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By Lina Chica, Arturo Barrientos, O. Bustamante

Hydrocyclone is a device commonly used in mineral processing industry. Underflow control plays a fundamental role in hydrocyclone operation. This affirmation supports the fact that hydrocyclone underflow has effect in some aspects of separation performance like capacity, split ratio, cut size and bypass. Hydrocyclone operation state is associated to underflow characteristics: air core formation and discharge shape. Many studies attempt to understand size separation phenomenon and the discharge influence but none of them has taken an energy point of view. This work presents the results of a mechanical energy dissipation for hydrocyclone operation from a mechanical energy balance. The experimental results related to Newtonian suspensions show that underflow energy dissipation does not control the operation because this magnitude is small compared to interior energy dissipation. However, discharge energy dissipation provides enough information to describe underflow conditions and its influence in separation conditions. In the modelling non dimensional parameters have been considered for hydrodynamic description and for geometrical and operation hydrocyclone characteristics. Energy dissipation from the continua media approximation results into a relevant concept to understand the hydrocyclone performance and improve industrial installations.

Jan 1, 2014

By Reuter M. A., R. D. van der Weijden, W. F. C. van Wageningen

"Copper(II) can be recovered or removed from acidic copper sulfate solutions as cuprite or metallic copper powder by reduction with carbohydrates. The copper powder characteristics, such as size and shape of particles, determine the tendency to adhere to reactor walls and to agglomerate. In order to make this process suitable for a commercial scale pipe reactor, process conditions and the reactor configuration were varied in order to influence the copper characteristics in a positive way. The aim was to achieve proper particle throughput in the pipe reactor and to obtain a well defined copper powder.In this paper the effect of both, chemical and physical parameters on the shape and size of particles were systematically studied in a number of autoclave experiments. These parameters include mixing, Cu(II) concentration, pH, temperature, seeding, use of additives and reactor materials. Additionally, Monte Carlo simulations of copper growth inside a Kenics static mixer were made. Results show that the use of additives and the use of static mixers influence particle characteristics the most."

Jan 1, 2003

By G. S. Hansford, G. E. Searby

"Ferrous iron oxidation kinetics was measured in continuous culture at temperatures between 65 and 75ºC, using thermophilic microbes suitable for high temperature bioleaching. The resulting specific oxidation rates were modelled as a function of the ferric/ferrous iron ratio. The results were compared to those obtained by conventional mesophilic microbes.Microbially mediated ferrous iron oxidation is a vital sub-process in the mesophilic bioleaching of sulfide minerals and is expected to be of similar importance at elevated temperatures using thermophilicmicrobes.A thermophilic archaeal culture used in chalcopyrite bioleaching was successfully grown in continuous culture on ferrous sulfate, indicating the capability of the microbes to sustain growth for long periods on the energy provided by the conversion of ferrous iron to ferric iron, the primary leaching agent in sulfide mineral bioleaching.Steady state data was obtained at residence times of between 70 and 10 hours, with washout occurring at residence times between 11 and 9 hours, corresponding to a maximum growth rate (µmax) of between 0.09 and 0.11 hr-1. The reactions were followed by measurements of the solution redox potential, soluble iron concentrations, and offgas analysis of the oxygen and carbon dioxide utilisation rates."

Jan 1, 2003

By S. Banisi, A. R. Ghasemi, M. Maleki-Moghaddam

Direct observation of the charge shape and its motion in industrial mills are not possible, it is then customary to use transparent end, small-scale mills (i.e., model mills) to determine the charge trajectory directly by visualization methods. Because of a short length of the model mills, the end-wall effects could introduce a significant bias on the observed charge trajectories and shape. The shorter the mill, the stronger the bias. This could be due to some material bridging between the end walls. In this research, the end-wall effects were investigated by gradually increasing the model mill length and analysing the charge trajectory and shape variation at a given operating conditions (i.e., ball filling, mill speed, liner type). The unbiased mill length was assumed to be beyond the mill length where no significant change observed in the charge trajectory and shape. For all tests, the torque of the charge was also measured by a torque sensor. The special design of the model mill with the diameter of 100 cm made possible to increase the mill length in steps of 3.6 cm up to 21.6 cm. Four types of liners, five steel ball fillings (10, 15, 20, 25, 30% v/v) and three mill speeds (55, 70, 85% of critical speed) were tested. The ball sizes ranged from 4 to 12 mm. The results indicated that when the mill length was below 10.8 cm the end walls prevented the charge from free falling. This resulted in lower impact point angles and lower power draws compared with the case of no end-wall effects. When the same experiments were performed using an iron ore instead of balls with the same size range, the impact of end-wall effects was more pronounced. For an increase of 30% in the speed (from 55 to 85%), the torque due the change in the charge shape decreased by 41% (from 3.7 to 2.2 kgf.m) when mill filling was 30%. At the same operating conditions when steel balls used the torque decreased only by 19% (from 9 to 7.2 kgf.m). This was expected due to irregular shapes of the ore particles which facilitated bridging. Three-dimensional DEM simulations also resulted in the similar conclusions.

