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By R. Harris

The vacuum thermal route for magnesium production today accounts for roughly 80% of the global production of magnesium despite significant investment in the competing electrolytic technologies, This is up from 30% of the global production 10 years ago and is all the more significant because global magnesium production has more than doubled in the same time, A review of the sophisticated anhydrous magnesium chloride production technologies provides some explanation for this sea change in technology usage, However, an examination of the economic factors provides compelling reasons, The present review outlines some of the salient strengths and weaknesses of the competing technologies, It also offers suggestion as to where future R and D and economic effort needs to be vested to improve the sustainability of the world magnesium market in terms of its value and impact.

Jan 1, 2006

By Laxman M. Amaratunga, David N. Yaschyshyn

"In the mining industry several types of fills are used for backfill operations. They are broadly categorized into three basic types: rock fill, hydraulic/slurry fill, and paste fill. Recently, paste fill has become the popular alternative for backfilling because of its many environmental and operational advantages including its ability to use total tailings, both fine and coarse fractions.Amaratunga and Annor (1989) first presented the concept of agglomeration of fine tailings, which are otherwise excluded from backfilling, for utilization in backfill as a readily available supplementary fill material. Previous experimental work investigated the use of agglomerated fine gold mill tailings in low density slurry fills (60 -70% pulp density), consisting of varying agglomerate and tailings compositions.This paper presents the ongoing research into utilizing these agglomerates in a high density paste fill (70 -85% pulp density). Various binder dosages, curing period and combinations of pellet to tailings ratios were studied. Slump of the raw fill and compressive strength of the cured fill were examined. Results from the above study indicate that agglomerated tailings paste fill (ATPF) has superior strength characteristics when compared to total tailings paste fills.IntroductionThe Canadian mining industry produces more than 500 million tonnes of tailings and waste rock annually. These tailings consist of a coarse fraction and a fine fraction and can be either reactive (acid generating) or non-reactive. Most mining operations utilize the coarse fraction for backfilling while the fines have been traditionally disposed of in surface tailings ponds. Recently, paste fill has been developed which uses a fraction of the fine tailings (10 - 30% w/w of >45 µ,m) in the fill. This development allows a mining company to use a portion of the fines for backfill, but still requires surface impoundment of the unused portion of fine tailings. Reactive tailings have the added problem of generating acid after being oxidized in the presence of air and water. Treating acid mine drainage (AMD) seepage from these ponds has proven to be a costly environmental problem and long term liabilty.One practical method to reduce the environmental impacts associated with the tailings pond and to modify the physical and chemical properties of the fine mill tailings so that they can be utilized and disposed of in an environmentally safe manner through surface or underground applications is through agglomeration using the Cold-Bond Tailings Agglomeration technology (CBTA). Amaratunga and Annor (1989) first presented the concept of agglomeration of fine tailings for use as coarse aggregates for underground backfill, gravel or surface covering material. CBT A reduces the necessity of impounding tailings on surface while providing a suitable coarse aggregate resource material for practical use. Although the CBT A technology has been mainly limited to pelletization agglomeration alone, other forms of agglomeration like pressure agglomeration which include the techniques of briquetting and extrusion have also proven successful (Amaratunga, 1995)."

Jan 1, 1996

By Z. D. Hora

Sev_eral dozen si lica occurrences have been reported from various parts of Brit ish Columbia. Some represent hydrothermal veins or parts of pegmatite bodies; other are recrystall ized sandstones. Several vein type deposits were mined for smelter flux and as a source of white chips for stucco dash and simi lar products. Some quartzites were studied as potential sources of high-grade silica for ferrosilicon and silicon metal production. The province's only production of silica for ferrosilicon has come from a pegmatitic quartz plug near Oliver in southern British Columbia. Its reserves are now practically depleted.

