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By Richard Morland

The Ekati Safety Guarantee is a conversation that has been taking place at Ekati for the last two years. It is a challenging, confronting, inspiring conversation which encourages people to see and pursue the possibility of guaranteeing that nobody who works at Ekati will be seriously injured or killed at work. The conversation takes us out of the normal, incremental approach to safety improvement; it takes us out of the world of striving, of seeking, of trying, and allows us to stand in, and be a stand for the future possibility of Zero Harm. It requires an unreasonable stand for, and commitment to, our own safety and the safety of our colleagues. A Powerful Conversation The safety guarantee began with conversations between executive team members and has been propagated regularly through the line through management meetings, pre-shift meetings, during workplace inspections, job safety observations, job and project planning, orientation and induction sessions, and when opportunities present themselves. This is a conversation that continues outside of Ekati with family, with government, with community members. It is a stand for safety as a value. The conversation about the safety guarantee is now pervasive at Ekati and forms part of a framework of initiatives that have led to sustained improvement in safety performance. During the last two years, the recordable injury frequency at Ekati has dropped to its lowest level in Ekati?s history. At the same time, job safety observations have increased from 500 per month to 4000 per month, whilst the overall number of people at Ekati has reduced by 30%. It has led to new ways of thinking about the conduct of operations. It influenced the 2008 upgrade of the Ekati process plant, resulting in the development and implementation of a crane lift protocol that eliminated injuries during over 100 lifts in two weeks, in an area of difficult geometry and with multiple entrances. It created space to successfully conduct a challenging commissioning period for the process plant crusher, during which time the machine was disassembled and reassembled several times, without incident or injury. No production pressure was permitted to interfere with this work, in line with our stated aim that we wanted everyone involved to guarantee that they would not be seriously injured or killed?our people had the space to do the work at a pace, and in a way, that guaranteed this outcome.

May 1, 2010

By Pierre Gaucher

It is possible to selectively mine an orebody by combining the use of the SSW probe with any bulk mining methods as well as narrow vein exploitations. In other words, thanks to the use of the SSW probe, mining operators will be able to reduce and control dilution that is generally associated to every mining operation. Already, quick and substantial savings have been obtained. Falconbridge mines have demonstrated in Sudbury and Raglan operations, that the SSW probe can log nickel, copper and iron sulphides in blast holes. They have raised the grade and reduced dilution by outlining the limits of the ore zones before selectively loading explosives in the blast holes. By lowering the probe in a blast hole, a profile of the ore content is instantly measured and recorded. Logging cored diamond drill holes at the mine have demonstrated that the ore content (nickel, copper, cobalt, PGM) as assayed is proportional to the intensity of the probe?s electromagnetic response (EM), probably because the nickel / pyrrhotite ratio is uniform within a given orebody. The probe also measures the intrinsic conductivity of the sulphides and the percentage of magnetite. All probe readings are displayed and automatically stored at a 10-cm interval within the same reading unit. A 30-meter blast hole takes less than 2 minutes to survey. The whole instrument is light (12 kg) and very simple to use. One operator can carry the SSW system and survey either down or up-holes. The probe works from ?40°C to +50°C. Plotting the measurements of the SSW probe in blast holes (2-3-4-6-10 inches in diameter) before blasting allows to determine the exact shape of the orebody within the waste rock and uneconomic low-grade ore. Thus, only the portion of the holes that contains ore is blasted. The dilution is then much reduced and, by leaving the waste and low-grade ore in place, the mine saves on transportation, blasting, crushing, backfilling, milling, etc. Thousands of dollars are thus saved. Some savings may also be achieved during the development of stopes by guiding development drifts and by replacing diamond drilling by percussion drilling. In some circumstances, when the probe shows that some of the rich ore was not drilled-off, additional blast holes will allow to recover pockets of rich ore that otherwise would have been abandoned in the walls of a stope.

