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By R. E. T. Hill

"A laboratory study was undertaken to determine the condensed equilibrium phase relations at 600°C in that portion of the quaternary Fe-Ni-Cu-S system which lies in the neighbourhood of the monosulphide solid solution (MSS). The study sought to determine to w hat extent copper affects the temperatures of stability and compositions of iron-nickel sulphides in bulk compositions similar to those of massive Fe-Ni-Cu ores. Experimental data, including stable phase assemblages and phase compositions, are presented.In the quaternary system at 600°C MSS forms stable phase assemblages with pentlandite, chalcopyrite solid solution, pyrite and vaesite. Over the range of bulk compositions displayed by natural ores copper as well as metal/sulphur ratio have a significant effect on the thermal stability of pyrite and pentlandite. Errors therefore accompany the widespread practice of ignoring copper or chalcopyrite when the mineralogical and compositional changes that have accompanied the initial cooling of primary magmatic sulphides or their subsequent homogenization during isochemical metamorphism are being deciphered. These errors are most significant for ores the bulk compositions of which lie tow ard the sulphur-deficient side of the cupriferous MSS. Temperatures as much as 300°C above the copper-absent value are possible for the interpreted upper stability limits of pentlandite in these ores.The experimental data show that up to 2.0 at% copper can occur in pentlandite stable at 600°C in a bulk composition equivalent to natural magmatic ores. This is equivalent to nearly 10 vol% chalcopyrite. Pentlandite contains more copper than coexisting MSS and the copper content of both phases increases with increasing iron."

Jan 1, 1984

By E. C. I. Hammerbeck

"Geological controls and constraints in space and time define the milieu of the nickel deposits of Southern Africa. Primary, magmatic deposits are of two types, e.g. synvolcanic or syntectonic deposits confined to certain orogenic domains, and those related to intracratonic, post-orogenic magmatism, e.g. the Great Dyke, the Bushveld Complex and the Insizwa intrusion. Epigenetic and supergene deposits form a separate, unrelated group and are of minor economic importance.The metallogenic evolution of syntectonic nickel deposits is particularly well illustrated in the Zimbabwean Province, where the relationships between Archaean greenstone development and nickel mineralization are best illustrated. Volumetrically subordinate, nickel-poor greenstones in the 3500 m.y. old Sebakwian Group are followed by more common komatiite development in the Lower Greenstones (3000 m.y.), and, finally, by very significant komatiites with important nickel mineralization in the 2700 m.y. old Upper Greenstones of the Bulawayan Group. Comparable nickel mineralization is not known in the Raapvaal Province, in spite of ubiquitous komatiitic magmatism of the Onverwacht Group (3500 m.y.) and other greenstone sequences. No komatiitic rocks younger than about 3200 m.y. are known in this region, orogenic activity in the Kaapvaal tectonic province having ceased at about 3100 m.y., whereas the Zimbabwe Province remained tectonically active until at least 2600 m.y.The tectonic environment, host-rock petrology and mode of emplacement, as well as some details of the nickel mineralization, are the parameters employed to classify the Southern African magmatic nickel deposits. A rating of the deposits is introduced that reflects the original resources of the deposit, its average nickel content, its mining history and potential to facilitate ready comparison with and assessment of the nickel deposits listed in the classification, as well as some important nickel deposits worldwide."

Jan 1, 1984

By P. C. Kapur

Several empirical and semi-empirical laws of comminution, which describe the relationships between the cumulative grinding energy input and the degree of size reduction of brittle solids, have been rationally derived in the time-domain in a unified manner, starting with an integro-differential equation of grinding kinetics. The analysis leads to and provides explicit interrelationships between the energy-size reduction laws associated with Kick, Rittinger, Holmes, Bond, Charles and others, and gives useful estimates of their relative merits and validity. It is shown that Holmes' expression is, in fact, a solution to the grinding equation; consequently, this classical law is compatible with the modern theory of comminution based on population balance on particulate species

Dec 1, 1971

By K. El-Barawi, Hussein M. Kamal

Chlorination was performed of iron-rich chromite ore from Barramyia, United Arab Republic (UAR), together with its concentrate. The effects of change of grain size, chlorine gas flow rate, time and temperature were studied. The extent and mechanism of chlorination were followed through chemical and structural analyses of the feeds and complete chemical analysis of the chlorination products. By conducting the chlorination process for short periods at 600°C or lower temperatures, products having high Cr-Fe ratios suitable for ferrochrome production can be obtained.

