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By C. F. Vos, J. D. Miller, J. C. Davidtz

"This work presents the potential for improving the flotation recovery of slow-floating sulphide minerals with the use of starvation dosages of a normal dodecyl (n-C12) trithiocarbonate (TTC) co-collector, together with a sodium isobutyl xanthate (SiBX) and dithiophosphate (DTP) collector mixture.At potentials below –150 mV (SHE), addition of nC12-TTC with SiBX improves the hydrophobicity of pyrrhotite, yielding captive bubble contact angles greater than those measured for SiBX or nC12-TTC alone, suggesting a low potential synergistic effect. This synergistic effect is further studied using Fourier transform infrared (FTIR) spectroscopy, the results indicating an increase in the surface concentration of the collector species when in a mixture. Thus, nC12-TTC with SiBX may act as an immobile surface anchor to which SiBX/SiBX2 molecules bond, increasing the localized concentration of collector species.Bench-scale flotation tests using mixtures of SiBX/DTP/nC12-TTC on a platinum group element (PGE)-bearing ore from the Bushveld Complex in South Africa confirm an improved metallurgical performance at very low substitutions (approx. 5 molar per cent) of SiBX. The improved recoveries for PGE, Cu, and Ni are correlated with improvements in the flotation kinetics of their slow-floating components. IntroductionShort-chain (less than C6) xanthates are very effective for the bulk flotation of sulphides (Fuerstenau, 1982), and early work (Leja, 1968; Gaudin, 1957; Plaksin and Bessonov, 1957; Taggart, Giudice, and Ziehl, 1934) indicated that the presence of oxygen in flotation slurries is necessary for the oxidation of the xanthate collector at the sulphide mineral surface to induce hydrophobicity. Fundamental research into the chemistry and adsorption mechanisms of xanthates over the years (Finkelstein and Poling, 1977; Woods, 1976; Winter and Woods, 1973) has revealed that for iron-bearing sulphide minerals, adsorption occurs predominantly through a charge transfer process. Oxidation of the adsorbed collector to the corresponding dimer takes place if the mixed potential of the system is greater than the reversible potential for dimer formation. In oxygenated slurries the rate of adsorption and oxidation of the collector depends greatly on the substrate surfaces. For chalcopyrite (Guler et al., 2005; Leppinen, 1990; Roos, Celis, and Sudrassono, 1990) and pentlandite (Hodgson and Agar, 1989) a two-step interaction with xanthate is proposed in which the chemisorbed xanthate is further oxidized to the dimer. The initial interaction of xanthate with pyrrhotite is through physisorption where xanthate physisorbs onto positive surface sites followed by oxidation to dixanthogen (Khan and Kellebek, 2004; Bozkurt, Xu, and Finch., 1998). This process is, however, slow and increased reaction time is needed to improve flotation recovery (Buswell and Nicol, 2002)."

Oct 1, 2018

"Pressure leaching is an option for copper recovery from chalcopyrite. Leaching takes place at high temperatures and pressures in the presence of an oxidizing agent. This work shows how the performance of pressure leaching circuits may be improved by optimizing the configuration of autoclaves and the heat removal method. The objective was achieved by creating an autoclave model that combines mass balances, energy balances, and population balances. A base case circuit consisting of a single autoclave was chosen, and this base case was compared with options for increasing capacity by adding more autoclaves to the circuit. These capacity increase options include circuits in which the additional autoclave is added in parallel, in series, and in series with thickening between the two autoclaves. The copper extraction, productivity, and cooling requirements for these options are compared. The series circuit with interstage thickening has the highest extraction and productivity; however, the cooling duty in the first autoclave is high. In addition to comparing circuit options, three options for heat removal were investigated: cooling coils, quench water, and flash recycling. The flash recycle option results in the highest copper extraction, and the quench water option the lowest copper extraction. IntroductionBackgroundCopper sulphide ores and concentrates containing chalcopyrite are typically hard to leach under atmospheric conditions. Smelting of these ores may also be a challenge, due to the inability of smelting processes to handle low-grade ores, as well as impurities such as arsenic and antimony. Alternative hydrometallurgical routes to treating chalcopyrite are therefore required. One option is pressure leaching, which is the focus of this work.In the pressure leaching process, sulphide ores and concentrates are leached in autoclaves at temperatures of 200 to 220°C and a pressure of about 3000 kPa (Schlesinger et al., 2011). An oxidizing agent, usually oxygen, is required to oxidize sulphide ions to sulphate ions. The oxidation of sulphur to sulphate is exothermic; consequently, a method of heat removal is necessary in order to maintain the temperature in the autoclave."

