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By Allan E. Martin

As part of a comprehensive investigation of tae mechanism of desulfurization of iron and steel by slags, the Blast Furnace Studies Section, Metallurgical Division, Bureau of :lines, in cooperation with the Institute of Technology., University of Minnesota, has made a study of the forms in which sulfur occurs in blast-furnace slag. This report presents data on the three sulfides most important in iron smelting, namely, ferrous sulfide, manganous sulfide, and calcium sulfide. The tendency of these sulfides to form colloids in the molten slag was determined by an examination of quenched samples with an ultramicroscope. Vogt5/ conducted experiments on sulfide silicate melts and examined synthetic blast-furnace slags in a partly crystallized condition. His conclusions were that FeS, CaS, and MnS, or isomorphous compounds, such as (FeXCay)S and (MnxCay)S, were precipitated from the melt, depending on the composition of the slag. In all specimens sulfides were visible and were spherical.

Jan 1, 1941

By R. G. Sandberg

The Bureau of Mines investigated a hydrometallurgical procedure to recover gold, silver, and byproduct lead from a complex lead-zinc sulfide ore. A ferric chloride (FeCI3) preleach, at 40° C in 6 h, extracted about 50 pct of the zinc and formed insoluble silver and lead chlorides. Subsequent acid thiourea leaching, for 1 to 3 h at 40° C, extracted about 85 pct of the gold and silver. Lead chloride was solubilized from the remaining residue with NaCI brine solution at 55° C in 1 h. Lead metal was recovered from the brine solution in an electrolytic cell with an anion perms elective membrane at a current efficiency of 95 pct and current density of 100 A/m2. Spent FeCl3 leach solution was reoxidized in the anode compartment at a current efficiency between 75 and 95 pct.

Jan 1, 1986

By John F. Elliott

Because of the importance of the steel industry in the economy, a program of study was undertaken to develop a computer model by which it would be possible to predict the need of the industry for raw materials and energy in the next several decades. This report gives the results obtained it a preliminary 6-month program.

Jan 1, 1973

By W. G. Pariseau

This Bureau of Mines report is an evaluation of the state of knowledge about gravity flow from bin hoppers, the most commonly used method of handling bulk materials where the force of gravity is used. The requirements for flow to be initiated and to continue, formulas developed experimentally or mathematically from various assumptions to describe the materials flow, and the question of whether or not a material will flow over the entire cross sectional area of the bin hopper according to the flow regime developed are the primary areas discussed. The work of A. W. Jenike, whose pioneering investigations raised bin hop- per design from the trial and error state, is examined in depth and its limitations and assumptions are pointed out. Bin hopper design depends heavily upon prior experience, and suggestions for further studies of bin hopper flow to include the effects of feeders are made.

Jan 1, 1972

By A. C. Rice

This report describes a chemical process for preparing solutions of trivalent rare-earth chlorides from sulfate solutions obtained by treating bastnasite concentrate. The chief impurity in the final solution is cerium, and this element is less than 1 percent of the rare-earth oxides. The solution is used directly in the separation of rare-earth elements by ion-exchange methods. The attractive features of the process are that the chemicals are inexpensive and the steps few. The process starts with precipitating the rare-earth hydroxides from sulfate solutions with caustic soda. After the hydroxides are dried to oxidize the cerium, they are treated with dilute hydrochloric acid to dissolve away the trivalent rare-earth elements, leaving the tetravalent cerium. Details for controlling the leaching step are described. The process shortens older procedures by omitting the usual oxalate or double-sulfate-precipitation step.

Jan 1, 1959

By Jules Gordon

Presents the results of mining tests conducted on a forward rotating bucket wheel excavator designed to continuously mine coal at 1080 tons/hour, Goals of the program are to determine the feasibility of the forward rotating bucket wheel principle as an effective means of reducing fragmentation and loading costs associated with surface mining, with additional benefit in reducing, coal preparation costs and stripping overburden. Tests took place at the Navajo Mine in Fruitland, New Mexico, Results show that the excavator performed as expected and can reduce fragmenting and loading costs up to 80°. Presented are: 1) production machine design specifications and projected economies extrapolated from the test data, and 2) recommendations for further work in dust control.

