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By Roy EI. Durr, Glen R. Davidge

"This paper presents the results of structural analyses and full-scale destructive tests conducted on liner plate culverts. The purpose of this work was to establish a design method and evaluate the suitability of using these structures in potential roof-fall areas for a rehabilitation application in lower stress and relaxed mining environments. Field evaluation of the design is currently in progress.Theoretical ultimate resistance functions were established for two different culvert shapes and were found to be representative of their experimental behaviour. The ultimate resistance function was used to determine their plastic behaviour to a rapidly increasing deflection condition, to determine the energy absorption capacity of these structures, and to predict their response to impact loading.IntroductionThe Kidd Creek mine of Falconbridge Limited is located justnorth of Timmins, Ontario. The area under rehabilitation for which this program was developed is the 2600 level of the No. I mine. The problem of effectively securing selected drifts at the 2600 level in NO.1 mine, for access to a high-grade ore block, is key to the economics of the operation. Diamond drill test holes had indicated a loosened rock mass above the 2600 level of about 7.5 m thick in response to the extensive mining operation below this level. This level forms the arbitrary boundary between the No. I and No. 2 mines, and has extensive volumes of cemented rock fill below it and largely untouched ore above it to the 2000 level in the North orebody. The walls at that level were showing relaxed ground conditions typical of de-stress: sub-horizontal joints opening up, and peeling.Due to the ground conditions, the consequent safety risks, the high grade of the ore, the potential production delays, and the likelihood of several phases of rehabilitation, regularly used drift rehabilitation employing rock bolts, cable bolting, or shotcrete was not practical. Two options were deemed possible alternatives to suit these conditions, steel sets with blocking and lagging, and liner plate culverts with backfill. Culverts were chosen."

Jan 1, 1995

By J. A. Hillier

"IntroductionThe purpose of sampling is to remove a portion of material from a stream which is representative of it in size, moisture and mineral content.To prevent the effects of segregation, generally caused by the way in which a conveyor, pipe or launder is loaded or directed, the sampler should cut proportionally the entire cross section of the stream.If one conveyor transfers to another at a right angle, fines may be dropped on the near side, and the coarse material thrown to the opposite side. Segregation can also occur as a result of the motion of a conveyor belt passing over the idlers causing the coarse material to roll to the sides of the belt.When slurry changes direction of flow in a launder or pipe, the heavier and coarser fraction will centrifuge to the outside of the curve and tend to remain on one side of the stream. Similarly, if two streams joining in a common launder are not mixed at the point of confluence, they will continue down the launder unmixed . This effect is particularly noticeable in a plastic lined launder.Therefore, a proportional sample is usually accomplished by a constant rate of cutter travel across the entire stream, making certain that the cutter is not full or splashing over before reaching the end of travel.The cutter should operate on a constant interval based on time, tonnage and uniformity of flow. The opening should be at least three times the width of the largest piece to be sampled. The cutter width is more critical with ore samples where particle sizes are large. With slurry samples, the opening is usually much larger than the minimum in order to obtain sufficient samples"

Jan 1, 1989

By J. Y. Kim, Kenneth Stowe, Stephen Chryssoulis

"A series of flotation tests was carried out on Brunswick Mining ore with various pH modifiers (soda ash, lime, KOH) and added ions (ferric, nitrate, sulphate) in the copper lead rougher circuit. The main objective was to identify downstream effects on sphalerite activation and subsequent zinc rougher flotation. Some significant differences in zinc flotation were obtained. Most notably, soda ash and nitrate ions had a positive impact and ferric ions a pronounced negative effect on selectivity.Selected products from the flotation tests were deslimed at 400 mesh, washed with methanol, air dried, placed in teflon vials purged with nitrogen and stored at -15 degrees C. Numerous liberated sphalerite and pyrite particles were selected under a stereoscope and placed in rows on indium foil. The surface compositions of the particles were analyzed with an innovative laser probe (LIMS). The very small analysis area of the LIMS enables the surfaces of individual grains to be characterized. In addition, the rapid analysis time allows a statistically significant number of grains to be analyzed quickly.Surface lead appears to play a major role in zinc activation/flotation. Possible mechanisms are proposed to explain the variations in metallurgical performance at the different test conditions.IntroductionAlthough the bulk composition of mineral grains is an important consideration for the mineral processor it is ultimately surface composition and topography (edges and dislocations preferred sites for reactions) that control reactivity in flotation and cyanidation (passivation, encapsulation and preg-robbing). Determination of the surface properties of particles from process streams poses a particular challenge for the surface chemist for a variety of reasons, including:"

