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By P. Latostenmaa, T. Veneranta, J. Järvi, E. J. Peuraniemi

Boliden Harjavalta has operated a copper flash smelter since 1949 thus the smelter celebrates 70th anniversary of flash smelting in 2019. This paper shortly describes the historical perspective of the smelter and gives an update of the current operational issues and process modifications made during the recent years. The plant has carried out several major investments lately providing a firm view on the future. A new landfill area for the final slag was commissioned in 2018. A modernization of the concentrate storage area, a new acid plant and a debottlenecking project of the smelting line have been recently commissioned. At the same time, the tankhouse capacity will be expanded. This paper focuses on smelter modernizations. INTRODUCTION Boliden is a metal company operating mainly in northern Europe with core competencies in the fields of exploration, mining, smelting and metal recycling. Boliden Harjavalta, located in Finland, is part of the Smelters Business area of the Boliden Group and operates a copper and nickel smelter with related sulphuric acid plant in Harjavalta, and a copper refinery in Pori. As a short historical review, Harjavalta’s history may be dated back to the year 1910 when the Outokumpu ore body in eastern Finland was discovered. By the end of 1913, a copper mine was in operation and a copper plant based on Hybinette process was ready for commissioning. Due to difficulties in metal recoveries and throughput the Hybinette process was permanently shut down in 1929, and 100% of the mining production was sold as concentrate abroad. As the mine production increased steadily, a decision of a new smelter was made in early 30’s. In 1936 Outokumpu’s copper smelter based on electric smelting was commissioned in Imatra. The smelter was dismantled and transferred to Harjavalta during the final stages of the Second World War. The copper refinery started in Pori already in 1941 and the first copper anodes were cast in Harjavalta in 1945. First sulphuric acid plant started operation in 1947. Due to the post-war shortage of electrical energy, the plant metallurgists initiated a major development work to start exploiting the latent heat of concentrates. Thus, the flash smelting method was developed in Harjavalta and commissioned in 1949. Ten years later, flash smelting was also applied for nickel concentrates. Table 1 summarizes major historical and technical milestones of Harjavalta. The history of flash smelting is described in details in another paper of this conference (Jåfs et al., 2019).

Jan 1, 2019

By R. W. Allgood

"THE world-wide shortage of elemental sulphur, which became sharply apparent in 1950, has focused attention on the commercial exploitation of sulphur-bearing materials such as pyritic ores, sour natural gas, and smelter gases. Although there •are no known commercial deposits of elemental sulphur in Canada, there are vast quantities of these sulphur-bearing materials. The International Nickel Company of Canada and Canadian Industries Limited have for many years collaborated in an effort to develop economic processes for the recovery of sulphur from the smelter gas arising from Inco's metallurgical operation at Copper Cliff, Ontario. While sulphuric acid has been •produced at Copper Cliff for over twenty years, recent developments will result in a 60 per cent increase in acid production early in 1952 and, later in the year, in commencement of the operation of the largest single unit ever erected for the manufacture of liquid sulphur dioxide.The purpose of this paper is to discuss •briefly the general factors associated with the recovery of sulphur from the Copper Cliff smelter gases and to describe the sulphuric acid operations and the liquid sulphur dioxide development.Processes for the manufacture of elemental sulphur, liquid sulphur dioxide, and sulphuric acid from sulphur-dioxide-bearing smelter gases are well known and in some cases •highly developed."

Jan 1, 1952

By Henry Hengeveld

Are the IPCC results credible? The most recent IPCC assessment is??an admirable summary of research activities in climate science? US National Academy of Science 2001 report to President Bush Joint statement by Academies of Science from 17 other countries ? May 2001 ?The work of the?IPCC represents the consensus of the international science community on climate change science. We recognize IPCC as the world?s most reliable source of information?and endorse its method of achieving this consensus.?