May 1, 2001

By A. V. Corlett

MR. C. S. Gibson: Mr. Chairman, I listened with much interest to Mr. Corlett's paper. Those of us who are directly engaged in mine ventilation and dust control are impressed by the improved atmospheric conditions to be derived from the use of methods of mining such as those in operation at Aldermac, which Mr. Corlett has just described, and those employed at Noranda. It is a well known fact that drilling-dust is one of the most potent factors in the production of silicosis in mines handling ores containing quartz, so that from that angle the use of diamond drills, instead of percussion drills, to drill ore for blasts in stopes is an important development. A second point which I think merits mention is blasting. Blasting, we all know, creates the most dust in a mine and the fact that you can drill ore for a large blast with diamond drills and fire it, say, on Saturday night, and then have all the next day to ventilate the workings, is a great advance in dust control. 1 have wondered if Mr. Corlett, or possibly those at Noranda, can en-vision the use of the diamond drill as a means of advancing cross-cuts and drifts, preparing stopes, etc. I believe it is a matter which is receiving considerable attention at the moment in some parts of the world and J thought it would be interesting to have Mr. Corlett's reaction on that point. MR. A. V. CORLETT: I am not quite so hopeful of using diamond drills as a means of drilling holes in the ordinary drift. Maybe some of the diamond drill men can give us some further information on that point. MR. R. D. LoNGYEAR: The diamond drill manufacturers are working on that problem, but until further work is done we have nothing definite to offer. Drilling holes with a diamond drill to compete with rock drills for advancing drifts and cross-cuts is a desirable objective, because of the elimination of drilling dust and the ability to cut a smooth bore of uniform diameter. To reach this objective, higher rates of penetration are required, which can only be achieved by discovering the optimum bit rotating speed, by reducing vibration, and by further improving the bits and machines. We are optimistic, but the problem is still largely in the research stage.

Jan 1, 1940

By G. N. Nnadi, R. J. Mitchell

"The response of cemented backfills subjected to simulated blast loadings is studied using centrifugal modelling techniques. Scaling requirements for centrifugal modelling are developed and the results of the similitude analysis show that an acceleration field is required to capture the true dynamic response of backfill models. Experiments have been conducted at various centrifugal accelerations. The effects of ring blasting were simulated by an impact loading on the exposed fill face. The behaviour of the cemented backfill was monitored with accelerometers as well as dynamic stress gauges.Cemented backfill response to impact loadings was found to depend strongly on simulated gravitational stress level. Results also show that the characteristics of the response changes with distance from the impact. Finally, the results of the models were used to predict prototype peak accelerations, velocities and displacements. The results reported in this study indicate that centrifuge modelling may be a useful tool for dynamic studies of blast damage to backfills. Centrifuge modelling can be carried out at low costs and can be used to design prototype instrumentation systems. IntroductionThe response of cemented mine backfills to blast loadings is of concern to the mining industry because these backfills provide local and regional support during ore pillar extraction. Considerable research has been reported on the static stability (Smith et al., 1983) and on effects of reinforcements on cemented backfills (Mitchell, 1989). However, information regarding dynamic aspects of cemented backfill is limited. O'Hearn and Swan (1989) reported on the response of cemented backfill to blast loading, but these blasts were not very dose to the backfill . A schematic representation of a rock-backfill system is shown in Figure I.The mechanics of transfer of explosive energy to rock and subsequently to the backfill, and the resulting responses, are complex. Achison (1968) listed more than twenty factor s affecting the blast fragmentation of rock and grouped these into the categories of explosive parameters, charge parameters and rock parameters. Although significant advances have been made, during the past two decades, in understanding the mechanics of blasting, the degree of uncertainty associated with predicting the behaviour of backfills subjected to dynamic loadings makes the application of simple design safety factors insufficient. Comprehensive testing programs or prototype instrumentation is required to evaluate the risks associated with blast or earthquake loadings on backfill."

