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By D. S. Cronan, S. P. Varnavas

Abstract - Metalliferous precipitates from submarine hydrothermal discharges have been investigated at four inshore locations off Milos in the Hellenic Volcanic Arc. The fine fraction of the sediments shows considerable variability in the concentrations of elements frequently associated with hydrothermal activity. Manganese varies from 30 ppm to 2500 ppm, encompassing the entire range of values found off Santorini also in the Hellenic Arc. Iron occurs in lower concentrations than off Santorini and Yali, while other elements often associated with hydrothermal activity such as Pb, Zn, As, and Cu also show enrichments in sediments from the hydrothermal vent areas. Selective leaching studies have shown that most elements are variably distributed between the different phases of the sediments but with enriched Pb, Zn, and Mn mainly in easily soluble secondary phases. Hydrothermal inputs are strongest at Palaeochori Bay, less at Voudia Bay and lowest at the Airport Springs and Rivari. The weathering of sulfide and possibly other orebodies is also thought to contribute to some of the elements enriched, while background concentrations are largely supplied from detrital sources.

Jan 1, 1999

By Palaniappan Chidambaram

Despite the advances in processing technologies, construction techniques, inspection methods, and materials, the number of process safety incidents are still increasing, and often the same types of incidents are being repeated. While regulators are enforcing stringent requirements in regards to safety management systems, process safety incident statistics reflect a failure in effective implementation. Upon closer look at the implementation of safety management systems, it becomes evident that the systems were not built on robust risk recognition. The risk-based implementation approach enables facilities to develop systems focused on managing specific risks and quickly gain momentum and confidence to take next steps towards implementing comprehensive systems. This paper will cover the importance of risk recognition and governance, risk based implementation and the role of Process Hazard Analysis in managing operational risks through the lifecycle.

Jan 1, 2014

By William Petruk, Donald Leroux, Michael Cooper

"Brunswick's primary flotation circuit (CuPb) produces a low grade concentrate containing considerable amounts of undesirable sphalerite and pyrite. To determine the cause of the poor selectivity, a series of Quantitative Mineralogical Analyses (QMA) were performed on several CuPb circuit streams. It was observed that significant fractions of sphalerite and pyrite reporting to the concentrate was liberated, meaning that their depression was not complete. The study highlighted the need for some R&D efforts to be spent in sulphide flotation fundamentals.IntroductionThe viability of many mining projects strongly depends on the performance of their concentrators. More than ever, competitive grade concentrate and high metal recoveries are criteria of paramount economic importance. The selectivity of solid/solid separation processes used in concentrators must be maintained at high levels or continuously improved.Flotation is the solid/solid separation process used by most base metal producers. In spite of its low operating cost, flotation remains a very complex process. To make it selective, precise reagent dosages and electrochemical conditions must be maintained. The difficulty in controlling flotation lies in the numerous heterogeneous reactions that can take place between the different solid, liquid and gaseous phases involved. This complex chemistry makes flotation selectivity difficult to understand and, therefore, to improve from a theoretical point of view.Brunswick Mining and Smelting, near Bathurst N.B., operates a 10500 tpd concentrator which produces four concentrates through five stages of sequential flotation (Figure I). Various reagents are added at key process stages while the ore undergoes different electrochemical conditions. Although the selectivity is important at all stages, the performance of the very first separation, the CuPb circuit, is the most critical. It is here where mineral misplacement to the wrong stream has the greatest economic consequences."

Jan 1, 1996

By R. J. Chase, C. Davies

"The Merelani graphite-tanzanite deposit is located in northeast Tanzania, 14 kilometers south of Kilimajaro International Airport and in close proximity to the towns of Moshi and Arusha. The graphite mineralization is hosted by relatively undeformed linear Proterozoic metasedimentary gneisses, several of which have been subjected to hydrothermal alteration resulting in tanzanite mineralization. Exploration work comprised detailed geological mapping coupled with pit and trench channel sampling and a subsequent 1500 meters of diamond drilling. In addition, metallurgical tests have shown the graphite to be of unusually coarse flake size, crystallinity and high purity.Feasability studies have shown the economic viability of a major coarse flake graphite deposit with the measured resource to 50 meters in excess of 9 million tonnes assaying over 85 graphitic carbon. Production is due to start by the end of the first quarter of 1994 with the processing plant design capacity initially set at 15 000 tonnes per annum.In addition to graphite production, tanzanite will be produced through selective mining within the graphite open pit in the upper horizon and from underground workings within the lower horizon.The Merelani graphite-tanzanite deposit will be the first major orebody to be exploited through means of private funding since Tanzania gained independence"