Jan 1, 2014

By Anatoly Usov

The detailed researches of a broad circle of problems connected to development of the electric pulse method destruction materials (EPD) of a various nature and area of use are executed. The electrical and power characteristics of process, physical fundamentals of selectivity of a breakdown and destruction are investigated, the device of electric pulse (EP) disaggregation and ?omminution of materials are developed, the technological efficiency of disintegration of industrial minerals estimated. Due to its technological advantages, the EPD could have a great potential in minerals mining and processing technologies. Low specific power and weight-and-size characteristics of EP installations based on the existing out-of-date electric equipment are at present the main reasons hindering the effective application of the method in mining and processing technologies. The main studies carried out in Russia in the field of electro technical equipment development for EP technology are presented. The pulse capacitors service life affects greatly the economic efficiency of the process because the capacitors cost accounts for a considerable, and in some cases, the most part of the operational costs. Determined and analyzed in the study are the ways which could significantly improve the specific characteristics of high voltage pulse generators (VPG), such as to use of high-frequency voltage transformation to develop a charger; to use pulse transformers (PT) with iron magnetic circuits made of materials characterized by high magnetic permeability, in pulse generating circuits; as well as to use special ways which could produce voltage pulses with a short front. The experiments have proved the possibility to adapt these technological solutions for EP devices, and a further strategy of the EP technologies development and application has been suggested on this base. Keywords: electric pulse disaggregation, electric pulse installation, charger battery, high voltage pulse generator

Sep 1, 2012

By Ersin Yazici, Ahmet Bas, Haci Deveci

Pregnant leach solutions from waste of printed circuit boards (WPCB) leaching contain many impurity metals (Fe in particular) at significant levels. These impurities should be reduced to acceptable levels to avoid problems in downstream recovery processes e.g., low current efficiencies in electro-winning of copper from sulfate solutions in the presence of ferric. In this study, removal of iron in the form of goethite from synthetic (30 g/L Cu2+ and 1 M SO42-) and real leach solutions of WPCB was studied in some detail. The influences of initial concentration of iron (1-4.5 g/L Fe3+), pH (2.5-4.0), temperature (80-90°C) and seeding (23.5 g/L) were investigated over a period of 4 h. A significant increase in the iron precipitation was observed (i.e., from 68% to 96% over 4 h) with rising the pH from 2.5 to 4.0. The addition of seeds had also increased the removal rate over 4 h albeit to a limited extent i.e., from 96% to 99%. For the real leach solutions of sulfate (H2SO4-H2O2) and sulfate/chloride leaching (H2SO4-CuSO4-NaCl), precipitation of iron was found to be 63-73% (pH 2.5) and 93-98% (pH 4.0), respectively. The precipitates were further characterised by SEM-EDS analysis which showed the presence of copper (1-25%) in the precipitates indicating significant copper co-precipitation from the solution. These copper losses can be attributed to the formation of copper compounds such as anthlerite and brochantite within the range of pH (2.5-4.0) tested. This study showed that iron can be readily removed from synthetic/real leach solutions of WPCBs to a large extent (=93%) at the expense of high copper losses particularly at pH 4.0.