Dec 1, 1971

The paper, presented at the North of England Institute of Mining and Mechanical Engineers' general meeting held in Newcastle-upon-Tyne, 8th April 1916, presents experimental work undertaken to observe the quenching effect of different substances, to find the most efficient of these substances, and to arrive at a possible explanation of their preventive action. The coal-dusts experimented with were such as passed through a 100-mesh sieve (10,000 holes to the square inch), and were obtained by grinding the coals. The quenching substances, used in as fine a state of division as possible, included gypsum, dried Chance mud, quicklime, magnesia, magnesia alba (levis), anhydrous sodium carbonate, sodium bicarbonate, soda-crystals, Glauber salts, ground shale and boiler-ashes

Dec 1, 1916

For the convenience of those who are unfamilar with thermodynamics, the following brief description and explanation is given of the thermodynamical terms and methods used in this book. It must, however, be strongly emphasized that the account given below is not an introduction to chemical thermodynamics; its sole purpose is to give the reader a rough understanding of the methods used in the earlier chapters. For further information, reference must be made to the standard textbooks on chemical thermodynamics by Glasstone.

Jan 1, 1953

By Z Hu

The technique of reclaiming disturbed land by use of a hydraulic dredge pump (HDP) (which is a set of hydraulic machines for earthwork), termed 'digging deep to fill shallow has been used in the reclamation of subsidence areas in Chinese coal mines. This paper discusses the operational principle of the technique and summarises its reclamation procedures, which are being used in current reclamation practice. The soil condition reclaimed by the HDP was studied. The results showed that the pioneer crops to be planted in the reclaimed soil should be the ‘pulse’ family crops, and that improvements to the reclaimed soil and the HDP technique itself are needed. Bused on the analysis of the previous technical processes, a new rational technical model for the HDP reclamation method is presented in this paper.

Jan 4, 1996

By C. M. Lesher, R. R. Keays

"The komatnte-associated Fe-Ni-Cu sulphide mineralization at Kanihalda, Western Australia, is generally believed to be magmatic in origin, but a number of postmagmatic processes significantly modified the original distribution, structure, texture, mineralogy and chemistry of the ores. Two important types of mobilized magmatic sulphides are interpillow/interbreccia sulphides and hydrothermal vein-type sulphides. Interpillow and interbreccia sulphides occur interstitial to pillowed or volcaniclastic footwall metabasalts beneath or adjacent to the stratiform contact ore horizons. They are mineralogically and compositionally similar to massive ores (and are similarly depleted in PGE relative to the compositions of bulk samples of mined ores), but normally do not contain the distinctive chalco-phile ferrochromites characteristic of contact ores. They are interpreted as magmatic sulphides that have been mobilized from the overlying or adjacent massive sulphide layer during peak tectono-nietamorphism.Hydrothermal sulphide-quartz + albite veins also occur in the footwall metabasalt and contain unannealed deformation fabrics indicative of emplacement during retrograde metamorphism. The high Ni and Pd contents of these sulphides (7-13% Ni, up to 70 ppm Pd) indicate that the metals have been derived from the spatially associated komatiites and/or contact ores, consistent with the Pd depletion previously inferred for massive ores. Very low Ir contents and high Pd/Ir ratios of the vein-type sulphides confirm an aqueous transportation-deposition mechanism; hydrothermal transfer of PGE results in strong decoupling of Pd from Ir.There appears to be a complete continuum of sulphide mobilization at Kambalda ranging from whole-scale phy sical dislocation (fault offset ores) and selective mobilization (stringer sulphides) through nietamorphie replacement (interpillow/interbrec- cia sulphides) to jiydrothermal dissolution and redeposition (vein-type sulphides)."

Jan 1, 1984

By R. J. Bridges

Mining operations on the Witwatersrand are conducted for the most part in rocks of highly quartzitic character. They comprise the following types: Conglomerates, grits, and quartzites, to which on the Far East Rand must be added fine-grained quartzitic shales and shales. In addition, vein quartz occurring as small veins, veinlets and fissure fillings, and igneous rocks forming dykes, must be mentioned, although they constitute only a small percentage of the rock broken. The following is an account of the character and mineralogical composition of the various types.

Jan 1, 1947

By A. G. Waters, N. J. Bristow

A comparative study was made of an untreated and a heated haematite ore and a sinter produced from a feed consisting of 100% ore, to study the influence on reduction behaviour of sinter bonding phases such as SFCA (silico-ferrite of calcium and alumina). Under low-temperature reduction conditions the order of increasing reducibility followed that of increasing porosity and surface area but under similar conditions at 900 degrees C the sinter exhibited higher reducibility than the ores even though the total porosity and chemical reducibility of the individual phases were lower. This behaviour can be explained in terms of the higher total porosity of the natural ore at low temperatures and the higher level of fine pores in the sinter at high temperatures due to the presence of SFCA, which acts to support the fine (c.0.1 micrometre) pores created by the reduction process. This leads to the conclusion that the main role of SFCA in sinter during high-temperature reduction is to maintain a high level of fine porosity. Some implications of this work for granule design and sintering practice are discussed

