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By R. V. Lundquist, H. Leitch

Two hydrated calcium aluminates , formed by side reactions in the leaching step and desilication step of the lime- soda sinter process , were investigated to better define their influence on alumina recovery . The two calcium aluminates , Caз [ Al ( OH) 6 ]₂ and зCa0.Al½ 03 · ( 8-12 ) H₂ ) , were prepared and identified by chemical and X- ray analysis . The relative proportions of each of these compounds formed in typical leach solutions at several temperatures were determined . The influence of free lime as a promoter of calcium aluminate formation was also investigated . The formation and precipitation from leach liquors of calcium aluminates contributes to the low alumina recoveries in the process . The presence of carbonate ion in the leach solution suppresses calcium aluminate formation and precipitation and results in higher alumina recovery . Hydrated calcium aluminates are formed in the aging of lime - soda sinters in the normal atmosphere .

Jan 1, 1963

By V. Castranova, T-M. Ong, V. Vallyathan, M. J. Keane, W. E. Wallace Jr.

"Inhalation of certain forms of silica, asbestos and some other respirable dusts can result in pulmonary fibrosis, characterized by destruction of the surfaces of alveoli and respiratory bronchioles. Fibrous thickening of the alveolar septa decreases the lung's capacity for gas exchange.Pulmonary macrophage damage by respired dust may initiate the fibrotic response.In one proposed mechanism, dust particles interact with the plasma membrane of a macrophage. This damages the cell or induces some hyperactivity of the cell, resulting in excessive release of lysosomal enzymes and reactive forms of oxygen (1). These reactive enzymes or radicals then damage the alveolar surface epithelial cells. A second mechanism has also been pro¬posed (2,3) in which dust damage to the macrophage causes the release of mediator substances which induce pulmonary fibroblast cell proliferation and increased collagen synthesis. This produces fibrous tissue in the terminal air spaces (4,5).Mineral surface interactions with plasma membrane lipoproteins have been proposed as a mechanism of lytic damage of pulmonary cells by silica dust in numerous models (6,7). The significance of dust surface proper¬ties has been further revealed in studies showing significant changes in dust induced cytotoxicity as a function of dust surface crystallinity and organic or inorganic contamination or coating of mineral surfaces (8,9). Such modification of the mineral surface might interfere with surface sites responsible for the toxicity of dusts for pulmonary macrophages, thus interrupting the early stages of the process of fibrosis.In vitro cellular assay systems using erythrocyte hemolysis or the release of macrophage cytosolic or lysosomal enzymes following dust challenge, have been used to analyze the initial mechanism of dust damage to cells. However the ability of these assays to predict the pulmonary disease producing potential of various dusts is imperfect owing to some ""false positive"" results. These assays as performed are therefore questionable models for the initial lesion in pneumoconiosis or silicosis. In particular, kaolin frequently is found to have comparable biological activity to silica quartz in these assays (10,11).Silica and kaolin have distinctly different fibrogenic potentials. Silica is highly fibrogenic, resulting in both acute and chronic silicosis (12). Some epidemiological data and animal experimentation data have indicated that long term exposure to kaolin can result in pneumoconiosis; however, kaolin is relatively benign as compared to silica (13-18). Kaolin is also of interest because it is one of the major mineral inclusions in Eastern U.S. bituminous coals. We have observed that exposing respirable sized native silica or kaolin for two hours to pulmonary macrophages results in a greater enzyme release for kaolin exposures, on a dust mass basis. Exposure of erythrocytes to the dusts also results in greater levels of hemolysis by kaolin for equal mass respirable dust doses. Therefore, these results do not correlate positively with known disease inducing potentials of the two dusts.Characterization of physical and chemical surface properties of dusts involved in occupational exposures, and characterization of the alteration of those surface properties which are likely to occur upon deposition of the dust in the lung, should improve the identification of respiratory disease hazards.Inhaled dust particles deposited in the lower respiratory tract will come in contact with pulmonary surfactant. This surfactant forms a surface film on and emulsion in the liquid hypophase coating of the alveoli and respiratory bronchioles. The primary constituent of this pulmonary surfactant is the lipid diacyl glycerophosphorylcholine, lecithin (19). Because this lipid is also a major component of cell membranes, it is possible that surfactant can interact with mineral dust to alter its Interaction with macrophages and other pulmonary cells and, thus, it"