Jan 1, 1994

By Emmanuel Henry

The Kiruna Mine, operated by Luossavaara-Kiirunavaara AB (LKAB), is a large-scale sublevel caving operation located in Arctic Sweden. Iron ore is extracted at a rate of 60 000 tpd from a four-kilometre long, 80-100 m thick and 60-degree dipping orebody. Actual production depth is 800 m under the top of the footwall and about 550 m under the average regional ground level. Because no support is left between the footwall and the hanging wall and despite the relatively low mining depth, extraction results in the formation of a huge stress shield modifying the original stress field and concentrating it just beneath the mining level. Effects of stress concentration on the rock mass are monitored through field observations and a seismic system. Severe stress-induced deterioration of openings is visible to a certain radial distance from the mining level: pillar crushing and fault slips are more and more common and extended. The seismic system, installed in collaboration with CANMET, confirms the field observations and completes them in the rock mass: fault slips and major seismic events are recorded. The system proves its effectiveness to outline the extension of the dynamic response of the rock mass, which actually seems much larger than field observations let think.

May 1, 2001

By S. C. Bouffard

Barrick's Zaldivar operation in Chile produces copper by heap leaching, solvent extraction, and electrowinning. The heap consists of a dynamic pad, and its stacking and operating conditions have changed over its 11 years of operation. These changes have included pad re-mining midway through the cycle, tightening of the irrigation drip lines, an increase of the coarseness of the particles, and an increase of the heap height. This paper reviews the heap operating data to understand the effects of these changes on the kinetics and recovery of copper minerals. Field tests demonstrated that neither re-mining nor tightening the irrigation grid added value for both low and high grade oxide and sulfide ores. The P80 of the feed ore was increased by 0.8 mm, which did not reduce the copper recovery of oxide and sulfide ores. The increase of the heap height above 8 m lowered moderately the copper recovery from sulfide minerals, and very slightly the recovery from oxide minerals. Despite the lower recovery, the higher tonnage stacked in the taller heap increased the copper output. Optimizing the chemistry of the agglomeration and feed solution holds more promise for increasing the copper recovery than the above physical changes.

Jan 1, 2007

By Cy Jordan, Ben Burdett, Adrian Dance, Jack Rainey

"In 1997, EIMCO Minerals installed a knowledge-based control system on one of the five primary grinding lines at Highland Valley Copper. The objective of the system is to maximise throughput without affecting circuit product size or flotation recovery. The system was commissioned in October 1997 on a SAG mill/ball mill circuit following a plant audit and upgrade of the control instrumentation.The system monitors and controls the SAG mill power, bearing pressure and recycle load by manipulating the solids feedrate, water addition and mill speed. The two ball mill and cyclone circuits are controlled through water addition at various points in the circuit as well as the number of operating cyclones.An on-line particle size analyser is used to measure the cyclone overflow quality. Models of the SAG mill charge level and overflow product size are also incorporated. A method of predicting the SAG mill power response to feedrate changes is used to lessen the effect of dead time for improved mill power control. In the future, inferred measurements of SAG feed particle size and hardness will allow changes in ore behaviour to be predicted and compensated for by the system.This paper describes the development of the project -from installation and commissioning to modifications and refinement -along with prospects for the future.BackgroundIn early 1997, EIMCO Minerals was contracted by Highland Valley Copper to install a knowledge-based or expert system control strategy on one of the five grinding lines in the mill. This was to become the start of the Advanced Control Project at Highland Valley Copper (HVC). This paper will review the progress of the Project as well as discuss the prospects for the future.Following a preliminary engineering study (or plant audit) by EIMCO in 1996, it was decided to implement an advanced control system in order to improve plant operations and increase productivity. The study suggested that such a system had a pay-back period of a few months through increased throughput without loss in flotation recovery. Highland Valley already had successfully applied higher level control through their Elsag Bailey distributed control system (DCS) and this was the next stage in process optimisation."