Jan 1, 1977

By Bryan R. Carmenati

This report documents the need for formal health and safety, and equipment operations training in the mine construction industry. The outlines, objectives, and training texts were developed based on the recommendation of needs of mine construction personnel, and those of Dames and Moore (Safety Analysis of Shaft Sinking operations, 1977) and Kinton, Inc. (A Training Program for Conventional and Raise Drill Construction Personnel; Phase I, 1979). The training material samples contained herein (and under separate cover in its entirety) are designed to improve the safety and production of those in mine construction. An instructor-directed presentation is recommended. The results of the study are presented in the Findings and Recommendations section of this report.

Jan 1, 1982

By F. R. Cattoir, T. A. Sullivan

Commercial uranium metal was electrore fined to a high- purity product using molten- salt electrolytes in an inert atmosphere cell . Electrorefined uranium that contained , after consolidation , less than 30 ppm of metallic impurities was prepared . A method of leaching the electrolyte crystals to remove the salts was developed . Cathode current efficiencies from 90 to 100 percent were obtained . Two molten- salt electrolytes were prepared and evaluated : (1 ) lithium chloride - potassium chloride - uranium trichloride and ( 2 ) sodium chloridepotassium chloride - uranium trichloride . Very little difference was found in the purity of the uranium metal produced in either system . The lithium chloride - potassium chloride - uranium tri - chloride electrolyte was preferable from an operational standpoint .

Jan 1, 1964

By R. A. Cummings

Certain roof shales in coal mines deteriorate upon exposure to the atmosphere, causing difficulties in the mining operations and adding to the cost. This report presents the results of both field investigations, in a West Virginia mine, and laboratory studies on the effects of atmospheric moisture on roof shales. Based on these observations a conceptual procedure is presented on how shale deterioration might be predicted during exploration, and guidelines are given as to how air tempering or conditioning chambers may be designed to reduce moisture effects. Recommendations for further studies are included. An annotated bibliography of the literature constitutes the second volume.

Jan 1, 1981

By John Kosek

The electrochemistry of carbon monoxide, nitric oxide and nitrogen dioxide was investigated at a variety of electrode materials in different supporting electrolytes. A portable detector for carbon monoxide was developed using a porous gold anode in perchloric acid supporting electrolyte. This detector has two full scale ranges, 0-100 ppm and 0-500 ppm. A portable detector for mixtures of nitric oxide and nitrogen dioxide was developed using a porous silver cathode in sulfuric acid supporting electrolyte. Nitrogen dioxide was determined in the gas stream by electroreduction. The nitric oxide in the gas stream was oxidized to nitrogen dioxide by passing it over Cr(VI) on firebrick. Electroreduction gave the sum of NO + N02. Analog circuitry was used to display the amounts of NO and N02 separately. Two ranges were available for each gas. They were 0-10 and 0-50 ppm for NO and 0-2 and 0-10 ppm for N02.

Jan 1, 1979

By E. P. Youngman

The mining law of British North Borneo is entitled " The Mining Ordinance , 1927. 113 The only mining regulation or rule available is " Rules 313 , 114 passed in accordance with article 26 of the ordinance of 1927. Before the passage of this legislation , the country had no specific law governing the granting of mineral rights , although the land law contained provisions relating to mining lands . The land ordinance of 19135 still controls in a few details . All references in this paper , unless otherwise specifically designated , are to the mining ordinance .

Mar 1, 1933

By Sean Gallagher, Thomas G. Bobick, William S. Marras

Twelve healthy, experienced underground cool miners performed lifting capacity tests in stooped and kneeling postures using a modified psychophysical procedure. Subjects adjusted weight in a lifting box to the maximum they could handle without undue fatigue in an asymmetric lifting task. Lifting periods were 20 min in duration and the frequency was 10 lifts/min. Tests were performed under a 48-in. roof that restricted the subject&apos;s posture. Psychophysical. physiological, and biomechanical dependent measures included the maximum acceptable weight of lift (MAWL), heart rate (HR), rate of oxygen consumption (VO2), ventilation volume rate (VF), respiratory exchange ratio (R), and integrated electromyography (EMG) of eight trunk muscles. Results indicated that the MAWL was significantly lower when kneeling than when stooped (p < 0.05), Furthermore, metabolic demands were greater in terms of HR (p < 0.005) mid VO2 (p < 0.05) when kneeling. Left and tight erectores spinae muscles exhibited increased EMG activity- in the kneeling posture (p < 0.001). It was concluded that psychophysical lifting capacity is decreased, while the metabolic stress and internal load on the spine are increased, in the kneeling posture. Results of this Bureau of Mines study indicate that it may be advisable to reduce the weight of materials that are handled repetitively in the kneeling posture.