Jan 1, 1988

By Robert W. Ageton

Optimal planning for mining the deep, lead-zinc-silver deposits of the Coeur d'Alene mining district, Shoshone County, Idaho, could be facilitated by a knowledge of the magnitude and direction of the pressure acting in the virgin rock. The distribution of primary stresses should be considered in order to prevent possibly destructive mining-induced stress concentrations. This particular investigation was concerned with determining stress in a zone 4,000 feet below the surface and known to be ender stress concentrations due to mining operations. Disking of the stress-relief cores obtained in a vertical down hole permitted qualitative evaluation from visual observations; the results indicate that a high lateral stress existed at the time the measurements were made. Stress-ellipsoid determinations gave a compressive principal stress of -13,000 psi oriented about N 45° W and nearly horizontal, a compressive principal stress of -11,000 psi oriented about S 45° W and abut 60° off the vertical pointing away from the vein, and a compressive principal stress -5 -7,000 psi oriented N 45° E and about 60° off the vertical, pointing toward the vein. Subsequent to the overcoring stress-relief drilling, a rock burst occurred about 100 feet northwest of the test site.

Jan 1, 1967

By R. L. Crosby

The Bureau of Mines investigated alloys of copper with 2, 3, and 4 vol pct alumina and with 2 vol pct yttria. Alloys were prepared by a coprecipitation process and were fabricated by pressing and sintering of powders, extrusion, and swaging. Tensile properties at room and elevated temperatures, stress-rupture strength, electrical conductivity, and density were measured. The superiority in elevated temperature strength of dispersion-strengthened copper to OFHC copper was confirmed. Increasing the oxide content from 2 to 4 vol pct produced only a small improvement in strength properties and decreased the electrical conductivity. The 3 vol pet alumina alloy had the best overall combination of properties.

Jan 1, 1969

Provide reasonably priced, reliable fire protection for blasthole drills. Approach An automatic fire sensing and suppression system using both dry and gaseous chemicals was developed, and is more shock and vibration resistant than similar industrial fire protection systems. How It Works Temperature sensors mounted in the drill's machinery house, hydraulic room, operator cab, and transformer area detect the heat from a fire, and trigger a sequence of actions. The same fire fighting sequence can be initiated from manual alarm boxes in the cab, hydraulic room, or machinery house. Electrical power to the drill Is immediately cut off, and a horn sounds to warn the drilling crew. After a 40-second, built-in, delay to allow time for drill's ventilating fan to stop, gaseous and dry chemical fire extinguishing agents are piped to and released in various rooms of the drill. The gaseous extinguishing agent (Halon 1301) is released in the machinery house, hydraulic room, and operator cab where dry chemical clean-up from electrical panels and machinery would be difficult and costly. Dry chemical is piped to the transformer room at the rear of the machine. Location of the principal components of the system are shown in the drawing.

Jan 1, 1979

By Cecil E. Lester

Since the advent of coal mining, the minimal lighting in the under¬ground working place has been an obstacle to the safe and efficient performance of the miner's many tasks. Compounding this problem is the fact that the machines being operated in the working place are so large that the vertical and horizontal clearances around the machinery are severely limited. Consequently, in these poorly lighted and congested working places, the machine operator is unable to utilize his peripheral vision. He cannot see hazards as they develop and, too often, cannot react in time to avoid serious injury or death to himself or his fellow miners. The greatest hazard to miners inby the last open crosscut is from falls of roof which are often preceded by warning signs such as falling rock fragments, roof supports taking weight, or a sudden reduction in the height of the working place. These warning signs often go undectected because the machine operator's attention is focused on the small circle of light emitted from his cap lamp. Congress recognized the illumination deficiencies, and, in the Federal Coal Mine Health and Safety Act of 1969, charged the Secretary of the Interior with the authority and responsibility for development and promulgation of minimum standards for illuminating working places in coal mines. These standards have been developed and, as stated in the April 1, 1976 Notice, Federal Register, Volume 41, No. 64, will be promulgated on October 1, 1976, as mandatory regulations under Section 75.1719, Title 30, Code of Federal Regulations. The regulations require that the designated surfaces within the miner's normal field of vision be illuminated to 0.06 foot-lamberts while self¬propelled mining equipment is being operated in the working places. The term "working place" is defined in the Act as "the area of a coal mine inby the last open crosscut".