Jan 1, 2014

By Andrzej Luszczkiewicz, Alicja Bakalarz

The application of new collectors is considered to improve the beneficiation of Polish sedimentary complex copper ores from the Legnica-Glogow Copper Basin (SW Poland), the upgradeability of which becomes more difficult because of ores grade declining. One group of potential collectors is represented by nonpolar reagents. According to the available literature data, only selected sulfides float in the presence of the nonpolar liquids. The paper presents laboratory scale flotation results for the main sulfide minerals occurring in the Polish copper ores applying either thiol (potassium ethyl xanthate) or nonpolar (aqueous emulsion of n-dodecane) collectors. The investigated feed contained 1.91 % Cu in the form of sulfide minerals such as bornite, chalcopyrite, chalcocite and covellite. Other sulfide minerals including galena, pyrite and sphalerite were also present in the samples. Several flotation tests with various doses of each collector were conducted. Mineralogical analyses of flotation products were carried out and the results compared. A comparison of the results indicated that all sulfide minerals floated well with high recoveries ranging from 91 % to 99 % in the presence of the thiol collector. The use of the nonpolar collector provided results in flotation of sulfide minerals with different terminal recoveries from 61 % for chalcopyrite to 100 % for sphalerite. The most significant differences in flotation in the presence of both types of collector under various conditions of upgrading were observed for chalcocite, chalcopyrite and covellite. Similar flotation results were observed for sphalerite and galena for both collectors. The studies confirmed selective flotation of sulfides from the copper sulfide ores of the Legnica-Glogow Copper Basin in the presence of nonpolar collectors.

Jan 1, 2014

By Sebastian Fredes, Williams Calderon, Mauricio Toledo, Gonzalo Montes-Atenas

The influence of the temperature on leaching kinetics of copper-bearing minerals has been widely acknowledged: the leaching of copper oxide ores is generally described as exothermic reactions while copper sulfide ores are associated with endothermic reactions. Reports studying the influence of temperature on leaching kinetics at laboratory scale frequently involve the implementation of either fully flooded isothermal systems or jacketed column setups. Nevertheless, at industrial scale controlling or monitoring the temperature or temperature changes is almost impractical. In fact, leaching process is usually a large tonnage operation and changing the temperature of vast amounts of material would require an enormous amount of energy and highly specific heat transfer equipment. Preliminary computations on the amount of energy required to increase the temperature of a heap or dump in 1°C indicates that it would be impossible to find an energy source able to accomplish the task. In order to provide a solution to this matter it is suggested to create an energy managing protocol (EMP) that permits heat up or down the porous body locally taking advantage from the temperature gradients and from the reactivity of different regions within the material as a function of the leaching cycles. The aim of this study is to evaluate different heat transfer regimes in a 1 ton pilot column leach operation. It was found that best results of copper recovery are obtained when heating up the column in horizontal bands starting from the top of the column moving downwards as the leach cycle evolves. The system is expected to be suitable for industrial applications, but further development of the technique is required, particularly in the design of the heat transfer dispositive.

Jan 1, 2014

By Markus A. Reuter, Joep Verwoerd, Marc J. A. Pijnenborg, Yongxiang Yang

"Incineration is a proven disposal technology for all waste materials with heat release potentials, and provides high degree of toxic destruction and control for a broad range of hazardous materials. In the Netherlands, all the hazardous wastes are processed at AVR-Chemie located at the Rotterdam harbour, through rotary kiln incinerators. The newly enforced regulations from the European Union with stricter emission levels require a better understanding of the incineration process and improved process control. However, the transport phenomena and combustion processes within the kiln system are very complex and not well understood. In order to get better understanding of the incineration process, research has been carried out to study the fluid flow and combustion behaviour of the incineration system. Computational Fluid-dynamics (CFD) was used to simulate the gas flow and waste combustion process, and temperature measurements of the operating rotary kiln incinerator were conducted to validate the CFD model. This paper will present the latest results from the current research project for simulating gas flow and combustion heat transfer for a wide range of hazardous waste streams.The simulation of the waste incineration process was carried out using a general-purpose CFD code Phoenics. The rotary kiln and the secondary combustion chamber (SCC), with a waste processing capacity of 50,000 ton/y and an energy input of 30 – 40 MW, is translated into a CFD model. The model includes a k-e turbulence model and a global gas-phase combustion model (3-gas or 7-gas combustion model). The 3- gas model (Simple Chemically-Reacting System, SCRS) predicts only the thermal effect of the fuel combustion, and only one global fuel is used, therefore, real chemical species are not taken into account. In the 7-gas combustion model, (an Extended SCRS, ESCRS), different forms of waste fed into the incinerator have been modelled into a mixture of a general hydrocarbon fuel C3H4 and other components such as CO, CO2 and H2O. Thus, all the incoming fuel streams with different compositions and calorific values can be properly converted into separate inlets. The combustion of the waste is assumed to take place only in gas phase in two steps: (1) primary combustion of the main fuel component C3H4 to form CO and H2, (2) secondary combustion of CO and H2O to form CO2 and H2O. The rate of each combustion reaction is assumed to be controlled by turbulent mixing of fuel and oxidant (air or oxygen), i.e. the Eddy-Break-up (EBU) model. The resulted temperature field was validated with temperature measurement data, and the simulated temperature distribution from both 3-gas and 7-gas model have reasonable agreement with the measured data."