Jan 1, 1984

By R. O. Burt, R. W. Bruce

"IntroductionGravity concentration, the separation of two or more minerals due to the difference in their relative specific gravity and usually in a fluid medium, is the oldest recorded form of mineral processing.The principles of gravity concentration were known to, and practiced by, the ancients and Hoover's commentary to De Re Meta/lied'' notes many early references.Over the centuries, as direct smelting ores became more and more uncommon, the mineral processing industry developed and along with it many varied methods of concentration. Gravity concentration declined rapidly in importance in the early twentieth century, and it is only in the last decade that its advantages are being re-evaluated.A significant proportion of ores are processed by gravity; a large proportion being in the iron and coal industries<'>, or in the treatment at very high volume of relatively coarse alluvial deposits. The tin dredges of South East Asia and Beach sand plants of Australia are prime examples.An indication of the broad application of gravity concentration is the variety of minerals presently recovered. A list is given in Table 1; this list is not exhaustive.Principle of Gravity ConcentrationGravity concentration methods separate minerals of different specific gravity by their relative movement in response to gravity and one or more other forces, the latter often being the resistance to motion offered by a viscous fluid, such as water or air.The relative movement of minerals to one another is achieved by a variety of methods. These are: separation in a fluid of intermediate density (heavy media separation); by stratification (such as in jigging); in a flowing fluid (cones, spirals, sluices etc.) and with a horizontal shear (shaking tables etc.)."

Jan 1, 1989

By L Thompson, R C. West, T S. Kho

In 1978, the Outotec direct to blister flash (DBF) smelting process was commercialized with the commissioning of the Glogow 2 smelting facility in Poland. Since then four further DBF facilities have been constructed, two at Olympic Dam, one in Zambia and most recently one at Glogow 1 in Poland. The DBF smelting process differs considerably from conventional smelting process in both chemistry and unit operations, presenting opportunities for flowsheet capital and operating cost savings particularly when the concentrate copper grade is high. WorleyParsons has amassed considerable expertise in the Direct to Blister process and in this paper the process is compared to the modern two stage Double Flash process. The processes are modeled, and the key operating parameters, consumables and production metrics are directly compared. Subsequent flowsheets, key equipment lists and capital costs are also presented for comparison and discussion. The results show the range of concentrates which are most economically treated by the DBF process relative to those best treated in conventional processes along with those concentrates which could be treated by either process. INTRODUCTION The Outotec Direct to Blister (DBF) process was developed and installed at Glogow in 1978 (Czernecki et al., 2006). Currently there are a total of five DBFs built on three sites: Glogow No.2, Olympic Dam No.1, Olympic Dam No.2, KCM Zambia and Glogow No.1, being the most recently constructed. The DBF process was the first flash furnace process to produce blister copper and paved the way for the subsequent development of the flash converter and other continuous converting processes. Today four flash converters are in operation taking the total number of flash furnaces producing blister copper to eight. In all DBF operations it is the unique ore and concentrate composition which made selection of the DBF process the most attractive. In all cases, the concentrate is relatively high in copper but low in iron because chalcopyrite is not the major constituent. When considering smelting options for high copper, low iron concentrates a key question is then often asked, “At what point does it become economic to switch from two stage smelting and converting process to the DBF process?”

Jan 1, 2019

By Dennis L. Murr, James E. Wennen

"The through-put and energy efficiency of an autogenous (AG) grinding mill are adversely affected by variability in rock size and rock competency. This applies to both fully autogenous and semi-autogenous (SAG) grinding circuits. In this paper we focus on an approach to overcome the problem of inconsistent mill through-put related to variability in mill feed size and rock competency. The focus is on ores containing hard, competent rock. This approach consists of preparing feed to an autogenous mill that contains 20% coarse media rock and 80% of material crushed to pass 37 mm. Results of pilot-scale testing for two iron-ores will be presented to show that a 10% to 12% reduction in unit energy consumption is possible with prepared feed, compared with feeding the mill with conventional primary crusher discharge.INTRODUCTIONIn the past 30 years or so, autogenous grinding and semi-autogenous grinding have been the comminution technologies of choice for most mining and mineral processing operations. These technologies saved both capital and operating expenses associated with the installation and operation of multi-stage crushing and screening plants required for conventional rod mill – ball mill circuits. However, SAG and AG are inherently inefficient in terms of energy consumption, especially for very hard ores. In cases of hard ore, changing characteristics of rock fed to the mills causes wide fluctuations in mill capacity, which contributes to the inefficiency. Rising electric power costs make this the most expensive unit operation used in the extraction of valuable minerals from an ore. The objective of the concept discussed here is to reduce the energy consumption in AG grinding for hard ore and eliminate the use of large-diameter steel grinding balls that are required for SAG grinding"