Nov 1, 2002

By Laura Kelsey

Contaminant Robust In Situ Water Extractor CRIWE Nafion-based water clean-up Extract purified water from natural extraterrestrial sources In situ water processing for downstream electrolysis Chemically resistant to process contaminants such as acid

May 1, 2013

By R. Burnette

Gold has been mined from a variety of deposit types that range in age from Archaean to Recent. The large variability in the geological settings of the gold deposits implies transport and concentration of gold by magnetic, hydrothermal and sedimentary processes. The factors that control the concentration of gold at certain sites and the grade estimation thereof remain major topics of debate. Due to the complex nature of the Witwatersrand Basin a mineralogical study, including mineralogical, petrographic and geochemical investigation was launched on TauTona Mine in order to characterize the various reef facies. The aim of the investigation was to determine if a correlation could be found between macroscopic characteristics of the reef, hanging wall and footwall, and the microscopic nature of the ore (especially gold grade). Petrograpgic and mineralogical results indicate that a correlation exist between gold, detrital and hydrothermal sulphides, uraninite, carbon, detrital heavyminerals and phyllosilicates. No correlation exist between gold and Mg, Fe or S. It appears that clast supported reef is of higher wade than matrix supported, but more work is suggested. No correlation exists between reef thickness and grade. The reef samples had the lowest phyllosilicate content compared to the hanging wall and footwall samples with pyrophyllite the most dominant. All of the correlations diagrams showed significant scatter and suggests a multi- factorial mineralization model. Gold distribution is also controlled by sedimentary features and thus it is not possible to select a single model for the formation and distribution of gold. It is evident that both sedimentary and hydrothermal factors influenced the mineralization and gold distribution on TauTona mine. It is thus essential that all related theories be incorporated in the development of a grade prediction model.

Jan 1, 2011

By W. Fergusson

This paper takes a look at the use of rubber to provide corrosion resistance and wear resistance in the mining industry. The longer life and reduced down time involved with the use of rubber are stressed, and examples are given of applications in grinding mills, skips, discharge chutes and screens.

Jan 1, 1979

By Yin Wang, Lin Li, Zhongwei Bi, Like Wei, Wen Li, Shaogang Li, Bin Zhang, Hongjie Li

Presently,Many long-wall fully-mechanized faces in shallow depth coal seams are below room and pillar goaf in Shendong mining area. When the working face is advanced out of concentrated coal pillar in upper room and pillar goaf, strong strata behaviors often cause support crushing accident. Aiming at a support crushing accident which happened in Shigetai coal mine of Shenhua group in Shendong mining area, this paper analyses the stress transfer process while mining out of concentrated coal pillar by numerical simulation software FLAC3D. According to the feature, simplifying the roof of upper room and pillar goaf as supporting-beam structure explains mechanism of large area collapse in room and pillar goaf roof. Based on the feature of supporting-beam structure, deep-hole blasting concentrated coal pillar technology is proposed to control the strong strata behaviors in Shigetai coal mine. The blasting control effect is confirmed through characteristics of strata behaviors, growth circumstance of ground crack and multi-point extensometer monitoring results. By using control technology, Shigetai coal mine has been successfully avoided support crushing accident.

Jan 1, 2015

By W. T. Irvine

"The Britannia ore deposits are approximately 20 miles north of Vancouver; and occur in a prominent ridge facing Howe sound. A large ironstained bluff first attracted the serious attention of early prospectors. This; upon investigation; proved to be the outcrop of a large copper orebody. The highest outcrops were 4; 300 feet above sea-level.The original discovery was made in 1888, but no real development took place until 1902. The first mining was done in what came to be known as the Jane orebody, and some production was obtained from this in 1905. Underground exploration led to the discovery of several other orebodies. The first main adit, the 1,050-foot level, was driven to tap the ore at an elevation of 3,300 feet above sea-level. During succeeding years, however, long adits were driven from points lower down on the mountain side. These, with connecting shafts, followed the ore to horizons well below sea-level. The lowest working has now reached to 880 feet below sea-level. The property has been in almost continuous operation since its original exploitation in 1905. Until the end of 1944, 732,414,420 pounds of copper and 261,125 ounces of gold had been produced from the mine."