Jan 1, 1976

By L. O. Bacon, H. R. Joesting, J. H. Getz

"INTRODUCTION For a number of years manganiferous iron ore has been mined on a small scale at Boston Hill, in Grant County, N. Mex. Total production up to 1943 is estimated to be over 793,000 long tons, containing 8 to 35 percent manganese and 26 to 46 percent iron. 4/ During 1941 to 1943 production was estimated to be 206,000 long tons, containing about 13 percent manganese and 37 percent iron. During 1944 daily production was several hundred tons, mostly from a single open pit. Several moderately large deposits have been mined: and many smaller ones have been found.From February to April 1945 geophysical surveys were carried out on Boston Hill by the Division of Geophysical Exploration, in cooperation with District 5, Central Region, Bureau of Mines, to determine if hitherto undiscovered manganiferous iron deposits exist. Field work was interrupted for a total of about 1 month during this period by work on other projects in nearby areas. Previous to the geophysical surveys, a preliminary examination was made by H. R. Joesting to determine if geophysical methods could be utilized in exploring the area. 5/Field measurements were made by L. O. Bacon and J. H. Getz, project geo¬physicists of the Bureau of Mines, under the general supervision of H. R. Joesting. A grid survey of the area, to locate geophysical stations, was made by Paul Russell, Bureau of Mines engineer, who also collected specimens for laboratory tests. Most of the computations and the preliminary magnetic and resistivity maps were made by L. 0. Bacon."

Feb 1, 1948

By Kenneth M. Earl

In its investigation of deposits of strategic minerals, the Bureau of Mines did same development drilling at the Perkiomen Creek deposits, 5 miles east of Phoenixville, Pa. This area was the center of much copper mining from 1851 to 1858. The most productive vein was the Perkiomen-Ecton mines, owned by the Perkiomen Consolidated Mining CQ. The mines were closed in 1858, and no further production has been recorded. The Perkiomen-Ecton vein ranges in thickness from 2 to 19 feet. The principal mineral of value is chalcopyrite, with minor amounts of galena and sphalerite. No definite record was found as to the grade of ore min d. It was reported that 617 tons of 18-percent copper are obtained by hand sorting 12,200 tons of mine-run ore was shipped in 1851-1852. To cut the vein below the old mine workings, the Bureau of Mines diamond-drilled five holes aggregating 2,216.2 feet. The vein, where intercepted by drilling, carried narrow stringers of copper, lead, and zinc minerals.

Jan 1, 1950

By A. B. Hooker, L. C. IlsLey

"The last previous Bureau of Mines publication relative to details of permissible electric mine lamps is Bulletin 332, which describes 16 lamps approved prior to May 1930. Some of the lamps have become obsolete through the development of improved models which, with several new types, make it desirable to supplement the Bureau's published data relative to permissible electric mine lamps.In the following descriptions, lamps approved since May 1930 and prior to July 1, 1935, are placed in the three following groups: (1) Electric cap lamps, (2) electric hand lamps, and (3) lamps for miscellaneous applications,ELECTRIC CAP LAMPS APPROVED UNDER SCHEDULE 6B1. Edison model J lamp, approval no. 24. - The features that distinguish this lamp from earlier models of Edison electric cap lamps are:(a) The battery consists of two F-2 cells of square cross section and about 1-1/4 inches higher than M-14 cells in the model H lamp, making the battery narrower and higher than any of the earlier models of Edison cap lamps.(b) The cells are insulated from each other and the Monel-metal casing by enclosure in vulcanized-rubber baglike enclosures. Both cell terminals are insulated from the cell jar.(c) The battery is equipped with rubber-tube Bunsen-valve-type gas vents.(d) The battery casing is secured by a new-type magnetic lock.(e.) The battery and cover terminal clips have been redesigned to give a wiping contact."

Jun 1, 1936

By Carl R. Peterson

This report describes the development and testing of a prototype tunneling machine. Principal efforts were aimed at testing of the fragmentation subsystem of a continuous drill and blast hard rock excavation machine suitable for use in underground mining and tunneling applications. The concept utilizes a unique self -shielding spiral blasting pattern that permits efficient performance with relatively small single shots, while at the same time directing major blast fragments at right angles to the tunnel axis. A major accomplishement was the development of a remote controlled, loading and initiation system in which explosive slurry and a detonator are Simultaneously placed (pumped) into the blasthole via a loading hose. The special electric long-delay detonator is inductively ignited upon emplacement, and the machine remains at the face during the blast.

Jan 1, 1976

By John C. Edwards

A computer code for laminar, steady-state, incompressible, two-dimensional flow developed by Gosman (2)3 was modified by the Bureau of Mines to calculate shock (minor) loss at the intersections of ventilation ducts. Turbulent flow was simulated using laminar flow equations and an appropriate wall shear stress. Results of the calculation showed good agreement with the experiment.