Jan 1, 1994

By J. Gillies

"Those of you who were at last years C.M.P. meeting are aware there was discussion at that meeting concerning the best method of assisting the assayers of metal mines to exchange new ideas and methods of assaying. The opportunity to advise you of what came of that discussion is very much appreciated.There are several societies, including the Chemical Institute of Canada, the Spectroscopy Society and others that could be of some assistance to assayers. However, since these societies cover a rather broad field and not many mine assayers have the opportunity to attend their meetings, it was felt that an organization oriented to the specific needs of the mine assayers would be of more value to them.Several years ago an attempt was made to hold meetings for the benefit of assayers in conjunction with the Conference of Metallurgists held each year by the Metallurgical Society of the C .I.M.M. This did not work because very few of the mine assayers attended the meetings.With the very evident success of the type of meetings the C.M.P. have and the excellent groundwork done by your secretary, Mr. Stevens, in talking about this to mine management and assayers at many mines across the country, it was decided to hold a meeting at Noranda on October 8 to discuss how best we could help ourselves solve our problems.For the initial meeting it was felt that perhaps it would be better to start with a smaller group, so invitations were sent to mines in Ontario and Quebec that were geographically fairly close to Noranda."

Jan 1, 1970

AGENDA ? Company Overview ? Industry Direction ? Technology to support maintenance ? data access, connectivity, process historian, downtime & production reporting. ? Case Studies Company Overview Corporate Offices Client Base ?16 consecutive years of growth & profitability ?#39 of Top 50 Control Companies (Worldwide) ?470 employees ?TSX: MTK Industry Direction Improved visibility into the business so they can: ? Reduce cost through better understanding of where costs are being incurred and making timely decisions. ? Optimize operations while leveraging existing assets. ? Have a single version of the ?truth? ? Deliver reliably to stakeholders on the demand for increased accountability (safety, environmental, regulatory performance etc?). ? Respond quicker to market conditions in order to out perform the competition ? Best in Class approach. Web is becoming the standard user interface.

Apr 1, 2005

By L. A. Gomieroa

The Caetité-Brazil uranium facilities produce about 340 t/y of uranium from an ore averaging 0,25 U %. The process steps are ore crushing, heap leaching with sulfuric acid, U separation and purification by solvent extraction with tertiary amine followed by stripping with sodium chloride solution and precipitation as ammonium diuranate that is dryed. A change in the milling process is being evaluated to increase the production and the uranium recovery. Heap leaching will be changed to conventional tank agitated leaching of the ?590 ground ore slurry in sulfuric acid medium. The replacement of the stripping reagent is also being considered.

Aug 1, 2010

By Ron Hatch, M. K. Witte

"INTRODUCTIONThe proper selection of carbon for a gold carbon in pulp (CIP) circuit involves careful evaluation of several physical, chemical and economic factors. A series of evaluations are required to maximize gold recovery at the lowest capital and operating costs, whether the carbon is selected for an existing gold mill circuit or a new mill under design.Although evaluation may proceed through various stages, it is the intent of this paper to outline some of the preliminary testwork that should be carried out to screen potential carbons for a particular application.An examination of the specification sheets supplied by the various carbon manufacturers may indicate some desirable properties on which to make cursory selection. This exercise by itself will not provide the basic data needed for selecting the best carbon for a particular ore pulp and metallurgical circuit. The necessity of further metallurgical evaluation is indicated by the fact that different carbons perform differently depending on the physical and chemical nature of the leach pulp. In the case of an existing mill, actual leach slurries using mill water are available and should be used for testwork. In the case of new mills, leach pulps must be prepared to simulate the proposed circuit.Five coconut shell activated carbons were obtained from various suppliers, all reported to be 6 x 16 mesh carbons recommended for CIP circuits. A metallurgical evaluation was made utilizing two leach pulps with significantly different characteristics. This paper describes the test procedures utilized and the results obtained from the testwork."