Jan 1, 1954

By H. Tan

The effect of carbonaceous matter on gold extraction was investigated in cyanide systems with pure gold as well as pre-robbing sulfide gold ores. Auger studies demonstrated that the carbonaceous matter preferentially smeared on iron sulfide rather than aluminosilicate surfaces during wet or dry grinding. During mechanically mixed leaching, coating of sulfides and silicates and stripping of carbonaceous matter occurred simultaneously. TEM and XPS studies indicated preferential coating in the form of elemental (graphitic) carbon at the edges and the defect sites of particles. Interestingly, carbonaceous matter extracted from the gold ore was predominantly graphite and not preg-robbing in a solution with a high KCN concentration. However, the carbonaceous coating had a significantly detrimental effect on gold dissolution when gold was pre-ground with the gold ore. Artificial coating on gold surfaces with the natural carbonaceous matter from the ore was also found to substantially retard gold dissolution. With the addition of the natural carbonaceous matter from the gold ore, gold extraction from two non preg-robbing sulfide gold ores was inhibited owing to carbonaceous coating. The presence of carbonaceous matter significantly reduced the current density for gold oxidation and increased the current density for pyrite oxidation. This could explain the fact that carbonaceous coating hindered gold dissolution while enhanced sulfide preg-robbing.

Jan 1, 2005

By J. Clark

Erosion control during the mining cycle can be more effectively planned using Erosion and Sedimentation Control Plans (ESCPs). This raises the issue of who should develop an Erosion and Sedimentation Control Plan Guidance document (ESCPG) to standardize the content of ESCPs. A search for ESCPG documents in Canada revealed no examples for mine sites. In the U.S. there are a number of regulatory authorities who developed such documents for mine sites, including EPA. An ESCPG is expected to result in: (a) plans will be more standardized (b) more clarity and efficiency for those generating ESCPs; (c) assisting regulators tasked with reviewing/approving ESCPs; (d) providing guidance for the mine effluent permitting process relative to sediment control; (e) providing a basis for developing and including ESCPs in the Environmental Assessment (EA) phase and the mine economic assessment; (f) applying and optimizing ESCPs above the ?watersheds? of sediment ponds; (g) utilizing the ESCPG document for ?exploration? sites; (h) lowering the risk of adversely impacting water quality downstream of mining activities; (i) providing a methodology for determining the need for sedimentation pond(s) during the construction and production phases; and (j) providing a clear environmental sustainability message relative to sediment control if the mining industry takes the lead in developing an ESCPG. ESCPs will proactively create increased administrative (regulatory) efficiency in the EA and sub-EA reviews relative to erosion control and sediment release from mine sites. This also assists the new initiative in BC, One Project, One Process (OPOP) and synchronous permitting (a variation of concurrent permitting): as an example, enhanced erosion control planning at the EA phase then allows the synchronous permitting initiative to proceed efficiently, particularly for the mine permit (Ministry of Energy, Mines and Natural Gas) and effluent permit (Ministry of Environment). Approximately twenty more management plans (e.g. ARD/ML, explosive management, emergency response, hazardous waste, sediment pond operation, environmental effects, environmental sampling, etc.) may also be entered into the EA process to create increased efficiency, and then feed into the synchronous permitting effort. The BC OPOP initiative also adds support to the Canadian Federal ?One Project, One Review Process? approach. The ESCP and a sediment pond management plan will also address the Canadian Metal Mining Effluent Regulations requirement for all discharges from mine sites to meet a grab sample of 30 mg/L Total Suspended Solids.

Aug 1, 2013

By A. B. Irwin

Abstract The techniques used in recognizing, recording, and interpreting structures in the Slocan sedimentary ceries in the West Kootenay district of B.C. are presented here in the hope that they will be of use to others working in complexly folded areas. The general pattern of folding in the Central Slocan area is obscured by lack of outcrop over a large part of the country, lack of marker horizons, local complexities of folding, and several systems of faulting. 1t was found necessary to observe and record in great detail all primary and secondary structural features and to analyse those observations on a statistical basis. The determination of bedding tops as well as bedding attitudes proved to be of fundamental importance in determining the pattern of folding. The interpretation of secondary linear and planar structures confirm:; this pattern. Accordingly, the thickness of the Slocan sedimentary series is computed to be several times that formerly postulated. Introduction The data upon which this paper is based were collected largely during the field seasons of 1947 and 1948 when the writer was employed by the British Columbia Department of Mines on detailed mapping in the Slocan mining camp. Additional observations were made by the writer during 1950 when engaged in property examinations for the Geological Survey of Canada. This presentation is largely a condensation of part of a more comprehensive thesis (5) and is restricted to observations and conclusions pertaining to the mapping of complex folds, stripped of any hypothetical discussion. Except for some unique occurrences of primary structures, there are no features or techniques described here which are not presented in standard textbooks on structural geology. It is felt that the major contribution of this paper is the method used in applying these standard techniques to a specific field problem and in interpreting the results.