Jan 1, 1977

By E. L. Garton

Bureau of Mines routine crude-oil analyses of 88 samples from 60 fields are presented in this report. Similar analyses from other fields in California have been published in previous reports listed in the appendix, page 52. Yearly production of crude oil in California and the percentage of United States production represented by California production for 1948-54 are given in table 1. [ ] Analyses in this report are of samples from the fields listed in table 2, with production data for 1953, cumulative production through 1953, and year of discovery of each field. Information regarding the source and general characteristics of the samples is included in table 3 with a summary of analytical and computed data.

Jan 1, 1956

By John W. Frey

This paper presents one of a series of digests of foreign mining legislation and court decisions that is being prepared in advance of a general report relative to the right of American citizens to explore for minerals and to own and operate mines in various foreign countries . This interpretation of the laws of Persia has been prepared from the best available information in Washington but is released subject to correction and amplification , if necessary , by the proper American diplomatic and consular officers , to whom it is being referred through the courtesy of the Department of State .

Nov 1, 1929

By R. V. Ramani, V. T. Burgos, J. A. McClay

The data for Test I1 describes an underground bituminous coal mine operating in a 72 inch seam, with an estimated production rate of 4,257,000 tons per year. The system includes 15 continuous mining sections, conveyor belt haulage, and a rail network for supply and personnel transportation. The following section includes the input data sequence, annual cost report, and cash flow analysis "report for this data set.

Jan 1, 1975

By Fred D. Wright

Some new equipment for drilling vertical holes, cleaning blast holes, hauling explosives, and conditioning Diesel exhaust gas has been developed. at the Bureau's Experimental Oil-Shale mine near Rifle, Colo, The equipment has application, not only in oil-shale mining, but in many of the country's underground mines in which room-and-pillar methods of mining are employed. This report presents the Bureau's experience in testing the following equipment in the Experimental Oil-Shale mine: 1. A four-drill benching jumbo for drilling 23-foot vertical blast holes 2. A jet borehole blower for efficient cleaning of deep, vertical blast holes. 3. An explosives truck equipped with two compartments to provide safe conveyance for dynamite and detonators. 4. A mobile, electric substation to provide switching equipment, low-voltage and overload protection, and transformer facilities to remote locations in the mine. 5. A chemical conditioner for scrubbing the exhaust gases from Diesel-powered equipment used in underground operations. 6. Other units of equipment which have been tested at the Experimental mine.

Jan 1, 1951

By Donald O. Capstick

In 1481, U.S. Bureau of Mines personnel conducted a survey of mines, prospects, and mineral resources in the Table Mountain RARE II area. There are no mines or active prospects in the study area. One prospect in the study area, the Waterfall Prospect, is estimated to contain 480 tons (440 t) of indicated subeconomic tungsten resources averaging about 0.18 percent tungsten trioxide (W03). Other tungsten occurrences are at the Stevens Prospect, just northwest of the area. Stone and sand and gravel deposits in the area are not considered to be resources because equal or better quality material is available closer to major markets. INTRODUCTION The 4,400-acre Table Mountain study area is 13 mi (21 km) southwest of Bishop, California, on the eastern flank of the Sierra Nevada range. The John Muir wilderness adjoins the study area on the southwest (fig. 1).

Jan 1, 1982

Estimate costs for projected uranium in-situ mining operations. Approach Develop a computer model and an associated data base which will allow users to supply data applicable to a specific mining site in order to estimate total capital and operating costs for a potential in-situ mining operation at the site. How the Model Works The model requires a minimal amount of input from the user. The data input must be known or estimated information about a potential in-situ mining operation. The user can also supply any additional project specifications. The computer model uses a process-engineering approach and determines through a discounted cash flow analysis the total capital and operating costs for the life of the project. This time-span measures from the start of the pilot-scale operation through to the site's restoration and reclamation. The model will determine the production cost per pound of material mined subject to the rate of return identified by the user. Conversely, it will also solve for the rate of return realized for the specific sales price per pound. [ ] Currently the model's data base can tai ns costs, rates, and specifications for Texas and Wyoming, the only states where commercial uranium in-situ mining is being conducted. However, this model can be used by anyone who is conducting in-situ leaching or who plans to leach uranium in-situ. At least part of any uranium deposit has a potential for in-situ mining.

Jan 1, 1982

To provide a means for rapidly evaluating proposed mine layouts in order to avoid potential hazards while minimizing loss of coal. The Approach: Development of a computer program that will compute many possible mine layouts by changing the mine plan until the arrangement giving minimal hazards with optimum extraction is found. How It Works: The Hazard Evasion Program for Mine Planning, developed by the Bureau's Denver (Colo.) Mining Research Center, tests hundreds of possible solutions to a mining layout, and by sorting out the 10 best (based on the criteria of maximum safety for workers with minimum abandoned coal), limits the number of choices that need to be considered and appraised for applicability to a given mine scheme. The program is applicable for room and pillar or longwall mining, for oil and gas well hazards, and for other hazards that can be described mathematically such as channel sands, potential bad roof areas, faulting, voids, or water pockets.