Jan 1, 1991

By Mario Giavani

"IntroductionBy the 1980s, the continuous casting process had almost replaced the ingot casting of steel in Japan, Europe and North America. While economic benefits were probably initially the prime motivator, the transition rapidly proved that continuous casting in conjunction with ladle metallurgy offered a much greater degree of process control and made possible routine steel specifications not previously available.This new technology demanded improved procedures for the quantitative addition of the required metallurgical reagents, especially as regards the more volatile or toxic elements such as calcium , boron, carbon, sulphur, lead and tellurium. The injection of a thin steel tube containing the additive into the metal bath of a ladle refining station offers the best procedure for this. In the industry this has been referred to as ""Cored Wire "".Operators using this technology find that they are faced with balancing the injection speed against the small cross section of the tube to feed the required amount of reagent within the short time span available to the operation. Large-ladle shops requiring major quantities usually resort to multiple machines and high speeds. Many machines approach a maximum feed rate of 400 m/min. Higher speeds exceed the melting rate of the system, and the ferro static buoyancy of the tube will cause it to coil up the ladle wall and possibly resurface into the slag layer, and even eject itself above the surface. Under these conditions, exact control of element recovery becomes difficult, especially with the commonest addition, calcium silicon alloy.Many experts are persuaded that the final melting position of the carrier tube has major importance in establishing consistent element yield to the bath.For instance, the vapour pressure of calcium at l500 °C is close to I bar. Reaching a melting depth sufficient to accommodate this value is considered to be critical to achieving an acceptable and reproducible yield.Many studies have elaborated semi-empirical formulae to establish the melt zone depth, connecting this value essentially to the diameter of the tube , the injection rate and the superheat of the steel. The author's experience in steelmaking could not confirm such formulae in many cases, and he set about to develop a mathematical model which would be useful in addressing this problem, taking into account the several parameters which will regulate the behaviour of a filled tube immersed in molten steel."

Jan 1, 1991

By M. J. Brodie

"The decision to proceed with mine decommissioning, generally involves a number of complex and independent factors. These factors, including potential for re-opening, legal requirements, contingent liability, asset depreciation, due diligence, and public relations are discussed in the context of the financial implications on a net-present- value basis. It is concluded that the decision to delay mine decommissioning is commonly not in the best financial interests of the mine operator. Some measures to reduce decommissioning costs and expedite the process are presented.IntroductionThe primary audience for this paper is mining executives, although it should be of interest to all professionals involved in the planning and carrying out of mine decommissioning. Historically, mines were abandoned, not decommissioned. Then, as decommissioning became required, it was assumed that salvage revenue would pay for decommissioning. During the I980s, it became apparent that mine decommissioning costs would exceed salvage revenue for nearly all sites, and that a substantial net cost for decommissioning would be realized for some sites. Throughout this period, the approach to decommissioning has evolved through the sequential addition of measures to meet the increasing regulatory burden. This has resulted in a process in which the elements of decommissioning may not be optimized with respect to each other for the most favourable net present value to the corporation. Additional considerations which are not specific to mine decommissioning, such as environmental policy, due diligence and public relations, may now come to bear on the decision-making process.This paper addresses the issue of mine decommissioning as a three-step process. The first step involves identification and evaluation of all of the issues that relate to mine closure, the most importantof which is the potential for re-opening of a mine. Assuming that it is decided that a mine is unlikely to re-open, the second step is to determine when to carry out the decommissioning work. This aspect is examined through a net present value (NPV) approach. Finally, details regarding who does the work and how the various tasks are divided up must be resolved.Every mine is a unique concentration of minerals at some specific location, hence the development, operation and closure of a given mine must be regarded as a special case. Superimposed on the site-specific considerations are the size, history and financial status of the associated corporation."

Jan 1, 1995

By Mary Kama, Kaul Gena

"Magnetic skarn ore (MSO) is one of the major copper bearing ore extracted by the Ok Tedi Copper Mine in Papua New Guinea. Copper minerals are recovered by flotation while the iron not associated with copper are discarded as tailings. The objective of this investigation was to determine the iron ore reduction kinetics for the Ok Tedi MSO and ascertain if it can be processed to produce sponge iron for a mini steel plant in Papua New Guinea.SEM-EDAX analyses of the Ok Tedi MSO indicated 10.1% C, 30% O, 0.6% Mg, 1.1% Si, 21.1% S, 0.8% Ca and 36.2% Fe. Most of the iron is in sulfide form. Both naturally occurring and roasted sinters of Ok Tedi MSO samples of different particle sizes were reduced by charcoal carbon at three different temperatures and seven different reduction times. Analyses of the reduced products indicated a metallic iron content of more than 65 wt.% on average.Results showed that there was no significant difference in reduction between fluxed and control materials. Only a slight increase in kinetics with reduced particle size, hence the reaction rate constant (K) did not vary much within the temperatures investigated. Reaction kinetics increases with increasing reduction time at 900°C. Therefore, more iron reduction is observed with particles of 106 µm size. In addition, the results also confirmed that the reduction energy used was higher at 800°C and lower at 1,000°C. In summary, iron reduction can be improved but close monitoring of temperature and reduction times are essential to determine the reaction kinetics of the Ok Tedi MSO. INTRODUCTIONMost mines in Papua New Guinea mine large quantities of iron in the form of sulfides, carbonates, oxides and sulfates that are eventually disposed off as tailings. The Ok Tedi magnetic skarn ore (MSO) contains a significant amount of hematite, magnetite, siderite, ilmenite and pyrite that can be a source of iron. The mineralogical compositions of Ok Tedi MSO reveals more iron minerals than copper, yet all iron containing minerals are collected in the tails from the main copper production stream. Therefore, this study is conducted to investigate the possibility of producing direct reduced iron (DRI), or sponge iron, from the MSO. Such sponge iron may serve as the feedstock for electric arc/induction furnace based mini steel plants in Papua New Guinea."