Jan 1, 1951

By Abhilash

Uranium is conventionally extracted using a process that employs strong acid (H2SO4) and an oxidant (MnO2) as leaching agents. This method often creates environmental problems, requires large amounts of energy, and involves a complex operational plant. It is not, however, economically attractive to extract uranium from low-grade ores by chemical leaching. Because the content of U3O8 in the Indian ore is usually below 0.1% by weight, it is necessary to develop an alternative process to enable the efficient and economic recovery of uranium. Uranium ore from the Narwapahar mines, UCIL is a type of vein deposit found in India, which accounts for ~54% in India. The ore (0.047% U3O8), though of Singhbhum area, possess exceptionally different mineralogy due to presence of some refractory minerals and richness of apatite (5%) resulting in a maximum 78% recovery through conventional processing at UCIL, with a very high consumption of sulfuric acid and pyrolusite, besides possible loss of uranium as uranium phosphate. To avoid usage of environmentally non-benign oxidants, remediation of influence of phosphates, and improve the overall process output of uranium; an alternate extraction technology using microbial isolate(s) is worthwhile exploring and the same is presented in the paper. The microbial isolate enriched with Acidithiobacillus ferrooxidans grown from source mine water was employed for bio-leaching of uranium while varying pH, pulp density (PD), particle size, etc. On varying pH at 35oC using 20%(w/v) PD and <75µm particle size, 83.5% and 78% uranium bio-recovery were observed at 1.7 and 2.0 pH in 40 days against maximum recovery of 46% and 41% metal in control experiments respectively. Whereas, it was observed that grinding of ore to finer size actually helped dissolution of uranium. Finer size particles (<45µm) gave a maximum biorecovery of 93% in 40days at 10%(w/v) PD, 1.7 pH and 35oC. The bio-recovery of uranium fell down from 93% to 82.73% and 60% on increasing the pulp density from 10% to 20% and 30% respectively for particles of <45µm size. The higher uranium dissolution during bioleaching at 1.7pH can be correlated with increase in redox potential from 433 mV to 664mV in 40 days.

Aug 1, 2010

By T. H. Etsell, P. C. Holloway

Vanadium is concentrated in the fly ash which is produced as a solid waste from oil sands operations in northern Alberta. Although a process flowsheet using sodium chloride as a roasting reagent has been developed at the University of Alberta, recent studies examine the p otential o f p otassium o r c alcium s alts a s alternative reagents for roasting Suncor fly ash to recover vanadium. Suncor fly ash was roasted with CaO, Ca(OH)2, CaCO3, CaSO4.2H2O and KC1 at 750, 850 and 950°C. Water leach extractions for the calcium compounds were low (<45%); leaching with 100 g/L Na2CO3 gave maximum extractions of 56 to 69% at 950°C. Ash roasted with KCI behaved similarly to ash roasted with NaCl. These tests indicate that similar roasting conditions (25 to 30% KCI, 850°C, and 2 to 4h) could be used to achieve similar water leach extractions (75 to 85%). However, the lower solubility of KVO3 in solution, compared to NaVO3, would make the use of KCI instead of NaCl less attractive from a process and economic standpoint. Mineralogically, leucite (KAlSi3O8) was the predominant phase in ash roasted with KCl while, in crystalline samples of ash roasted with calcium compounds, anorthite (CaAl2Si2O8) and pseudobrookite (Fe2TiO5) were identified. Ash roasted below 950°C with the calcium compounds remained poorly crystalline.