Jan 1, 2016

By S. V. Rungan

The modern mining industry is increasingly being tasked to comply with various legal, industry and social prerequisites. In addition to complying with these, the mining industry is further expected to effectively report on their compliance. Although there are many models that aid the mining industry in compliance and reporting, it is perhaps opportune for a new model to be introduced. The Compliance Spindle is postulated as a new and alternative model which is easy to understand and has the possibility of implementation in South Africa and other jurisdictions as well. The Compliance Spindle is also an effective tool to educate future compliance officers. The new model provides for all aspects of compliance and reporting and can be easily modified to take account of new developments in the mining compliance and reporting arena.

Jan 1, 2010

By P. J. D. Lloyd

An account is given of the development of a process to concentrate gold and other valuable minerals and to produce a discardable waste. In this process, the ore is coarsely milled, a bulk flotation concentrate is prepared, and the flotation tailing is scavenged in a hydrocyclone, which returns coarse gangue, moderately coarse valuable minerals, and locked valuable minerals back to the mill. The engineering developments required by this circuit in order that it will fit underground, and the progress made towards the achievement of those requirements, are reviewed. If the waste is to be suitable for use as a backfill in a deep-level, flat tabular excavation, it should be capable of being placed hydraulically, and should have both low voidage and high rates of drainage. Such a material could be prepared by the fine screening of the overflow from the cyclone in the proposed circuit. Possible methods for the handling of the concentrate and the recovery of its valuable constituents are described. The paper concludes with a discussion of the possible benefits from the use, in deep-level Witwatersrand mines, of a system involving concentration underground, extensive backfilling using the tailings from the concentration process, and hydraulic hoisting of the concentrate.

Jan 1, 1979

By J. Rajala

The Kupol mill facility processed a high grade free milling gold/silver ore containing 28.2 g/t Au, 324.8 g/t Ag and approximately 0.5% pyrite during 2008 operation. Gold predominantly occurs a selectrum in the ore and silver is predominantly present in the forms of acanthite, stephanite, pyrargyrite and proustite. Mill start-up was in mid-May 2008 and the mill reached the design throughput of 3 000 tpd in October. The ore was ground to approximately 70%?53 microns. A Knelson Concentrator recovered 9.8% gold and 0.5% silver. The gravity tails reported to a cyanidation circuit that has 14 hours pretreatment and 116 hours leaching. The slurry from cyanidation was then processed by counter current decantation (CCD) thickening to wash and separate the leach residue from the pregnant leach solution. Precious metals are recovered fromthe pregnant solution using the Merrill-Crowe process. The washed CCD leach residue slurry is treated with calcium hypochlorite to destroy cyanide and then sent to the tailings impoundment. Leaching is performed with a new technology called ?CELP? (CANMET Enhanced Leach Process). The Kupol mill overall gold and silver recoveries for 2008 were 95.4% and 85.6% respectively, which were 2.8% and 7.5% higher than targets. Gold and silver extractions in the leach circuit were 94.2% and 84.5% respectively. Leach profiles indicated that gold extraction reached a plateau in the 4th tank while minor silver dissolution occurred in the 5th tank. With the CCD circuit included, total gold and silver extractions increased to 95.4% and 86.6%, respectively. Optimization of the leaching strategy made it possible to reduce sodium cyanide concentration to as low as 410 ppm without compromising precious metals extractions. Silver was effectively leached from the refractory silver minerals because CELP produced more oxidized mineral surface relative to the conventional cyanidation leached mineral surfaces. The average cyanide consumption for 2008 was 1.3 kg/t. The new leaching technology proved to be very robust and performed efficiently even with changes in feed grade and ore mineralogy. Laboratory experiments produced results that were indicative of plant performance. The robustness of the technology and the laboratory test work contributed to the success of the Kupol mill start-up.