Jan 1, 2016

By E. Hinton, L. Bloomquist

"This paper describes a guidance system for autonomous underground mining vehicles, which does not require any infrastructure or inertial positioning systems to aid the guidance process.BackgroundINCO Limited mines approximately ten million tons per annum through 12 operating mines in the Sudbury, Ontario, area (Fig. 1). With challenges from operating in a cyclical marketplace as well as new technologies making alternative nickel ores more competitive to refine, the Mines Research department embarked on a strategy that pointed toward automation as a tool to help the company become even more economical in mining.The mining industry has been looking for ways and means to mine orebodies more and more inexpensively. Automation and the lessons learned from manufacturing had a great influence in the direction of research at INCO Limited over the past ten years. Guidance systems have evolved over the years but the majority of commercially available systems rely on some form of infrastructure. This, in part, has caused some resistance from operators to install and maintain automated or semi-automated systems for guidance of underground machinery.Internal industrial studies cited travel time to and from the workplace as one of the major time sinks in the shift of underground miners. Depending on the mine, it may be as much as two hours moving in and out of an area. Some work areas have accommodated this by having “hot changes” at the work place. However, at some point in time, there are two people tasked with the same job and on site at the same time to make this overlap occur.Tele-operation of underground hard rock equipment eliminated this overlap and also provided a comfortable environment in which to work. By taking advantage of the communications network installed, the miners proved that they could operate three machines with relative ease. This was accomplished by a vision-based, “painted line,” autonomous guidance system termed the light rope system.With a few years’ experience with the system, some issues have arisen, including the cost of the rope itself (Fig. 2).The vehicle’s route is limited to the paths defined by the light rope, and a system of switching power to the light rope to select different routes is required. The rope itself is subject to damage from nearby blasts. Also, the system offers no obstacle detection; the vehicle may be switched off as a means of shutting the machine down thus protecting personnel in the area."

Jan 1, 2001

By P. M. Huck, R. John

"The National Uranium Tailings Program was established in 1982 to develop, in part, a mathematical predictive model which would allow the assessment of the impact of uranium mill tailings on the environment and particularly on humans. . To achieve this , various studies were undertaken to establish the role played by key constituents of the tailings. This paper summarizes the findings of a study carried out under that program, to examine the leachability of barium-radium sulphate sludges produced in the treatment of uranium mill tailings decants. The investigators performed detailed chemical an alysis of the sludge, applied geochemical computer models to investigate sludge leaching behaviour, and conducted experiments to assess the impact of bacteria on leaching. The modelling showed that the redox state o f the sludge-leachant system was the most important factor. Substantial bacterially-mediated dissolutio n of the sludge and release of radium was demonstrated experimentally under suitable reducing conditions . INTRODUCTIONIn September 1981, Phillip A. Lapp presented the final report of the National Technical Planning Group on uranium tailings research to the federal government (Lapp, 1981). Lapp' s group had performed an in-depth survey of the status of uranium tailings research in Canada and, as a result, recommended that a national program be funded in the amount of $18 .6 million. Half of this fund ing was to come from the federal government, with the two producing provinces , Ontario and Saskatchewan, providing the balance. However , the provinces declined to support the program and the federal government decided to inaugurate a reduced program with $8.5 million o f funds .In late 1982, the formation of the National Uranium Tailings Program (NUTP) was announced by the minister of state for mines. A primary objective of this program was to develop a mathematical predictive model that would permit the assessment of the impact of uranium mill tailings on the environment, a nd particularly on humans. The program was to use existing information to the greatest possible extent, and then fund research to fill in gaps or substantiate data where necessary .The NUTP was established to administer this program of contract research over a five-year sunset life. By the end of the 1986-87 fiscal year the NUTP had completed about 100 contracts. One of those projects was to study the effect of placing barium-radium sludge ba ck within the tailings matrix. Th is paper gives the results of that study."