Jan 1, 2004

By T. A. Chepushtanova, I. U. Motovilov, V. A. Luganov, G. D. Guseynova

"Kazakhstan has significant reserves of oxidized nickel ore with low nickel content. Processing of such ores is effective via pyrometallurgical technologies such as smelting to ferronickel or matte with consecutive extraction of metals from melting products. There are also many options for direct hydrometallurgical processing. However, they do not provide high nickel recovery.We studied extraction of nickel and cobalt by using combined technology of low-grade ore processing from the Shevchenko Kazakhstan deposit, which includes smelting to poor matte followed by hydrometallurgical processing of the matte. The nickel content in the initial ore was 0.75–0.9%. Pyrite concentrate of Sokolov-Sarybai Kazakhstan deposit containing 0.17% cobalt and 0.06% nickel had been used as a sulphidizer at smelting.As a result of the study, we were able to extract up to 98% of the nickel and up to 80% of the available cobalt. Obtained matte contained 3.1% nickel, 0.29% cobalt, 71.6% iron and 24.3% sulfur. Matte leaching was carried out by hydrochloric acid. The iron content in the pregnant solution was 170–185 g/dm3. Nickel and cobalt precipitation from the pregnant solution was carried out by hydrogen sulfide. Initial matte or cast iron was used as neutralizers during the process. Practically complete precipitation of nickel was achieved at 3–5% excess of neutralizer at 333–343°K in 4 hours; up to 95% of cobalt precipitation was achieved in 50% excess of neutralizer at 363°K in 8 hours. The purified solution contained 200–600 mg/dm3 of nickel, 80-100 mg/dm3of cobalt and 175–185 g/dm3 of iron. The purified solution allows to obtain iron oxides by high-temperature hydrolysis, and to regenerate hydrochloric acid.As a result of non-ferrous metals precipitation we obtained sulfide concentrate with concentration of Ni up to 25% and concentration of Co up to 5.5%. The technology is recommended for semi-industrial testing."

Jan 1, 2016

By J. Petit, P. Girard, A-M. Gilbert, D. Faucher

L&apos;annee 2000 a été une année stratégique et significative pour l&apos; Aluminerie de Bécancour dans la réduction des gaz a effets de serre. L&apos; équipe s&apos; etait donne comme defi un jour d&apos;arriver a l&apos;objectif de zero effet d&apos;anode dans les sa11es de cuve (720 cuves au total). Le cha11enge s&apos;averait tres ambitieux car la fa<;on d&apos;alimenter une cuve d&apos;electrolyse pour obtenir son maximum de rendement faraday est de travailler le plus pres possible de l&apos;effet d&apos;anode pour eviter l&apos;embourbement de ce11es-ci. Ceci signifie que techniquement nous a11ons en moyenne, quotidiennement, 12500 fois pres de l&apos;effet d&apos;anode sur !&apos;ensemble de nos 720 cuves qui produisent aujourd&apos;hui environ 405 000 tonnes d&apos;aluminium liquide annuellement. Des 695 kg equivalent en C02 par tonne d&apos;aluminium produite en moyenne annue11ement, de 1990 a 2000, nous en sommes rendus ace jour a environ 35 kg equivalent en C02 par tonne produite. Nous sommes pres d&apos; atteindre notre objectif mais les demiers gains sont plus difficiles a atteindre. Les strategies d&apos;automatisme et d&apos;informatique, incluant l&apos;aspect de !&apos;implication humaine sur les bonnes pratiques de travail sur les cuves d&apos;electrolyse, sont les cles de ces resultats.

Jan 1, 2006

By Collin Bartlett, H. Storch

"Modern metallurgical processes operating with oxygen enriched air, such as the Outotec Flash Smelter and Flash Converter, generate very concentrated SO2 off-gas, which in combination with Outotec sulphuric acid plant technology allows the production of high pressure steam to be used for power generation. Outotec combines well proven technology of sulphur burning plants for this purpose with metallurgical plants.The application of Outotec’s proven LURECTM process enables processing of SO2 gas of up to 25 vol.-%. This process maximizes the energy recovery from the SO2 oxidation at a suitable high temperature level which can be turned into high pressure steam. The application of the Outotec HEROSTM heat recovery system enables the generation of low pressure steam from the absorption energy released at the intermediate absorption step. Additionally, energy is also recovered in the acid coolers for boiler feedwater pre-heating.The concept of integration of high and low pressure steam in combination with the pressurized operation of the boiler feedwater deaerator, thus heating up the boiler feed water to temperatures around 160…170°C, enables indirect transfer of low pressure steam (for deaerator operation) into more valuable high pressure steam, which improves the degree of heat recovery. This is the characteristic of Outotec’s HEROS+TM process.The increased generation of high pressure steam will in turn enable the generation of more electricity when compared to a standard traditional sulphuric acid process."