Jan 1, 1974

By Brian T. Brady

The year 1991 recorded unprecedented change throughout the world; war in the Middle East, economic recession in key industrial nations, upheaval in Eastern Europe, and the disintegration of the former U.S.S.R. These issues and growing environmental concerns will affect the entire world mining industry. Environmental issues continue to have an ever greater effect on industrial minerals. In the United States, major issues involving the Clean Air Act, Clean Water Act, and the recent Stormwater Rule by the U.S. Environmental Protection Agency (EPA) affect many types of mineral operations. Significant developments include an important decision in 1991 by a Federal Appellate Court to overturn EPA's asbestos ban on certain products, partly on environmental grounds, and proposed legislation that would overhaul or abandon the 1872 Mining Act. On a global scale, prominent issues include environmental concerns over mining in the Antarctic and Arctic regions and a cutback in plans to clean up the Kola Peninsula in the Commonwealth of Independent States (C.I.S.).

Jan 1, 1993

By B. L. Razzaboni, P. Bolsaitis

"The formation of reactive oxygen species resulting from the interaction of silica dust particles with red blood cell membranes was investigated; particularly, the effect of surface hydroxyl (silanol) group concentration on the rate of formation of such reactive oxygen species was investigated. The rate of formation was measured indirectly through the effect of catalase, a hemoprotein peroxidase, on silica-induced hemolysis. It was found that the addition of exogenous catalase to erythrocytes markedly reduces the hemolysis caused by silica particles. Furthermore, the amount of catalase required for deactivation of silica per unit area of particle surface is lower for fumed silica particles and calcined crystalline particles than for uncalcined, crystalline silica, suggesting a correlation between the concentration of OH groups at the silica particle surface and its potential for generation of H2O 2• The addition of albumin, a copper chelator, also decreases hemolysis. These results suggest that the hemolysis caused by silica particles is at least partly related to the formation of H2O2 at the particle surface and its subsequent reaction with Cu+ ions. The relationship between the concentration of surface silanol groups on the silica surface and the amount of catalase required to decrease hemolysis may also provide a method for testing potential fibrogenicity of respirable dusts. IntroductionReactive hydroxyl groups on silica surfaces are known to be cytotoxic and are believed to play a major role in silicosis (1-9). It has been proposed that this cytotoxicity results from hydrogen bonding to cell membranes and a resulting increase in membrane fluidity and permeability (4). Surface hydroxyl groups on silica surfaces have also been shown to interact with carbonyl oxygens in cell membranes (1,5). An extensive study by Nolan et al. (6) of the relationship between the negative surface charge resulting from ionized silanol groups and the hemolytic activity of crystalline a-quartz (Min-U-Sil) has shown a positive correlation between hemolytic activity and the surface concentration of silanol groups. These authors demonstrated that the hydrogen bonding of polyvinyl-N-oxide (PVPNO) with silanol groups, as well as the bonding of metal cations to the ionized sm- groups, results in significant decreases in hemolytic activity. Furthermore, it has been found that the complete removal of surface hydroxyl groups from the surface of respirable silica particles nearly eliminates the hemolytic potential of silica (7), suggesting that hydroxyl groups might be involved in other cytotoxic processes associated with silica-induced lung injury. Reactive oxygen species have been .implicated in cellular damage caused by respirable silica particles. Evidence for the presence .of oxygen radical species (02, OH°, H2O2) generated by silica, especially on freshly formed surfaces, has been produced by various investigators. Kalbanev et al. (8) detected H2O 2 in aqueous suspensions of quartz. Electron spin resonance and spin trapping by Shi et al. (9) confirmed the presence of OH"" radicals in aqueous suspensions of quartz, and Gulumian and van Wyk (10) suggested that both glass and quartz produce hydroxyl radicals in the presence of H2O 2 • Gabor et al. (11) detected the presence of malondialdehydereactive lipid peroxides (i.e., lipid-0°) in cultures of macrophages and respirable silica particles using the thiobarbituric acid (TBA) reaction test. Will (12), however, reported that iron enhances the TBA value of peroxidized lipids, and Scheulen and Kappus (19) found that catalase augmented malondialdehyde formation, thereby increasing the TBA values."

Jan 1, 1990