Jan 1, 2012

By Jean Fortin

In order to remain competitive, the search for excellence has been and will remain the only viable option facing the Mount-Wright operations. Safety and environment, process and technology as well as cost performance have been the focus points on which the operations have concentrated their efforts in order to meet and exceed our company&apos;s "Vision 2000" plan. Some of our mine&apos;s accomplishments have been a new work organization, a world class maintenance and a new collective agreement. The concentrator, maintenance and production departments have evaluated their processes and implemented various improvements in areas such as power supply, dewatering, blasting, implementation of service centers for large and small vehicles, fleet standardization, crusher, mills and silos improvements... etc. Safety and work environment for personnel have been our driving force in order to achieve this plan.

May 1, 2003

By M. P. Amsden

"Ecstall Mining Limited, a subsidiary of Texasgulf, Inc., Operates the Kidd Creek Mine, Concentrator and Zinc Plant at Timmins, Ontario. Two different ore types are mined and milled to produce concentrates of copper, zinc, lead and tin. The ores are processed at the Concentrator in three separate individual milling circuits, each with the capacity to treat up to 3500 tons per day. Two circuits treat copper-zinc ore 1t an average combined rate of 6500 tons per day and the third circuit treats 3500 tons per day of silver-lead zinc ore. Conventional crushing, grinding and flotation procedures are followed. The purpose of this paper is to describe Ecstall's experience with rubber mill linings in the grinding circuits.CrushingBoth ores are crushed to minus 6 inches at the Mine and delivered by rail to the Concentrator where they are reduced by secondary and tertiary crushing to minus 5/8 inch.GrindingThe crushed ores are prepared for selective flotation by grinding with rod mills and two stages of ball milling. flotation circuit middling products are reground in regrind mills prior to further treatment. A typical flowsheet of one of the grinding circuits is shown in Figure 1.All the grinding units are Allis-Chalmers Mills. The rod mills are 10 1/2 feet diameter by 16 feet long. Both the primary and secondary ball mills are 12 feet diameter by 18 feet long and all regrind mills are 6 feet diameter by 12 feet long. The primary mills are charged with 1 13/16 inch forged balls. Secondary mills are charged with 1 1/2 inch forged balls and the regrind mills are charged with 1 inch forged balls. All cyclones are Kreb units. The primary cyclones are Dl5B hydrocyclones, the secondary cyclones are D6B hydrocyclones and all regrind cyclones are D6B hydrocyclones."

Jan 1, 1974

By M. Falutsu

"The PSI-200 is a rugged, innovative, and easy to install on-stream size analyzer. Its calibration is simple and can be done on-line, during operation. Two measurements are displayed on the panel, which are expressed as percent passing a selected size, or as any statistical diameter. These two measurements are given as two continuous 4-20 mA output signals. Operation alarms are displayed on the screen or are given as digital output signals.The PSI-200 has been used in various applications at Lakefield Research. Particle sizes ranging from 10 µm to 450 µm have been monitored successfully, with an accuracy of 1- 2%. Having the size measured continuously and reliably, optimum conditions have been established for the grinding circuit, resulting in a superior quality in pilot plant testing.INTRODUCTIONThe challenge of any operating plant is to optimize product quality, maximize throughput and minimize operating costs. The importance of particle size measurement at a grinding circuit is well recognized. Monitoring continuously the particle size and keeping the product as uniform as possible is crucial to the whole mill operation regardless of the nature of the operation.Various techniques and instruments have been developed over the years attempting to give reliable on-line size analysis data. The operating difficulties and the reliability of these equipment still present major drawbacks and none of them proved to be widely accepted.PSI-200 is a relatively new on-line analyzer. The operation is simple and of low cost and the maintenance required minimal. It measures particle size and it displays two parameters of the solids size distribution, either weight fraction of passing a certain size or any statistical diameter. Two analog outputs can be sent to a process control system and through a supervisory control loop the correct action can be taken to maintain the desired particle size (perhaps adjust the feed rate to the grinding mill)."

Jan 1, 1993

By H. J. Meyer

"A hydrostatic elevation difference meter has been developed for use in measuring elevations along gravity traverses. Elevations of stations 100 feet apart can be obtained at a rate of 1/2 mile per hour and to an accuracy better than 1/3 foot. This can be done along traverses which have not been cut and chained. The instrument is durable, lightweight and constructed of materials which will withstand any temperature encountered in field work.It is believed that this device will more than double the rate at which gravity surveys over mining prospects can be carried out."