Jan 1, 2014

By Katsutoshi Saibara

Network communication note is a cloud system for an earthwork project. It enables backhoe operators and dump truck drivers to monitor their own works in progress currently and performed up to the present, and to have opportunity to reflect on their own bearings in the earthwork operations, and then could increase their situational awareness to the actual work conditions. First, this paper presents problems and purpose. Secondly, the configuration of the network communication note is reported. Thirdly, examples of communications enhanced by the network communication note are shown. Finally, remarks are described.

Aug 1, 2013

By Seungyeol Lee

Currently, a new construction method using a robotic system is widely spreading in construction sites. This study is related to the design of glazing robot?s teach pendant which can improve convenience of handling and hence improve the productivity through the efficient interaction between an operator and a robot while doing glazing works, e.g., curtain wall installing. The suitability of selection and arrangement of control switches was assessed according to mechanical motions of a glazing robot, and design guidelines for improving convenience and productivity were drawn up through questionnaires carried out by site operators. To verify the proposed design guidelines, working time comparison of the proposed teach pendant and the existing teach pendant was executed.

Aug 1, 2013

Pillars are used in various forms in underground mining. For several decades pillar design has been an issue in both soft and hard rock underground mining. The major use of pillars is in room-and-pillar type mining. Pillars are critical structures in the production levels of block cave mines. With most mines leaning towards the use of block caving for ore extraction today, pillar design has become even more important. Empirical pillar design is popular. The use of numerical modeling is becoming more common in the design of underground mine pillars. A critical review of both the empirical and numerical modeling approaches to the design of underground mine pillars reveal some fundamental flaws. In general, pillar design approaches often assume the pillars are vertical, and are subjected to pure compression. Pillar failure criteria are then based on this assumption. Most papers on numerical modeling for pillar stability assessment use vertical pillars. This paper shows that where pillars are not subjected to pure compression the empirical pillar design approaches are inadequate, and that when using numerical models for the assessment of pillar performance, more care is needed in the determination of the average pillar stresses. The practice of relating field scale pillar strength to laboratory scale intact rock strength determined from conventional laboratory compression tests in empirical design equations is misleading when pillars are inclined or subjected to compressive and shear stresses. New data is added to the hard rock empirical pillar stability chart, and it is shown that it is misleading to conclude that failure of pillars with width to height ratios greater than 2.3 should not be anticipated. New empirical pillar design charts are presented for pillars at various degrees of inclination for different ko-ratios.

Aug 1, 2013

By A. Mellek, M. Pischtschan, M. Perrucci

ABB has received an order for one of the most challenging mill drive projects in its history. With one SAG mill and one ball mill to be added at an iron ore mine in Sweden, the customer’s plant managers wanted to have the most efficient solution for driving their mills but had the budget limitations typically faced by the majority of mining companies during periods of market downturn. To find the best balance between cost of acquisition and highest performance throughout the lifetime of the plant, ABB was selected to deploy a synchronized bypass solution, in which only one drive system is used for two different mills in series. However, being one of the first grinding mills in the world with such a solution was not the only challenge the ABB team faced: The inclusion of some mill application functions - e.g., frozen charge protection, automatic positioning and creeping mode - brought the demands on the engineers to another level. With only one frequency converter and one mill application controller available, the configuration logic and interlocks had to be meticulously designed and thoroughly tested to ensure a smooth and safe startup. The solution offers a footprint reduction and more operator flexibility at a reduced investment as each mill can be run in both directions, and wear on the mechanical components can be greatly reduced due to ABB’s premium ring-geared mill drive (RMD). This paper will describe the details of the project, the configuration developed and the tests performed to guarantee correct software functionality. Mill startup is scheduled for January 2016.

Jan 1, 2016