Jan 1, 1989

By Michel Aubertin

Les rejets miniers sont communément utilisés, depuis plus de 60 ans, comme matériau de remblayage des chantiers souterrains. Les roches stériles et les rejets de concentrateur sont employés comme remblais car ils sont disponibles sur les sites miniers à un coût réduit pour aider au support de terrain. Le remblayage des ouvertures est également avantageux car il permet de réduire la quantité de rejets entreposée en surface. Dans les mines souterraines, le remblai des chantiers doit aider à maintenir un espace de travail sécuritaire, tout en favorisant la récupération du minerai et le contrôle de la dilution. Il est alors essentiel d'évaluer précisément les pressions exercées par le remblai sur les murs et sur les barricades installées près de la base des chantiers. Dans cette présentation, des solutions existantes pour évaluer les pressions dans les chantiers sont brièvement revues. Les auteurs présentent ensuite des solutions analytiques récemment développées à cette fin, qui permettent de tenir compte du transfert des contraintes du remblai aux parois des chantiers et des galeries. Les solutions proposées, qui sont basées sur la théorie de l?effet d?arche, prennent en compte l'influence de la géométrie des ouvertures et de la position des barricades. La méthode de calcul permet aussi de calculer l?effet des pressions d?eau pour un remblai partiellement ou totalement submergé. Les solutions s'appliquent au cas d?un remblai récemment mis en place, alors que l?effet de la pression interstitielle ne peut pas être négligé, et aussi à plus long terme sous une condition drainée. Des résultats expérimentaux et des simulations numériques sont utilisés pour valider les équations proposées. Les résultats analytiques et numériques montrent notamment que la pression totale sur une barricade peut être grandement augmentée par la pression d?eau, tandis que la contrainte effective peut être réduite par les pressions interstielles (par rapport à la condition drainée ou sèche). On discutera aussi des implications pratiques de ces résultats pour l?application des remblais souterrains.

Nov 1, 2008

By L. Beiza, L. Velásquez-Yévenes

Chalcopyrite is by far the most abundant copper sulphide on Earth, but it has proved to be problematic in its processing by leaching, mainly related to its refractory nature, slow kinetic rates of dissolution and the formation of an inhibiting product layer on its surface during leaching. This study is focussed on the electrochemistry of chalcopyrite dissolution in acidic chloride system, which has recently gained attention as a feasible alternative to conventional sulphate media for chalcopyrite leaching. It is well understood that chalcopyrite dissolution from mineral grains depends strongly on the solution redox potential at the mineral surface as well as the composition of the product layer that may form on its surface. The chloride ions in solution support the Cu(II)/Cu(I) couple as the primary oxidant, as they can form complexes with the cuprous ions formed, increasing the dissolution rate. Additionally, these ions increase the potential range where chalcopyrite can be oxidized. The chemical reaction that occurs on the surface of chalcopyrite in chloride solutions in the presence of cupric ions will be characterized and the coulometry of the reaction will be reported to understand what is happening on the surface of chalcopyrite. Electrochemical experiments have been carried out to investigate the behaviour of mixed potential by open circuit potential (OCP) measurement for 30 minutes using sulphuric acid at pH 1 under nitrogen at 25⁰ C. The effect of chloride was analysed at 0, 20, 50 and 100 g/L and cupric ions from 0 to 50 g/L. The potentials obtained were then used to carry out chronoamperometry tests for a period of 30 minutes in absence of cupric ions. The mixed potential did not show a significant difference with an increase in cupric concentrations in the absence of chloride. Increased mixed potentials and current densities were observed at higher chloride and cupric concentrations. Chronoamperometry tests at those potentials were used to construct a voltammogram trace which has the same trend as a normal cyclic voltammogram but with much lower current densities. INTRODUCTION As a result of the depletion of copper oxides, the leaching of copper sulphide minerals has become the focus of many studies. Chalcopyrite, (CuFeS2) which is the most abundant of copper minerals, has proved to be challenging to process via hydrometallurgy, mainly related to its refractory nature, slow kinetic rates of dissolution and the formation of an inhibiting product layer on its surface, during leaching.

