values greater than 6.0, these cations adsorbed as a specific species causing the zeta potential to increase and became more positive as the pH value increased (alkaline). This effect could be due to the adsorption of some hidroxy complex species of these cations, which contributed to the positive charge. The effect of metallic cations (Ca2+, Mg2+ and Al3+ concentration, at pH 4.0, 7.0 and 10, showed the following results: a) at pH 4.0, increasing the concentrations of Ca2+ and Mg2+ resulted in on a small reduction in the value of the zeta potential. At this pH, increasing the concentration of A131 cations caused the zeta potential to increase due to specific adsorption of a negatively charged Al3+ hydroxy complex b) at pH 7 and 10, increasing the concentrations of Ca2+ and Mg2+ caused the zeta potential to change its charge from negative to positive.

Jan 1, 2004

By C. Larsen, R. A. Walker, A. Voth, C. Daoust

"The 3000 t/d mill at Hernia Gold Mines Inc. was commissioned in March, 1985. By Canadian standards the concentrator is highly automated, however, unlike the retrofit systems in many other plants, the Hernia process control system was installed during plant construction. This paper describes the Hernia control system beginning with system development (justification, architecture, start up, etc.), proceeding to current applications (crushing, grinding, leaching, etc.) and finally discusses some of the short term objectives for system improvement.INTRODUCTIONThe Hernia Gold Mines Inc. operation is located in the Marathon area of Northwestern Ontario. Controlled by Noranda Minerals Inc. (50.1 %), the cost of bringing the mine into production was nearly $300 million. A unique feature of the mine development was the extraordinarily short elapsed time of three years from Noranda's initial involvement to the start of milling operations. Additional background information on this project can be found in the trade literature (e.g. Tinter (1986). Scales (1987).)The Hernia concentrator is designed to process 3000 tpd of ore and commenced operation in March, 1985. Figure 1 provides a general plant flowsheet indicating the major circuits. Typical annual production statistics are included on the figure and these have been extrapolated from the available 1987 year-to-date data. Larsen and Tessier (1986) have previously described the operational aspects of the mill.In a metaphorical sense, the Hernia concentrator is like the traditional bride, ""wearing something old (e.g. the cyanide leach process), something new (e.g. a plant wide digital control system installed during construction), something borrowed (e.g. crushers from Gaspe) and something blue (e.g. the cladding on the surface buildings). While the prospect of fully undressing this bride is of considerable interest, here we choose to focus on something new. In particular, we choose to examine the process control system in some detail since Hernia is one of Canada's more highly autcmated gold mills. The control system is of interest because it has received suostantial credit for maximizing metal production and minimizing operating costs. With reference to the latter, it is worthy of note that Hem lo reports recent operating costs of less than $100 U.S./oz."

Jan 1, 1988

By Ian S. Leslie

Seismic monitoring systems for mining operations are being utilized more than ever before in the characterization of rock mass response to underground and open pit mining. This paper provides a review of the use of microseismic monitoring for rock mechanics applications at mines throughout the world. Some practical considerations for the installation of these systems are presented along with techniques for optimizing seismic array coverage. Case studies and installation examples are also provided. Recent applications of advanced seismic analysis techniques are discussed including the determination of event mechanisms, mapping of maximum peak particle velocity (PPV) and seismic hazard fields, and the use of source parameter data for large event re-entry protocol.

Jun 1, 2012

By Megan Becker, Aubrey Mainza, Indigo Research Laboratories, Jenny Wiese, Gaynor Yorath, Lucy Little