Jan 1, 1998

By R. C. Reed, L. T. Wu, H. C. Harada, K. Kawagish, R. T. Wu

Oxidation of pure metals is a chemical reaction in which the metal loses one or more electrons, such that the atom of the metal changes from the neutral state to a positively charge ion and reacts with oxygen to form an oxide of the metal. The oxide can form as a protective and adherent scale that slows down further oxidation, or may spall off repeatedly, exposing fresh metal surface to react with oxygen. In multi-component alloy systems such as typical high temperature NiCrAlY bond coats, more than one oxidation mechanism may take place at once and thus, complicates the study of oxidation. To better understand the competition between formations of oxides of different compositions, a thermodynamic assessment is carried out to study the oxidation mechanism of a Ni-27Cr-9Al (at %) ternary alloy. Based on the assessment, it is demonstrated that the layering of different oxides can be determined, with the most stable oxide (alumina) existing directly above the metal-oxide interface and the least stable oxide (nickel oxide) locating on the outer most layer. A comparison between the calculated results and previously published experimental observations shows excellent agreement.

Jan 1, 2010

By Lei Pan, Roe-Hoan Yoon

"Sea water flotation is becoming a reality due to shortages of fresh water. To better understand the mechanisms involved in sea water flotation, we have studied the effects of KCl and MgCl2 on the surface forces present in the wetting films of water formed on hydrophobic surfaces. The measurements have been conducted using the force apparatus for deformable surface (FADS), which is capable of measuring both the surface and hydrodynamic forces responsible for bubble-particle interactions. The results obtained with the gold surfaces hydrophobized with butanethiol (C4SH) show that the wetting films of Ultrapure water do not rupture despite the relatively high water contact angle (??= 80o) and the presence of a long-range hydrophobic force with a decay length (D) of 25 nm in the film. The film is metastable with its equilibrium thickness (he) at 140 nm, where the repulsive double-layer force is equal in magnitude to the capillary force as shown in Figure 1. The film loses its metastability and ruptures in a 10-2 M KCl solution, in which the double-layer force decreases substantially due to the decrease in Debye length (?-1) while the decay length of the hydrophobic force remains as large as 23 nm.The effects of MgCl2 has also been studied using a C4SH-coated gold surface with a water contact angle of 87o. It has been found that in a 10-4 M solution double-layer force decreases due to the decrease in the negative ?-potentials and Debye length, which should help destabilize the wetting film. However, the film remains stable due to the decrease in the decay length of the long-range hydrophobic force from 45 nm in Ultrapure water to 14 nm in the MgCl2 solution. Thus, the results obtained in the present investigation support the view that the difficulties in sea water flotation may be due to the presence of MgCl2 rather than the presence of NaCl in sea water (Ramos, et al., 2013)."

Jan 1, 2016

By T. W. Cavers

The Dwight-Lloyd sintering machine was the answer to the flue-dust problem of the copper blast-furnace smelter. Then came concentration by flotation, which threatened to eliminate the blast furnace from the smelting field altogether, and again the sintering process solved the problem. As is well known, the sintering process is dual in its function; it expels sulphur from the charge and it converts a powdery material into nodules or chunks that hold together. The charge is ignited on top just as it passes over the edge of the first suction box, and the oxygen of the air that is drawn downward through the charge breaks up the sulphide and oxidizes about fifty percent of the sulphur. The heat produced by this reaction in the upper stratum of the charge ignites that lying immediately below, and, when the pallett has travelled the full length of the machine, the tire has reached the graces and the fine concentrate has changed its characteristics by being partially fused and has become a more or less solid mass. When the Granby Company was smelting its ore as mined, one small D-L machine was adequate for the treatment of the flue dust, but as soon as the policy of smelting the concentrate was adopted, it became necessary to add two large machines to the sintering plant. The three sintering units, of which two are 42 in. by 396 in. and the other 42 in . by 264 in. in hearth area, have a combined capacity of from 370 to 450 tons (dry) of charge per day. The capacity varies directly as the hearth area. The sinter produced is about 88 per cent of the dry charge, or 325 to 400 tons per day. The sintered fines returned for resintering average between 30 and 35 per cent of the charge, but this is not as great a disadvantage as might appear, since the addition of hot fines improves the burning qualities of the mixture. From 50 to 54 per cent of the sulphur is eliminated in the sintering operation.