Jan 1, 2019

"The Society for Mining, Metallurgy, and Exploration (SME) Inc. developed a guide of minimum standards for reporting exploration results, mineral resources, and mineral reserves for the purpose of informing the general public. The SME Guide has been adopted by the Society.History1. In 1988, at the request of members of the Society for Mining, Metallurgy, and Exploration (SME), Inc., the President of SME formed Working Party #79, Ore Reserve Definition, with the mission to develop guidelines for the public reporting of exploration results, resources, and reserves. A Subcommittee was appointed by the Working Party to draft these guidelines and submit recommendations to SME. The Subcommittee's recommendations were published by SME in the April 1991 issue of ""Mining Engineering"", and as a document entitled ""A Guide for Reporting Exploration Information, Resources, and Reserves"" (the SME Guide) in January 1992. Work continued on an ad-hoc basis until 1996, when Working Party #79 was renamed the SME Resources and Reserves Committee and became a standing committee.In 1994, the Council of Mining and Metallurgical Institutions (CMMI) started a concerted international effort to create a set of international definitions for reporting mineral resources and mineral reserves. An ad-hoc International Definitions Group was formed, with representatives from mining and metallurgical institutions from the United States (SME), Australia (AusIMM), Canada (CIM), the United Kingdom (IMM) and South Africa (SAIMM). A major breakthrough came on October 18, 1997 when the CMMI International Definitions Group met in Denver, Colorado and reached a provisional agreement (the Denver Accord) on definitions of mineral resources and mineral reserves. Concurrently, and since 1992, the United Nations Economic Commission for Europe (UN-ECE) was developing an international framework classification for mineral resources and mineral reserves. Starting in October 1998, joint meetings were held in Geneva between the CMMI International Definitions Group and the UN-ECE Task Force, resulting in agreement to incorporate the CMMI definitions into the UN framework classification."

Jan 1, 2003

By B. N. Church, A. R. Pettipas

"The second vertical derivative method of processing aeromagnetic data from low level helicopter surveys yields results correiatable with the known geology and may be utilized to indicate possible targets for future exploration in the Silver Queen and Equity Silver mines areas, near Houston in central British Columbia . The principal zones of alteration associated with mineralization, known from detailed mapping, are further delineated and extended in a way not possible by a cursory examination of the original magnetic data.IntroductionThe second derivative method of processing aeromagnetic data is a long established procedure used to enhance the short wavelength content of the magnetic fields. Some recent exam pies of the use of the second derivative technique have been published by Chandler (p. 385), Sun Yunsheng et al. (p. 424) and Yarger (p. 223) in Hinze, 1985. According to theory, the ""second vertical derivative"" is closely related to the rate of curvature of magnetic (or gravity) fields and is particularly useful in resolving and sharpening local anomalies. The contours on second derivative maps may coincide with important features such as lithological boundaries, faults and mineralized zones.In the Houston area, central British Columbia, aeromagnetic data supplied by local mining companies provide a ready base for analyses. Examples are data sets for the Silver Queen and Equity Silver mines centred 35 km and 34 km south and southeast, respectively, from Houston (Fig. 1), (Cochrane, 1970 and Church, 1985)."