Jan 1, 2009

By L. H. W. Walker

As part of an overall design of a computer based mining managerial system, the geological and mineral estates management disciplines find themselves centrally placed in terms of producing fundamental data both before and during the mining operation. Computerisation of all aspects of these fields of endeavour has come to be seen as essential for complete integration with other mining orientated disciplines. Release 1 .l. of the Anglo American system of mineral estates management has been tested and is in the process of being implemented at several Anglo American Gold Division mines.

Jan 1, 1987

By M. B. Cortie

The historical development of materials engineering in the mining industry Is briefly reviewed, and some of the factors currently influencing the industry in South Africa are discussed. Material usages in various parts of the mining operation are surveyed. The predominant mechanisms in the degradation of materials in mines are wear, corrosion, and fatigue. The issue of corrosion-abrasion Is considered, but it Is concluded that abrasive wear predominates in most rock-handling and comminution applications and that, in general, little economic benefit Is to be gained in those applications by the use of existing corrosion-resistant alloys. However, alloys with a measure of corrosion resistance find profitable application elsewhere in the mining environment. The use of other engineering materials such as polymers, ceramics, al1l1inium, and various ferrous alloys may be economically viable in a variety of niche situations. Identification of the most cost-effective material in each case calls for a systematic approach and some patience.

Jan 1, 1996

By J. Gilliland

The Grootegeluk coal-beneficiation plant was erected in the Waterberg coalfield, near Ellisras in the Transvaal, to supply Iscor's steelworks with a predetermined tonnage of coking coal in accordance with strict quality requirements. This plant has to handle a high tonnage of raw coal, which is not easy to beneficiate, in order to produce 1,82 X IQ6t of coal. Extensive tests were conducted on borehole cores and a mass sample of coal obtained from the area. These tests were carried out on a laboratory and pilot-plant scale, and were aimed at the establishment of the most effective beneficiation methods and the choice of suitable equipment. This led to the completion of a full set of design and manufacturing drawings that resulted in the project approach . described in this paper.

Jan 1, 1982

By G. Sommer, R. P. Chaix, G. T. W. Ormrod

Recent developments in the instrumentation and automation of uranium-processing plants by G. SOMMER, Ing. (Grad.) (Visitor), G. T. W. ORMROD (Visitor), and R. P. CHAIX, B.Sc. (Visitor) The paper discusses work at the National Institute for Metallurgy on the evaluation of measuring techniques for the automatic control of free acid in leaching. of the ratio of ferric to ferrous ion in leaching, of pH in liquid-liquid extraction. and of uranium in loaded solvent. Commercially available instruments. and the modifications that have been made to adapt them to South African uranium plants, are also described.

By W van Drunick, S Naik

To date, Anglo Research has carried out several projects, based on the techniques developed in the AMIRA P9 (AMIRA International Limited), to develop comminution and flotation models for several Anglo Base Metals and, to a lesser degree, Anglo Platinum flotation plants. Plant optimization is thus achieved through steady-state sampling, model-fitting and simulation using the JK SimMet and JK SimFloat software packages. The surveys can vary depending on the needs of the plant/client. The survey can therefore include as little as a single piece of equipment, an entire milling/flotation circuit, or a complete circuit from primary comminution to final flotation concentrate (i.e. the ?integrated survey?). The presence of the AR team on-site usually precipitates in face-value observations that can lead to initial improvements. This stems from the knowledge-sharing on best practice that exists in parallel with the surveys. Numerous (reasonable) changes can then be simulated, thus indicating the optimization step most likely to result in the best efficiency improvements. The simulations can include changes in the flowsheet, ore characteristics, mill loads, grinding media size, change in grind, flotation residence time, air hold-up and several more. Plant surveys can result in process changes that provide the plant with either: higher plant tonnage, improved plant grind, additional flotation recovery and/or improved product grade. The additional benefit of performing an integrated plant survey is that the effects of an optimization change in the comminution circuit can be simulated using the flotation model. This paper describes a number of case studies where individual and integrated plant surveys were conducted by AR for Anglo Base Metals.