Jan 1, 1934

By Chris Brothen

The introduction of new technology in mine operations has provided real opportunities for increased efficiencies and production gains which translate into enhanced profits. Computing and network technology usage has become integrated into surface mining operations and on average these investments in technology have proven beneficial for efficiency and productivity improvements. Embracing new technologies however, does not guarantee positive results. The expectations or improvements derived through the technology must be confirmed and clarified well before implementation. Tire Pressure and Temperature Monitoring Systems are an excellent example of an existing technology that can provide full time automated performance measurements of tires operating under harsh conditions and environments. Prompt warnings or alarms signaling when a tire has exceeded operating capacities will provide savings through lowered maintenance costs and increased productivity. To truly quantify the projected savings in tire life, fuel consumption, and increased levels of production, all costs associated with the technology, both direct and indirect must be considered. Apart from the initial cost of the system implementation, ongoing maintenance and support costs must be considered as well as the costs of system integration into existing mine operations

May 1, 2008

By Akira Miura, Katsuyuki Sato, Yuken Fukano

JX Nippon Mining and Metals Corporation has developed the JX Iodine Process, which is an innovative and patented copper-leaching process for low-grade primary sulfide ores. This process consists of the irrigation of ferric iron and a low concentration of iodide solutions. One-meter column leaching tests were conducted on ore samples from two different mines. At the end of experiments, the total copper recovery exceeded 70% for Sample A and 50% for Sample B with the iodine method, which was significantly higher than that with conventional ferric leaching of 14% for Sample A and 20% for Sample B. To elucidate the reason for the JX Iodine Process effectiveness, cross sections of leached residues were studied. Reaction products were confirmed around chalcopyrite even in the central area of particles in Sample A, however, reaction products were recognized at a depth of only 1 mm from the ore rim in Sample The resistance of Sample A to the leachate appeared to be lower than that of Sample B because Sample A had a high permeability and porosity, whereas Sample B had been affected strongly by a potassium alteration. No reaction products were visible on conventional leaching samples, even at the ore surfaces. INTRODUCTION Hydrometallurgical copper leaching (heap leaching or dump leaching) has been used extensively for copper recovery from oxide and secondary-sulfide ores, but not for primary copper sulfides, which contain mainly chalcopyrite as copper minerals. Although they are major resources of copper, primary copper sulfides are difficult to process because of their refractory nature. Extensive leaching studies have been carried out to leach primary copper sulfides (chalcopyrite), including biological and chemical, using a variety of oxidants and additives to enhance copper recovery. Watling (2013) reviewed acid-chloride-oxidizing agents with chalcopyrite. Abdollahi et al. (2015) tested silver as a catalyst for bioleaching with a chalcopyrite-bearing molybdenite concentrate. Hiroyoshi, Miki, Hirajima and Tsunekawa (2000) found a specific redox-potential zone for high-speed chalcopyrite leaching by controlling the ratio of ferric and ferrous iron. However, no ambient-temperature economic process has been developed for leaching primary copper sulfide, which usually has a low copper grade.

Jan 1, 2019

By Donald S. Cameron

By dispersing gold in high surface area form supported on metal oxides, its inert character can be transformed to make economical, effective catalysts. Gold has already been demonstrated in a number of fuel cell applications such as gas phase catalysts, electro-catalysts, and electrical connectors. In this paper, the various types of fuel cell systems are reviewed, and several opportunities for gold identified. Low temperature fuel cells, including alkaline and solid polymer electrolyte types rely on high surface area platinum group metal catalysts which are highly susceptible to poisoning by low concentrations of carbon monoxide in the fuel supply. Hydrogen is frequently obtained by steam reforming hydrocarbons, followed by the water gas shift (WGS) reaction. A promising initial use for supported gold catalysts is in catalysing this WGS reaction. Research has shown that gold supported on iron oxide (Au/a-Fe2O3 ) WGS catalysts are more active than the current commercial copper oxide / zinc oxide catalysts, and effective at temperatures as low as 120oC. Products from reformer/ water gas shift reactors can be further purified by removing traces of carbon monoxide. If a small proportion of oxygen is introduced into the fuel gas stream, carbon monoxide can be preferentially oxidized to carbon dioxide even in the presence of hydrogen. Gold nanoparticle catalysts on iron oxide support (Au/a-Fe2O3 ) have exhibited higher activity than commercially available platinum on alumina (Pt/?- Al2O3 ) preferential oxidation catalysts. The low temperature of this reaction may make it feasible to incorporate these catalysts within the fuel cell itself. Proton exchange fuel cells provide several possible applications for catalytically active gold and its alloys. Carbon supported platinum group metals would benefit greatly from improved electrical conductivity if gold replaced some or all of the carbon support material. As electrode current densities are raised, electrical resistance constitutes an increasing proportion of voltage losses within the fuel cell. Dramatic reductions in cell stack voltage losses have already been demonstrated by reducing inter-cell contact resistance using gold plating. The low temperature oxidation properties of gold catalysts have been investigated in controlling gaseous emissions from direct methanol fuel cells, and gold also provides essential catalysis in building direct borohydride oxidation fuel cells. The prospect of a range of other applications for gold in fuel cells to contribute useful improvements in corrosion resistance and conductivity is assessed. Globally, fuel cells have been developed for a wide range of applications including stationary generators, cars and buses, industrial vehicles and small portable power supplies, each of which represents a substantial market. Hence there are likely to be many and varied opportunities for gold catalysts to contribute to the performance and economics of the systems being commercialized.