Jan 1, 1990

By Z. Zhao, B. Li

"Fractures are the key channels for fluid flow and mass transport in fractured rocks of low/negligible matrix permeability. In single rock fractures, surface roughness causes fluid flow in tortuous paths, and reduces the overall fracture conductance. A number of empirical models have been proposed to relate the reduced hydraulic aperture to the mechanical aperture due to surface roughness, which were revisited and compared. Using two of those relationships between hydraulic apertures and mechanical apertures, we studied the influences of local surface roughness of fractures on fluid flow and solute transport processes at the macroscopic scales of fracture networks. The results show that fracture roughness can affect the flow rates and residence time to varying extent, mainly depending on the empirical models between hydraulic apertures and mechanical apertures. However, fracture roughness has negligible influences on the general patterns of fluid flow (channeling) and solute migration (e.g., travel paths and shape of breakthrough curves). This is because the connectivity of a fracture network is mainly determined by other geometrical parameters (fracture positions, orientations, and lengths), rather than roughness or apertures. INTRODUCTIONIn fractured crystalline rocks of low or negligible matrix permeability, fluid flow and contaminant migration mainly occur within the connected fractures. An understanding of fluid flow and contaminant migration in fractured rocks is a crucial issue in many deep underground projects, e.g. underground repositories for radioactive waste, CO2 sequestration, enhanced geothermal systems, oil and gas production, etc. Rock fractures are typically rough-walled, and surface roughness appears to have first order control on the mechanical and hydraulic behavior of single rock fractures (Boutt et al., 2006).It is well known that the mechanical aperture of a rock fracture is usually larger than its hydraulic aperture, due to fracture surface roughness (Tsang and Witherspoon, 1983). However, for naturally fractured rocks including numerous discontinuities, the effects of this reduced hydraulic aperture in local fractures on macroscopic fluid flow and solute transport in complex fracture systems still remain unclear. Many previous studies assumed identical hydraulic and mechanical apertures in discrete fracture network models for simplicity (Min et al., 2004; Zhao et al., 2011). Therefore, the main objective of this study is to evaluate the influences of local surface roughness of fractures on fluid flow and solute transport processes at the macroscopic scales of fracture networks, by employing the empirical models that relate the hydraulic aperture to the mechanical aperture."

Jan 1, 2015

By E. Ghali, N. Sorour, G. Houlachi

"The binary Fe53Mo47 and ternary Fe54Mo30P16 coatings have been electrodeposited from citrate-based electrolyte on mild steel (MS) substrates. The electrodeposition has been conducted for 6 hours at 20 mA cm-2 and 30°C. The electrochemical tests were carried out in chlorate solutions containing 300 g L-1 NaCl and 4 g L-1 K2Cr2O7 at pH 6.4 and 80°C. A number of surface characterization techniques such as SEM-EDS, XRD and EMP were used to study the microstructure of the alloys. The electrocatalytic activity of these coatings was investigated using steady-state polarization and galvanostatic technique. This study revealed that the Fe-Mo-P coating could be considered as a promising cathode material for the hydrogen evolution reaction (HER). The results showed an important decrease of hydrogen overpotential for Fe-Mo-P alloy as compared to that of Fe-Mo and especially MS which is a traditional cathode in chlorate industry. The HER overpotential for Fe54Mo30P16 at current density of 250 mA cm-2 was decreased by 30% in comparison to that of MS (1029 mV), and by 16.5% to that of Fe53Mo47 coating (857 mV).INTRODUCTIONSodium chlorate is used for manufacturing of several daily consumption products. This chemical is mainly employed for the production of chlorine dioxide (ClO2) that is a bleaching agent used in the pulp and paper industry. The ClO2 is also consumed for generation of perchlorates, chlorites and other chlorates, as an herbicide and in uranium processing (Cornell, 2002). Sodium chlorate is produced industrially via following overall formula in un-divided electrochemical cell (Nylén & Cornell, 2009):"

Jan 1, 2016

By J. J. Jonas

The categories of interpass time encountered in hot rolling are characterized. These are shown to fall into three broad categories: short (in rod rolling); intermediate (in strip processing); and long (in plate schedules). The effects of interpass time on recrystallization and carbonitride precipitation are described, and particularly on the interaction between these two mechanisms. The interactions, in turn, determine the final microstructure produced as well as the mechanical properties.

Jan 1, 2005

By R. Baker

A novel electrochemical half-cell and corresponding working electrode were designed to evaluate the electro-catalytic activities of catalysts in an environment close to that of an operating proton exchange or polymer electrolyte fuel cell (PEMFC). Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) techniques were employed using the novel cell to characterize various methanol electro-oxidation parameters that contribute to the overall reaction on a fuel cell anode. The effect of temperature on methanol oxidation kinetics was examined in the potential range of 0.31 to 0.65V (vs. NHE). The data was collected in the temperature range of 20 to 80°C. Based on the experimental analysis and literature data, an equivalent circuit model (ECM) for methanol oxidation was proposed and was used to fit the EIS experimental data. The experimental data and ECM electrochemical data was used to extract electrochemical kinetic parameters for methanol oxidation such as the exchange current density, Tafel slope, and energy of activation for the reaction. Kinetic data, especially at different temperatures, is very limited in the literature.