Jan 1, 2007

By Ralph H. Nafziger

This paper reviews the major deposits of lower-grade chromite in the world, and a wide variety of methods used for the recovery of chromium from them. Gangue materials in more coarsely sized ores can be separated by gravity means, whereas flotation techniques are required for finer-grained materials. However, unless there is considerable Iron In the ores, physical means cannot increase the Cr/Fe ratios. Chemical techniques such as hydrometallurgical methods, chlorination, roasting and leaching, and smelting are required for this purpose. A greater understanding of the physical properties of chromites and the chemical reactions that take place in the recovery operations is required before. the recoveries from lower-grade chromites can be maximized. More efficient recovery operations can be realized If It can be shown definitively that the reduction of chromites occurs via either a gas-solld or solid-solid mechanism, for example. The effects of specific impurities on the chromite reduction reactions need to be better understood, as do reagent and pH control in the flotation of chromite.

Jan 1, 1982

Iron ore pellets with or without additives are commonly used as alternate charge material in both conventional and newer ironmaking processes. The performance characteristics of these pellets are normally assessed on the basis of their reducibility values, reduction strength and resistance to clustering. These properties depend mainly on the type and amount of additives and on the sintering phenomena of the pellets during firing. In the case of composite pellets (ore-coal pellets), reduction and sintering of the iron ore fines occur simultaneously. The thermodynamic and reaction mechanisms of the processes involved in the reduction of iron ore pellets with and without reductants, additives, etc., may not necessarily be identical. The reduction and sintering characteristics of pellets greatly influence the reaction mechanism and the surface morphology of the reduced pellets. The approaches in the literature to the analysis of these reduction and sintering phenomena are broadly categorized as follows: (i) empirical models, (ii) models based on kinetics, and (ill) models based on morphological changes. The relative merits and de-merits of these models are illustrated by their application to the reduction of fluxed ore-coal composite pellets. A critical analysis of the investigations that have been conducted on the reduction and sintering behaviour of such pellets is given. It is shown that, although elegant empirical models and kinetic equations have theoretical significance and can be usefully employed in elucidating the reaction mechanisms of iron ore lumps, they are sometimes not directly applicable to fluxed ore-coal composite pellets. In studies of the latter, the approach should be to correlate the morphological changes with the reduction mechanism. The paper also gives a brief account of an investigation on the reduction and sintering aspects of fluxed composite reduced iron pellets.

Jan 1, 1996

By H. M. Friede, R. H. Steel

Tin mining and smelting in the Transvaal during the Iron Age by H. M. FRIEDE*. Ph.D. and R. H. STEEL* (Visitors) This paper reviews the historical, archaeological, and metallurgical evidence on Iron Age tin mining and tin smelting in Southern Africa. The results of the analysis of twenty samples of tin ore, tin slag, and tin ingots found associated with Iron Age materials in the Transvaal (mostly in the Rooiberg area) are reported and discussed. The types of ingots preserved in local collections are described. A small experimental tin-smelting furnace was constructed and worked according to traditional African Iron Age technology. Qualitative and quantitative results of this experiment are reported.

Jan 7, 1976

By R. D. Hancock

The loading and selective properties of a number of commercial and experimental resins developed for the extraction of base metals were evaluated. Particular applications that ",:ere considered included the extraction of copper from artificial dump liquors, the treatment of Iow-grade copper, nickel, and cobalt liquors, and the removal of nickel from a cobalt electrolyte. Reagents that showed promise were two experimental resins developed at Mintek containing pyridyl imidazole active groups and two Dow resins, XF4195 and XF4196.