Oct 1, 2003

By A. W. Chan

"An interactive computer simulation model of conveyor systems used in oil sands mining has been developed to aid in the selection of mining equipment and the evaluation of operating policies. The materials handling links between supply points, such as bucket-wheel excavators and draglines, and demand points such as bins and extraction plants are modelled in such a way that the conveyor model can be interfaced with any combination of these equipment submodels. Detailed calculations of the power demand of each conveyor section based on operating characteristics and conveyor design parameters are included to permit the close monitoring of energy requirements. Various interactive features are incorporated so that an operator can not only monitor, but also control, the mining operations in the model and experiment with different operating strategies.IntroductionThe interactive simulation model of conveyor systems described in this paper is one of a number of detailed computer models being jointly developed by the National Research Council and Canstar Oil Sands Ltd. on the mining equipment and operations used in oil sands mining. Reference I presents an overview of this whole series of models, their interrelationships and the underlying motivation for their development.A network of conveyors constitutes one of the practical ways for transporting mined material in an oil sands plant. The materials handling links between supply points, such as bucket-wheel excavators, bucket-wheel reclaimers and bins, and demand points such as dumps, bins and extraction plants can be represented by a series of interconnected conveyor sections. For example, the fluctuations of the feed rate at the bucket-wheel excavator, the flow of ore material through the conveyor network and the arrival of this material at the extraction plant can be simulated."

Jan 1, 1982

By J. Kuipers, R. W. Lawrence, P. B. Marchant, W. Brooks, J. T. Chapman

"Bioleach testing and piloting was conducted on refractory gold sulphide concentrate from Austin Gold Venture in Nevada during 1988. The objective of the test programme was to determine the technical and commercial viability of bioleaching as a concentrate pretreatment step prior to gold extraction by cyanidation. Baseline CIL cyanidation typically resulted in < 20% gold extraction from the Austin concentrate. Bioleaching enhanced gold extraction up to 95% using conventional CIL techniques. This paper summarizes the bioleach test programme and results, including pilot plant studies onsite, and describes the commercial design details for a possible retrofit of the Austin flotation tailings leach circuit to accommodate 20 tpd and 40 tpd capacity concentrate bioleach facilities.INTRODUCTIONBioleach testing on a refractory carbonaceous sulphide concentrate from Austin Gold Venture (AGV), was initiated in late 1987 as part of an ongoing programme at Austin to investigate alternatives to concentrate smelting. Preliminary batch biooxidation tests at Coastech indicated that over 90% gold extraction by carbon-in-leach (CIL) cyanidation of the bioleach residue could be achieved, compared with less than 20% gold extraction on untreated concentrate by similar CIL processing.Subsequently, a more rigorous laboratory study was undertaken at Coastech to establish continuous biooxidation operating criteria on a bench scale. The objective of continuous testing in the laboratory was to provide confirmation of enhanced CIL response based on continuous bioleach products and to determine key process operating and design parameters for pilot testing. The success of the laboratory test program led to the installation of a mobile pilot plant at Austin Gold Venture. The plant was operated by Coastech and AGV during 1988 to provide scaleup data and design criteria for commercial design and feasibility analysis. Based on pilot plant operating data, a detailed commercial bioleach plant was designed as a possible retrofit to the existing 1000 tpd CIL plant. Capital and operating costs were estimated to provide a commercial feasibility study of bioleaching as an oxidative pretreatment for Austin refractory concentrate."