Jan 1, 1985

By Ayako Iwakoshi

Highly concentrated pastes of gold nanoparticles were successfully produced by use of a special kind of protective polymer and a mild reductant. Solid part of the pastes consists of up to 85wt% of gold nanoparticles, 10~30 nm in diameter, and residual protective polymer. This component can be diluted by any kinds of solvent at arbitrary rates. Electronics, optics, catalysts, colorants and surface metal coatings are possible application fields. 1. Introduction Noble metal nanoparticles are of interest in a variety of fields ? such as colorants, metal coatings, electronics(1), optics(2), and chemical catalysis(3). Especially, in the color field, the gold nanoparticle has been known as an aesthetic red colorant for stained glass and fine glassware, such as Venetian glass. The mechanism of coloring is attributed to surface plasmon absorption of gold nanoparticles(4,5). The gold nanoparticle in stained glass shows very clear red color, which is very durable for hundreds years. On the other hand, the red color of organic pigment in paint films often fades away within several years. We intended to reproduce the elegant and stable coloring of stained glass in paint films. In order to color a very thin, 20~50?m, paint film like stained glass, production of highly concentrated dispersion of gold nanoparticle is necessary. To achieve this, there were two issues to be overcome. One is how to prevent the coagulation of gold nanoparticles in highly concentrated solution. So far, several methods to prepare gold nanoparticles(6,7) were reported. But only a few methods succeeded to stabilize the gold nanoparticle dispersion at higher concentration than ppm order. The other is controlling of the particle size, this is because the color of gold nanoparticles is very sensitive to the particle size. Only when the particle size lies around 10 nm, the suspension exhibits red color like stained glass.

Oct 1, 2003

By Ralph L. Rutherford

Introduction During the past twenty-five years we have seen considerable exploration for oil on the plains of southern and east-central Alberta. This exploration has to some extent gone on in cycles, with periodic starts, stops, and occasionally some reversals. Each major attempt is usually supplemented by the application of some new method of exploration and, following each period of exploration, drilling tests are made. Whereas oil-bearing horizons are the ultimate objective of these explorations, the preliminary investigation frequently aims at a discovery of structure based on the long accepted belief that accumulations of oil and gas are to a marked degree structurally controlled. At the inception of this general exploration for oil, it was natural that attention should be directed to areas where there was surface evidence of deformation of the underlying strata, but, as the programme progressed, it was found that these surface manifestations of structure were often deceptive when attempts were made to project them to depth, to involve the deeper strata. Drilling of test wells was the only satisfactory method of obtaining exact information.

Jan 1, 1946

By T. Junne, L. Eltrop, S. Moreno-Leiva, J. Haas, W. Kracht

The energy systems of the future will be highly renewable. The flexibility that is consequently required can be provided with many options, the main ones being energy storage, transmission reinforcement, and demand side management. The role of the latter is explored for the copper industry, using the scheduling of maintenance services as an example of Solar-Paced Design - the coupling of energy demand with solar resource availability. We used a linear energy optimization model to define the minimum-cost configuration for a fully renewable energy system of a copper concentration plant under different scenarios for the scheduling of maintenance services. For the case we studied, (total) costs were 4% lower when the maintenance was scheduled in winter. We expect that exploring the potential of such Solar-Paced Design in the copper industry will allow new potentials for a more cost-effective full renewable energy supply of this critical industry. INTRODUCTION The mitigation of climate change requires a worldwide transformation of the energy system by the significant expansion of renewable energies and the electrification of various sectors and processes (Teske et al., 2015)(International Energy Agency IEA, 2018). Moreover, considering the decreasing costs of renewable energy technologies and the intensive use required to deliver the goals in the Paris Agreement, we can expect to have highly renewable energy systems in the near future. However, to rebuild and expand our energy systems, we need certain materials, including copper. Also, energy systems based on renewables are more copper-intensive than conventional ones (Kleijn, van der Voet, Kramer, van Oers, & van der Giesen, 2011). The mineral industry, in turn, needs clean energy to achieve a better environmental performance (e.g. solar energy for copper production (Moreno-Leiva et al., 2017)) and to avoid negative secondary effects induced by the strong expansion of clean technologies. But there is something else the minerals industry can offer in this bi-directional relation with energy systems.