Jan 1, 1982

By P. Kind

Design criteria and recent developments in large-capacity Wemco flotation cells by P. KIND, Ph.D. (Clausthal), B.Sc. (Visitor) The scaling-up of the large flotation cells that have been developed during the past few years has been based on hydrodynamic considerations and has resulted in a 500 ft3 cell unit. Plant results on a porphyry copper ore show that the 500 ft3 unit is equivalent to the previously used 300 ft3 model.. . Plant tests on the use of 300 ft3 flotation cells for the recovery of phosphate, particularly from the coarse size fractions, are also described.

Jan 3, 1976

By J. J. C. Heynike

The relationship between population growth and steel consumption since the beginning of the twentieth century is indicated, reference being made to the increasing capacity of production units and the resultant increased pollution in the same area. The need for the control of fugitive emissions with its associated high cost is pointed out. There is a direct relationship between energy and pollution, and examples are given of several improvements that have been made to achieve better energy usage and reduced pollution. Several practical examples of air-pollution control systems are described as applicable to the main metallurgical steel processes of today. In conclusion, reference is made to the fact that, with the improvements attained in reducing pollution, the public will not tolerate a decline in the standards already attained. Environmental control and better energy utilization will continue to be important aspects of steel-plant design and operation.

Jan 1, 1978

By G. V. R. Landman

Changes in the explosion behaviour of mixtures of coal dust, methane, and air when exposed to different energy sources are discussed. Changes to the lower explosive limits, minimum ignition energies, and rates of pressure rise when the same hybrid mixture of coal dust, methane, and air is exposed to ignition sources which are either spatially extended or spatially concentrated, are examined. A diagram is presented from which coal-dust loadings and methane presence can be determined which are below the lower explosible limits, and stated as a safety factor.

Jan 1, 1995

PREFACE During the past year, the Council of the SAIMM undertook a major strategic-planning exercise to review all its current activities, and to redefine its scope and objectives in the light of changing circumstances. The following are the four main concerns that prompted Council to take stock of the situation. (1) Over the past five years, the SAIMM has become heavily involved in a variety of new activities. (There are many examples, of which the expansion in book publications and the establishment of physical metallurgy as a third major discipline with its own colloquia and schools are perhaps the most important.) While these new activities have considerably broadened the SAIMM's scope, they have resulted in a significant increase in the day-to-day workload of the President, Office Bearers, and Council members, and of the secretarial staff based at Kelvin House.

Jan 1, 1986

By G. Raspa

The paper describes a computer procedure for evaluating and selecting recoverable reserves in a mine worked by sublevel stoping. The boundaries of the volume to be mined are optimally defined by means of the 3-dimensional Lerchs-Grossmann algorithm, separately applied to both sides of the panels. The procedure, which has been developed for Masua Mine (Sardinia), also provides for smoothing the optimized boundaries, positioning the drilling drifts, interactive design of drilling fans and calculation of tonnage and grade of each volley. These tonnages and grades form the input of another procedure evolved for production planning.

Jan 1, 1987

By L. W. Helle

The investigation, which was conducted at Iscor's Newcastle works (in Natal), was aimed at the development of reliable, consistent, and cost-effective methods of sampling. In the sampling of hot metal, it was found that lollipop and spoon samples had identical sulphur analyses, and negligibly different silicon analyses. Thus, spoon sampling of the hot metal was implemented, with a resultant saving of over RIOO 000 per annum on lollipop samplers. In the sampling of steel, aluminium -killed samples were found to have lower phosphorus analyses than titanium killed samples. Spoon sampling was rejected in this application since the use of titanium wire would be too costly. It was decided that titanium would be used as the deoxidant in lollipop samples of steel, and that the Leco carbon! sulphur analyser would be used as the sole arbiter of sulphur content.

Jan 1, 1983