Jan 1, 1989

By P. Au, P. Patnaik, H. Saari, D. Y. Seo, S. Bulmer

Ti-48Al-2Cr-2Nb-xW (where x = 0, 0.5, and 1 at. %) powders were consolidated by hot isostatic pressing (HIP). The consolidated samples were solution heat treated above the a-transus followed by stepped cooling to room temperature. Selected samples were subsequently aged at 950 °C for up to 72 hours. The post-heat treatment microstructure was examined by optical and electron microscopy. It was found that increasing holding time above the a-transus generated a more homogenous microstructure. Utilizing the stepped cooling sequence, especially with a transition temperature of 1270 °C, massively transformed gamma (Ym) was diminished. Aging caused coarsening of the fully lamellar microstructure in the 0%W and 0.5%W samples while almost no coarsening occurred in the 1 % W sample. Precipitates began to form during aging in samples containing W. The precipitates at the lamellar interfaces are fine and have a needle like shape, while precipitates at the lamellar grain boundaries are coarse and circular in shape. The size and number of the precipitates depend on aging time and the level ofW content.

Jan 1, 2006

By R. T. Seaman

There are several hydrometallurgical alternative processing options under development for high enargite and arsenic containing copper concentrates ranging from biological, atmospheric, medium temperature oxidation to total oxidative leaching. The most developed of these options is the CESL process boasting pilot campaigns totaling more than 8760 hours of fully integrated continuous operation, as well as, over two thousand batch scale oxidation tests performed on dozens of concentrates for flowsheet development. This paper reports the observed deportment of arsenic under varying arsenic, iron and acid oxidation conditions; it also describes the impact of iron to arsenic ratios and residue recycle on overall arsenic behavior and its stability in residue. INTRODUCTION The CESL Hydrometallurgical Process (CESL) was originally developed to compete with smelting of clean chalcopyrite concentrates. High Treatment Charges and Refining Charges (TC/RCs) combined with premiums on London Metal Exchange (LME) grade copper from onsite refining made treatment of copper concentrates using CESL a viable option at the time. As world demand for copper increased and a subsidized Chinese refining market developed, smelting contracts became more favourable for the miner and focus was placed on modifying the CESL Hydrometallurgical Process to handle concentrates with elevated deleterious elements. Dozens of pilot campaigns processing concentrates containing elevated concentrations of uranium, fluoride, mercury and nickel all led to further developments of the CESL Hydrometallurgical Process. In 2016 a United States patent was granted for a novel modification of the CESL Hydrometallurgical Process for recovery of copper from arsenic-bearing and/or antimony-bearing copper sulphide concentrates, Henry Salomon de Friedberg (2016). To date, over 2000 bench scale tests along with five fully integrated closed loop pilot campaigns, totaling over a year of online operation time, have been conducted processing arsenic bearing copper concentrates. This paper summarizes the observed behavior of arsenic under varying autoclave and process conditions.

Jan 1, 2019

By K. Regl, J. Berneder

"AMAG investigated different aspects to improve the resistance against grain coarsening in aerospace alloys during recrystallization and was successful in finding several opportunities to minimize this effect. The studies show that one aspect to counteract grain coarsening is the chemical composition and subsequently all phases that are formed during homogenization. Starting with a fine grain (~ 50 µm) can lead to a final grain size of few mm. On the other hand with a coarse initial grain size (approximately 150 µm) and the right chemical composition the grain size can stay almost constant despite different deformation steps. Additional we investigated different sequences for the component production to eliminate the problem of grain coarsening as a coarse grain has a detrimental effect on product performance.INTRODUCTION In the aircraft industry, aluminium sheets are most commonly deformed in their soft state, followed by solution heat treatment and natural or artificial aging. If the preceding deformation is in a critical amount, during the recrystallization at solution heat treatment grain coarsening can occur. A subsequent deformation to this condition leads to an orange peel surface, which requires additional polishing. Next to this extra effort the coarse grain size produces a drop in the mechanical properties, often below specification limits. If there is no subsequent deformation, this effect is not visible and without destructive testing there is no possibility to detect the error. As mentioned before, this effect occurs during recrystallization, which is a process that is driven by the stored energy in the microstructure. The two most important aspects for an increase of the stored energy are the increase of the grain boundaries fraction (smaller grain size) and the increase of the dislocation density caused by deformation. The increase in dislocation density during the deformation arise from trapping of existing dislocations and from the generation of new dislocations. During recrystallization all grains are built completely new, so all dislocations are removed (Humphreys & Hatherly, 2004). There are three requirements for recrystallization:"