Jan 1, 2019

By D. Laguitton, D. Cimon

"BILMAT is one of the most powerful algorithms in existence for material balance computation in mineral processing flowsheets. It is based on a hierarchical decomposition coupled with the Lagrange multipliers method widely reported in the literature. Flowrates can be calculated optionally for pulp, solid or water. Assays are adjusted for a variety of subnetworks, such as assays of the solid as well as assays of fractions of the solid called level 4 data (l: pulp, 2:solid and water, 3:assays of solid, 4:assays of classes of solid).BILMAT4 is a new implementation of BIU1AT that operates in a new microcomputer environment and makes the method more accessible than ever. Its main features are a full-screen colour editor allowing graphic flowsheet drawing and data entry with automatic error checking. Mass balance equations are automatically generated by analysis of the graphics and corresponding data, thus relieving users from the error-prone definition of networks. Sensitivity analysis is performed to assess confidence intervals of computed flowrates and adjusted assays.BILMAT4 incorporates an option for gold leaching circuits where the element to be balanced appears in both the solid and liquid phases with negligible effect on the mass flows of solids. Recoveries are computed in all streams. This program is currently released by CANMET as part of the CAMP collection for Computer Aided Mineral Processing. A complete sample run of the program is discussed."

Jan 1, 1989

By M. R. Henzinger, W. Schubert

"The quality of the backfill applied at a shield driven tunnel is of significant importance failure of the lining. The used material also affects the interplay between support and excavation behaviour.In this research the state of the actual bedding situation is investigated by an analytical approach, laboratory tests and numerical simulations. The numerical simulation using continuum methods have shown shortcomings. These shortcomings regarding the instability of large strain simulations restrict the possibility to reproduce the relocation of the backfilling material. The performed scaled model tests have shown that the regripping process of a double shielded tunnel boring machine affects the soil failure within the gap. With the analytical results the influence of the wall friction can be predicted. Therefore the angle of the failure surface can be determined. The results have shown that the wall friction significantly increases the failure angle. INTRODUCTIONFor tunnel boring machines (TBM) with single (SM) or double (DSM) shield, precast liningsegments are used as rock support. These segmental linings are installed within the protection of the TBM shield. In order to reduce the friction while advancing, the shield diameter is smaller than the diameter of the cutter head and therefore also smaller than the excavation boundary. The difference depends on the expected radial convergences. Since the lining segments are mounted within the shield the steering gap between the shield and the excavation boundary increases and is hereinafter called annular gap.In the process of tunneling in hard rock, the annular gap is usually filled with fine grained and closely graded gravel, termed as pea gravel. The backfilling process starts as soon as possible after the shield tail passes the lining. Due to the operational procedure within the working area of a TBM, a fully backfilled annular gap might not be established after every ring closure. This leads to an unfavorable distribution of the pea gravel leaving the segmental lining partially without bedding. Segmental linings can develop sufficient resistance only when properly bedded."

Jan 1, 2015

By Masaru Kato

The plated gold being used by the electronics industry can be broadly classified into two categories: soft gold and hard gold. Soft gold is used for circuit metallization and for bonding semiconductor chips, while hard gold is indispensable as the contact material on electrical connectors, electromechanical relays, and printed circuit boards. The traditional baths from which to plate soft gold as well as hard gold contain the cyanide complex, [Au(CN)2]-, as the source of gold, which liberates free cyanide ions during the plating. The free cyanide is not only highly toxic but also attacks photoresists used to delineate circuit patterns and bonding pads. For these reasons, non-cyanide baths are in use to plate soft gold, whereas hard gold can be plated only from cyanide baths at present. In this presentation, the current status of both electrolytic and electroless non-cyanide processes for plating soft gold will be reviewed.

Oct 1, 2003

By F. Parada L

Two copper concentrate with medium and high enargite content were leached in a 3 L autoclave reactor under conditions based on the CESL process. Copper, arsenic, sulfur and iron were checked in all the experiments and antimony, zinc and molybdenum were evaluated in selected tests. The 98% of the obtained copper extraction is agree with others authors, but the behavior of arsenic, iron an sulfur have some differences. The solid residue was characterized by chemical analysis, DRX and QEMSCAN®. Finally a comparative analysis with neutral roasting as an option for the treatment of this concentrate is done.