Jan 1, 1972

By Tommee Larochelle, Henry Kasaini

"Simulation of rare earth element solvent extraction processes for plant design and optimization is complex, requires extensive bench scale and pilot scale testing, and is traditionally performed using proprietary algorithms. The complexity of simulation is mainly due to traditional simulation software solvent extraction modules not being designed to simulate rare earth separation processes because of the interaction between each element. This paper presents an alternative method for designing and optimizing rare earth element solvent extraction separation processes using METSIM to converge each stage of the battery individually until the full battery reached ultimate convergence. A feed-forward controller is used to control the organic to aqueous flow ratio feeding the solvent extraction modules. This method minimizes the complexity of simulating such processes by using inexpensive batch solvent extraction data, and allowing for rapid theoretical optimization, by varying the process configuration and parameters from a graphic interface instead of the traditional code-based interface of most proprietary models. Comparison of the model predictions to pilot plant data reveals that the method can be used to accurately model rare earth solvent extraction processes, as illustrated by its application in the development of Rare Element Resources innovative process.INTRODUCTIONThe Rare Earth Elements (REEs) consist of 16 metals, specifically the 15 lanthanide elements and yttrium, which is typically found in the same mineral deposits as the lanthanides. Scandium can be associated with the rare earth elements, but is usually only present in trace amounts, and therefore omitted. The term “rare earths” originates from an old term used to designate minerals (earths) and their believed scarcity upon their initial discovery. The rare earths designation is now considered a misnomer because it was demonstrated that the crustal abundance of some rare earth elements, such as cerium, is known to be higher than many common metals, such as copper. However, enriched deposits are fairly uncommon compared to other similarly abundant metals. The REEs are typically divided into groups commonly consisting of light rare earths (LREEs), medium rare earths (MREE), and heavy rare earths (HREEs). Light rare earth elements include lanthanum to neodymium, medium rare earths include samarium to gadolinium and the heavy rare earth elements include terbium to lutetium, and yttrium. The REEs exhibit similar chemical characteristics and are usually extracted from the ore and processed into a mixed rare earth concentrate. The rare earth concentrate requires further processing in order to separate the REEs from each other and produce a series of single element products."

Jan 1, 2016

By V. Ogarlaci

Over 90% of the Romania&apos;s lignite reserve is located in the region of Oltenia, which is why this area is given special attention in the country&apos;s coal resources. Because the lignite deposit of Oltenia is comprised of 1-8 exploitable coal layers, their capitalizing calls for urgent arrangements to ensure rational exploitation under conditions of total safety, minimum losses and efficiency. The technology used the coal pits of North-Western Oltenia is the technology of excavation, transport and dumping in a continuous flow by using the complexes of excavation, transport and high-capacity dumping. The theme of this paper is of particular importance because the rhythmic operation in complete safety, is necessary both for sizing and keeping within the bounds of acceptable values, throughout the process of excavation of the geometric elements of the coal faces, marked by: the height of benches, slope angle and width of berms. Geometric dimensions of the benches of the open pits, the height of benches, slope angle and width of berms shall be calculated and shall be based on: the massif structure that forms the benches; physical-mechanical characteristics of rocks from the bench; working conditions, characterized mainly by mining and extraction methods applied; functional parameters of the mechanical equipment used to perform various operations on the coal face etc. For this study it was necessary a broad field for task tracking, measurement, research and design elements of the coal face, for land survey and a desk activity by: processing of topographic data, laboratory analyses on physical and mechanical properties of rocks and numerous specialized studies. In the final part, we bring some contributions to elucidating the issues of special importance for the lignite coal pits of Oltenia, coming up with data, graphics, formulas, solutions and concrete dimensioning of coal faces in terms of using technology in a continuous flow.