Jan 1, 2003

By Janusz S. Laskowski

"Frothers offered by different manufacturers are marketed with some information on their chemical and physical properties (e.g. density, viscosity, color, water-solubility, safety/toxicity, etc.). But frothers are used in flotation to generate fine bubbles and to stabilize the forth, and this information is only provided in a very qualitative description of the visual appearance of bubbles and froths. The terms “powerful” and “selective”, which have been commonly used to characterize frothers, have intuitive rather than scientific meaning.This paper introduces the DFI (Dynamic Foamability Index) plotted vs. CCC (Critical Coalescence Concentration) diagrams to classify flotation frothers (Fig. 1). The frothers characterized by low CCC and high DFI values have properties of strong flotation frothers, while those with high CCC and low DFI values are more selective. The proposed frother classification system, based on simple CCC and DFI measurements, provides, for the first time, a solid ground-work for characterization of the flotation frothers."

Jan 1, 2003

By M. H. Moys, M. M. Bwalya

"INTRODUCTIONThe grinding rate prediction scheme makes use of the energy spectra output from the DEM simulations and the statistical quantification of material strength, which can be done using the drop-weight tester or some other similar equipment. The prediction scheme is evaluated using milling experiments performed under well-defined conditions.MATERIAL STRENGTH QUANTIFICATIONUsing the drop weight test machine, particles of a wide size range were broken singly using different energy inputs. A characteristic equation key to milling rate prediction that relates the probability of fracture with energy input and number of impact attempts was obtained and is stated as follows:"

Jan 1, 2003

Calcium sulfate whiskers are considered to be a prosperous reinforced material in application due to their high mechanical properties. But the hydration occurs easily at moist atmosphere or in aqueous solution. The surface topographies of the calcium sulfate hemihydrate whiskers and the hydrates were analyzed by on-line observation and using XRD. The results indicated the transformation of the crystal type and shape of calcium sulfate hemihydrate whiskers and the reduction of whiskers? aspect ratio. The hydration process of the calcium sulfate hemihydrate whiskers and the effective parameters were further discussed based on FT-IR measurements. The conclusions were obtained that the hydration of calcium sulfate hemihydrate whiskers can be divided into the three phases, namely, initial hemihydration phase, dehydration phase, and coarsening, dissolving and the re-formation of calcium sulfate dehydrate crystal phase. In addition, it was found that in the hydration process of calcium sulfate hemihydrate whiskers the calcium sulfate dihydrate whiskers are formed at first and then converted into the calcium sulfate dihydrate with different crystal shapes, but in the hydration of gypsum hemihydrate the gypsum dihydrate is formed without transition products. The surface active site-calcium ion which has strong trend to react with H2O, the surface ?OH and the inner channels are considered to play important roles in the hydration process of calcium sulfate hemihydrate whiskers.

Jan 1, 2014

By Kyle Bartholomew, Robert McIvor

"Functional performance analysis of closed circuit grinding provides valuable insight into the two components of ball mill circuit grinding efficiency: classification system efficiency and mill grinding efficiency. Classification system efficiency isolates the combined effect of classifier performance and circulating load ratio from other circuit variables, such as ore grindability and the mill grinding environment. Optimization of classification system efficiency ensures grinding energy is applied to particles needing further size reduction and not to overgrinding. Entirely based on size distribution data, classification system efficiency precisely distinguishes subtle changes in classification system performance. Use of the functional performance equation to isolate mill grinding efficiency allows for proper optimization of the mill grinding environment by isolating confounding effects of changes in classification and ore grindability. Variables such as mill percent solids and grinding media selection can be optimized using the mill grinding efficiency subcomponent of functional performance. First published by McIvor in 1988, the functional performance equation provides a set of standardized, quantitative optimization criteria, simple and powerful, which link circuit performance to plant design and operating variables that can be manipulated. Functional performance optimization has been applied in numerous mineral processing plants globally and continues to gain acceptance as a practical means for grinding circuit optimization. In this paper, examples of derivation and industrial application demonstrate the means by which functional performance analysis dissects grinding circuit efficiency into its subcomponents allowing the reader to apply this straightforward, powerful optimization methodology at their mineral processing operation."