By I. AITKENS

It is a common misconception that all yellow stones are topazes and that all topazes are yellow; but neither statement is true. The real topaz is a rather rare mineral, and a large number of yellow stones that masquerade as topaz are nothing more than yellow quartz, known as citrine, but almost universally called topaz. The true topaz is often called "Brazilian" topaz by the jeweler to distinguish it from yellow quartz; nevertheless, both terms are freely applied in trade to other yellow stones. Topaz is considered the most popular yellow stone for jewelry and is often used as the principal stone in brooches or pendants, especially in old-fashioned ornaments. However, many other species yield pretty yellow stones, some of which are far more numerous and less costly than the topaz.

Sep 1, 1931

By Arnold P. Pipilen

In a study of the principal factors affecting the transport of coal-water mixtures through a centrifugal pump and a pipeline, the interrelation between solids concentration, velocity, and pressure drop was established for a bituminous lump coal (minus 2 inch) in concentrations up to 48 weight-percent. An optimum concentration was found to exist for maximum capacity of a given pipe-line, and for minimum energy requirements per ton of coal. Coal size degradation by particle fracture took place in the pump; abrasion and attrition to form fines took place in both pump and line. A novel system of studying flow of solid-liquid mixtures in pipelines by the determination of relative sound intensities was developed.

Jan 1, 1966

By L. E. Green

For shortwall mining to be profitable, the additional capital investment of about $1 million for shortwall roof supports must be offset by decreased total operating costs and/or increased coal production. The Bureau of Mines therefore conducted a demonstration project to compare shortwall and room-and-pillar mining. Daily two-shift production from the bureau of Mines-Beth-Elkhorn Corp. shortwall demonstration n project averaged 975 tons of raw coal, compared with 905 tons from a room-and-pillar unit operating undo r similar conditions. The estimated direct operating costs for the shortwall and room-and-pillar unite were $4.21 and $4.03 pier ton, respectively. The profitability of the shortwall system was found to depend not only on the increased depreciation cost of the powered roof supports and the decreased cost of supplies and materials but also on such factors as the fixed and variable indirect costs and the selling price of the coal. Shortwall mining was demonstrated to be a viable alternative to room-and-pillar mining.

Jan 1, 1977

By Roy F. Waters

An inventory was made by the Bureau of Mines of wastes of mineral origin, water requirements, treatment of wastes, and water treatment practice of 163 industrial installations in the Lower Missouri River Basin. This is the second and concluding report on the survey, conducted in cooperation with the Missouri Basin Field Committee of the Department of the Interior as part of the Missouri Basin project. Principal industries covered by this second report are: Sand and gravel, coal, meat, ice, brewing, paint, petroleum, chemical, fabricated metals, and a number of industries having either no waterborne wastes, or none of mineral origin. Gravel, sand, and silt from 47 producers are the major wastes, totaling 6 million tons annually, Coal mine wastes in the form of slurried solids from washing crude coal are second in volume, totaling 100,000 tons per year. They contain an average of about 40 percent coal. Salt is the third largest waste, amounting to 28,000 tons per year, Next is calcium carbonate, most of which is formed in water treatments, Because of its high unit value, chromic acid is important, although the waste quantity is much smaller; cyanide wastes are also significant because large quantities of sodium hydroxide and chlorine are consumed in their treatments prior to disposal. The various industries discharging wastes use 38 billion gallons of water annually; the recirculation rate is 109 billion gallons per year. The plants discharging no waterborne mineral wastes use 2 billion gallons of water per year and recirculate more than 1 billion gallons. Sand and gravel plants use 13.5 billion gallons; petroleum refineries use 10 billion gallons in direct use and recirculate 82 billion gallons per year.