Jan 1, 2014

By Farzad Mohammadi, Patrick Littlejohn, David Sanguinetti

Arsenic levels in metal concentrates are increasing as mining companies turn to developing low grade and complex ores. When arsenic bearing minerals are smelted, arsenic deports as gases which must be neutralized by a scrubber system. The resulting scrubber effluent is high in dissolved arsenic and requires treatment before the wastewater can be discharged or re-used. Conventional arsenic removal relies on lime addition followed by calcium arsenate formation and precipitation as hydroxides. As an alternative, arsenic removal with sulphide precipitation is receiving more attention due to potential advantages of the technology. Process streams high in arsenic often contain concentrations of dissolved metals that may be selectively recovered during sulphidization, producing a product that can be reprocessed and reducing waste generation. This paper will review laboratory testing completed for arsenic removal through sulphide addition and precipitation of arsenic (III) sulphide in combination with metals recovery to offset arsenic removal costs.

Jan 1, 2014

By D. T. Smith, S. J. Strohmayr

Originally developed as a step change in ultrafine grinding efficiency, the IsaMill™ has made inroads into conventional ball mill and tower mill mainstream grinding duties during the last 5 years - beginning with the Anglo Platinum mainstream grinding projects in South Africa. At the 2006 SAG Conference, plant testwork on the incorporation of IsaMill™ technology into the McArthur River (Northern Territory, Australia) Pb/Zn primary grinding circuit was reported. The IsaMill™ has now become an integral component of that circuit, treating up to 1mm top size feed and directly producing P80 45 µm rougher flotation feed. Two 1.1 MW IsaMills™ are now used in this duty contributing to a 27% increase in overall plant throughput and a reduction in rougher feed size distribution. In this paper, we report on the current state of development and performance of the IsaMill™ in the primary grinding duty at McArthur River and also consider future directions.

Jan 1, 2012

By Emilie Williams

The Mouska Mine uses primarily shrinkage mining to extract the narrow veins that contain its mineralization. Mining is currently occurring on levels 12 to 14, reaching depths of 800 m below surface. Although the mine is not considered ?deep?, no backfill is available to fill empty stopes and certain areas remain open for over 500 m in height. As only narrow sill pillars remain to separate the levels, a highstress environment is created. Seismic activity was first observed when mining reached Level 11 (600 m deep) and has steadily increased since then. Seismic activity is associated with the highly-stressed sill and rib pillars; no geological structures have demonstrated significant seismic potential to date. In response to this increase in activity, pillar dimensions have been increased with depth and dynamic ground support has been installed. Seismic and pressure monitoring have been implemented, among other types of instrumentation. The following paper further describes the challenges associated with using conventional methods in the high-stress environment typical of the Canadian Shield, as well as several solutions implemented to mitigate these risks.

Feb 1, 2008

"The Kidd Creek concentrator is situated adjacent to Highway 101, twenty-four kilometres east of the center of the city of Timmins, Ontario. Sulphide ore, received by train from the minesite twenty-nine kilometres away, is processed at a rate of twelve thousand metric tonnes per day. Saleable concentrates of copper, zinc, lead and tin are produced.The concentrator contains secondary crushing, grinding, flotation, gravity separation and concentrate handling facilities. The total concentrator manpower complement is one hundred and sixty-four which includes supervision and operating personnel. Twenty-one shift personnel are required to operate the processes involved and they occupy fifteen different operating positions in addition to that of the supervisor. These positions include:1 Central Control Operatorl Metallurgical Leader1 Dryer Control Operatorl Crusher Leader3 Copper-Lead-Zinc Flotation Circuit Operators1 Pyrite Flotation Circuit Operator1 Tin Plant Operator2 Grinding Operators1 Concentrate Operator2 Crusher Operators1 Spare Operator1 Tailings Area Operator1 Automatic Sample System Operator1 Dryer Area Helper1 Crusher Helper1 Tin Plant Helper"

Jan 1, 1981

By R. C. Urquhart

Since the first use of the electric arc furnace Henri Moissan (1892) and its use by Paul Hérholdt (1902) to melt steel, it has been successfully used as a pyrometallurgical smelting tool in the production of calcium carbide, iron, ferrous and non-ferrous alloys. Commercial forms of the electric arc furnace have evolved from round, single-phase single electrode units to rectangular three electrode three-phase units to round three electrode three phase units and ultimately to rectangular six electrode three-phase units. DC electrical supply has also been used to replace the three phase power supplies in some cases. This paper examines how these electric arc smelting furnaces have evolved in size, efficiency and configuration within the constraints of the smelting process, electrodes and electrical power supply equipment.

Jan 1, 2014