Jan 1, 2014

By Jan Svoboda, Toyohisa Fujita

"The current status and history of innovation in magnetic methods of material treatment are reviewed. The milestones and key drivers of innovation are identified, advantages of magnetic separation in comparison to other physical methods of material manipulation are discussed and reasons for failure to live up to its potential and expectations are identified. The future focus in such diverse areas as mineral processing, waste treatment, recycling and biosciences is discussed and the research and development needs are outlined.Our walk through the innovation landscape in magnetic separation illustrates the enormous effort that has been expended over the years to convert a wealth of novel idea into workable techniques. Remarkable progress has been achieved and numerous successful innovations have been introduced into material treatment operations. On the other hand these techniques have experienced their fair share of failures. The reasons for these cover a wide spectrum of risks that accompany any effort to implement new technology."

Jan 1, 2003

By H. Mengbing, A. Potokin, A. Usov

"Revealed and analyzed in the study are the ways of significant perfection of specific characteristics of the equipment, such as use of high-frequency voltage transformation to create a charger; use of pulse transformers, with core made of materials with high magnetic permeability, in pulse generating circuits; as well as use of special ways to produce voltage pulses with a short front. The experiments have proved the possibility to adapt these technological solutions for electric-pulse installations, and suggested on this base is a strategy of further development and application of electric-pulse technologies. The different applications joint work schemes of voltage sources with two levels voltage and energy in electric pulse technologies are investigated. The possibility of increasing energy efficiency of destruction is shown."

Jan 1, 2014

By T. C. Sun

Two wasted activated sludges (WAS), from an industrial wastewater treatment and a sewage treatment plant respectively, and 7 collectors are used to investigate the feasibility of air flotation thickening of WAS by adding the collectors used in mineral processing. The collectors experimented include straight chain fat acids with different chain length, sodium oleate, alkyl sodium sulphonate, sodium dedecylsulfonate, and dodecylamine. The results show that the thickening efficiency varied depending on different collectors. Of the collectors experimented, dodecanoic acid and dodecylamine are best collector for thickening both sludges.

Jan 1, 2014

By Majid Saghaeian, Rasool Hejazi, Parisa Ghobadi

"Pulp handling in mineral processing circuits is very complicated due to its inherent different specifications compared with other fluids such as water. Because any variation in ore property (e.g. size and abrasion index) and pulp specification (e.g. density, solid content and pressure) causes problem in this part and reduces the plant availability and throughput as a result. The most common issues in the hose system are sumps and pipe-line blockage, wearing of the pumps impeller and liner, and pipe tearing specially at elbows and bends. High pressure grinding roll (HPGR) is employed in a closed circuit with a screen as the first stage of grinding in Zarand Iranian Steel Complex (ZISCO). Wearing of the pump and pipeline transferring the screen undersize stream was the main problem from the plant commissioning. The plant couldn't achieve to the design capacity because of this defect. Although various practical solutions such as improving the pipes and impeller material quality and eliminating the elbows, as much as possible, were done in order to downtime minimizing, but damages didn’t vanish. Since HPGR discharge contains somewhat rough and abrasive particles, the mentioned modifications didn't effective very much. Therefore, converting of the wet screen to dry and using of belt conveyor to the screen undersize handling was employed based on the plant capability evaluation and experimental and pilot trial results. Although this reformation imposed another additional cost (for conveyor system), but it had significant advantages such as increasing the plant availability up to 96%, reducing the operating costs of the wear parts, providing more stable operating condition for the HPGR performance and decreasing abrasion rate of the HPGR rolls liner because of the lower moist feed."