Apr 1, 1991

"The Archaean komatiite-associated nickel sulphide deposits at Kambalda, Western Australia, exhibit a number of stratigraphic features that are indicative of a strong volcanic control on ore localization, including (1) a restriction to specific basal cumulate metakomatiite host units, (2) confinement within distinctive synvolcanic embayments in the footwall and (3) variations in the internal structure and composition of overlying and adjacent barren metakomatiite flow's and the distribution of interflow metasediments with proximity to the ore zones.The high magnesium content of the host units (up to 45% MgO volatile-free) in comparison with that of aphyric or spinifex- textured lavas (16-32% MgO) has been considered previously to indicate either magmas/lavas rich in intratelluric olivine or selective accumulation of olivine phenocrysts. The marked linear trend of the oreshoots, basal host units, footwall embayments and the volcanic stratigraphic relationships have been used as evidence for local linear feeding fissures. Rare relict igneous olivine in some host units is, however, demonstrably not intratelluric, and there is no direct or indirect evidence of a proximal eruptive site (e.g. footwall feeders, pyroclastic breccias, ultramafic intrusives) at Kambalda such as at some other deposits of this type. Kambalda is interpreted as a distal rather than proximal volcanic environment.Emplacement of the komatiite sequence at Kambalda was probably controlled by the locations of a few specific eruptive sites relative to regional topographic gradients and influenced by the topography of the pre-existing volcanic surface. Olivine enrichment in the basal host units occurred by in-situ fractionation and cumulus crystallization of olivine during longitudinal lava flow within linear lava conduits, possibly centralized on depressions between non-overlapping footwall basalt flows. The distinctive stratigraphic relationships are attributed to localization of lava conduits along the volcanic pitchline, flanked by more slowly moving parts of the flows. There are analogies with the physical volcanology of Modern basaltic and Proterozoic komatiitic lava flows.A corollary of this model is that the lava conduits thermally eroded and assimilated sulphidic sediments, contributing additional sulphur to sulphur-saturated komatiites or possibly inducing sulphide separation in originally sulphur-undersaturated komatiites. The latter would account for the restriction of ores to linear cumulate komatiite host units (thermally active lava conduits) and the locally mutually exclusive, but stratigraphically equivalent, relationship between the ores and sulphidic metasediments at Kambalda."

Jan 1, 1984

By C. Chope

The Minister for Roads and Traffic's opening speech highlights some of the topics to be covered in the conference with particular reference to the Channel Tunnel, the recent breakthrough of whose service tunnel marked a historic moment three and a half years after passing of the Channel Tunnel Act and which was the first example in recent years of a major transport project entirely privately funded. The Minister also mentioned the building of UK road tunnels, research and development, and the role of UK consultants in the single European market

Jun 13, 1905

By A. J. Beer, A. Wetherelt

Paper presented at the UK minerals industry conference held in Leeds, UK, 3-5 April 1995. Camborne School of Mines has developed a simple, cost-effective light-sectioning method that has been used successfully in tunnels and small stopes. Light sectioning provides an almost visual examination of the stope's excavated profile. An illuminated section of walls, roof and floor is recorded photographically. Overbreak and underbreak can then be easily quantified by reference to the designed shape. The prototype rig is described. Use of a fish-eye lens to capture a greater field of view is discussed. Calibration was achieved by comparison with images made with a conventional wide-angle lens with nominal distortion. The system is reliable under a range of operating conditions including dust, heat and humidity. It is also simple and easy to use, does not require skilled personnel and is low cost

Jun 18, 1905

By N. T. Moxon, D. Mead, S. B. Richardson

A laboratory and theoretical study of air decks was carried out to assess the effects of the size and location of air-decks on fragmentation. The degree of fragmentation was found to depend on both factors. As the size of the air-deck increases the degree of fragmentation is reduced relative to a full column charge. However, the reduction is relatively small until a critical size is exceeded. The critical size depends on the strength and structure of the surrounding material. A critical air-deck length of 30-35% of the original explosive column was determined for the model materials used in the study. A theoretical explanation of the results was derived based on pressure decay rate relationships. The location of the air-deck also influences fragmentation. The interaction and oscillation of the two shock fronts from the top and bottom charges mean that mid-column air-decks produce better fragmentation for the same air-deck length and explosive loading as top-column or bottom-column air-decks.