Jan 1, 2005

By Nicolas Gatelier, Sophie Laurent, Thierry You

Hard-rock caverns for hydrocarbon storage are a very particular type of underground facility controlled not only by local administrative and regulatory constraints that can be very specific, but also by the possible risks of geotechnical or geomechanical failure. Each such facility throughout the world is a prototype that needs to be adapted to very different site conditions. The straight forward application of design methodologies from relatively similar fields (mines, tunnels) can be very useful, but risks holding back the scientific and technical improvements needed by an engineering industry in full development. Here we look at various case histories and at problems that have been raised where recent attempts at standardization would appear to have been ill adapted, and where storage designers, through experience and judgment, may still provide innovative engineering solutions.

Jan 1, 2015

By C. Zangerl, H. Lechner

"Large scale rock slides in deeply incised Alpine valleys are common hazards that can endanger human life, settlement areas and critical infrastructure such as highways, railways and reservoirs (Bonzanigo et al., 2007). In order to perform reliable forecasts of the behaviour of rock slides influenced by large dam reservoirs the geometry, the kinematics, the deformation behaviour and the hydrogeological situation need to be understood profoundly. Based on generic rock slide models the influence of the rock slide geometry on the stability as well as the impact of the buoyancy forces and water load of the reservoir at the toe of the slope are the main focus of this study. Various assumptions of hydraulic conductivity, groundwater conditions of the rock slide and impoundment depth of the reservoir are analysed using limit equilibrium approaches.Generally, deep seated rock slides are characterised by deformation along one or multiple shear zones where most of the measured total slope displacement localizes. Many large rock slides, especially those observed in foliated, mica-rich crystalline rock masses (e.g. paragneisses, mica schists, phyllites), do not fail suddenly or reach high velocities. Instead, many of them move slowly and reach velocities of centimetres per year or even less. Some show episodic accelerations, sometimes reaching alarming levels, but then subside to non-critical levels again. However, there is a potential that deep-seated rock slides fail rapidly, develop into far-reaching run-out rock flows, and cause catastrophic events. Whereas the role of triggers in promoting phases of acceleration is often understood, the same cannot be said regarding the kinematics and dynamic processes by which the rock slide mass decelerates, re-stabilises or accelerates to a catastrophic degree once the trigger impetus has been removed. Thus key questions of the presented work concern the geotechnical, geometrical and hydrogeological conditions under which a slowly moving rock slide is triggered to accelerate to irreversible, maybe dangerous velocities. The development of the sliding zone is generally influenced by pre-existing discontinuities such as brittle fault zones, shear and tensile fractures, foliation and bedding planes. These geological structures determine the geometry of the sliding zone which can either be rotational or translational. During the gravitationally induced failure process the geometry of the rock slide undergoes a change.Several observed post-failure geometries in metamorphic rocks show a concave topography in the middle to upper part of the rock slide and a typical convex or bulge-like topography at the toe of the slope (Zangerl et al., 2012). Whereas the sliding zone of the upper part of such a rock slide mass is rather steep and planar, the inclination of the sliding zone at the toe can be close to zero and act against the driving forces (Alonso et al., 2010). A shear zone that meets alluvial deposits at the foot of the slope encounters a stabilizing impact on the mechanical behaviour. This buttressing effect of alluvial sediments has a remarkable influence on the slope stability."

Jan 1, 2015

By A. F. Laurin, A. L. Dorr

"Because of its wide areal extent, its numerous lithological facies and its high degree of metamorphism, the Quebec portion of the Grenville province has only partly been explored and prospected. Rock types that are economically among the most interesting in the Grenville are those of mafic and ultramafic compositions, because of their great potential for coppernickel and chromium-platinum. The peculiar mode of occurrence and the distribution of these igneous masses in which copper-nickel mineralization is known to occur indicate' two common geological features: (1) aerial photographs and/or topographic maps strongly' suggest close spatial (and possibly temporal and genetic) association of most of these mineralized mafic and ultramafic intrusions with circular structures; (2) when plotted on a large-scale map comprising the Quebec portion of the Grenville, these circular structures fall along two lines which could correspond to major tectonic features. Even though the genetic links among the mineralized mafic-ultramafic masses, the circular structures and the linear features are not yet fully understood, their associations are believed to be empirically valid and should therefore be used as geological tools by those interested in exploring the Grenville for copper-nickel and possibly chromium-platinum deposits. It should be noted that these mafic and ultramafic bodies do not appear to be spatially related to anorthosite complexes."

Jan 1, 1971