Jan 1, 2014

By Yagmur Sirinyurt, Ayhan Ali Sirkeci, Gülay Bulut, Mustafa Özer, Tuncer Acar

"The basic requirement of glass industry for the silica sand is at least 99% SiO2 content. On the other hand, coloring impurities such as Fe and Ti, must be removed. Flotation is the most widely used method for the purification of silica sands from impurities. In this study experimental studies were carried out to reduce Fe content of Mersin (Turkey) district silica sands by flotation. Silica sand sample with a d80 particle size of 1.85 mm was reduced below 0.5 mm in size. Then the size fraction -0.5 +0.106 mm was subjected to flotation tests. In flotation tests, sulfonate-type R801-R825, fatty acid based DER NA 7 (Produced by a Turkish company) and HA110-HA150 a blend of various chemicals produced by Mersin Cam-Is Mining Company (producer of glass raw materials) were used as collectors. Flotation tests showed that sulfonate type R801-R825 collectors provided much better results in acidic medium (pH: 3). The optimum pH value for DER NA, HA150 and HA110 collectors was found to be 7. It was observed that the addition of collector at once caused an increase in the amount of floated product that resulted in a loss of silica to the tailings. In the case of multistage addition of the collector much better selectivity was achieved. As a result of flotation tests conducted under best conditions, a concentrate assaying 0.046% Fe was obtained with a weight percentage of 93.4 when DER NA 7 was used as a collector. In the case of R801-R825 a concentrate was produced with 0.058% Fe content with a yield of 98.4%. On the use of HA150-HA110 the concentrate was produced with 96% weight recovery and 0.052% Fe content."

Jan 1, 2014

By U. A. Peuker, A. Grohme

"The cost effective and sustainable production of high purity rare earth elements is still challenging. The most commonly used method, known as solvent extraction, is very complex, needs many steps to separate the rare earth ions in a high purity, and causes a lot of environmental problems. An alternative method is the utilization of a separation column filled with adsorbent material. Within the column the desired target substance can be selectively separated out of a multi component mixture in one step. To find out if an adsorption material is suitable for the separation with a column, a characterization of the adsorbent material is necessary. In this paper are described the usage of modified activated carbon (oxygen and phosphorous modification), Di-(2-ethylhexyl) phosphoric acid (D2EHPA) impregnated Amberlite® XAD 7 HP and Lewatit® VPOC 1026 as adsorption materials. Several adsorption isotherms and process conditions are determined to characterize the selectivity between the adsorption materials and different rare earth ions. With these isotherms the mass specific rare earth ion retention for the adsorbent materials can be calculated. In addition to the isotherms the best working parameters are investigated e.g. pH-value and the time for equilibration. Finally, the separation factors between two rare earth elements are determined. The separation factor shows how successful a two element system can be separated."

Jan 1, 2014

By Eduard Stefanescu, James M. Mwase, Egon Sehner, Stoyan Gaydardzhiev

"The study is focused on investigating the production of synthetic rutile of 95% purity or higher from a Norwegian ilmenite ore concentrate. This was to be achieved using a sequential process involving oxidative-reductive roasting at 975°C, followed by magnetic separation to further concentrate the sample and finally leaching with 20% HCl to remove mostly Fe-based impurities leaving behind synthetic rutile. The key process parameters considered were roasting time (1 and 2 hrs), leaching temperature (100, 125 and 145°C), pulp density (15 and 25wt%) and leaching time (3 and 6 hrs). The option of directly leaching the concentrate without pre-treatment was also evaluated. Test work was conducted using samples screened to a size fraction of 105-212 µm. Samples were leached in a 1 L glass autoclave. The reactor was hermetically sealed and thus the resulting pressure was not controlled but was dependent on the process temperature. The product from leaching was calcined and analysed via XRD and SEM to determine the purity of the product. The magnetic separation step was found to be ineffective and discontinued early in the study. Thus far a product with 97% synthetic rutile purity as analysed by SEM has been produced by directly leaching the concentrate at a temperature of 145°C, pulp density of 25wt% and leaching time of 6 hrs.INTRODUCTION The study investigates the use of a process route comprising oxidative-reductive roasting, followed by magnetic separation and then hydrochloric acid leaching and calcination to produce synthetic rutile from ilmenite concentrate. The grade of synthetic rutile produced should be suitable for chlorination to produce pigment grade TiO2. Hence the proposed process should produce a product consisting of no less than 95% synthetic rutile. Additionally, the product should have no more than 1.5wt% combined content of CaO and MgO (Zhang et al., 2011) as they tend to form high-boiling-point chloride leading to the malfunctioning of fluidized bed chlorinator (Cardarelli, 2008). Finally the product should have no more than 2.1wt% of Fe2O3."

Jan 1, 2018