Aug 1, 2013

By G. Vibert Douglas

IN a previous paper by Douglas and Gillies (1), a simple field test was given for gold. Later work by the present writers, and by others who have kindly written to us, shows that the test is not as satisfactory as it was hoped. In many cases, the gold mirror is completely obscured by a dense precipitate which, up to the present, it has been found impossible to remove. After many attempts, we have temporarily given up the iodine test and have been working on a simple pyridine reaction based on the work of Putnam, Roberts, and Selchow (2): The ore to be tested is ground to a fine flour. Place half a gram of this powdered ore (an amount that will cover a Canadian ten-cent piece, not heaped) in a six-inch test-tube and add 5 c.c. of aqua regia. The aqua regia. should be made up on each occasion, using four parts of hydrochloric acid and one part of nitric acid, both concentrated. Shake the solution in the test-tube for about one minute and allow to settle until dear. The rime to settle may be 30 to 60 minutes. When dear, a drop of the solution is with-drawn with a fine, dean eye-dropper or capillary tube and placed on à small glass plate. A slide such as is used for mounting rock sections is suitable. Now place an equal sized drop of pyridine solution on the plate beside that of the aqua regia solution to be tested. The pyridine solution, containing nine volumes of hydrogen bromide to one volume of pyridine, can be made up in advance and carried in a glass-stoppered bottle. Join the two drops with a glass thread or fine, dean stick, and allow the merged drops to stand undisturbed. I t is well to place the slide on a piece of white paper so that the presence of the crystals which may form can be easily seen. The time for their formation will vary with the amount of gold present, but the slide should be allowed to stand for at least 30 minutes before negative results are reported. A hand lens of at !east ten magnifications is essential. If gold is present, minute red crystals will form around the margin of the drops as these drops slowly evaporate.

Jan 1, 1938

By W. T. Boyes, J. M. Harrison

"Squall Lake Gold Mines, Limited, owns a group of claims at Squall lake, northern Manitoba, about 75 miles east of Flin Flon and 3 to 4 miles north of the Nor-Acme mine at Snow lake. Gold mineralization was discovered in this locality several years prior to 1944, but it was only in that year that a comprehensive examination of the occurrences was begun. Development work to the end of 1946 has been encouraging and the deposits show interesting relations to rock structure.GEOLOGICAL SETTINGThe gold occurs in a sill of biotite-hornblende diorite at or near its contact with gneisses derived from arkosic sediments . In detail, the contact between the diorite and the arkose to the southeast of it is irregular, with interfingering of the two rock types. On the northwest side of the sill, between it and Squall lake, the rock is staurolite schist (see accompanying sketch-map).Several mineralized shear zones are known, of which those shown are the most important. Within the zones, the diorite is silicified and somewhat carbonatized. Fairly coarse arsenopyrite is the chief sulphide mineral in these zones but, locally, they contain also pyrite and pyrrhotite. Where quartz and chlorite are present, rather coarse gold is associated with them. In that part of the main zone where gold assays have been most consistent, the diorite is rich in albite."

Jan 1, 1954

By Anthony T. Eyton

Intelligent Systems: Advantages for Mining ? Increased safety (reduced risk to workers) ? Increased productivity (reduced downtime) ? Reduced maintenance costs ? Customized solutions for different mines ? Growing acceptance among mine managers A Typical Precarn Project ? Meets definition of intelligent systems ? Involves at least two Precarn members ? a technology developer partner and a user partner ? in a true collaboration ? Involves at least one university and may have various other players ? Leads to a demonstrated prototype ? Costs $2-4 million, and lasts 12-30 months ? Gets up to 40% of its funding from Precarn (max. $1 m) ? Produces new intellectual property -- owned by the project team