Jan 1, 1962

By O. C. Blade

This report on the properties of aviation gasolines and aviation jet fuels produced in the United States during 1955 was made under a co-operative agreement between the American Petroleum Institute and the Bureau of Mines of the United States Department of the Interior. Analytical data are presented for 116 samples of aviation gasoline and for 38 samples of aviation jet fuel. The analyses were made on samples typical of the manufacturers&apos; 1955 production in their laboratories and the results submitted to the Bureau of Mines for compilation. The products of 20 manufacturers of aviation gasolines and of 16 producers of aviation jet fuels are represented.

Jan 1, 1956

By C. P. Bowie, George L. Gates

"INTRODUCTION Experience in drilling oil and gas wells has shown that the voidance of blow-outs, twist-offs, fishing jobs, loss of circulation, and heaving and caving of shale formations into the drill hole depends largely on how well the drilling-mud fluid serves its purpose. A possible method for the control of the drilling fluids may be seen from a study of the relation between the particle-size distribution and some of the important drilling-fluid properties, such as the ability to build quickly a relatively impervious mud sheath on the wall of the hole in the porous formations penetrated by the bit during drilling operations. In a wartime economy, which urgently requires conservation of steel, proper functioning of the drilling fluid is particularly important because, as Parks 4/ has stated, intelligent use of good drilling fluids makes possible drilling of wells for thousands of feet in open holes without the necessity of setting protective strings of casing to control the movement of salt water, gas, and troublesome formations into the borehole; consequently, especially in deep wells, of proper drilling fluids materially reduces the need for casing and lowers the cost of drilling and completing the wells."

May 1, 1942

By Harold M. Smith

Among the more important raw materials now utilized for the commercial production of synthetic organic chemicals is natural &apos;gas. Natural gas has been used as a fuel and source of energy almost from its discovery, but its potentialities as a chemical raw material were not realized until recently. Research in the use of natural gas for Chemical synthesis received great impetus from the discovery by Brooks and Humphrey4/ in 1918 of alcohols in the diluted ?acid oil? obtained by sulfuric acid treatment of cracked petroleum distillates. Experimental data soon showed that hydrocarbons from natural gas could be converted to these same products. Laboratory methods for chlorination of natural-gas hydrocarbons, particularly of methane for the production of methyl chloride, methylene chloride, carbon tetrachloride, and chleroform were known before that time but were not developed commercially. Methods for obtaining alcohol by oxidation of hydrocarbons derived from natural gas also were known before 1918 but had not received commercial consideration. Since 1918, and particularly during the past 15 years, the work of chemists and chemical manufacturers throughout the world has resulted in an accumulation of data regarding the reactivity of natural-gas hydrocarbons, and related hydrocarbons found in refinery gases or made synthetically. These data have been used to develop methods for converting hydrocarbons into chemical products and thus form the basis for a large and growing industry.

Jan 1, 1947

By D. E. Larson

The U.S. Bureau of Mines investigated Fe-base alloys containing 8 pet Crwith Ni, AI, and Si additions as substitutes for standard AISI Type 304 stainless steel (SS) in high-temperature oxidizing applications. The objective of this study was to reduce the amount of Cr required to make an austenitic stainless steel while retaining satisfactory workability, mechanical properties, and oxidation resistance. Alloys prepared in this investigation had a composition of Fe-8Cr-lMn-0.07C with varying amounts of Ni, AI, and Si. A minimum of 10 pet Ni was required to achieve an austenitic composition. The microstructures of the austenitic alloys were very susceptible to room-temperature, deformation-induced martensitic transformations. When the alloys were cold worked or stressed, the materials had far greater tensile strengths than Type 304 SS at room temperature. At higher temperatures, tensile strengths and workability of several of the alloys were comparable to that of Type 304 SS. Although martensitic transformation caused the room-temperature properties of the experimental alloys to be quite different than those of Type 304 SS, the superior oxidation resistance and similar hot workability of several alloys encourage their use as replacements for Type 304 SS.

Jan 1, 1989