Particle shape characterisation has an important role to play in mineral processing, to clarify effects of shape on rheology, equipment wear rates, comminution, classification, sizing and flotation. However in industry, shape characterisation is not routine, and the most commonly used shape descriptor in the field (circularity/ angularity/ sphericity) is not invariant. This study aims to investigate shape measurements for a fine particulate ore sample measured with different analytical devices. Two Automated Scanning Electron Microscopy devices with Energy Dispersive X-ray Spectrometry (FEI QEMSCAN® and Zeiss Mineralogic®), and a camera based image-sizer using dynamic image analysis (Retsch CAMSIZER® XT) were compared. Each device was used to analyse the shape characteristics of specific particles in both a coarse sample (–212/+150 µm) and a fine sample (-53 µm) of UG2 platinum ore. Circularity and Roundness frequency distributions obtained from the three devices were then compared. For selected individual particles, circularity showed higher variability than roundness, and the sample circularity distributions obtained by the three devices were completely different. It is clear that circularity data from different studies relying on different devices should not be compared on an absolute scale. The shape parameter roundness was found to be a more robust descriptor than circularity, and it can give a stronger indication of a particulate sample’s shape characteristics on an absolute scale. However, there were still significant differences in the roundness measurements obtained by the CAMSIZER XT and the two Auto-SEM devices, which was attributed to the dissimilar mechanisms of image capture.

Jan 1, 2016

By A. E. Wraith, J. Protheroe Jones, P. J. Mackey

INTRODUCTION When Victoria became queen in 1837, that technical wonder of the 19th century—electricity— had progressed from being an exciting physical curiosity and was now a field of intense scientific investigation, invention and application. Its role in electrochemistry had been brilliantly quantified by Faraday in 1833–1834, and his earlier discoveries in electro-magnetism were to lay the foundations of electricity generation and the electric motor. In this age of electrical experiment, silver electro-plating emerged as a popular decorative art, at first using batteries to provide the deposition current, superseded by dynamos in the early 1840s. The decorative chemical and electroplating of precious metals was largely pioneered in England by the firm of G.R. Elkington and Co., founded in Birmingham by George Richards Elkington (1801–1865) in 1832, and protected by a series of patents which helped the company establish a leading position in the new field of ‘electrometallurgy’. In the same decade, the technique of electrotyping emerged, the first application of electro- forming by electrolytic deposition. Simultaneously invented by Spenser in England and Jakobi in Russia, but generally claimed for Jakobi, electrotyping involved plating a thick copper layer on to an electrically conducting mould wall embossed or incised with a pattern or profile which would consequently be replicated on the copper deposit—essentially a method of casting by electro-deposition with the mould wall as cathode. Woolrich’s invention of the low voltage magneto-dynamo in 1842 eliminated the need for batteries as a continuous source of deposition power, opening up the possibility of making more massive electroplated deposits, and by the mid-point of Victoria’s reign in 1869, the work of Wilde, Wheatstone and Siemens had produced the self-excited electro-dynamo, capable of higher voltages and yet greater deposition power. In this early Victorian period copper was extracted and refined by methods which had developed step-by-step over many decades. Only relatively rich copper ores containing more than, say, 6% Cu were economically useful, and the final copper product was far from pure. Copper production in Britain was located principally in the Swansea area of South Wales, based upon the ‘Welsh process’ of reverberatory batch smelting and refining, using locally mined coal and ore imported from Cornwall and elsewhere. Silver was an important by-product. Much of the output was exported and South Wales remained a principal supplier to the world copper market until the 1890s. It was here at Pembrey, a few miles west of Llanelli, that a new primary copper smelter was stablished in 1849 under the name Mason and Elkington, arguably to supply the Elkington company’s market for electrotype products.

Jan 1, 2019

By Nathalie Gauthier

Bien que le système de ventilation du Puits Penna soit de taille imposante et que plus de $30M y seront engloutis pour son développement, aucun budget spécifique n?avait été préalablement consenti pour refroidir l?air acheminé aux places de travail dans la partie profonde de la mine. Le système de ventilation a été conçu en deux étapes distinctes : le réseau du haut de la mine lequel dessert jusqu?à 1550 m de profondeur et le réseau du bas de la mine (de 1550 m à 2200m) qui a été créé ultérieurement. Le réseau inférieur a été imaginé de façon à acheminer l?air frais directement au gisement et de permettre l?évacuation aux extrémités afin de rejeter l?air chaud immédiatement après l?avoir utilisé. Au total, lorsque le réseau de ventilation sera complété, plus de 670 m3/s d?air sera véhiculé dont jusqu?à 495 m3/s pour la partie inférieure de la mine considérant une capacité totale maximum de 710 m3/s en utilisant la mine adjacente.

May 1, 2003