May 1, 2002

By Ana Adé

The use of gold compounds in homogeneous catalysed organic reactions has been undervalued for many years due to the preconceived opinion that gold is an expensive and extremely chemically inert metal. However, recent reports have changed this assessment and gold salts in small amounts are known to display high catalytic activity.[1] Thus, it has been reported recently that anhydrous AuCl3 catalyses the formation of C-C and C-O bonds (usually mediated by hydrochloric and other protonic and Lewis acids).[2] Some examples include Michael type additions, selective cross cycloisomerisation/dimerisation of propargyl or allenyl ketones, benzannulation between o-alkynylbenzaldehides and alkynes or cyclisation of alkenyl furans. It is noteworthy that some of these reactions[2a] can be also catalysed by silver salts but with much lower yields. The 1,3-dipolar cycloaddition of nitrones to alkenes is a powerful synthetic method that has found numerous applications in the synthesis of a variety of carbon frameworks.[3] Several laboratories have focused on the development of Lewis acidic reagents to modulate the selectivity of the reaction.[4] Despite the extensive study performed, there are not many examples in which a metallic complex catalyses the dipolar cycloaddition. Most of these reactions require the presence of a metallic complex and nitrone in a 1:1 molar ratio. Recently, we have carried out stoichiometric reactions of the N-benzil-C(2-pyridil)nitrone, 1, with different dipolarophiles in the presence of zinc and silver compounds.[5] Apart from an increase of the reaction rate and the selective formation of one of the possible isomers, we have shown the formation of zinc and silver-nitrone complexes during the reaction, which behave as the intermediates in the cycloaddition process. As suggested by the results obtained with silver complexes, we decided to test gold derivatives (in the oxidation states of I and III). Interestingly, we have found that they can be used not only as stoichiometric reagents but they can also mediate these cycloadditions in catalytic amounts (5 to 10 mol % respect to the nitrone). Here we present the results on the 1,3-dipolar cycloaddition reaction of the N-benzil-C(2-pyridil)nitrone (2-PyBN), 1, and methylacrilate, 2, (Eq. 1) catalysed by gold(III) derivatives.

Oct 1, 2003

By Elisabeth Kolar, Rik Catthoor, Frederik H. Kriel, Rossen Sedev, Gareth Hatch, Army Research Laboratory, Craig Priest, Scott Middlemas

"This paper reports solvent extraction of rare earth elements (REEs) carried out using a microfluidic device and considers the REE loading limit of the organic phase under laminar flow. The microfluidic device contacts aqueous and organic phase streams for a precisely defined contact time (subsecond resolution) and then separates them for offline analysis. Experiments are reported examining the effect of contact time on extraction. We focus on three REEs: one ‘light’ (Nd), one ‘mid’ (Dy), and one ‘heavy’ (Yb) REE, which are extracted using Cyanex® 572. It appears that loading limits may be locally exceeded in the organic phase near to the liquid-liquid interface, where third phase deposits are observed. Third phase formation was also observed close to the liquid-liquid interface in two-dimensional confinement, showing similar third phase adsorption on glass plates. It is also shown that, under microfluidic flow, a typical first ‘split’ between heavy REEs and light REEs can be carried out without exceeding loading limits.INTRODUCTIONMicrofluidic solvent extraction has emerged as a useful tool for studying extraction of metals in a mineral processing context (Ciceri, Mason, Harvie, Perera, & Stevens, 2013; Ciceri, Perera, & Stevens, 2011; Kriel et al., 2015; Mason, Ciceri, Harvie, Perera, & Stevens, 2013; Priest, Zhou, Klink, Sedev, & Ralston, 2012; Priest et al., 2011). The main advantages are the extremely well-defined and tunable flow behaviour, large surface-to-volume ratios, short contact times, and minimisation of sample and reagent amounts. Two main flow configurations have been studied to date: droplet-based and co-flowing streambased extraction. In the former, droplets are formed at a microchannel junction (usually a T-junction or flow-focusing junction) and flow downstream as plugs or ‘free’ droplets. In our case, stream-based extraction, the chip is a plate (often glass) with embedded microchannels (i.e. with cross-sections of tens of micrometres) that carry the aqueous and organic phases in contact without forming droplets. Thus, these chips play the role of a mixer in a conventional mixer-settler and phase separation takes place by branching the streams or collection in a vessel at the chip outlet. Stream-based extraction requires stable streams that are usually supported by a particular channel geometry (e.g. guide structure or small ‘pillars’) or surface chemistry, and flow parallel bounded by the liquid-liquid interface(Aota, Nonaka, Hibara, & Kitamori, 2006; Hibara et al., 2005; Hibara et al., 2002). Phases are disengaged downstream at a Y-junction, which is a qualitative difference between microfluidic and bulk extractions."