Jan 4, 1993

By T. Piirainen, T. Alapieti

"The Koillismaa layered igneous complex is the result of igneous activity that occurred 2436±5 m.y. ago. Its crystallization took place in three separate but connected magma chambers, the total volume of which is estimated at more than 2000 km'. These chambers were located partly in a feeder system within Archaean granitoids and partly in an unconformity between these grani­ toids and Early Proterozoic supracrustal rocks. The composition of the parental magma that initially filled the chambers is thought to have been that of a relatively MgO-rich tholeiite. Sulphides and platinum-group minerals are mainly concentrated in the marginal series of the western part, where they are encountered over a distance of 25 km. This marginal series is an originally nearly horizontal series of rock types that displays a reversed differentiation trend, grading inwards from gabbroic to ultramafic rocks, followed bv rocks of the layered series. The chilled margin is not encountered anywhere in its original position at the contact, probably as a consequence of magmatic erosion, but remnants are to be found in the form of elongated xenoliths. Partly melted siliceous fragments from gneissic country rock typical of the lower part of the marginal series indicate pronounced contamination.Chalcopyrite, pentlandite and pyrrhotite±pyrite are the predominant sulphides. The accessory sulphide minerals include covellite, violarite, marcasite, mackinawite, sphalerite and argentian pentlandite. Platinum-group minerals are represented by froodite, michenerite, merenskyite and sperrylite. Other accessories that have been identified are electrum and native copper and gold. The mean of the Cu/(Cu+Ni) ratio in the mineralizations is 0.67 and Pt/(Pt+Pd) 0.31.It is suggested that the sulphide phase was formed in the marginal series as the solubility of sulphur in the basic magma was lowered by contamination, possibly assisted by some other factors. The sulphur isotope data support the juvenile origin of the sulphur."

Jan 1, 1984

By J. H. E. Jeffes, C. Diaz

The heat balance and chemical equilibria involved in the production of blister copper from a chalcopyrite concentrate in a single operation are examined. It appears that two stages—one oxidising and one reducing—will be required. The analysis indicates that on thermal grounds the process is possible with a dry, high-grade chalcopyrite concentrate, if oxygen enrichment to about 30 per cent is used, but that copper losses in the slag will be serious and will require a secondary recovery operation. More extensive data on the activities of copper oxide in slags are required to elucidate this point more effectively

Dec 1, 1971

By R. P. Foster, ed.

The short selection of papers in the special issue provides an insight into the level of exploration activity in Africa and the science and technology that are underpinning it. A country-by-country survey is followed by discussion of geochemical exploration in tropical soils, the Liptako region of Niger, structural styles of deposits in Zimbabwe's Bulawayo-Bubi greenstone belt, structural controls in Zimbabwe's Eldorado shear zone, the regional framework for deposits in the Odzi-Mutare-Manica greenstone belt of Zimbabwe and Mozambique, and the Iperindo deposit in Nigeria's Ilesha schist belt

Apr 1, 1996

By G. Richards

Application of the Internet of Things (IoT) technologies - the interconnection of uniquely identifiable embedded computing devices within the existing internet infrastructure - to the mining industry is discussed. IoT technologies are aimed at making projects safer, better optimised and more economic and are applicable to current or new underground or open-pit mines, regardless of size. Two examples are presented of successful implementation of IoT technologies, the Chelopech gold, copper and silver mine in Bulgaria, where production has increased from 500 000 to 2 000 000 tonnes/y and communication costs have been reduced by US $2 500 000 over 2 y, and the Pilbara project in Western Australia, where remotely controlled wirelessly connected autonomous trucks have covered ca. 3 000 000 miles and hauled almost 250 000 000 t of ore since 2008

Apr 1, 2015

By R. H. . T. Garnett

Contributed remarks on paper published in the Transactions, Mining industry section, vol. 100, September- December 1991, A121--45

Jan 12, 1992

Thermodynamical data of importance in connection with copper smelting have been reviewed and a collection of the most reliable information is presented in Tables XXV-XXVIII and Figs. 67 and 6 8 (folding plate). The data given in these figures and tables consists of (i) graphs and equations showing the variations in the temperature range 0-2000°C. of the standard free energies of formation of most of the oxides and sulphides met with in copper smelting (Table XXV and Fig. 67); (ii) equations showing the temperature variation of the free energy of formation of iron silicates (Table XXVI); (iii) graphs showing the variation with temperature in the range 1000°-1600°C. of the standard free energies of the principal reactions occurring in the smelter (Fig. 6 8 ); (iv) the standard heats of formation at 1200°C. of the main iron and copper compounds and gases reacting in the smelter (Table XXVII); (v) the standard heats of reaction at 1200°C. of a few of the reactions for which the free energy relationships were given in Fig. 6 8 (Table XXVIII). The data presented are discussed in more detail.

Jan 1, 1953