Jan 1, 2018

By A. Ghahreman

Activated carbon is proven to be able to catalyze arsenic oxidation in aqueous solution under acidic conditions. A commercially available granular coconut shell based activated carbon (AC) has been evaluated for catalysis of arsenic oxidation in this study. The rapid small-scale column test (RSSCT) has been developed to simulate and predict the performance of a carbon-based arsenic treatment system in a pilot scale reactor. Effects of residence time, aeration rate, and initial arsenic concentration in the influent solution on the AC catalysis of arsenic oxidation under dynamic and continuous conditions were studied by manipulating these parameters during RSSCTs. The effectiveness of the AC on arsenic oxidation was examined over the course of constant diffusivity based RSSCT operation. Residence time and initial arsenite concentration are proven to be the most effective impacting parameters on the arsenic oxidation process. For the 218 min residence time, the highest steady-state arsenic oxidation efficiency achieved was 98% with 1 g/L As(III) being treated at pH=1 under 0.05 L/min oxygen aeration. In a long-running RSSCT, the oxidation efficiency did not seem to deteriorate over a course of 666 hours operation, corresponding to 13986 mL total influent throughput volume. INTRODUCTION Arsenic is toxic to both animals and plants and inorganic arsenicals are proven carcinogens in humans. The increased extraction of low grade and complex mineral resources has introduced high ratios of arsenic into metallurgical processes. Discharge of arsenic by acid mine drainage resulting from mining activities has added intensive pressure on the need for proper treatment (Lawrence & Higgs, 1999). Since trivalent arsenite is more toxic and has lower affinity to solid surfaces for adsorption, many treatment systems initiate with an oxidation step to convert arsenite to arsenate and reach the ultimate immobilization of arsenic by the following precipitation of arsenate (Nazari, Radzinski, & Ghahreman, 2016). Scorodite precipitation has been studied extensively as a means of arsenic immobilization due to its high stability and negligible potential of releasing arsenic (Filippou & Demopoulos, 1997). As a stable ferric arsenate mineral, crystalline scorodite can contain up to 30 wt% arsenic (Paktunc, Dutrizac, & Gertsman, 2008). Arsenic must be in its pentavalent oxidation state in order for scorodite to be precipitated via oxidizing ferrous ions (Clancy, Hayes, & Raskin, 2013).

Jan 1, 2019

By Terry McNulty

"Previous papers (McNulty 1998 and 2004) have dealt with the causes of successful and less successful achievement of design production rate by new processing plants in the minerals industry. Examination of many case histories has allowed the construction of curves or profiles that represent projects with similar characteristics that equate to differing degrees of care exercised during the project development phase. Simplistically, decreasing care is reflected by increasing risk and a heightened likelihood of poor technical and/or financial performance.This contribution provides an update, including recent case histories, and presents a modified Series 1A curve that includes the best 23 case histories, out of a total of 81 examined, or 28%. This is done to show that some very carefully developed and executed projects can ramp-up quickly and that owners of new projects should avoid being too pessimistic in projecting early cash flow if they are certain that they have done their homework. The role of metallurgical process development in the reduction of project risk is discussed and several financial analyses are presented that express the potential monetary value of a well-designed and professionally executed metallurgical program."

Jan 1, 2014

By M. Lahtinen, H. Takala, B. Saxén

Oxidic zinc fume dusts are formed in electric arc furnace (EAF), Waelz furnace operations, and also in the Top Submerged Lance (TSL) furnace of Outotec Ausmelt. These dusts are normally considered as secondary raw materials for zinc metal production, as they are mainly originated from steel scrap recycling or zinc plant residue processing. The latest development in zinc fuming is direct smelting of zinc concentrates in the Ausmelt TSL furnace and hydrometallurgical treatment of produced fume dust. This technology is for primary zinc production like roasting and concentrate direct leaching, as concentrates are directly treated. The various oxidic zinc raw materials differ in composition and content of impurities. Thus, they require different hydrometallurgical processes to produce pure zinc metal. In addition to zinc these dusts typically contain also lead, silver and indium, which can be recovered and can increase recovered metal value significantly. From the impurity point of view the most relevant elements in the fume dusts are iron, arsenic, fluoride, chloride and cadmium. This paper describes hydrometallurgical processes to treat Ausmelt TSL fume dusts to extract valuable metals at high recovery and also to control and separate various impurities efficiently.

Jan 1, 2014