Jan 1, 2016

By A. Kishimoto, Yoshida Honmachi, T. Uda, Y. Taninouchi

Recycling of e-scrap is often performed by utilizing a pyrometallurgical Cu smelting process. Several valuable metals, including precious metals, can be efficiently recovered through the Cu smelting process. However, recovery of Sn is quite difficult because it is distributed in slag during the smelting process. Sn is used as solder and plating in electronic devices, and its recycling will be more important in the future. In light of this background, a pretreatment process that can extract Sn directly and selectively from e-scrap was developed in this study. The proposed Sn extraction process involves alkaline leaching using iodate ions, IO 3, as an oxidizing agent. We conducted leaching experiments for Sn, Sn-Ag-Cu alloy solder, and Cu, and the effective dissolution of Sn was confirmed. In principle, the electrodeposition of Sn from the leach solution and regeneration of IO3 are possible by a subsequent electrolysis process. The results obtained in this study suggest that the proposed leaching process can be an effective and useful pretreatment for Cu-smelting-based e-scrap recycling. INTRODUCTION Electronic scrap (e-scrap), including waste printed circuit boards (PCBs), is one of the fastest growing waste treatment streams in the global urban environment. E-scrap contains numerous valuable metallic elements, including Cu, Sn, and precious metals, in rich quantity. Furthermore, some metals and other materials contained in e- scrap are hazardous to human health and the environment when they are not properly managed. The recycling of e- scrap is therefore a major concern in terms of resource supply and waste treatment, and it has been performed by many companies using a variety of methods.

Jan 1, 2019

By J. D. Templeton

A petroleum well that is not in use because it has ceased to produce oil/gas economically and dry holes are referred to as abandoned wells. Once a well is abandoned it is plugged with cement and can take anywhere from two days up to a week to cure depending on the number of plugs in the well. Since plugging a well costs capital, most wells are abandoned at the lowest possible cost and with the minimum obligations set by regulation agencies. These wells can present an enduring liability to petroleum companies. However, the depth and abundance of abandoned petroleum wells makes them an economically attractive source of geothermal energy. Geothermal energy harvested from an oil/gas well is a renewable energy source as long as it is extracted in a sustainable manner. The energy can be used to generate electricity, used directly for heating, incorporated into a water desalination process, or used by a heat pump for heating/cooling applications. In this paper we examine the possibility of extracting geothermal energy from abandoned oil/gas wells by studying the heat transfer in underground geothermal heat exchangers installed in these wells. The design configurations for the geothermal heat exchangers embedded inside a petroleum borehole can be a u-tube design or a shell and tube design (i.e. double pipe). Using in-situ gathered information from some representative petroleum boreholes, the effects of key parameters such as geothermal gradient, ground temperature values, and the flow inside of the tubes are evaluated. In order to provide a constant power production the inlet temperature can be adjusted to keep the difference between outlet and inlet temperatures equivalent. Higher differences between inflow and outflow temperatures will result in a less sustainable load put on the in-situ geothermal energy. Adding insulation to certain sections of the designs can minimize the transfer of thermal energy from the fluid to the surroundings. Insulation can also limit the thermal loss between the inflow and outflow tubes in the shell and tube design. Minimizing the energy loss of these designs leads to an increase in the outlet temperature, meaning a higher grade of heat. The sustainability of long term geothermal heat extraction is a balance between the rate at which geothermal energy is extracted and the rate at which the ground formation can replace this heat. Higher outlet temperatures can lead to a larger amount of power generation, and a higher coefficient of performance for heat pump applications.

Aug 1, 2013

The original JKMRC AG/SAG mill model was developed over 30 years ago and has been upgraded a number of times since then, with the current published version being the Variable Rates model that is now over 15 years old. Since this model was developed further enhancements have been derived, some of which are applied in-house and some which have yet to be incorporated. The published and the commercially available model in JKSimMet is currently undergoing a comprehensive overhaul with a vastly extended data base for model evolution and validation. Improvements developed within the AMIRA P9 project, in-house development and a number of collaborative projects, are being incorporated into the upgraded model structure. Enhanced capabilities will include: power-based breakage rates scaling; a far wider mill filling range (from 10% to 40%) that exhibits peak in throughput as mill filling increases; higher ball loads; improved pebble discharge function; improved slurry discharge function incorporating important mill design and operational influences; and the new size dependent breakage function. The model will also be able to accommodate some influence of liner design and multi-component ores (blends of hard and soft components). This upgrade is still a work in progress but substantial changes have been made to date. This paper presents some of the new improvements and their influence on the predictive capability of the model.

Jan 1, 2012